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Polarised IR reflectance spectra of κ-[Et4N](BEDT-TTF)4M(CN)6·3H2O (M=CoIII, FeIII, CrIII) single crystal and FT-NIR Raman spectra of powdered samples were measured as a function of temperature. The salts undergo two phase transitions at about T=240 and 150 K. From Raman spectra results that on decreasing temperature below 240 K a charge redistribution is gradually developed. The electronic dispersion in IR spectra was analysed with Drude–Lorentz model to determine the optical transport parameters. The phase transition at T=150 K has an influence on both electronic and vibrational spectra, in particular, a new energy gap is formed (charge gap) and a new band at 1342 cm−1, assigned to BEDT-TTF+ cations, is observed. [Copyright &y& Elsevier]

Radon is the second leading cause of lung cancer after smoking. Since the previous quantitative risk assessment of indoor radon conducted in France, input data have changed such as, estimates of indoor radon concentrations, lung cancer rates and the prevalence of tobacco consumption. The aim of this work was to update the risk assessment of lung cancer mortality attributable to indoor radon in France using recent risk models and data, improving the consideration of smoking, and providing results at a fine geographical scale. The data used were population data (2012), vital statistics on death from lung cancer (2008-2012), domestic radon exposure from a recent database that combines measurement results of indoor radon concentration and the geogenic radon potential map for France (2015), and smoking prevalence (2010). The risk model used was derived from a European epidemiological study, considering that lung cancer risk increased by 16% per 100 becquerels per cubic meter (Bq/m 3 ) indoor radon concentration. The estimated number of lung cancer deaths attributable to indoor radon exposure is about 3000 (1000; 5000), which corresponds to about 10% of all lung cancer deaths each year in France. About 33% of lung cancer deaths attributable to radon are due to exposure levels above 100 Bq/m 3 . Considering the combined effect of tobacco and radon, the study shows that 75% of estimated radon-attributable lung cancer deaths occur among current smokers, 20% among ex-smokers and 5% among never-smokers. It is concluded that the results of this study, which are based on precise estimates of indoor radon concentrations at finest geographical scale, can serve as a basis for defining French policy against radon risk.

Background: Exposures to high-dose ionizing radiation and high-dose rate ionizing radiation are established risk factors for childhood acute leukemia (AL). The risk of AL following exposure to lower doses due to natural background radiation (NBR) has yet to be conclusively determined., Methods: AL cases diagnosed over 1990-2009 (9,056 cases) were identified and their municipality of residence at diagnosis collected by the National Registry of Childhood Cancers. The Geocap study, which included the 2,763 cases in 2002-2007 and 30,000 population controls, was used for complementary analyses. NBR exposures were modeled on a fine scale (36,326 municipalities) based on measurement campaigns and geological data. The power to detect an association between AL and dose to the red bone marrow (RBM) fitting UNSCEAR (United Nations Scientific Committee on the Effects of Atomic Radiation) predictions was 92%, 45% and 99% for exposure to natural gamma radiation, radon and total radiation, respectively., Results: AL risk, irrespective of subtype and age group, was not associated with the exposure of municipalities to radon or gamma radiation in terms of yearly exposure at age reached, cumulative exposure or RBM dose. There was no confounding effect of census-based socio-demographic indicators, or environmental factors (road traffic, high voltage power lines, vicinity of nuclear plants) related to AL in the Geocap study., Conclusions: Our findings do not support the hypothesis that residential exposure to NBR increases the risk of AL, despite the large size of the study, fine scale exposure estimates and wide range of exposures over France. However, our results at the time of diagnosis do not rule out a slight association with gamma radiation at the time of birth, which would be more in line with the recent findings in the UK and Switzerland.

Knowledge of sedimentation rates in lakes is required to understand and quantify the geochemical processes involved in scavenging and remobilization of contaminants at the Sediment-Water Interface (SWI). The well-known 210 Pb excess ( 210 Pb ex ) method cannot be used for quantifying sedimentation rates in uranium-enriched catchments, as large amounts of 210 Pb produced by weathering and human activities may dilute the atmospheric 210 Pb. As an alternative dating method in these cases, we propose an original method based on 232 Th decay series nuclides. This study focuses on an artificial lake located in a granitic catchment downstream from a former uranium mine site. The exponential decay of 228 Ra excess ( 228 Ra ex ) with depth in two long cores yields sedimentation rates of 2.4 and 5.2 cm yr -1 respectively. These sedimentation rates lead to the attribution of the 137 Cs activity peak observed at depth to the Chernobyl fallout event of 1986. The 228 Ra ex method was also applied to two short cores which did not display the 137 Cs peak, and mean sedimentation rates of 2.1 and 4.0 cm y -1 were deduced. The proposed method may replace the classical radiochronological methods ( 210 Pb ex , 137 Cs) to determine sedimentation rates in granitic catchments., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Uncertainties on the mathematical modelling of radon ((222)Rn) transport in an unsaturated covered uranium mill tailings (UMT) soil at field scale can have a great impact on the estimation of the average measured radon exhalation rate to the atmosphere at the landfill cover. These uncertainties are usually attributed to the numerical errors from numerical schemes dealing with soil layering, and to inadequate modelling of physical processes at the soil/plant/atmosphere interface and of the soil hydraulic and transport properties, as well as their parameterization. In this work, we demonstrate how to quantify these uncertainties by comparing simulation results from two different numerical models to experimental data of radon exhalation rate and activity concentration in the soil-gas measured in a covered UMT-soil near the landfill site Lavaugrasse (France). The first approach is based on the finite volume compositional (i.e., water, radon, air) transport model TOUGH2/EOS7Rn (Transport Of Unsaturated Groundwater and Heat version 2/Equation Of State 7 for Radon; Saâdi et al., 2014), while the second one is based on the finite difference one-component (i.e., radon) transport model TRACI (Transport de RAdon dans la Couche Insaturée; Ferry et al., 2001). Transient simulations during six months of variable rainfall and atmospheric air pressure showed that the model TRACI usually overestimates both measured radon exhalation rate and concentration. However, setting effective unsaturated pore diffusivities of water, radon and air components in soil-liquid and gas to their physical values in the model EOS7Rn, allowed us to enhance significantly the modelling of these experimental data. Since soil evaporation has been neglected, none of these two models was able to simulate the high radon peaks observed during the dry periods of summer. However, on average, the radon exhalation rate calculated by EOS7Rn was 34% less than that was calculated by TRACI, and much closer to the measured one for physically-based soil radon diffusion models. Unlike TRACI, EOS7Rn was able to simulate qualitatively seasonal variations of both radon exhalation and concentration. These results show that EOS7Rn produces less numerical errors than TRACI, and can be considered as a promising model for predicting radon transport in the landfill, if soil evaporation is modelled and its numerical inversion for parameter estimation is realized., (Copyright © 2015 Elsevier Ltd. All rights reserved.)