Search

Light emission by metals at room temperature is quenched by fast relaxation processes. Nevertheless, Mooradian reported in 1969 the observation of photoluminescence by metals pumped by a laser. Strikingly, while it is currently at the heart of many promising applications, this phenomenon is still poorly understood. In this work, we report a theory which reproduces quantitatively previously published experimental data. We first provide a general formula that relates the emitted power for a frequency, direction and polarization state to a sum over all transitions involving matrix elements, electronic distribution of all bands and the Green tensor. We then consider the case of intraband recombination and derive a closed-form expression of the emitted power depending only on macroscopic quantities. This formula, which is a generalization of Kirchhoff's law, answers many of the open questions related to intraband photoluminescence.

Chiral engineering of TeraHertz (THz) light fields and the use of the handedness of light in THz light-matter interactions promise many novel opportunities for advanced sensing and control of matter in this frequency range. Unlike previously explored methods, this is achieved here by leveraging the chiral properties of highly confined THz surface plasmon modes. More specifically, we design ultrasmall surface plasmonic-based THz cavities and THz metasurfaces that display significant and adjustable chiral behavior under modest magnetic fields (B<500mT). For such a prototypical example of non-hermitian and dispersive photonic system, we demonstrate the capacity to magnetic field-tune both the poles and zeros of cavity resonances, the two fundamental parameters governing their resonance properties. Alongside the observed handedness-dependent cavity frequencies, this highlights the remarkable ability to engineer chiral and tunable radiative couplings for THz resonators and metasurfaces. The extensive tunability offered by the surface plasmonic approach paves the way for the development of agile and multifunctional THz metasurfaces as well as the realization of ultrastrong chiral light-matter interactions at low energy in matter with potential far-reaching applications for the design of material properties., Comment: 41 pages, including supplementary information

Under high electrical current, some materials can emit electromagnetic radiation beyond incandescence. This phenomenon, referred to as electroluminescence, leads to the efficient emission of visible photons and is the basis of domestic lighting devices (e.g., light-emitting diodes). In principle, electroluminescence can lead to mid-infrared (mid-IR) emission of confined light-matter excitations called phonon-polaritons, resulting from the coupling of photons with crystal lattice vibrations (optical phonons). In particular, phonon-polaritons arising in the van der Waals crystal hexagonal boron nitride (hBN) exhibit hyperbolic dispersion, which enhances light-matter coupling. For this reason, electroluminescence of hyperbolic phonon-polaritons (HPhPs) has been proposed as an explanation for the peculiar radiative energy transfer within hBN-encapsulated graphene transistors. However, since HPhPs are confined, they are inaccessible in the far-field, so that any hint of electroluminescence is only based on indirect electronic signatures and needs to be confirmed by direct observation. Here, we demonstrate far-field mid-IR ({\lambda} = 6.5 {\mu}m) electroluminescence of HPhPs excited by strongly biased high-mobility graphene within a van der Waals heterostructure, and we quantify the associated radiative energy transfer through the material. The presence of HPhPs is revealed via far-field mid-IR spectroscopy due to their elastic scattering at discontinuities in the heterostructure. The associated radiative flux is quantified by mid-IR pyrometry of the substrate receiving the energy. This radiative energy transfer is shown to be reduced in hBN with nanoscale inhomogeneities, demonstrating the central role of the electromagnetic environment in this process., Comment: 30 pages including Extended Data and Supplementary Material (Main text: 8 pages, 4 figures)

Semiconductor colloidal nanocrystals are excellent light emitters in terms of efficiency and spectral control. Integrating them with a metasurface would pave the way to ultrathin photoluminescent devices with reduced amount of active material and performing complex functionalities such as beam shaping or polarization control. To design such a metasurface, a quantitative model of the emitted power is needed. Here, we report the design, fabrication and characterization of a $\approx$ 300 nm thick light-emitting device combining a plasmonic metasurface with an ensemble of nanoplatelets. The source has been designed with a new methodology based on a local form of Kirchhoff's law. The source displays record high directionality and brightness., Comment: Supplementary + manuscript

Electroluminescence, a non-thermal radiative process, is ubiquitous in semi-conductors and insulators but fundamentally precluded in metals. We show here that this restriction can be circumvented in high-quality graphene. By investigating the radiative emission of semi-metallic graphene field-effect transistors over a broad spectral range, spanning the near- and mid-infrared, we demonstrate direct far-field electroluminescence from hBN-encapsulated graphene in the mid-infrared under large bias in ambient conditions. Through a series of test experiments ruling out its incandescence origin, we determine that the electroluminescent signal results from the electrical pumping produced by interband tunneling. We show that the mid-infrared electroluminescence is spectrally shaped by a natural quarter-wave resonance of the heterostructure. This work invites a reassessment of the use of metals and semi-metals as non-equilibrium light emitters, and the exploration of their intriguing specificities in terms of carrier injection and relaxation, as well as emission tunability and switching speed., Comment: Main text (8 pages , 3 figures ) + Supplementary Information ( 19 pages , 19 figures)

Photon Bose-Einstein condensation and photon thermalisation have been largely studied with molecular gain media in optical cavities. Their observation with semiconductors has remained elusive despite a large body of experimental results and a very well established theoretical framework. We use this theoretical framework as a convenient platform to revisit photon Bose-Einstein condensation in the driven-dissipative regime and compare with the lasing regime. We discuss the thermalisation figures of merit and the different experimental procedures to asses thermalization. We compare the definitions of lasing and condensation thresholds. Finally, we explore the fluctuations of the system and their relation to the different regimes., Comment: 14 pages, 4 figures

Novel platforms interfacing trapped cold atoms and guided light in nanoscale waveguides are a promising route to achieve a regime of strong coupling between light and atoms in single pass, with applications to quantum non-linear optics and quantum simulation. A strong challenge for the experimental development of this emerging waveguide-QED field of research is to combine facilitated optical access for atom transport, atom trapping via guided modes and robustness to inherent nanofabrication imperfections. In this endeavor, here we propose to interface Rubidium atoms with a photonic-crystal waveguide based on a large-index GaInP slab. With a specifically tailored half-W1 design, we show that a large chiral coupling to the waveguide can be obtained and guided modes can be used to form two-color dipole traps for atoms at 116~nm from the edge of the structure. This optimized device should greatly improve the level of experimental control and facilitate the atom integration.

Driven by the need to develop efficient atom-photon interfaces, recent efforts have proposed replacing cavities by large arrays of cold atoms that can support subradiant or superradiant collective states. In practice, subradiant states are decoupled from radiation, which constitutes a hurdle to most applications. In this work, we study theoretically a protocol that bypasses this limit using a one dimensional (1D) chain composed of N three-level atoms in a V-shaped configuration. Throughout the protocol, the chain behaves as a time-varying metamaterial: enabling absorption, storage and on-demand emission in a spectrally and spatially controlled mode. Taking into account the quantum nature of atoms, we establish the boundary between the linear regime and the nonlinear regime. In the nonlinear regime, we demonstrate that doubly-excited states can be coherently transferred from superradiant to subradiant states, opening the way to the optical characterization of their entanglement., Comment: 13 pages, 10 figures

We report on the synthesis of hybrid light emitting particles with a diameter ranging between 100 and 500 nm, consisting in a compact semiconductor CdSe/CdS/CdZnS nanocrystal aggregate encapsulated by a controlled nanometric size silica and gold layers. We first characterize the Purcell decay rate enhancement corresponding to the addition of the gold nanoshell as a function of the particle size and find a good agreement with the predictions of numerical simulations. Then, we show that the contribution corresponding to F\"orster resonance energy transfer is inhibited.

Coupling quantum emitters and nanostructures, in particular cold atoms and waveguides, has recently raised a large interest due to unprecedented possibilities of engineering light-matter interactions. However, the implementation of these promising concepts has been hampered by various theoretical and experimental issues. In this work, we propose a new type of periodic dielectric waveguide that provides strong interactions between atoms and guided photons with an unusual dispersion. We design an asymmetric comb waveguide that supports a slow mode with a quartic (instead of quadratic) dispersion and an electric field that extends far into the air cladding for an optimal interaction with atoms. We compute the optical trapping potential formed with two guided modes at frequencies detuned from the atomic transition. We show that cold Rubidium atoms can be trapped as close as 100 nm from the structure in a 1.3-mK-deep potential well. For atoms trapped at this position, the emission into guided photons is largely favored, with a beta factor as high as 0.88 and a radiative decay rate into the slow mode 10 times larger than the free-space decay rate., Comment: 14 pages, 6 figures

Despite the fact that incandescent sources are usually spatially incoherent, it has been known for some time that a proper design of a thermal source can modify its spatial coherence. A natural question is whether it is possible to extend this analysis to electroluminescence and photoluminescence. A theoretical framework is needed to explore these properties. In this paper, we extend a general coherence-absorption relation valid at equilibrium to two non-equilibrium cases: luminescent bodies and anisothermal bodies. We then use this relation to analyse the differences between the isothermal and anisothermal cases and to study the near-field emission of an electroluminescent source., Comment: 16 pages, 3 figures

We study light absorption by a dipolar absorber in a given environment, which can be a nanoantenna or any complex inhomogeneous medium. From first-principle calculations, we derive an upper bound for the absorption, which decouples the impact of the environment from the one of the absorber. Since it is an intrinsic characteristic of the environment regardless of the absorber, it provides a good figure of merit to compare the ability of different systems to enhance absorption. We show that, in the scalar approximation, the relevant parameter is not the field enhancement but the ratio between the field enhancement and the local density of states. Consequently, a plasmonic structure supporting hot spots is not necessarily the best choice to enhance absorption. We also show that our theoretical results can be applied beyond the scalar approximation and the plane-wave illumination., Comment: 12 pages, 4 figures

We study theoretically the scattering of light by an ensemble of $N$ resonant atoms in a sub-wavelength volume. We consider the low intensity regime so that each atom responds linearly to the field. While $N$ non-interacting atoms would scatter $N^2$ more than a single atom, we find that $N$ interacting atoms scatter less than a single atom near resonance. In addition, the scattered power presents strong fluctuations, either from one realization to another or when varying the excitation frequency. We analyze this counter-intuitive behavior in terms of collective modes resulting from the light-induced dipole-dipole interactions. We find that for small samples, their properties are governed only by their volume when $N\gtrsim 20$., Comment: 5 pages

A one-dimensional atom -- an atomic system coupled to a single optical mode -- is central for many applications in optical quantum technologies. Here we introduce an effective one-dimensional atom consisting of two interacting quantum emitters coupled to a cavity mode. The dipole-dipole interaction and cavity coupling gives rise to optical resonances of tunable bandwidth with a constant mode coupling. Such versatility, combined with a dynamical control of the system, opens the way to many applications. It can be used to generate single photon light pulses with continuous variable encoding in the time-frequency domain and light states that show sub-Planck features. It can also be exploited to develop a versatile quantum memory of tunable bandwidth, another key ingredient for quantum networks. Our scheme ensures that all above functionalities can be obtained at record high efficiencies. We discuss practical implementation in the most advanced platform for quantum light generation, namely the semiconductor quantum dot system where all the technological tools are in place to bring these new concepts to reality.

By measuring the transmission of near-resonant light through an atomic vapor confined in a nano-cell we demonstrate a mesoscopic optical response arising from the non-locality induced by the motion of atoms with a phase coherence length larger than the cell thickness. Whereas conventional dispersion theory -- where the local atomic response is simply convolved by the Maxwell-Boltzmann velocity distribution -- is unable to reproduce the measured spectra, a model including a non-local, size-dependent susceptibility is found to be in excellent agreement with the measurements. This result improves our understanding of light-matter interaction in the mesoscopic regime and has implications for applications where mesoscopic effects may degrade or enhance the performance of miniaturized atomic sensors., Comment: 5 pages, 3 figures; Supplemental material : 9 pages, 4 figures

Quantum plasmonics lies at the intersection between nanophotonics and quantum optics. Genuine quantum effects can be observed with non-classical states such as Fock states and with entangled states. A N00N state combines both aspects: it is a quantum superposition state of a Fock state with N excitations in two spatial modes. Here we report the first observation of two-plasmon (N=2) N00N state interferences using a plasmonic beamsplitter etched on a planar interface between gold and air. We analyze in detail the role of losses at the beamsplitter and during the propagation along the metal/air interface. While the intrinsic losses of the beamsplitter are responsible for the emergence of quantum nonlinear absorption, we note that N00N states decay N times faster than classical states due to propagation losses.

Optical non-linearities at the single photon level are key features to build efficient photon-photon gates and to implement quantum networks. Such optical non-linearities can be obtained using an ideal two-level system such as a single atom coupled to an optical cavity. While efficient, such atom-photon interface however presents a fixed bandwidth, determined by the spontaneous emission time and thus the spectral width of the cavity-enhanced two-level transition, preventing an efficient transmission to bandwidth-mismatched atomic systems in a single quantum network. In the present work, we propose a tunable atom-photon interface making use of the direct dipole-dipole coupling of two slightly different atomic systems. We show that, when weakly coupled to a cavity mode and directly coupled through dipole-dipole interaction, the subradiant mode of two slightly-detuned atomic systems is optically addressable and presents a widely tunable bandwidth and single-photon nonlinearity.

We study theoretically the concept of homogenization in optics using an ensemble of randomly distributed resonant stationary atoms with density $\rho$. The ensemble is dense enough for the usual condition for homogenization, viz. $\rho\lambda^3 \gg 1$, to be reached. Introducing the coherent and incoherent scattered powers, we define two criteria to define the homogenization regime. We find that when the excitation field is tuned in a broad frequency range around the resonance, none of the criteria for homogenization is fulfilled, meaning that the condition $\rho\lambda^3\gg 1$ is not sufficient to characterize the homogenized regime around the atomic resonance. We interpret these results as a consequence of the light-induced dipole-dipole interactions between the atoms, which implies a description of scattering in terms of collective modes rather than as a sequence of individual scattering events. Finally, we show that, although homogenization can never be reached for a dense ensemble of randomly positioned laser-cooled atoms around resonance, it becomes possible if one introduces spatial correlations in the positions of the atoms or non-radiative losses, such as would be the case for organic molecules or quantum dots coupled to a phonon bath., Comment: 9 pages, 5 figures. Corrected mistakes in references

Quantum entanglement is a stunning consequence of the superposition principle. This universal property of quantum systems has been intensively explored with photons, atoms, ions and electrons. Collective excitations such as surface plasmons exhibit quantum behaviors. For the first time, we report an experimental evidence of non-local control of single plasmon interferences through entanglement of a single plasmon with a single photon. We achieved photon-plasmon entanglement by converting one photon of an entangled photon pair into a surface plasmon. The plasmon is tested onto a plasmonic platform in a Mach-Zehnder interferometer. A projective measurement on the polarization of the photon allows the non-local control of the interference state of the plasmon. Entanglement between particles of various natures paves the way to the design of hybrid systems in quantum information networks., Comment: 6 pages, 3 figures

Surface plasma waves are collective oscillations of electrons that propagate along a metal-dielectric interface. In the last ten years, several groups have reproduced fundamental quantum optics experiments with surface plasmons. Observation of single-plasmon states, waveparticle duality, preservation of entanglement of photons in plasmon-assisted transmission, and more recently, two-plasmon interference have been reported. While losses are detrimental for the observation of squeezed states, they can be seen as a new degree of freedom in the design of plasmonic devices, thus revealing new quantum interference scenarios. Here we report the observation of two-plasmon quantum interference between two freely-propagating, non-guided SPPs interfering on lossy plasmonic beamsplitters. As discussed in the article "Quantum optics of lossy beam splitters" by Barnett et al. (Phys. Rev. A 57, 2134 (1998)) , the presence of losses (scattering or absorption) relaxes constraints on the reflection and transmission factors of the beamsplitter, allowing the control of their relative phase. By using this degree of freedom, we are able to observe either coalescence or anticoalescence of identical plasmons., Comment: 5 pages, 4 figures, 1 table

Thermal emission can be conveniently described using Kirchhoff law which states that the emissivity is equal to the absorptivity for isothermal bodies. For a finite size system, absorptivity is replaced by an absorption cross section. Here, we study the link between thermal emission and absorption by a finite size object which is not isothermal. We define a local absorption rate for a given incident plane wave and we prove that it is equal to the local emissivity rate. Hence, Kirchhoff law can be extended to anisothermal media. A practical consequence is the possibility of analysing thermal radiation by a variety of non-equilibrium systems such as microwave radiation in geophysical remote sensing or X-UV radiation by plasmas. This result provides a theoretical framework to analyse thermal emission by hot electrons in quantum wells, tunnel junctions or graphene. It paves the way to the design of a new generation of incandescent emitters made of subwavelength hot emitters coupled to cold antennas. The antennas control the emission spectrum, direction and polarization of the emitted radiation., Comment: 6 pages, 2 figures