Search

Your search keyword '"Han, Shaoyue"' showing total 1 results
Start Over Author "Han, Shaoyue"
1 results on '"Han, Shaoyue"'

1. Ring-opening silylation of N-arylindoles via endocyclic C–N bond cleavage triggered by silylboranes.

Author

Tian, Ye, Sun, Hanying, Cui, Benqiang, Han, Shaoyue, Wang, Tianle, Shi, Yanhui, and Cao, Changsheng

Subjects
SCISSION (Chemistry), SILYLATION, STYRENE, STEREOSELECTIVE reactions
Abstract

The cleavage of heteroaromatic endocyclic carbon–heteroatom bonds to assemble C–Si bonds is scarce. Here, we demonstrate an unprecedented dearomatization silylation of N-arylindoles arising from reductive activation initiated by electron-rich silylboronic complexes to deliver silyl styrenes with perfect stereoselectivity. [ABSTRACT FROM AUTHOR]

Published
2024
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results