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In this study, the shielding properties of novel polymer composites, developed by integrating glycidyl methacrylate with nanoparticles of bismuth oxide (Bi2O3) and tungsten oxide (WO3), were explored. The ability of the composites to attenuate gamma radiation was evaluated by measuring the emissions from Ba-133, Co-60, Cs-137, and Na-22. X-ray diffraction (XRD) spectra were obtained for both the pure polymer glycidyl methacrylate and the samples containing nanostructures of Bi2O3, Bi2O3/WO3, and WO3, and scanning electron microscopy (SEM) was used to analyze the samples. The incorporation of Bi2O3 and WO3 nanoparticles into the polymer glycidyl methacrylate matrix significantly enhanced the composites' ability to attenuate gamma radiation, as demonstrated by the increased linear and mass attenuation coefficients. The results showed good agreement between the experiment and the XCOM database. The composites exhibited significant efficiency in attenuating lower-energy gamma rays, which is particularly advantageous in the medical and nuclear industries.

Following the finding of power conversion efficiency above the Shockley–Queisser limit in BaTiO3 (BTO) crystals, ferroelectric oxides have attracted scientific interest in ferroelectric photovoltaics (FPV). However, since ferroelectric oxides have a huge bandgap (>3 eV), progress in this sector is constrained. This paper proposes and demonstrates a new ferroelectric BaTi1−xCoxO3 powder (0 ≤ x ≤ 0.08), abbreviated as BTCx, that exhibited a bandgap decrease with increased Co content. Notably, changing the composition from x = 0.0 to 0.08 caused the system to show a bandgap drop from 3.24 to 2.42 eV. The ideal design with x = 0.08 displayed an abnormal PV response. Raman spectroscopy measurements were used to investigate the cause of the bandgap decrease, and density functional theory was used to interpret the analyzed results. According to our findings, Co2+ doping and oxygen octahedral distortions enhance bandgap reduction. This research sheds light on how bandgap tuning developed and laid the way for investigating novel low-bandgap ferroelectric materials for developing next-generation photovoltaic applications.

Materials with ferroelectric properties, low bandgap energies, high polarization, low loss, and thermal stability are essential for future solar-cell applications. Researchers have attempted to obtain such materials by using several approaches. In this vein, a novel approach is reported in this work using gamma ray irradiation. The effect of gamma radiation on the structural, optical, and ferroelectric characterizations of bismuth (Bi)-doped barium titanate (BaTiO3 (BT)), namely Ba0.95Bi0.05TiO3 ceramics (abbreviated as (Bi:BT)), was investigated. X-ray diffraction, structure refinement, and Raman study revealed the presence of a perovskite structure with a tetragonal phase in all investigated samples. Morphological study revealed a nonuniform grain size and some porosity. Gamma irradiation-induced combined effects were proved by a detailed analysis of bond lengths, bond angles, octahedral distortions, oxygen vacancies, and charge compensations. Electron paramagnetic resonance (EPR) study gave direct evidence of oxygen vacancies in the irradiated samples. After gamma irradiation, UV–vis study indicated a decrease in the bandgap from 3.14 to 2.80 eV and a significant increase in visible light absorption. Cole–Cole plots confirm as an increase in gamma-ray dose results in higher levels of electron hopping. Study of the P–E hysteresis loop demonstrated that ferroelectric properties could be maintained after gamma irradiation, with a slight decrease in remnant polarization. The behaviour of the P–E was correlated with increasing gamma dose in the investigated ceramics, demonstrating a strong gamma dependence in the loops’ profile. We guess that the present approach may be a promising technique for enhancing the multifunctionality of electronic devices.

The article explores the cosmopolitan philosophy of Palestinian American literary theoretician Edward Said. As a true cosmopolite, Said calls for equality among nations, people and culture. However, there is a debate on whether Said is a true cosmopolite because he is actively involved in the Palestinian struggle. Said believes that a man oppressed by an unjust law is not considered as free.