Search

In the extreme space environment, spacecraft endure dramatic temperature variations that can impair their functionality. A VO2-based smart radiator device (SRD) offers an effective solution by adaptively adjusting its radiative properties. However, current research on VO2-based thermochromic films mainly focuses on optimizing the emissivity tunability (Δε) of single-cycle sandwich structures. Although multi-cycle structures have shown increased Δε compared to single-cycle sandwich structures, there have been few systematic studies to find the optimal cycle structure. This paper theoretically discusses the influence of material properties and cyclic structure on SRD performance using Finite-Difference Time-Domain (FDTD) software, which is a rigorous and powerful tool for modeling nano-scale optical devices. An optimal structural model with maximum emissivity tunability is proposed. The BaF2 obtained through optimization is used as the dielectric material to further optimize the cyclic resonator. The results indicate that the tunability of emissivity can reach as high as 0.7917 when the BaF2/VO2 structure is arranged in three periods. Furthermore, to ensure a longer lifespan for SRD under harsh space conditions, the effects of HfO2 and TiO2 protective layers on the optical performance of composite films are investigated. The results show that when TiO2 is used as the protective layer with a thickness of 0.1 µm, the maximum emissivity tunability reaches 0.7932. Finally, electric field analysis is conducted to prove that the physical mechanism of the smart radiator device is the combination of stacked Fabry–Perot resonance and multiple solar reflections. This work not only validates the effectiveness of the proposed structure in enhancing spacecraft thermal control performance but also provides theoretical guidance for the design and optimization of SRDs for space applications.

In recent years, smart windows have attracted widespread attention due to their ability to respond to external stimuli such as light, heat, and electricity, thereby intelligently adjusting the ultraviolet, visible, and near-infrared light in solar radiation. VO2(M) undergoes a reversible phase transition from an insulating phase (monoclinic, M) to a metallic phase (rutile, R) at a critical temperature of 68 °C, resulting in a significant difference in near-infrared transmittance, which is particularly suitable for use in energy-saving smart windows. However, due to the multiple valence states of vanadium ions and the multiphase characteristics of VO2, there are still challenges in preparing pure-phase VO2(M). Machine learning (ML) can learn and generate models capable of predicting unknown data from vast datasets, thereby avoiding the wastage of experimental resources and reducing time costs associated with material preparation optimization. Hence, in this paper, four ML algorithms, namely multi-layer perceptron (MLP), random forest (RF), support vector machine (SVM), and extreme gradient boosting (XGB), were employed to explore the parameters for the successful preparation of VO2(M) films via magnetron sputtering. A comprehensive performance evaluation was conducted on these four models. The results indicated that XGB was the top-performing model, achieving a prediction accuracy of up to 88.52%. A feature importance analysis using the SHAP method revealed that substrate temperature had an essential impact on the preparation of VO2(M). Furthermore, characteristic parameters such as sputtering power, substrate temperature, and substrate type were optimized to obtain pure-phase VO2(M) films. Finally, it was experimentally verified that VO2(M) films can be successfully prepared using optimized parameters. These findings suggest that ML-assisted material preparation is highly feasible, substantially reducing resource wastage resulting from experimental trial and error, thereby promoting research on material preparation optimization.

Electrochromic smart windows can achieve controllable modulation of color and transmittance under an external electric field with active light and thermal control capabilities, which helps reduce energy consumption caused by building cooling and heating. However, electrochromic smart windows often rely on external power circuits, which greatly affects the independence and portability of smart windows. Based on this, an electrochromic smart window driven by temperature-difference power generation was designed and implemented. This smart window provides automatic and manual control of the reversible cycle of electrochromic glass from light blue to dark blue according to user requirements and changes in the surrounding environment, achieving adaptive adjustment of visual comfort and reducing energy consumption. The infrared radiation rejection (from 780 to 2500 nm) of the electrochromic smart window is as high as 77.3%, and its transmittance (from 380 to 780 nm) fluctuates between 39.2% and 56.4% with changes in working state. Furthermore, the temperature in the indoor simulation device with electrochromic glass as the window was 15 °C lower than that with ordinary glass as the window after heating with a 250 W Philips infrared lamp for ten minutes. After 2000 cycles of testing, the performance of the smart window was basically maintained at its initial values, and it has broad application prospects in buildings, vehicles, and high-speed rail systems.

Acoustic emission (AE) testing is a widely used nondestructive testing method for the early detection of failures in materials and structures. In this paper, an AE detection sensor combining optical fiber sensing with laser self-mixing interference (SMI) technology is proposed. A multi-coil optical fiber ring wound round a cylindrical acrylic skeleton was designed in order to sense the deformation caused by AE elastic waves, which was then demodulated using self-mixing interference technology. Finite element analyses were conducted in order to investigate the deformation of fiber under acoustic sources. AE signals induced via ball-dropping impact experiments were successfully detected by the proposed experimental system. The proposed SMI optical fiber AE sensing system has the advantages of being free from electromagnetic interference and having a simple structure, low implementation cost and high measurement resolution and sensitivity.

Molybdenum disulfide (MoS2) is a layered transition metal-sulfur compound semiconductor that shows promising prospects for applications in optoelectronics and integrated circuits because of its low preparation cost, good stability and excellent physicochemical, biological and mechanical properties. MoS2 with high quality, large size and outstanding performance can be prepared via chemical vapor deposition (CVD). However, its preparation process is complex, and the area of MoS2 obtained is difficult to control. Machine learning (ML), as a powerful tool, has been widely applied in materials science. Based on this, in this paper, a ML Gaussian regression model was constructed to explore the growth mechanism of MoS2 material prepared with the CVD method. The parameters of the regression model were evaluated by combining the four indicators of goodness of fit (r2), mean squared error (MSE), Pearson correlation coefficient (p) and p-value (p_val) of Pearson’s correlation coefficient. After comprehensive comparison, it was found that the performance of the model was optimal when the number of iterations was 15. Additionally, feature importance analysis was conducted on the growth parameters using the established model. The results showed that the carrier gas flow rate (Fr), molybdenum sulfur ratio (R) and reaction temperature (T) had a crucial impact on the CVD growth of MoS2 materials. The optimal model was used to predict the size of molybdenum disulfide synthesis under 185,900 experimental conditions in the simulation dataset so as to select the optimal range for the synthesis of large-size molybdenum disulfide. Furthermore, the model prediction results were verified through literature and experimental results. It was found that the relative error between the prediction results and the literature and experimental results was small. These findings provide an effective solution to the preparation of MoS2 materials with a reduction in the time and cost of trial and error.

Thermochromic smart windows are optical devices that can regulate their optical properties actively in response to external temperature changes. Due to their simple structures and as they do not require other additional energy supply devices, they have great potential in building energy-saving. However, conventional thermochromic smart windows generally have problems with high response temperatures and low response rates. Owing to their great effect in photothermal conversion, photothermal materials are often used in smart windows to assist phase transition so that they can quickly achieve the dual regulation of light and heat at room temperature. Based on this, research progress on the phase transition of photothermal material-assisted thermochromic smart windows is summarized. In this paper, the phase transition mechanisms of several thermochromic materials (VO2, liquid crystals, and hydrogels) commonly used in the field of smart windows are introduced. Additionally, the applications of carbon-based nanomaterials, noble metal nanoparticles, and semiconductor (metal oxygen/sulfide) nanomaterials in thermochromic smart windows are summarized. The current challenges and solutions are further indicated and future research directions are also proposed.

External optical feedback (EOF) has great impacts on the properties of lasers. It influences the stable operation of lasers. However, various applications based on lasers with EOF have been developed. One typical example is self-mixing interferometry technology, where modulated steady-state laser intensity is utilized for sensing and measurement. Other works show that laser dynamics can also be used for sensing, and the laser in this case is more sensitive to EOF. This paper reviews the sensing technology that uses the dynamics of lasers with EOF. We firstly introduce the basic operating principles of a laser with EOF and discuss the noise properties of and intensity modification in lasers induced by EOF. Then, sensing applications using laser dynamics are categorized and presented, including sensing by frequency-shifted optical feedback, relaxation oscillation frequency, and dynamics with self-mixing interferometry signals and laser optical chaos. Lastly, we present an analysis of the transient response waveform and spectrum of a laser with EOF, showing its potential for sensing.

Thermochromic smart windows can automatically control solar radiation according to the ambient temperature. Compared with photochromic and electrochromic smart windows, they have a stronger applicability and lower energy consumption, and have a wide range of application prospects in the field of building energy efficiency. At present, aiming at the challenge of the high transition temperature of thermochromic smart windows, a large amount of innovative research has been carried out via the principle that thermochromic materials can be driven to change their optical performance by photothermal or electrothermal effects at room temperature. Based on this, the research progress of photo- and electro-driven thermochromic smart windows is summarized from VO2-based composites, hydrogels and liquid crystals, and it is pointed out that there are two main development trends of photo-/electro-driven thermochromic smart windows. One is exploring the diversified combination methods of photothermal materials and thermochromic materials, and the other is developing low-cost large-area heating electrodes.

The Young’s modulus and internal friction are two important parameters of materials. Self-mixing interferometry (SMI) is an emerging non-destructive sensing method that has been employed for various applications because of its advantages of simple structure, ease of alignment and high resolution. Some recent works have proposed the use of SMI technology to measure the Young’s moduli and/or internal frictions by measuring the resonance frequencies and damping factors of specimen vibrations induced by impulse excitation. However, the measurement results may be affected by frequencies of SMI fringes, and the implementation requires extra signal processing on SMI fringes. In this work, we developed an all-fiber SMI system without SMI fringes to measure the Young’s modulus and internal friction simultaneously. Simulations and experiments were carried out to verify the feasibility of the proposed method. Two specimens of brass and aluminum were tested. The experimental results show that the standard deviations of Young’s moduli for brass and aluminum are 0.20 GPa and 0.14 GPa, and the standard deviations of internal frictions are 4.0×10−5 and 5.4×10−5, respectively. This method eliminates the influences of the SMI fringe frequency on the resonant frequency and requires no signal processing on SMI fringes, contributing to its simplicity as a method for the measurement of the Young’s modulus and internal friction.

Abstract Luminescent solar concentrators (LSCs) have attracted significant attention as promising solar energy conversion devices for building integrated photovoltaic (PV) systems due to their simple architecture and cost‐effective fabrication. Conventional LSCs are generally comprised of an optical waveguide slab with embedded emissive species and coupled PV cells. Colloidal semiconductor quantum dots (QDs) have been demonstrated as efficient emissive species for high‐performance LSCs because of their outstanding optical properties including tunable absorption and emission spectra covering the ultraviolet/visible to near‐infrared region, high photoluminescence quantum yield, large absorption cross sections, and considerable photostability. However, current commonly used QDs for high‐performance LSCs consist of highly toxic heavy metals (i.e., cadmium and lead), which are fatal to human health and the environment. In this regard, it is highly desired that heavy metal‐free and environmentally friendly QD‐based LSCs are comprehensively studied. Here, notable advances and developments of LSCs based on unary, binary, and ternary eco‐friendly QDs are presented. The synthetic approaches, optical properties of these eco‐friendly QDs, and consequent device performance of QD‐based LSCs are discussed in detail. A brief outlook pointing out the existing challenges and prospective developments of eco‐friendly QD‐based LSCs is provided, offering guidelines for future device optimizations and commercialization.

Functionalized iron oxide nanoparticles (IONPs) are of great interest due to wide range applications, especially in nanomedicine. However, they face challenges preventing their further applications such as rapid agglomeration, oxidation, etc. Appropriate surface modification of IONPs can conquer these barriers with improved physicochemical properties. This review summarizes recent advances in the surface modification of IONPs with small organic molecules, polymers and inorganic materials. The preparation methods, mechanisms and applications of surface-modified IONPs with different materials are discussed. Finally, the technical barriers of IONPs and their limitations in practical applications are pointed out, and the development trends and prospects are discussed.

Refrigeration technology plays a critical role in various aspects of daily life and industrial production. However, traditional refrigeration methods consume substantial energy and cause environmental pollution, hindering their ability to meet future refrigeration requirements. Radiative cooling as a refrigeration technology that does not require an external energy input has garnered significant attention owing to its energy-saving and environmentally friendly characteristics. In recent years, substantial advancements in radiative cooling technology have been made, ranging from improved cooling capacity to enhanced control over cooling effects and increased durability. Presently, radiative cooling technology has matured to the point where its practical applications have become feasible. Herein, we provide a comprehensive overview of radiative cooling technology, covering its basic principles, various design structures, and potential applications. Additionally, the current challenges associated with this technology are highlighted, aiming to offer essential suggestions for its future progress and improvement. [ABSTRACT FROM AUTHOR]

We investigated the influence of Zr[O.sub.2] on the microstructure and electromagnetic properties of MnZn ferrites by characterizing fracture surface micrographs, magnetic properties, and dc resistivity. Powders of [Mn.sub.o.68][Zn.sub.o.25][Fe.sub.2.07][O.sub.4] composition were prepared by the conventional ceramic technique. Toroidal cores were sintered at 1350 [degrees]C for 4 h in [N.sub.2]/[O.sub.2] atmosphere with 4% oxygen. The results show that the lattice constant and average grain size increase with Zr[O.sub.2] concentration, but excessive Zr[O.sub.2] concentration will result in exaggerated grain growth and porosity increase. The dc resistivity, activation energy, saturation magnetic flux density, and initial magnetic permeability increase monotonically when the Zr[O.sub.2] concentration is not more than 0.04 wt% and then decrease with further increase of Zr[O.sub.2] concentration. On the other hand, the porosity, drift mobility, resonance frequency, and core loss decrease initially and then increase with the increase of Zr[O.sub.2] concentration. Index Terms--Electromagnetic properties, microstructure, MnZn ferrites, Zr[O.sub.2] addition.

This study attempts to determine whether there is a spatial correlation between electricity generation and economic scale promoting coordinated development in Africa. We explore the spatial similarity and gray correlation degree between electricity generation and economic scale in Africa since the 21st century by adopting barycenter coupling and Gray Correlation Analysis method. We argue that there is a strong correlation between electricity generation and economic scale. Our findings indicate a significant spatial difference in electricity generation, mainly concentrated in Northern and Southern Africa. Furthermore, spatial pattern remains largely consistent over time, mirroring trends observed at the economic scale. Electricity generation and economic scale were concentrated in six countries- South Africa, Egypt, Algeria, Nigeria, Morocco, and Libya- and did not change significantly over time. A correlation analysis between electricity generation and the economic scale further confirmed this, with a linear coefficient of 0.907. Both the gravity centers of economic scale and electricity generation in Africa move farther in the north-south direction than in the East-West direction, with the former showing a Southwest-Northeast-Southwest track feature and the latter a Northeast-Southwest track feature. The spatial distribution of the gravity centers of electricity generation and the gravity centers of the economic scale in Africa are highly consistent; electricity generation highly correlates with the economic scale, consistent with the research conclusion obtained by the Gray Correlation Analysis method. This study suggests the coordinated development of electricity generation and economic scales in various African countries.