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The fabrication of a bionic super-hydrophobic metallic surface without any low-surface-energy modification is investigated, in which picosecond laser ablation, electropolishing and electrodeposition are used sequentially. The micro-cone structure is formed via laser ablation, and then the nano-pyramid structure is electrodeposited on the micro-cone structure, resulting in a hierarchical structure that is important for achieving super-hydrophobicity on an intrinsically hydrophilic material surface. In this study, the surface morphology and material removal mechanism are discussed with respect to the laser-ablated surface and the subsequent electropolished/electrodeposited surfaces. The condensation experiments results show that both types of surfaces are associated with relatively high contact angles (CAs) at normal temperatures, and the CAs are 147° and 160°, respectively. However, the CA on the laser-ablated surfaces at low temperatures decreases to as less as 107°, which may be owing to the easy transition from Cassie state to a metastable state or even the Wenzel state, leading to a degraded hydrophobic surface. By contrast, the CA on the sequentially processed surfaces still maintains at 150°, which should be attributed to the densely distributed nano-scale structures. The sequentially processed surfaces also show excellent long-term durability. Furthermore, this technique has been employed for fabricating super-hydrophobic surfaces with CAs > 151° and the sliding angles (SAs)