Search

Many astrochemical models of observed CO isotopologue line emission, earlier considered a good proxy measure of H$_2$ and hence disk gas mass, favor large deviations in the carbon and oxygen gas phase abundances and argue that severe gas phase CO depletion makes it a poor mass tracer. Here, we show that C$^{18}$O line emission is an effective measure of the gas mass, and despite its complex chemistry, a possibly better tracer than HD. Our models are able to reproduce C$^{18}$O emission from recent ALMA surveys and the TW Hya disk to within a factor of $\sim 2-3$ using carbon and oxygen abundances characteristic of the interstellar medium (C/H$=1.4 \times 10^{-4}$; O/H$=3.2\times 10^{-4}$) without having to invoke unusual chemical processing. Our gas and dust disk structure calculations considering hydrostatic pressure equilibrium and our treatment of the CO conversion on grains are primarily responsible for the very different conclusions on disk masses and CO depletion. As did previous studies, we find that a gas phase C/O of $\sim 1-2$ can explain observed hydrocarbon emission from the TW Hya disk; but significantly, we find that CO isotopologue emission is only marginally affected by the C/O ratio. We therefore conclude that C$^{18}$O emission provides estimates of disk masses that are uncertain only to within a factor of a few, and describe a simplified modeling procedure to obtain gas disk masses from C$^{18}$O emission lines., Comment: 20 pages, 9 figures

The depth-dependent abundance of both gas-phase and solid-state water within dense, quiescent, molecular clouds is important to both the cloud chemistry and gas cooling. Where water is in the gas phase, it's free to participate in the network of ion-neutral reactions that lead to a host of oxygen-bearing molecules, and its many ortho and para energy levels make it an effective coolant for gas temperatures greater than 20K. Where water is abundant as ice on grain surfaces, and unavailable to cool the gas, significant amounts of oxygen are removed from the gas phase, suppressing the gas-phase chemical reactions that lead to a number of oxygen-bearing species, including O2. Models of FUV-illuminated clouds predict that the gas-phase water abundance peaks in the range Av ~3 and 8mag of the cloud surface, depending on the gas density and FUV field strength. Deeper within such clouds, water is predicted to exist mainly as ice on grain surfaces. More broadly, these models are used to analyze a variety of other regions, including outflow cavities associated with young stellar objects and the surface layers of protoplanetary disks. In this paper, we report the results of observational tests of FUV-illuminated cloud models toward the Orion Molecular Ridge and Cepheus B using data obtained from the Herschel Space Observatory and the Five College Radio Astronomy Observatory. Toward Orion, 2220 spatial positions were observed along the face-on Orion Ridge in the H2O 110-101 557GHz and NH3 J,K=1,0-0,0 572GHz lines. Toward Cepheus B, two strip scans were made in the same lines across the edge-on ionization front. These new observations demonstrate that gas-phase water exists primarily within a few magnitudes of dense cloud surfaces, strengthening the conclusions of an earlier study based on a much smaller data set, and indirectly supports the prediction that water ice is quite abundant in dense clouds., Comment: 59 pages, including 23 figures, Accepted for publication in ApJ