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The construction of a magnetron-based source for neutral metal vapors is presented. The first photoelectron spectroscopy experiments with the source using synchrotron radiation at MAX-lab, Sweden are described. Photoelectron spectra of atomic copper, silver, and nickel are reported with an 80 meV resolution for Cu and Ag, previously not achieved in experiments using synchrotron light. [ABSTRACT FROM AUTHOR]

The electronic structure of the strongly Coulomb correlated cuprate CuGeO3 has been calculated by the local-density-approximation method (LDA +U). The parameterUwas varied from 0 to 8 eV. The results of the band-structure calculations are compared with experimental data obtained by means of X-ray photoelectron and resonant X-ray emission spectroscopy methods (Cu Land O KX-ray emission spectra). It is established that a LDA +Ucalculation withU= 4 eV reproduces well the X-ray photoelectron and X-ray resonant emission spectral data. [ABSTRACT FROM AUTHOR]

Resonant soft X-ray emission (RSXE) spectra of NaV2O5, MoxV1−xO2 and V2O3 have been recorded for a series of excitation energies at resonances of the V L- and O K-absorption band. Resonant excitation allows us, firstly, to separate V 3d and O 2p projected density-of-states of the valence band and, secondly, to study charge-neutral low-energy excitations due to resonant inelastic X-ray scattering (RIXS). We found that both the V L- and the O K-emission spectra clearly show components originating from O 2p- and V 3d-states, reflecting the high degree of hybridization of the valence band in all compounds. At threshold excitation we observed that NaV2O5 spectra are dominated by RIXS whereas MoxV1−xO2 and V2O3 spectra show bandlike features, which may be due to differences in the correlation effects of the compounds. We compared the RSXE spectra with cluster model calculations, which gives a good account for NaV2O5 whereas the RSXE spectra of the other compounds show RIXS only at certain energies well above the threshold. In fact, we interpret the trend in the RSXE spectra of the MoxV1−xO2 compound system as a successive filling of the (rigid) V 3d band with increasing Mo content. [Copyright &y& Elsevier]