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5. The role of natural science collections in the biomonitoring of environmental contaminants in apex predators in support of the EU’s zero pollution ambition

Author

Movalli, Paola, Koschorreck, Jan, Treu, Gabriele, Slobodnik, Jaroslav, Alygizakis, Nikiforos, Androulakakis, Andreas, Badry, Alexander, Baltag, Emanuel, Barbagli, Fausto, Bauer, Kevin, Biesmeijer, Koos, Borgo, Enrico, Cincinelli, Alessandra, Claßen, Daniela, Danielsson, Sara, Dekker, René W. R. J., Dietz, Rune, Eens, Marcel, Espín, Silvia, Eulaers, Igor, Frahnert, Sylke, Fuiz, Tibor I., García-Fernández, Antonio J., Fuchs, Jérôme, Gkotsis, Georgios, Glowacka, Natalia, Gómez-Ramírez, Pilar, Grotti, Marco, Hosner, Peter A., Johansson, Ulf, Jaspers, Veerle L. B., Koureas, Dimitris, Krone, Oliver, Kubin, Eero, Lefevre, Christine, Leivits, Madis, Lo Brutto, Sabrina, Lopes, Ricardo Jorge, Lourenço, Rui, Lymberakis, Petros, Madslien, Knut, Martellini, Tania, Mateo, Rafael, Nika, Maria-Christina, Osborn, Dan, Oswald, Peter, Pauwels, Olivier, Pereira, MGlória, Pezzo, Francesco, Sánchez-Virosta, Pablo, Sarajlić, Nermina, Shore, Richard F., Soler, Francisco, Sonne, Christian, Thomaidis, Nikolaos, Töpfer, Till, Väinölä, Risto, van den Brink, Nico, Vrezec, Al, Walker, Lee, Weigl, Stephan, Wernham, Chris, Woog, Friederike, Zorrilla, Irene, and Duke, Guy

Published
2022
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10. Correction to: Progress on bringing together raptor collections in Europe for contaminant research and monitoring in relation to chemicals regulation

Author

Movalli, Paola, Duke, Guy, Ramello, Gloria, Dekker, René, Vrezec, Al, Shore, Richard F., García-Fernández, Antonio, Wernham, Chris, Krone, Oliver, Alygizakis, Nikiforos, Badry, Alexander, Barbagli, Fausto, Biesmeijer, Koos, Boano, Giovanni, Bond, Alexander L., Choresh, Yael, Christensen, Jan Bolding, Cincinelli, Alessandra, Danielsson, Sara, Dias, Andreia, Dietz, Rune, Eens, Marcel, Espín, Silvia, Eulaers, Igor, Frahnert, Sylke, Fuiz, Tibor I., Gkotsis, Georgios, Glowacka, Natalia, Gómez-Ramírez, Pilar, Grotti, Marco, Guiraud, Michel, Hosner, Peter, Johansson, Ulf, Jaspers, Veerle L.B., Kamminga, Pepijn, Koschorreck, Jan, Knopf, Burkhard, Kubin, Eero, Brutto, Sabrina Lo, Lourenco, Rui, Martellini, Tania, Martínez-López, Emma, Mateo, Rafael, Nika, Maria-Christina, Nikolopoulou, Varvara, Osborn, Dan, Pauwels, Olivier, Pavia, Marco, Pereira, M. Glória, Rüdel, Heinz, Sanchez-Virosta, Pablo, Slobodnik, Jaroslav, Sonne, Christian, Thomaidis, Nikolaos, Töpfer, Till, Treu, Gabriele, Väinölä, Risto, Valkama, Jari, van der Mije, Steven, Vangeluwe, Didier, Warren, Ben H., and Woog, Friederike

Published
2019
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12. Chemical characterization of Arctic resuspended soils using trace elements and Sr and Pb isotope ratios

Author

Bruschi, Federica, Hobin, Kasper, Petroselli, Chiara, Moroni, Beatrice, Rotoloni, Alex Lorenzo, Masetti, Marco, Spolaor, Andrea, Grotti, Marco, Vanhaecke, Frank, and Cappelletti, David

Abstract

Mineral dust emission and transport can occur at high latitudes, impacting the Earth’s radiative budget and snow albedo. Even though the Arctic region is not often considered as a relevant dust source, in a context of arctic amplification, the importance of high latitude dust (HLD) sources is increasing. Although there is still a lack of knowledge concerning HLD sources and their impact, previous studies have shown how the dust produced there, affects the high Arctic.In this work, we have characterised both potential HLD source areas through the resuspension of soil samples and potential receptor areas through filtration of snow samples. The potential HDL sources considered are Iceland, Alaska and Svalbard Island (Norway), while the second ones, were obtained filtering snow, firn or ice sampled on different Svalbard glaciers. 31 trace elements (TEs) were quantified using tandem ICP-MS on the filters loaded by soil resuspension. Moreover, the Sr and Pb isotope ratios were measured on the whole set of samples using a MC-ICP-MS unit at the A&MS Lab at Ghent University. Specific TEs can be used to recognize different patterns in dust originating from regions characterized by a different geological composition and the analyses of two different isotopic systems is useful in order to differentiate eventual dust sources characterized by overlapping signatures for one of the two elements.The proposed methodology is therefore promising for tracing dust emission and transport in the high Arctic and potentially to reconstruct past circulation patterns by investigating the dust composition in ice cores., The 28th IUGG General Assembly (IUGG2023) (Berlin 2023)

Published
2023

13. Progress on bringing together raptor collections in Europe for contaminant research and monitoring in relation to chemicals regulation

Author

Movalli, Paola, Duke, Guy, Ramello, Gloria, Dekker, René, Vrezec, Al, Shore, Richard F., García-Fernández, Antonio, Wernham, Chris, Krone, Oliver, Alygizakis, Nikiforos, Badry, Alexander, Barbagli, Fausto, Biesmeijer, Koos, Boano, Giovanni, Bond, Alexander L., Choresh, Yael, Christensen, Jan Bolding, Cincinelli, Alessandra, Danielsson, Sara, Dias, Andreia, Dietz, Rune, Eens, Marcel, Espín, Silvia, Eulaers, Igor, Frahnert, Sylke, Fuiz, Tibor I., Gkotsis, Georgios, Glowacka, Natalia, Gómez-Ramírez, Pilar, Grotti, Marco, Guiraud, Michel, Hosner, Peter, Johansson, Ulf, Jaspers, Veerle L.B., Kamminga, Pepijn, Koschorreck, Jan, Knopf, Burkhard, Kubin, Eero, LoBrutto, Sabrina, Lourenco, Rui, Martellini, Tania, Martínez-López, Emma, Mateo, Rafael, Nika, Maria-Christina, Nikolopoulou, Varvara, Osborn, Dan, Pauwels, Olivier, Pavia, Marco, Pereira, M. Glória, Rüdel, Heinz, Sanchez-Virosta, Pablo, Slobodnik, Jaroslav, Sonne, Christian, Thomaidis, Nikolaos, Töpfer, Till, Treu, Gabriele, Väinölä, Risto, Valkama, Jari, van der Mije, Steven, Vangeluwe, Didier, Warren, Ben H., and Woog, Friederike

Published
2019
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14. Berlin statement on legacy and emerging contaminants in polar regions

Author

Ebinghaus, Ralf, primary, Barbaro, Elena, additional, Bengtson Nash, Susan, additional, de Avila, Cristina, additional, de Wit, Cynthia A., additional, Dulio, Valeria, additional, Felden, Janine, additional, Franco, Antonio, additional, Gandrass, Juergen, additional, Grotti, Marco, additional, Herata, Heike, additional, Hughes, Kevin A., additional, Jartun, Morten, additional, Joerss, Hanna, additional, Kallenborn, Roland, additional, Koschorreck, Jan, additional, Küster, Anette, additional, Lohmann, Rainer, additional, Wang, Zhanyun, additional, MacLeod, Matthew, additional, Pugh, Rebecca, additional, Rauert, Caren, additional, Slobodnik, Jaroslav, additional, Sühring, Roxana, additional, Vorkamp, Katrin, additional, and Xie, Zhiyong, additional

Published
2023
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16. Inter-laboratory study for the certification of trace elements in seawater certified reference materials NASS-7 and CASS-6

Author

Yang, Lu, Nadeau, Kenny, Meija, Juris, Grinberg, Patricia, Pagliano, Enea, Ardini, Francisco, Grotti, Marco, Schlosser, Christian, Streu, Peter, Achterberg, Eric P., Sohrin, Yoshiki, Minami, Tomoharu, Zheng, Linjie, Wu, Jingfeng, Chen, Gedun, Ellwood, Michael J., Turetta, Clara, Aguilar-Islas, Ana, Rember, Robert, Sarthou, Géraldine, Tonnard, Manon, Planquette, Hélène, Matoušek, Tomáš, Crum, Steven, and Mester, Zoltán

Published
2018
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21. Anthropogenic microparticles in the emerald rockcod Trematomus bernacchii (Nototheniidae): a 1998 snapshot from the Antarctica

Author

Bottari, Teresa, primary, Nibali, Valeria Conti, additional, Branca, Caterina, additional, Grotti, Marco, additional, Savoca, Serena, additional, Romeo, Teresa, additional, Spano, Nunziacarla, additional, Azzaro, Maurizio, additional, Greco, Silvestro, additional, D'Angelo, Giovanna, additional, and Mancuso, Monique, additional

Published
2022
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22. Precise determination of 204Pb-based isotopic ratios in environmental samples by quadrupole inductively coupled plasma mass spectrometry.

Author

Grotti, Marco, Vecchio, Maria Alessia, Gobbato, Dalia, Mataloni, Matilde, and Ardini, Francisco

Subjects
*INDUCTIVELY coupled plasma mass spectrometry, *QUADRUPOLE ion trap mass spectrometry, *ENVIRONMENTAL sampling, *QUADRUPOLES, *TIME series analysis
Abstract

The measurement of 204Pb-based isotopic ratios by quadrupole ICP-MS has been investigated. After multivariate optimization of the main operating conditions (sample uptake rate, spray chamber temperature, quadrupole voltages), the isotopic ratios were measured with an internal precision of ∼0.4% (% RSD, n = 12) at the Pb concentration of 1 μg L−1 and ∼0.2% at 10 μg L−1, close to the values usually reported for the measurement of major isotopes by quadrupole ICP-MS. The external precision was ∼0.3% (% RSD, n = 35) and the bias, after the correction of the isobaric overlapping of 204Hg on 204Pb, was lower than 2‰. The applicability of the developed method in the environmental field was demonstrated by the analysis of a time series of 84 atmospheric particulate samples collected from the Arctic and characterized by low Pb concentration, obtaining data in good agreement with the isotopic composition of airborne particulate deposited in central Greenland. [ABSTRACT FROM AUTHOR]

Published
2023
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40. Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018

Author

Bazzano, Andrea, Bertinetti, Stefano, Ardini, Francisco, Cappelletti, David, and Grotti, Marco

Subjects
isotope ratios, svalbard, atmosphere, analytical chemistry
Abstract

Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018. This repository contains source code and additional supplementary materials from our manuscript, "Supplementary material for Potential source areas for atmospheric lead reaching Ny-Ålesund from 2010 to 2018". Please, cite the main article as: Bazzano, A.; Bertinetti, S.; Ardini, F.; Cappelletti, D.; Grotti, M. Potential Source Areas for Atmospheric Lead Reaching Ny-Ålesund from 2010 to 2018. Atmosphere 2021, 12 (3): 388, doi:10.3390/atmos12030388.

Published
2021
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44. The Strange Case of Professor Promezio: A Cold Case in the Chemistry Museum

Author

Basso, Andrea, Alloisio, Marina, Carnasciali, Maria Maddalena, Grotti, Marco, and Vicini, Silvia

Subjects
lcsh:Chemistry, lcsh:QD1-999, lcsh:History (General) and history of Europe, lcsh:D, Inquiry-based Learning, History of Chemistry, Problem Solving, Forensic Chemistry, High School Introductory Chemistry
Abstract

Promezio is a famous Italian chemistry professor who is searching for missing element n. 61. In 1924 his laboratory is partially destroyed by a fire and he disappears. Almost one hundred years later high school students are recruited to investigate this strange case. “The strange case of Professor Promezio” represents a unicum in the panorama of laboratory activities for high school students: it is a cold case in which students are asked to investigate a fact that took place almost a century ago. Through the chemical analysis of different findings, the connection with historical events of that period, the study of the suspects' interrogation reports, the reproduction of the experiments conducted by Professor Promezio, the students will identify the possible culprit. A complex scientific problem is solved exploring different areas of chemistry and, in addition, interconnections with history, geography, ethics and other school subjects are deepened., Substantia, Vol. 4 No. 2 (2020)

Published
2020

45. Iron Speciation in Different Saharan Dust Advections and Effect of the

Author

Petroselli, Chiara, Moroni, Beatrice, Crocchianti, Stefano, Selvaggi, Roberta, Soggia, Francesco, Grotti, Marco, d'Acapito, Francesco, and Cappelletti, David

Subjects
filter blank, EXAFS, LISA, iron speciation, Saharan dust, Monte Martano (Central Italy), complex mixtures, selective leaching experiments, XANES
Abstract

In this work, we applied X-ray Absorption Spectroscopy (XAS) and selective leaching experiments for investigating iron speciation in different dust advections collected on different unwashed quartz fiber filters. XAS analysis evidenced a predominance of Fe(III) in 6-fold coordination for Saharan dust and a trend towards Fe(II) and 4-fold coordination in the order: Saharan dust, mixed Saharan, and non-Saharan aerosol samples. The role of the sampling substrate was evaluated explicitly, including in the analysis a set of blank filters. We were able to pinpoint the possible contribution to the overall XAS spectrum of the residual Fe on quartz as the concentration decrease towards the blank value. In particular, the filter substrate showed a negligible effect on the structural trend mentioned above. Furthermore, selective leaching experiments evidenced a predominance of the residual fraction on Fe speciation and indicated the lowest Fe concentrations for which the blank contribution is mu g for the first three steps of the procedure (releasing the acid-labile, reducible and oxidizable phases, respectively) and 10 mu g for the last step (dissolving the insoluble residuals).

Published
2020

47. Progress on bringing together raptor collections in Europe for contaminant research and monitoring in relation to chemicals regulation (vol 26, pg 20132, 2019)

Author

Movalli, Paola, Duke, Guy, Ramello, Gloria, Dekker, Rene, Vrezec, Al, Shore, Richard F., Garcia-Fernandez, Antonio, Wernham, Chris, Krone, Oliver, Alygizakis, Nikiforos, Badry, Alexander, Barbagli, Fausto, Biesmeijer, Koos, Boano, Giovanni, Bond, Alexander L., Choresh, Yael, Christensen, Jan Bolding, Cincinelli, Alessandra, Danielsson, Sara, Dias, Andreia, Dietz, Rune, Eens, Marcel, Espin, Silvia, Eulaers, Igor, Frahnert, Sylke, Fuiz, Tibor I., Gkotsis, Georgios, Glowacka, Natalia, Gomez-Ramirez, Pilar, Grotti, Marco, Guiraud, Michel, Hosner, Peter, Johansson, Ulf, Jaspers, Veerle L. B., Kamminga, Pepijn, Koschorreck, Jan, Knopf, Burkhard, Kubin, Eero, Lo Brutto, Sabrina, Lourenco, Rui, Martellini, Tania, Martinez-Lopez, Emma, Mateo, Rafael, Nika, Maria-Christina, Nikolopoulou, Varvara, Osborn, Dan, Pauwels, Olivier, Pavia, Marco, Pereira, M. Gloria, Ruedel, Heinz, Sanchez-Virosta, Pablo, Slobodnik, Jaroslav, Sonne, Christian, Thomaidis, Nikolaos, Toepfer, Till, Treu, Gabriele, Vainola, Risto, Valkama, Jari, van der Mije, Steven, Vangeluwe, Didier, Warren, Ben H., and Woog, Friederike

Published
2019

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