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An approach to compute the polarizability tensor of magnetic nanoparticles having general ellipsoidal shape is presented. We find a surprisingly excellent quantitative agreement between calculated and experimental magneto-optical spectra measured in the polar Kerr configuration from nickel nanodisks of large size (exceeding 100 nm) with circular and elliptical shape. In spite of its approximations and simplicity, the formalism presented here captures the essential physics of the interplay between magneto-optical activity and the plasmonic resonance of the individual particle. The results highlight the key role of the dynamic depolarization effects to account for the magneto-optical properties of plasmonic nanostructures.

An approach to compute the polarizability tensor of magnetic nanoparticles having general ellipsoidal shape is presented. We find a surprisingly excellent quantitative agreement between calculated and experimental magneto-optical spectra measured in the polar Kerr configuration from nickel nanodisks of large size (exceeding 100 nm) with circular and elliptical shape. In spite of its approximations and simplicity, the formalism presented here captures the essential physics of the interplay between magneto-optical activity and the plasmonic resonance of the individual particle. The results highlight the key role of the dynamic depolarization effects to account for the magneto-optical properties of plasmonic nanostructures. © 2013 Optical Society of America.

The optical and magneto-optical properties of hybrid Co-SiOx systems are studied as a function of Co concentration. The structures were prepared by alternate depositions of SiOx thin films and layers of 10-nm-diameter Co nanoparticles produced by an Ion Cluster Source. Both optical and magneto-optical constants of the system gradually increase with the amount of Co, though maintaining low optical absorption values in the visible range. The experimental results are well reproduced assuming that the nanoparticles have a cobalt core (7-8 nm in diameter) surrounded by a cobalt oxide shell (1-2 nm thick). The magneto-optical activity versus optical absorption figure of merit of this system is compared with other magneto-optical dielectric systems. © Springer Science+Business Media B.V. 2010.

In this letter, we present both experimental and numerical studies of the magneto-optical (MO) properties of nickel infiltrated opals. Ni can show interesting MO properties that can be controlled by nanostructuration through colloidal crystals templating. Nanostructuration allows the coupling of light to surface plasmon modes of Ni, and a clear dependence of the MO response as a function of the structural parameters of the template has been observed. This dependence can be used in future tunable devices such as switchers or MO modulators. © 2011 American Institute of Physics.

We study the effect of global and local dielectric variations on the polarization conversion rps response of ordered nickel nanowires embedded in an alumina matrix. When considering local changes, we observe a non-monotonous behavior of the rps, its intensity unusually modified far beyond to what it is expected for a monotonous change of the whole refractive index of the embedding medium. This is related to the local redistribution of the electromagnetic field when a localized surface plasmon is excited. This finding may be employed to develop and improve new biosensing magnetoplasmonic devices.

In this work, we study the plasmon-mediated enhancement of the magneto-optical (MO) activity in the case of Au/Co/Au nanodisks as a function of the Co content. We show that both the spectral shape and amplitude of the complex polar Kerr rotation are modified by the relative amount of gold (diamagnetic) and cobalt (ferromagnetic). We demonstrate that such shape modification is dictated by the predominance of the absorptive or dispersive part of the MO constant in each material, which is intimately related to the origin of their MO activity.

We report that the effect of an external magnetic field on the propagation of surface plasmons can be effectively modified through the coupling between localized (LSP) and propagating (SPP) surface plasmons. When these plasmon modes do not interact, the main effect of the magnetic field is a modification of the wavevector of the SPP mode, leaving the LSP virtually unaffected. Once both modes start to interact, there is a strong variation of the magnetic field induced modification of the SPP dispersion curve and, simultaneously, the LSP mode becomes sensitive to the magnetic field.

The deposition of a dielectric overlayer on top of Au/Co/Au multilayer films can significantly enhance the magnetic field induced modulation of the surface plasmon polariton (SPP) wave vector. This enhancement is analyzed as a function of the thickness of the dielectric overlayer and the associated SPP electromagnetic field confinement and redistribution. The decrease in SPP propagation distance is taken into account by analyzing an adequate figure of merit.

In this Letter we show that nanostructures made out of pure noble metals can exhibit measurable magneto-optic activity at low magnetic fields. This phenomenon occurs when the localized surface plasmon resonance of the nanostructure is excited in the presence of a static magnetic field parallel to the propagation of incident light. The large magneto-optical response observed comes from an increase of the magnetic Lorentz force induced by the large collective movement of the conduction electrons in the nanostructures when the resonance is excited.

The main objective of the thesis is to study the phenomenology associated to nanostructures possessing surface plasmons and magneto-optical activity, the so-called magnetoplasmonic structures. These structures will be applicable in a broad spectrum of research and industrial areas. In particular, they are important elements in addressing tunability capabilities in plasmon-based nano-optical device. Also a new branch of biosensors with enhanced sensitivity are based on magneto-optical modulation. The magneto-plasmonic materials studied along this thesis offer the unique ability to control their properties in more than one way, since the magneto-optical response will be dramatically affected by the excitation of a plasmon, but also, their optical response can be actively tuned by means of an external agent: a magnetic field. We will mainly concentrate on the first aspect, where the different materials and structures considered will lead to the enhancement of the magneto-optical response due to the modifications of the electromagnetic field induced by plasmon resonances. In what follows, we will briefly describe the surface plasmon polaritons , pointing out their main characteristics. Since we are going to mainly analyze the magneto-optical response, we will devote Chapter 2 to describe in detail the different magneto-optical configurations and experimental setups.

Surface plasmon polariton (SPP) excitation effects on the magneto-optical (MO) activity of Au capped Ag/Co/Ag trilayers are studied as a function of Co thickness. An enhancement of the transverse MO Kerr signal under SPP excitation as compared with that obtained without SPP excitation is measured with a maximum value of 150 times obtained for the trilayer with 8 nm Co. Such enhancement on the magneto-optical activity due to SPP excitation is also five times higher than that obtained in Au/Co/Au trilayers in similar conditions. The lower optical absorption in the studied range and the sharper plasmon resonance of Ag vs Au are responsible for these values. On the other hand, magnetic field-induced SPP wavevector modulation (k/k)SPP is studied for these trilayers and compared both with previous results in the Au/Co/Au system as well as with the theory. In the wavelength considered here, the obtained values are similar for both Ag- and Au-based structures and on the order of 10−4, pinpointing the role of the magnetic layer on the SPP wave-vector modulation.

We present in this work our current understanding on magnetoplasmonic structures, that is, systems whose constituents exhibit simultaneously magnetic and plasmonic properties. We analyze both the influence of the plasmon resonance on the magneto-optical properties of the system and the ability of the magnetic field to modulate the plasmon properties. In particular we show how, in magnetoplasmonic systems sustaining localized or propagating surface plasmons, the associated electromagnetic field enhancement gives rise to an enhancement of the magneto-optical activity. On the other hand, we have analyzed the modulation of the propagating surface plasmon polariton wavevector in noble metal/ferromagnet/noble metal trilayers by an external magnetic field. These phenomena can be addressed as new concepts for the development of active plasmonic devices.

Experimental and theoretical evidence of plasmon-enhanced Kerr rotation in purely ferromagnetic membranes with sufficiently small dimensions to be out of extraordinary optical transmission conditions (45 nm pore diameter, 90nm lattice constant), is reported in this work. It is shown that the spectral location of the enhanced Kerr rotation region varies as the refractive index of the material inside the pore is modified. A similar behavior is obtained if the pore radius changes while keeping the pore concentration unchanged. Those are clear signatures indicating that localized surface plasmon resonances propagating along the pores govern the magneto-optical response of the membrane

A nanostructure composed of Au/Co/Au nanodisks is fabricated. The behaviour of this system is completely different to that of a continuous Au/Co/Au layer. There is a relative enhancement of the Kerr rotation and ellipticity, as well as a strong dependence on the particle size. The origin of these properties is the plasmonlike structure that is supported by the nanosandwiches.

We study how the magneto-optical activity in polar configuration of continuous Au/Co/Au trilayers is affected by the excitation of localized plasmon resonances of an array of Au nanodiscs fabricated on top of them over a dielectric SiO2 spacer. We show that the effect of the nanodiscs array is twofold. First, it optimizes the absorption of light at specific photon energies corresponding to the localized surface plasmon excitation of the array, modifying the reflectivity of the system (we define this effect as the purely optical contribution). Second, upon localized plasmon resonance excitation, the electromagnetic field in the whole system is redistributed, and an enhanced magneto-optical activity occurs at those energies where the electromagnetic field in the magnetic layer is increased (this effect is identified as the purely magneto-optical contribution of the nanodiscs array).

A complete magneto-optical characterization of Pt capped Ag-Co-Ag sputtered trilayers with varying Co thickness is presented. Polar Kerr rotation and ellipticity exhibit a gradual increase in signal as the Co layer gets thicker, with a sharp feature around 3.75 eV due to the bulk Ag plasmon resonance. The transverse Kerr signal of such trilayers is strongly affected by the surface plasmon polariton (SPP) resonance excitation when measured in the Kretschmann configuration, with a maximum transverse Kerr effect for around 2 nm Co thickness which corresponds to the optimum SPP excitation. This behavior is in contrast with the monotonous increase in transverse Kerr signal with Co thickness measured when the SPP is not excited. These results are in qualitative agreement with simulations using the transfer matrix formalism, the discrepancies mainly being due to the deviation from 2-D growth of the system and possible Ag and Co oxidation effects.