1. Study of the Nucleating Effect of Nanozirconia Obtained by Green Synthesis on Low-Density Polyethylene (LDPE)
- Author
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Felipe Zanette da Silveira, Márcio Antônio Fiori, Tiago Elias Allievi Frizon, Luiz Fernando Belchior Ribeiro, Gustavo Lopes Colpani, and Humberto Gracher Riella
- Subjects
Degree of crystallinity ,Crystallization ,Thermal transitions ,Additives ,Nucleating agent ,Non-isothermal crystallization ,Materials of engineering and construction. Mechanics of materials ,TA401-492 - Abstract
The work evaluated the nucleating effect of nanometric zirconia (Zr-NP), obtained by the green sol-gel synthesis route using Euclea natalensis root extract as a reductant, in the low-density polyethylene (LDPE). The Zr-NP was characterized with x-ray diffraction (XRD) and transmission electron microscopy (TEM) which confirmed the presence of Zr-NP in the cubic crystalline phase with an average particle size of 6.73 nm. The Zr-NP was incorporated into the polymeric matrix by solubilization in concentrations ranging between 0 wt% and 6 wt%. Non-isothermal DSC analyzes demonstrated that a small addition of 1 wt% changes the degree of crystallinity from ~23% to ~56%, an increase of ~137%. The addition of Zr-NP also caused a small increase in crystallization and melting temperatures, and a large increase in the total crystallization time of LDPE.
- Published
- 2024
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