Search

Accurate assessment of soil nitrogen (N) storage and carbon (C) : N stoichiometry under impervious surface areas (ISAs) is key to understanding the impact of urbanization on soil health and the N cycle. Based on 888 soil profiles from 148 sampling sites in 41 cities across China, we estimated the country's N stock (100 cm depth) in the ISA soil to be 98.74±59.13 Tg N with a mean N density (NISA) of 0.59±0.35 kg m−2, which was significantly lower (at all depths) than the soil N density (NPSA=0.83±0.46 kg m−2) under the reference permeable surface areas (PSAs). The NISA was also only about 53 %–69 % of the reported national mean soil N density, indicating that ISA expansion caused soil N loss. The C:N ratio of ISA (10.33±2.62) was 26 %–34 % higher than that of natural ecosystems (forests, grasslands, etc.) but close to the C:N of PSA. Moreover, there was a significant C–N correlation in ISA soil, showing no signs of C–N decoupling as suggested by the previous studies. The ISA had smaller variances in the C:N ratio than did the PSA at regional scale, indicating convergence of soil C:N stoichiometry due to ISA conversion. The eastern subregion of China had the highest NISA, although its natural soil N density was among the lowest in the country. Unlike the vertical pattern in natural permeable soils, whose N density declined faster in the upper soil layers than in the lower layers, NISA decreased linearly with depth. Similarly to natural soil N, NISA was negatively correlated with temperature; but unlike natural soil C:N which was positively correlated with temperature, the C:NISA was negatively correlated with temperature. NISA was not correlated with net primary productivity, but was significantly correlated with the soil N density of adjacent PSA and the urbanization rate. These findings indicate the ISA soil had a unique N distribution pattern, possibly as the result of intensive disturbances during land conversion. The dataset “Observations of soil nitrogen and soil organic carbon to soil nitrogen stoichiometry under the impervious surfaces areas (ISA) of China” is available from the National Cryosphere Desert Data Center (https://doi.org/10.12072/ncdc.socn.db2851.2023) (Ding et al., 2023).

Radionuclide migration in clay-rich formations is typically dominated by diffusion considering the low permeability of these formations. An accurate estimation of radionuclide migration in host rocks using numerical tools plays a key role in the safety assessment of disposal concepts for nuclear waste. In the sandy facies of the Opalinus Clay (SF-OPA), the spatial variability of the pore space network and compositional heterogeneity at the pore scale (nm to µm) cause heterogeneous diffusion at the core scale (cm to dm). Such heterogeneous diffusion patterns affect the migration of radionuclides in various sedimentary layers even above the core scale (m). In this work, we study the heterogeneous diffusion of cations based on a two-dimensional (2D) structural model at the m-scale. As key parameters for the diffusive transport calculation, the effective diffusion coefficients in different sedimentary layers are quantified based on our previous developed up-scaling workflow from pore- to core-scale simulation combined with the multi-scale digital rock models. The heterogeneous effective diffusivities are then implemented into the large-scale structural model for diffusive transport simulation using the FEM-based OpenGeoSys-6 simulator. The sensitivity analysis focuses on the effects of the SF-OPA bedding angle and the effect of different layer-succession layout with different canister emplacement on the spatio-temporal evolution of radionuclide diffusion front line. Results show that the moving distance of the diffusion front is farther away from the canister center, along the direction with the neighboring layer having lower diffusion coefficient within the total simulation time of 2000 years. When the bedding angle increases, the diffusion front moves farther in in vertical upward direction direction, which has less retardation effect for the radionuclide from the ground surface point. For different layer-succession layout with different canister emplacement, the smallest migration distance of the diffusion front line is 1.65 m. Within 2000 years, for the conceptual model 2B that the canister is emplaced in the layer with the highest diffusivity coefficient, the diffusion front can migrate 0.19 m farther along vertical downward direction due to the influence of the neighboring layer. The numerical results provide insight into the effects of rocks heterogeneity on diffusion of radionuclides, contributing to enhanced long-term predictability of radionuclide migration in SF-OPA as potential host rock for a deep geological repository.

We present a method to precisely determine the ^{2}D_{3/2} state lifetime of a single trapped ^{174}Yb^{+} ion. This method is based on the detection of photons emitted from excited states, where a highly synchronized measurement sequence for laser control and an intensity-alternating sequence for atomic excitation and photon counting are used to minimize systematic errors. This method is easy to implement and is immune to fluctuations of magnetic field, laser intensity, and frequency detuning. Combined with the real-time approach of background photon correction, the radiative lifetime of the ^{2}D_{3/2} state is determined to be 54.83±0.18 ms, which represents an order of magnitude improvement in measurement precision. The accurately determined lifetime sets a benchmark for many-body atomic theories and is particularly useful to determine the coherence time limit of the optical clock.

Any site selection process for a final repository for high-level and heat producing radioactive waste is a national challenge and has to take into account, among others, regional geological settings. In Germany, the site selection has to restart from zero, and all potential host rocks have to be considered equal, including argillaceous rocks. Therefore, the Federal Institute for Geosciences and Natural Resources (BGR) performs appropriate experiments in the Swiss Mont Terri rock laboratory, which is located in the Jurassic Opalinus Clay. In this paper, activities and results from actual and still ongoing experiments, with participation of BGR, are presented exemplarily. All experiments aim for a contribution to understand particular aspects regarding the behaviour of underground facilities, BGR's focus lies mainly on aspects of the early lifetime of a repository, namely the construction, post-closure transient, and partly post-closure equilibrium phases. It is obvious that for a full understanding of the evolution of a final repository, knowledge and experience of many different groups, their studies and results covering all aspects, have to be included. In this paper, we can only emphasise a few representative examples on geophysical and geotechnical in-situ site investigations, geotechnical mine-by monitoring, laboratory investigations, and modelling aspects. The combined interpretation of these results enhance interpretations and is a prerequisite for a comprehensive understanding of a repository.

According to the overall requirements of ecological construction and environmental protection, rely on the national key ecological engineering, strengthen ecological environmental restoration and protection, improve forest cover, control soil erosion, construct important ecological security barrier in poor areas, inhibit poverty alleviation through ecological security in this area from environmental damage to the vicious cycle of poverty. Obviously, the dynamic monitoring of ecological security in contiguous destitute areas of Sichuan province has a policy sense of urgency and practical significance. This paper adopts RS technology and GIS technology to select the Luhe region of Jinchuan county and Ganzi prefecture as the research area, combined with the characteristics of ecological environment in poor areas, the impact factors of ecological environment are determined as land use type, terrain slope, vegetation cover, surface water, soil moisture and other factors. Using the ecological environmental safety assessment model, the ecological environment safety index is calculated. According to the index, the ecological environment safety of the research area is divided into four levels. The ecological environment safety classification map of 1990 in 2009 is obtained. It can be seen that with the human modern life and improve their economic level, the surrounding environment will be destroyed, because the research area ecological environment is now in good, the ecological environment generally tends to be stable. We should keep its ecological security good and improve local economic income. The relationship between ecological environmental security and economic coordinated development in poor areas has very important strategic significance.

Ammonium deposition at the International Institute for Sustainable Development Experimental Lakes Area (IISD–ELA), in northwestern Ontario, Canada, has doubled in the last 45 years and thus is no longer among the low nitrogen (N) deposition sites in North America. This may be related to the concurrent intensification of Manitoba agriculture to the west and upwind of the ELA. Large increases in ammonium deposition at the ELA were important in driving the observed trend and increased the NH4 + to NO3 − ratio of input to aquatic and terrestrial systems. Stable isotope analyses of two years of bulk (wet and dry) atmospheric deposition revealed very large ranges in δ15N−NH4 + (22‰ range), δ15N−NO3 − (18‰), and δ18O–NO3 − (19‰). Few other δ15N−NH4 +, δ15N−NO3 −, and δ18O–NO3 − values have been published for Canadian precipitation. Increases in δ15N of NH4 + and NO3 − in July occurred with increases in total N deposition. The wide range and seasonal trends of δ15N and δ18O values in ELA precipitation mean that studies characterizing N inputs to watersheds and lakes require an ongoing and comprehensive annual sampling regime. Global trends of declining δ15N of N deposition evident in lake sediment records may be a result of increases in NH4 + deposition with lower δ15N−NH4 + values. Similarly, the relationship in Lake Superior between increasing NO3 − and lower δ15N−NO3 − values may be explained by increased atmospheric deposition of N with low δ15N values.

A series of Al-5Ti-1B master alloys were obtained via fluoride salt process by holding them between 780°C and 880°C for 10-90 min. The influence of holding temperature and time during preparation on the microstructure and its refining performance were investigated by X-ray diffractometer, optical microscopy and scanning electron microscopy equ ipped with energy dispersive X-ray spectroscopy. The results indicated both the morphology and the distribution of TiB2 and Al3Ti were seriously affected by holding conditions. Inadequate TiB2 particles were generated when holding time was short. However, Fe-containing impurity particles that aggregated along the matrix grain boundaries were found after the prolonged holding time. The refining and microhardness test results revealed that Al -5Ti-1B, the one held at 820°C for 30 min showed the optimum refining efficiency on Al-Cu alloy.

An X-band GW-level polarization controllable TM01-TE11 mode converter for high power microwave (HPM) systems is proposed. The mode converter consists of a TM01-TE10 mode coupler, a TE11-TE10 mode coupler and four phase shifters. The overall axial dimension is less than 300 mm. By controlling the phase shifters, the online adjustment of vertical, horizontal and circular polarizations can be implemented. The simulation demonstrates that the transmission efficiency is higher than 95.6% from 9.4 GHz to 9.8 GHz. The power capacity of the mode converter is on GW-level.

This study investigated the value of computed tomography (CT) in the diagnosis and treatment of hepatic veno-occlusive disease (HVOD) caused by Sedum aizoon (SA). The clinical manifestations, treatment results, imaging findings, and histological findings of the liver were analyzed in 39 patients with HVOD caused by SA. Hepatomegaly, liver dysfunction, abdominal effusion, and geographic density changes on liver CT scans were found in all 39 patients. The pathological findings of histological liver examination included swelling and point-like necrosis of liver cells, significant expansion and congestion of the sinuses, endothelial swelling, and wall thickening with incomplete lumen occlusion of small liver vessels. CT geographic density changes were confirmed by histological examination of the liver in 18 patients. Sixteen patients with small amounts of ascites that started within 4 weeks of treatment recovered completely or significantly improved after symptomatic and supportive treatment. However, only 43.75% of the patients with larger amounts of ascites improved following symptomatic and supportive treatment. In conclusion, liver CT examination is a valuable, safe, and noninvasive tool for the diagnosis of HVOD caused by SA. In selected cases, liver CT examination may replace liver biopsy and histological analysis.

The influence on soil erosion by different bedrock bareness ratios, different rainfall intensities, different underground pore fissure degrees and rainfall duration are researched through manual simulation of microrelief characteristics of karst bare slopes and underground karst crack construction in combination with artificial simulation of rainfall experiment. The results show that firstly, when the rainfall intensity is small (30 and 50 mm h−1), no bottom load loss is produced on the surface, and surface runoff, underground runoff and sediment production are increased with the increasing of rainfall intensity. Secondly, surface runoff and sediment production reduced with increased underground pore fissure degree, while underground runoff and sediment production increased. Thirdly, raindrops hit the surface, forming a crust with rainfall duration. The formation of crusts increases surface runoff erosion and reduces soil infiltration rate. This formation also increases surface-runoff-erosion-damaged crust and increased soil seepage rate. Raindrops continued to hit the surface, leading the formation of crust. Soil permeability showed volatility which was from reduction to increases, reduction, and so on. Surface and subsurface runoff were volatile with rainfall duration. Fourthly, when rock bareness ratio is 50 % and rainfall intensities are 30 and 50 mm h−1, runoff is not produced on the surface, and the slope runoff and sediment production present a fluctuating change with increased rock bareness ratio. Fifthly, the correlation degree between the slope runoff and sediment production and all factors are as follows: rainfall intensity-rainfall duration-underground pore fissure degree–bedrock bareness ratio.

A series of sodium bentonite and thiamine were used as raw materials to prepare a new adsorbent – thiamine- modified bentonite. The adsorbent was applied in the pretreatment of pharmaceutical wastewater. The optimum preparation conditions of thiamine-modified bentonite were studied. The experiments showed that the removals of COD (chemical oxygen demand) reached 47.98 % under optimal condition. The FTIR results indicated that bentonite has been modified by thiamine. The X-ray diffraction result showed that the interplanar distance of modified bentonite was increased by intercalating thiamine. From the analyses of the SEM photographs, it can be clearly observed that the bentonite, after thiamine insertion reaction, loses its foliated structure and exhibits a rougher surface. Among several isotherm equations, Langmuir and Freundlich adsorption isotherms were investigated. They were widely used to describe equilibrium data for water and wastewater treatment applications. Adsorption isotherms correlate well with the Langmuir isotherm model. Detailed isothermal and kinetic studies show that the modified bentonite removes organic pollutants from pharmaceutical wastewater by physical adsorption processes.

For deep geological disposal of high-level radioactive waste (HLW) in granite, the temperature on the HLW canisters is commonly designed to be lower than 100 °C. This criterion dictates the dimension of the repository. Based on the concept of HLW disposal in vertical boreholes, thermal process in the near field (host rock and buffer) surrounding HLW canisters has been simulated by using different methods. The results are drawn as follows: (a) the initial heat power of HLW canisters is the most important and sensitive parameter for evolution of temperature field; (b) the thermal properties and variations of the host rock, the engineered buffer, and possible gaps between canister and buffer and host rock are the additional key factors governing the heat transformation; (c) the gaps width and the filling by water or air determine the temperature offsets between them.

The primary challenge in wireless communication with energy harvesting devices is to efficiently utilize the harvesting energy such that the data packet transmission could be supported. This challenge stems from not only QoS requirement imposed by the wireless communication application, but also the energy harvesting dynamics and the limited battery capacity. Traditional solar predictable energy harvesting models are perturbed by prediction errors, which could deteriorate the energy management algorithms based on this models. To cope with these issues, we first propose in this paper a non-homogenous Markov chain model based on experimental data, which can accurately describe the solar energy harvesting process in contrast to traditional predictable energy models. Due to different timescale between the energy harvesting process and the wireless data transmission process, we propose a general framework of multiple timescale Markov decision process (MMDP) model to formulate the joint energy scheduling and transmission control problem under different timescales. We then derive the optimal control policies via a joint dynamic programming and value iteration approach. Extensive simulations are carried out to study the performances of the proposed schemes.

An over mode method for suppressing the RF breakdown on metal surface of resonant reflector cavity in powerful backward wave oscillator is investigated. It is found that the electric field is redistributed and electron emission is restrained with an over longitudinal mode cavity. Compared with the general device, a frequency band of about 5 times wider and a power capacity of at least 1.7 times greater are obtained. The results were verified in an X-band high power microwave generation experiment with the output power near 4 gigawatt.

Let S be a closed convex set of matrices and C be a given matrix. The matrix nearness problem considered in this paper is to find a matrix X in the set S at which max {|𝑥𝑖𝑗−𝑐𝑖𝑗|} reaches its minimum value. In order to solve the matrix nearness problem, the problem is reformulated to a min-max problem firstly, then the relationship between the min-max problem and a monotone linear variational inequality (LVI) is built. Since the matrix in the LVI problem has a special structure, a projection and contraction method is suggested to solve this LVI problem. Moreover, some implementing details of the method are presented in this paper. Finally, preliminary numerical results are reported, which show that this simple algorithm is promising for this matrix nearness problem.