1. Coarsening dynamics of ternary polymer solutions with mobility and viscosity contrasts.
- Author
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Garcia, Jan Ulric, Tree, Douglas R., Bagoyo, Alyssa, Iwama, Tatsuhiro, Delaney, Kris T., and Fredrickson, Glenn H.
- Subjects
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POLYMER solutions , *VISCOSITY solutions , *PHASE separation , *GLASS transitions , *HAMILTON-Jacobi equations , *HYDRODYNAMICS , *GLASS transition temperature - Abstract
Using phase-field simulations, we investigate the bulk coarsening dynamics of ternary polymer solutions undergoing a glass transition for two models of phase separation: diffusion only and with hydrodynamics. The glass transition is incorporated in both models by imposing mobility and viscosity contrasts between the polymer-rich and polymer-poor phases of the evolving microstructure. For microstructures composed of polymer-poor clusters in a polymer-rich matrix, the mobility and viscosity contrasts significantly hinder coarsening, effectively leading to structural arrest. For microstructures composed of polymer-rich clusters in a polymer-poor matrix, the mobility and viscosity contrasts do not impede domain growth; rather, they change the transient concentration of the polymer-rich phase, altering the shape of the discrete domains. This effect introduces several complexities to the coarsening process, including percolation inversion of the polymer-rich and polymer-poor phases—a phenomenon normally attributed to viscoelastic phase separation. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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