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GNSS Radio Occultation (RO) refractivity climatologies for the stratosphere can be obtained from the Abel inversion of monthly average bending-angle profiles. The averaging of large numbers of profiles suppresses random noise and this, in combination with simple exponential extrapolation above an altitude of 80 km, circumvents the need for a "statistical optimization" step in the processing. Using data from the US-Taiwanese COSMIC mission, which provides ~ 1500-2000 occultations per day, it has been shown that this Average-Profile Inversion (API) technique provides a robust method for generating stratospheric refractivity climatologies. Prior to the launch of COSMIC in mid-2006, the data records rely on data from the CHAMP mission. In order to exploit the full range of available RO data, the usage of CHAMP data is also required. CHAMP only provided~ 200 profiles per day, and the measurements were noisier than COSMIC. As a consequence, the main research question in this study was to see if the average bending angle approach is also applicable to CHAMP data. Different methods for suppression of random noise - statistical and through data quality pre-screening - were tested. The API retrievals were compared with the more conventional approach of averaging individual refractivity profiles, produced with the implementation of statistical optimization used in the EUMETSAT Radio Occultation Meteorology Satellite Application Facility (ROM SAF) operational processing. In this study it is demonstrated that the API retrieval technique works well for CHAMP data, enabling the generation of long-term stratospheric RO climate data records from August 2001 and onward. The resulting CHAMP refractivity climatologies are found to be practically identical to the standard retrieval at the DMI below altitudes of 35 km. Between 35 km to 50km the differences between the two retrieval methods started to increase, showing largest differences at high latitudes and high altitudes. Furthermore, in the winter hemisphere high latitude region, the biases relative to ECMWF were generally smaller for the new approach than for the standard retrieval. [ABSTRACT FROM AUTHOR]

Global Positioning System (GPS) radio occultation (RO) provides continuous observations of the Earth's atmosphere since 2001 with global coverage, all-weather capability, and high accuracy and vertical resolution in the upper troposphere and lower stratosphere (UTLS). Precise time measurements enable long-term stability but careful processing is needed. Here we provide climate-oriented atmospheric scientists with multicenter-based results on the long-term stability of RO climatological fields for trend studies. We quantify the structural uncertainty of atmospheric trends estimated from the RO record, which arises from current processing schemes of six international RO processing centers, DMI Copenhagen, EUM Darmstadt, GFZ Potsdam, JPL Pasadena, UCAR Boulder, and WEGC Graz. Monthly-mean zonal-mean fields of bending angle, refractivity, dry pressure, dry geopotential height, and dry temperature from the CHAMP mission are compared for September 2001 to September 2008. We find that structural uncertainty is lowest in the tropics and mid-latitudes (50° S to 50° N) from 8 km to 25 km for all inspected RO variables. In this region, the structural uncertainty in trends over 7 yr is < 0.03% for bending angle, refractivity, and pressure, < 3m for geopotential height of pressure levels, and < 0.06K for temperature; low enough for detecting a climate change signal within about a decade. Larger structural uncertainty above about 25 km and at high latitudes is attributable to differences in the processing schemes, which undergo continuous improvements. Though current use of RO for reliable climate trend assessment is bound to 50° S to 50° N, our results show that quality, consistency, and reproducibility are favorable in the UTLS for the establishment of a climate benchmark record. [ABSTRACT FROM AUTHOR]

The article presents a study on simplified scheme for producing global navigation satellite systems radio occultation (GNSS RO) refractivity climatologies. It used several data analysis methods such as Abel transforms, statistical optimization (SO) and ionospheric noise variance estimation. Results show that the differences in the optimization processes for a source of GNSS-RO differences.

Historically, observational information about atmospheric temperature has been limited due to a lack of suitable measurements. Recent advances in satellite observations provide new insight into the fine structure of the free atmosphere, with the upper troposphere and lower stratosphere comprising essential components of the climate system. This is a prerequisite for understanding the complex processes of this part of the atmosphere, which is also known to have a large impact on surface climate. With unprecedented resolution, latest climate observations reveal a dramatic warming of the atmosphere. The tropical upper troposphere has already warmed about 1 K during the first two decades of the 21st century. The tropospheric warming extends into the lower stratosphere in the tropics and southern hemisphere mid-latitudes, forming a prominent hemispheric asymmetry in the temperature trend structure. Together with seasonal trend patterns in the stratosphere, this indicates a possible change in stratospheric circulation., (© 2023. The Author(s).)

The chemical composition of complex inorganic materials, such as copper concentrate, may influence the economics of their further processing because most smelters, and particularly the producers of high-purity electrolyte copper, have strict limitations for the permissible concentration of impurities. These components might be harmful to the quality of the products, impair the production process and be hazardous to the environment. The goal of the present work is the development of a method for the determination of fluorine in copper concentrate using high-resolution graphite furnace molecular absorption spectrometry and direct solid sample analysis. The molecular absorption of the diatomic molecule CaF was measured at 606.440nm. The molecule CaF was generated by the addition of 200µg Ca as the molecule-forming reagent; the optimized pyrolysis and vaporization temperatures were 900°C and 2400°C, respectively. The characteristic mass and limit of detection were 0.5ng and 3ng, respectively. Calibration curves were established using aqueous standard solutions containing the major components Cu, Fe, S and the minor component Ag in optimized concentrations. The accuracy of the method was verified using certified reference materials. Fourteen copper concentrate samples from Chile and Australia were analyzed to confirm the applicability of the method to real samples; the concentration of fluorine ranged from 34 to 5676mgkg -1 . The samples were also analyzed independently at Analytik Jena by different operators, using the same equipment, but different target molecules, InF and GaF, and different operating conditions; but with a few exceptions, the results agreed quite well. The results obtained at Analytik Jena using the GaF molecule and our results obtained with CaF, with one exception, were also in agreement with the values informed by the supplier of the samples, which were obtained using ion selective electrode potentiometry after alkaline fusion. A comparison will also be made for the three target molecules and the three independently developed methods for the determination of fluorine, although all three methods used direct solid sample analysis., (Copyright © 2017 Elsevier B.V. All rights reserved.)

Driven by increasing demand for the monitoring of industrial perfluorinated compounds (PFCs), the identification of novel fluorine containing compounds (FOCs) and the tracking of organofluorine drugs and their degradation products, there is a clear need for sensitive, fluorine-specific detection of unknown FOCs. Here we report the first ever direct fluorine-specific (speciation) method; capable of individually detecting untargeted FOCs in environmental and biological samples through the application of continuum source molecular absorption spectrometry (CS-MAS) using a commercial CS-AAS. Two model FOCs (2,4,6, trifluorobenzoic acid (TFBA) and 5-fluoroindol-5-carboxylic acid (FICA)) were used, achieving fluorine-specific detection across a range of 0.1 to 300 ng/mL fluorine, corresponding to a limit of detection of 4 pg F and 5.26 nM for both compounds. Both TFBA and FICA showed a similar response to CS-MAS detection, potentially enabling the quantification of fluorine content in novel FOCs without having molecular standards available. This paper also reports the use of reverse-phase high performance liquid chromatography (RP-HPLC) coupled off-line with CS-MAS for the identification of single organofluorines in a mixture of FOCs via fraction collection. The linear range of both FOCs was determined to be from 1 to 500 ng/mL. The limits of detection of those species were just above 1 ng/mL (100 pg) and can therefore compete with targeted analytical methods such as ESI-MS. Finally, as a proof of principle the analysis of a fluoride-containing groundwater sample from Ghana demonstrated that this method can be used in the detection of novel FOCs, with identification achieved through parallel ESI-MS. Coupled HPLC-CS-MAS/ESI-MS is the first analytical methodology capable of selectively detecting and identifying novel FOCs, making possible the quantification of all fluorine containing compounds in one sample. This is the necessary analytical requirement to perform fluoronomics.

A fast and reliable method has been developed for the determination of total and soluble fluorine in toothpaste, important quality control parameters in dentifrices. The method is based on the molecular absorption of gallium mono-fluoride, GaF, using a commercially available high-resolution continuum source atomic absorption spectrometer. Transversely heated platform tubes with zirconium as permanent chemical modifier were used throughout. Before each sample injection, a palladium and zirconium modifier solution and a gallium reagent were deposited onto the graphite platform and thermally pretreated to transform them into their active forms. The samples were only diluted and introduced directly into the graphite tube together with additional gallium reagent. Under these conditions the fluoride was stable up to a pyrolysis temperature of 550 °C, and the optimum vaporization (molecule formation) temperature was 1550 °C. The GaF molecular absorption was measured at 211.248 nm, and the limits of detection and quantification were 5.2 pg and 17 pg, respectively, corresponding to a limit of quantification of about 30 μg g(-1) (ppm) F in the original toothpaste. The proposed method was used for the determination of total and soluble fluorine content in toothpaste samples from different manufactures. The samples contained different ionic fluoride species and sodium monofluorophosphate (MFP) with covalently bonded fluorine. The results for total fluorine were compared with those obtained with a modified conventional headspace gas chromatographic procedure. Accuracy and precision of the two procedures were comparable, but the proposed procedure was much less labor-intensive, and about five times faster than the latter one., (Copyright © 2010 Elsevier B.V. All rights reserved.)