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Chromium depletion at grain boundaries (GBs) due to selective attack is a critical issue in the molten salt corrosion of NiCr alloys. Despite the importance of GBs in this process from numerous experimental studies, most theoretical work has predominantly focused on fluorine interactions with idealized crystalline surfaces, neglecting the complexity of GB local environments. This study aims to bridge that gap by employing density functional theory (DFT) to investigate the atomic interactions and Cr dissolution mechanisms at GB in NiCr alloys under molten fluoride salt environments. Specifically, a $\Sigma$5(210)/(001) symmetrical tilt GB is constructed to explore the adsorption energies of fluorine on Ni(100) and Cr-doped Ni(100) surfaces. We find that fluorine exhibits a strong preference for binding at GB sites, with Cr doping amplifying this effect, leading to higher adsorption energies compared to bulk Ni surfaces. Fluorine bonding with Cr significantly alters the interaction between Cr-F complexes and Ni substrate, and the consequent dissolution barriers for Cr atoms; the formation of CrF$_3$ largely reduces the energy barrier for Cr dissolution. This work highlights the essential role of GBs in enhancing fluorine adsorption and accelerating Cr depletion, providing new insights into the mechanisms of early-stage corrosion in NiCr alloys., Comment: 10 figures

This paper presents a novel Dialectal Sound and Vowelization Recovery framework, designed to recognize borrowed and dialectal sounds within phonologically diverse and dialect-rich languages, that extends beyond its standard orthographic sound sets. The proposed framework utilized a quantized sequence of input with(out) continuous pretrained self-supervised representation. We show the efficacy of the pipeline using limited data for Arabic, a dialect-rich language containing more than 22 major dialects. Phonetically correct transcribed speech resources for dialectal Arabic are scarce. Therefore, we introduce ArabVoice15, a first-of-its-kind, curated test set featuring 5 hours of dialectal speech across 15 Arab countries, with phonetically accurate transcriptions, including borrowed and dialect-specific sounds. We described in detail the annotation guideline along with the analysis of the dialectal confusion pairs. Our extensive evaluation includes both subjective -- human perception tests and objective measures. Our empirical results, reported with three test sets, show that with only one and half hours of training data, our model improve character error rate by ~ 7\% in ArabVoice15 compared to the baseline., Comment: Accepted ACL 2024 Main Conference

General-purpose artificial intelligence (AI) systems are built on massive swathes of public web data, assembled into corpora such as C4, RefinedWeb, and Dolma. To our knowledge, we conduct the first, large-scale, longitudinal audit of the consent protocols for the web domains underlying AI training corpora. Our audit of 14,000 web domains provides an expansive view of crawlable web data and how codified data use preferences are changing over time. We observe a proliferation of AI-specific clauses to limit use, acute differences in restrictions on AI developers, as well as general inconsistencies between websites' expressed intentions in their Terms of Service and their robots.txt. We diagnose these as symptoms of ineffective web protocols, not designed to cope with the widespread re-purposing of the internet for AI. Our longitudinal analyses show that in a single year (2023-2024) there has been a rapid crescendo of data restrictions from web sources, rendering ~5%+ of all tokens in C4, or 28%+ of the most actively maintained, critical sources in C4, fully restricted from use. For Terms of Service crawling restrictions, a full 45% of C4 is now restricted. If respected or enforced, these restrictions are rapidly biasing the diversity, freshness, and scaling laws for general-purpose AI systems. We hope to illustrate the emerging crises in data consent, for both developers and creators. The foreclosure of much of the open web will impact not only commercial AI, but also non-commercial AI and academic research., Comment: 41 pages (13 main), 5 figures, 9 tables

Large language models (LLMs) are notorious for hallucinating, i.e., producing erroneous claims in their output. Such hallucinations can be dangerous, as occasional factual inaccuracies in the generated text might be obscured by the rest of the output being generally factually correct, making it extremely hard for the users to spot them. Current services that leverage LLMs usually do not provide any means for detecting unreliable generations. Here, we aim to bridge this gap. In particular, we propose a novel fact-checking and hallucination detection pipeline based on token-level uncertainty quantification. Uncertainty scores leverage information encapsulated in the output of a neural network or its layers to detect unreliable predictions, and we show that they can be used to fact-check the atomic claims in the LLM output. Moreover, we present a novel token-level uncertainty quantification method that removes the impact of uncertainty about what claim to generate on the current step and what surface form to use. Our method Claim Conditioned Probability (CCP) measures only the uncertainty of a particular claim value expressed by the model. Experiments on the task of biography generation demonstrate strong improvements for CCP compared to the baselines for seven LLMs and four languages. Human evaluation reveals that the fact-checking pipeline based on uncertainty quantification is competitive with a fact-checking tool that leverages external knowledge., Comment: Accepted to ACL-2024 (Findings). Ekaterina Fadeeva, Aleksandr Rubashevskii, and Artem Shelmanov contributed equally