1. Revealing crucial effects of reservoir environment and hydrocarbon fractions on fluid behaviour in kaolinite pores
- Author
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Zhao, Rixin, Xue, Haitao, Lu, Shuangfang, Greenwell, H. Chris, and Erastova, Valentina
- Subjects
Condensed Matter - Materials Science - Abstract
Interactions of hydrocarbons (HCs) and clay surfaces are responsible for fluid behaviour within shale reservoirs. These interactions are affected by the diversity of HC components and the variations in environmental conditions. This study examines the interactions between kaolinite clay, featuring two distinct basal surfaces, and an array of HCs. We assess the impact of various molecular structures, functional groups, and environmental conditions (focusing on the reservoir temperature and pressure ranges) on the adsorption selectivity, surface packing, molecular alignment and orientation, and diffusion of HCs. Analyses of molecular interaction energies provide a quantitative elucidation of the adsorption mechanisms of HCs on the different kaolinite surfaces. Our findings suggest that molecular configuration, functional groups, and spatial effects dictate the distribution patterns of HCs for the different kaolinite surfaces. The differences in the interaction energy between various HCs with kaolinite reveal the adsorption strength of different HCs in the order of asphaltenes>heteroatomic HCs>saturated HCs>aromatic HCs. Furthermore, we observe that the adsorptive characteristics are highly temperature-sensitive; with increased temperatures markedly reducing the adsorption amount. Beyond a certain threshold, the effect of pressure rise on the fluid behaviour of HCs is non-negligible and is related to molecular packing and reduced mobility. Simulation results based on actual geological characteristics demonstrate notable adsorption disparities among hydrocarbon components on different kaolinite surfaces, influenced by competitive adsorption and clay surface interactions. Polar surfaces are predominantly occupied by heteroatomic HCs, whereas on non-polar surfaces, asphaltenes and heavy saturated HCs develop multi-layer adsorption structures, with molecules aligned parallel to the surface.
- Published
- 2024
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