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Quantum batteries have demonstrated remarkable charging properties, showing that a quantum advantage is possible in the realm of quantum thermodynamics. However, finding an effective strategy to store energy for long periods remains crucial in these systems. Here, we investigate different configurations of a waveguide-QED system acting as a quantum battery and show that, in this context, collective effects can slow down the self-discharging time of the battery, thus improving the storage time. Specifically, when the artificial atoms of the array are arranged randomly, the energy and ergotropy of the optical system are shown to decay at a subexponential rate over long periods, in contrast to the energy decay of a single atom in a waveguide. In the case of atoms arranged in an ordered lattice, collective effects slow down dissipative discharging only for a specific lattice spacing. Thus, in both configurations, collective effects can be used to boost the energy-protection properties of optical systems., Comment: 10 pages, 5 figures

We study the influence of single-atom dissipation and dephasing noise on the performance of Dicke and Tavis-Cummings quantum batteries, where the electromagnetic field of the cavity hosting the system acts as a charger. For these models a genuine charging process can only occur in the transient regime. Indeed, unless the interaction with the environment is cut off, the asymptotic energy of the battery is solely determined by the environment and does not depend on the initial energy of the electromagnetic field. We numerically estimate the fundamental figures of merit for the model, including the time at which the battery reaches its maximum ergotropy, the average energy, and the energy that needs to be used to switch the battery-charger interaction on and off. Depending on the scaling of the coupling between the battery and the charger, we show that the model can still exhibit a subextensive charging time. However, for the Dicke battery, this effect comes with a higher cost when switching the battery-charger interaction on and off. We also show that as the number of battery constituents increases, both the Dicke and Tavis-Cummings models become asymptotically free, meaning the amount of energy that is not unitarily extractable becomes negligible. We obtain this result numerically and demonstrate analytically that it is a consequence of the symmetry under permutation of the model. Finally, we perform simulations for different values of the detuning, showing that the optimal regime for the Dicke battery is off-resonance, in contrast to what is observed in the Tavis-Cummings case., Comment: 15 pages, 10 figures

Finding a quantum battery model that displays a genuine quantum advantage, while being prone to experimental fabrication, is an extremely challenging task. In this Letter we propose a deceptively simple quantum battery model that displays a genuine quantum advantage, saturating the quantum speed limit. It consists of two harmonic oscillators (the charger and the battery), coupled during the non-equilibrium charging dynamics by a non-linear interaction. We first present the model, then certify the genuine quantum advantage, and finally briefly discuss how the battery can be fabricated through the use of superconducting circuits., Comment: 7 pages, 1 figure

We investigate the scaling of the fermionic logarithmic negativity (FLN) between complementary intervals in the steady state of a driven-dissipative tight-binding critical chain, coupled to two thermal reservoirs at its edges. We compare the predictions of three different master equations, namely a nonlocal Lindblad equation, the Redfield equation, and the recently proposed universal Lindblad equation (ULE). Within the nonlocal Lindblad equation approach, the FLN grows logarithmically with the subsystem size $\ell$, for any value of the system-bath coupling and of the bath parameters. This is consistent with the logarithmic scaling of the mutual information analytically demonstrated in [Phys. Rev. B 106, 235149 (2022)]. In the ultraweak-coupling regime, the Redfield equation and the ULE exhibit the same logarithmic increase; such behavior holds even when moving to moderately weak coupling and intermediate values of $\ell$. However, when venturing beyond this regime, the FLN crosses over to superlogarithmic scaling for both equations., Comment: 13 pages, 6 figures

We propose a platform for implementing a universal, globally driven quantum computer based on a 2D ladder hosting three different species of superconducting qubits. In stark contrast with the existing literature, our scheme exploits the always-on longitudinal ZZ coupling. The latter, combined with specific driving frequencies, enables the reach of a blockade regime, which plays a pivotal role in the computing scheme.

Given a bipartite quantum system in an energy eigenstate, the dynamical description for one component can be derived via entanglement using the other component as a clock. This is the essence of the Page and Wootters mechanism. Moreover, if the clock is subject to a gravitational-like interaction, relative time evolution is then described by a Time-Dilated Schr\"odinger equation, in which the so-called Redshift Operator describes a purely quantum effect, analogue to gravitational time-dilation. Here we adopt a non-perturbative approach and present a finite-dimensional generalisation of this mechanism, expressing the quantum time-dilation effect as an effective interaction involving previously non-interacting system components. We name this a Time-Dilation induced Interaction Transfer (TiDIT) mechanism and discuss an example using two coupled spins as a quantum clock model. Our approach is suitable for implementations in current quantum technology and provides a new tool for exploring gravity at the intersection with quantum physics.

Several combinatorial optimization problems can be solved with NISQ devices once that a corresponding quadratic unconstrained binary optimization (QUBO) form is derived. The aim of this work is to drastically reduce the variables needed for these QUBO reformulations in order to unlock the possibility to efficiently obtain optimal solutions for a class of optimization problems with NISQ devices. This is achieved by introducing novel tools that allow an efficient use of slack variables, even for problems with non-linear constraints, without the need to approximate the starting problem. We divide our new techniques in two independent parts, called the iterative quadratic polynomial and the master-satellite methods. Hence, we show how to apply our techniques in case of an NP-hard optimization problem inspired by a real-world financial scenario called Max-Profit Balance Settlement. We follow by submitting several instances of this problem to two D-wave quantum annealers, comparing the performances of our novel approach with the standard methods used in these scenarios. Moreover, this study allows to appreciate several performance differences between the D-wave Advantage and Advantage2 quantum annealers., Comment: Minor changes

Quantum state tomography, aimed at deriving a classical description of an unknown state from measurement data, is a fundamental task in quantum physics. In this work, we analyse the ultimate achievable performance of tomography of continuous-variable systems, such as bosonic and quantum optical systems. We prove that tomography of these systems is extremely inefficient in terms of time resources, much more so than tomography of finite-dimensional systems: not only does the minimum number of state copies needed for tomography scale exponentially with the number of modes, but it also exhibits a dramatic scaling with the trace-distance error, even for low-energy states, in stark contrast with the finite-dimensional case. On a more positive note, we prove that tomography of Gaussian states is efficient. To accomplish this, we answer a fundamental question for the field of continuous-variable quantum information: if we know with a certain error the first and second moments of an unknown Gaussian state, what is the resulting trace-distance error that we make on the state? Lastly, we demonstrate that tomography of non-Gaussian states prepared through Gaussian unitaries and a few local non-Gaussian evolutions is efficient and experimentally feasible., Comment: In the fourth version of the paper, we corrected a typo in Lemma S55

Adopting a statistical approach we study the degradation of entanglement of a quantum system under the action of an ensemble of randomly distributed Markovian noise. This enables us to address scenarios where only limited information is available on the mechanisms that rule the noisy evolution of the model. As an application, we characterize the statistic of entanglement deterioration for a quantum memory formed by $n$ qudits that undergo randomly distributed local, uniform, Markovian noise evolution., Comment: 28 pages, 14 figures

The recent advances in machine learning hold great promise for the fields of quantum sensing and metrology. With the help of reinforcement learning, we can tame the complexity of quantum systems and solve the problem of optimal experimental design. Reinforcement learning is a powerful model-free technique that allows an agent, typically a neural network, to learn the best strategy to reach a certain goal in a completely a priori unknown environment. However, in general, we know something about the quantum system with which the agent is interacting, at least that it follows the rules of quantum mechanics. In quantum metrology, we typically have a model for the system, and only some parameters of the evolution or the initial state are unknown. We present here a general machine learning technique that can optimize the precision of quantum sensors, exploiting the knowledge we have on the system through model-aware reinforcement learning. This framework has been implemented in the Python package qsensoropt, which is able to optimize a broad class of problems found in quantum metrology and quantum parameter estimation. The agent learns an optimal adaptive strategy that, based on previous outcomes, decides the next measurements to perform. We have explored some applications of this technique to NV centers and photonic circuits. So far, we have been able to certify better results than the current state-of-the-art controls for many cases. The machine learning technique developed here can be applied in all scenarios where the quantum system is well-characterized and relatively simple and small. In these cases, we can extract every last bit of information from a quantum sensor by appropriately controlling it with a trained neural network. The qsensoropt software is available on PyPI and can be installed with pip., Comment: 4 pages, 2 figures

An important practical problem in the field of quantum metrology and sensors is to find the optimal sequences of controls for the quantum probe that realize optimal adaptive estimation. In Belliardo et al., arXiv:2312.16985 (2023), we solved this problem in general, by introducing a procedure capable of optimizing a wide range of tasks in quantum metrology and estimation by combining model-aware reinforcement learning with Bayesian inference. We take a model-based approach to the optimisation where the physics describing the system is explicitly taken into account in the training through automatic differentiation. In this follow-up paper we present some applications of the framework. The first family of examples concerns the estimation of magnetic fields, hyperfine interactions, and decoherence times for electronic spins in diamond. For these examples, we perform multiple Ramsey measurements on the spin. The second family of applications concerns the estimation of phases and coherent states on photonic circuits, without squeezing elements, where the bosonic lines are measured by photon counters. This exposition showcases the broad applicability of the method, which has been implemented in the qsensoropt library released on PyPI, which can be installed with pip., Comment: 35 pages, 16 figures

We study the possibility of deterministic protocols for extracting work from quantum systems. Focusing on the two-point measurement work extraction scenario, we prove that, with enough copies of the system, such zero-fluctuation protocols always exist if the Hamiltonian has a rational spectrum. Leveraging this result, we show that for any Hamiltonian, it is possible to construct an unitary driving protocol on sufficiently many copies of the system with work fluctuations strictly bounded within an arbitrary interval $\pm \delta$, albeit requiring exponentially many copies in $1/\delta$., Comment: 19 pages, 5 figures. Comments welcome!

Quantum optical systems are typically affected by two types of noise: photon loss and dephasing. Despite extensive research on each noise process individually, a comprehensive understanding of their combined effect is still lacking. A crucial problem lies in determining the values of loss and dephasing for which the resulting loss-dephasing channel is anti-degradable, implying the absence of codes capable of correcting its effect or, alternatively, capable of enabling quantum communication. A conjecture in [Quantum 6, 821 (2022)] suggested that the bosonic loss-dephasing channel is anti-degradable if and only if the loss is above $50\%$. In this paper we refute this conjecture, specifically proving that for any value of the loss, if the dephasing is above a critical value, then the bosonic loss-dephasing channel is anti-degradable. While our result identifies a large parameter region where quantum communication is not possible, we also prove that if two-way classical communication is available, then quantum communication -- and thus quantum key distribution -- is always achievable, even for high values of loss and dephasing., Comment: 35 pages, 4 figures

A fundamental problem in quantum thermodynamics is to properly quantify the work extractable from out-of-equilibrium systems. While for closed systems, maximum quantum work extraction is defined in terms of the ergotropy functional, this question is unclear in open systems interacting with an environment. The concept of local ergotropy has been proposed, but it presents several problems, such as it is not guaranteed to be non-increasing in time. Here we introduce the concept of extended local ergotropy by exploiting the free evolution of the system-environment compound. At variance with the local ergotropy, the extended local ergotropy is greater, is non-increasing in time, and activates the potential of work extraction in many cases. We then concentrate on specific schemes in which we alternate repeated local unitaries and free system-environment evolution. We provide examples based on the Jaynes-Cummings model, presenting practical protocols and analytic results that serve as proof of principle for the aforementioned advantages., Comment: 4 pages, 2 figures + supplemental material. Comments welcome

The no-go theorem regarding unconditionally secure Quantum Bit Commitment protocols is a relevant result in quantum cryptography. Such result has been used to prove the impossibility of unconditional security for other protocols, such as Quantum Oblivious Transfer or One-Sided Two Party Computation. In this paper, we formally define two non-deterministic versions of Quantum Private Queries, a protocol addressing the Symmetric-Private Information Retrieval problem. We show that the strongest variant of such scheme is formally equivalent to Quantum Bit Commitment, Quantum Oblivious Transfer and One-Sided Two Party Computation protocols. This equivalence serves as conclusive evidence of the impracticality of achieving unconditionally secure Strong Probabilistic Quantum Private Queries.

Quantum sensors offer control flexibility during estimation by allowing manipulation by the experimenter across various parameters. For each sensing platform, pinpointing the optimal controls to enhance the sensor's precision remains a challenging task. While an analytical solution might be out of reach, machine learning offers a promising avenue for many systems of interest, especially given the capabilities of contemporary hardware. We have introduced a versatile procedure capable of optimizing a wide range of problems in quantum metrology, estimation, and hypothesis testing by combining model-aware reinforcement learning (RL) with Bayesian estimation based on particle filtering. To achieve this, we had to address the challenge of incorporating the many non-differentiable steps of the estimation in the training process, such as measurements and the resampling of the particle filter. Model-aware RL is a gradient-based method, where the derivatives of the sensor's precision are obtained through automatic differentiation (AD) in the simulation of the experiment. Our approach is suitable for optimizing both non-adaptive and adaptive strategies, using neural networks or other agents. We provide an implementation of this technique in the form of a Python library called qsensoropt, alongside several pre-made applications for relevant physical platforms, namely NV centers, photonic circuits, and optical cavities. This library will be released soon on PyPI. Leveraging our method, we've achieved results for many examples that surpass the current state-of-the-art in experimental design. In addition to Bayesian estimation, leveraging model-aware RL, it is also possible to find optimal controls for the minimization of the Cram\'er-Rao bound, based on Fisher information., Comment: 42 pages, 9 figures

The development of quantum repeaters poses significant challenges in terms of cost and maintenance, prompting the exploration of alternative approaches for achieving long-distance quantum communication. In the absence of quantum repeaters and under the memoryless (iid) approximation, it has been established that some fundamental quantum communication tasks are impossible if the transmissivity of an optical fibre falls below a known critical value, resulting in a severe constraint on the achievable distance for quantum communication. However, if the memoryless assumption does not hold -- e.g. when input signals are separated by a sufficiently short time interval -- the validity of this limitation is put into question. In this paper we introduce a model of optical fibre that can describe memory effects for long transmission lines. We then solve its quantum capacity, two-way quantum capacity, and secret-key capacity exactly. By doing so, we show that -- due to the memory cross-talk between the transmitted signals -- reliable quantum communication is attainable even for highly noisy regimes where it was previously considered impossible. As part of our solution, we find the critical time interval between subsequent signals below which quantum communication, two-way entanglement distribution, and quantum key distribution become achievable., Comment: 36 pages, 7 figures

A relevant problem in the theory of open quantum systems is the lack of complete positivity of dynamical maps obtained after weak-coupling approximations, a famous example being the Redfield master equation. A number of approaches exist to recover well-defined evolutions under additional Markovian assumptions, but much less is known beyond this regime. Here we propose a numerical method to cure the complete-positivity violation issue while preserving the non-Markovian features of an arbitrary original dynamical map. The idea is to replace its unphysical Choi operator with its closest physical one, mimicking recent work on quantum process tomography. We also show that the regularized dynamics is more accurate in terms of reproducing the exact dynamics: this allows to heuristically push the utilization of these master equations in moderate coupling regimes, where the loss of positivity can have relevant impact., Comment: 12 pages, 5 figures. Close to published version

We propose to use a quantum spin chain as a device to store and release energy coherently (namely, a quantum battery) and we investigate the interplay between its internal correlations and outside decoherence. We employ the quantum Ising chain in a transverse field, and our charging protocol consists of a sudden global quantum quench in the external field to take the system out of equilibrium. Interactions with the environment and decoherence phenomena can dissipate part of the work that the chain can supply after being charged, measured by the ergotropy. We find that the system shows overall remarkably better performances, in terms of resilience, charging time, and energy storage, when topological frustration is introduced by setting AFM interactions with an odd number of sites and periodic boundary conditions. Moreover, we show that in a simple discharging protocol to an external spin, only the frustrated chain can transfer work and not just heat.

We present a comprehensive characterization of the interconnections between single-mode, phaseinsensitive Gaussian Bosonic Channels resulting from channel concatenation. This characterization enables us to identify, in the parameter space of these maps, two distinct regions: low-ground and high-ground. In the low-ground region, the information capacities are smaller than a designated reference value, while in the high-ground region, they are provably greater. As a direct consequence, we systematically outline an explicit set of upper bounds for the quantum and private capacity of these maps, which combine known upper bounds and composition rules, improving upon existing results., Comment: 18 pages; 7 figures

Quantum work capacitances and maximal asymptotic work/energy ratios are figures of merit characterizing the robustness against noise of work extraction processes in quantum batteries formed by collections of quantum systems. In this paper we establish a direct connection between these functionals and, exploiting this result, we analyze different types of noise models mimicking self-discharging, thermalization and dephasing effects. In this context we show that input quantum coherence can significantly improve the storage performance of noisy quantum batteries and that the maximum output ergotropy is not always achieved by the maximum available input energy., Comment: 16 pages, 8 figures

We propose a procedure for the robust preparation of maximally entangled states of identical fermionic qubits, studying the role played by particle statistics in the process. The protocol exploits externally activated noisy channels to reset the system to a known state. The subsequent interference effects generated at a beam splitter result in a mixture of maximally entangled Bell states and NOON states. We also discuss how every maximally entangled state of two fermionic qubits distributed over two spatial modes can be obtained from one another by fermionic passive optical transformations. Using a pseudospin-insensitive, non-absorbing, parity check detector, the proposed technique is thus shown to deterministically prepare any arbitrary maximally entangled state of two identical fermions. These results extend recent findings related to bosonic qubits. Finally, we analyze the performance of the protocol for both bosons and fermions when the externally activated noisy channels are not used and the two qubits undergo standard types of noise. The results supply further insights towards viable strategies for noise-protected entanglement exploitable in quantum-enhanced technologies., Comment: 9 pages, 6 figures

We demonstrate an asymmetry between the beneficial effects one can obtain using non-local operations and non-local states to mitigate the detrimental effects of environmental noise in the work extraction from quantum battery models. Specifically, we show that using non-local recovery operations after the noise action can in general increase the amount of work one can recover from the battery even with separable (i.e. non entangled) input states. On the contrary, employing entangled input states with local recovery operations will not generally improve the battery performances., Comment: 11 pages, 3 figures, it matches the journal version

We study the performance of quantum thermal machines in which the working fluid of the model is represented by a many-body quantum system that is periodically connected with external baths via local couplings. A formal characterization of the limit cycles of the set-up is presented in terms of the mixing properties of the quantum channel that describes the evolution of the fluid over a thermodynamic cycle. For the special case in which the system is a collection of spin 1/2 particles coupled via magnetization preserving Hamiltonians, a full characterization of the possible operational regimes (i.e., thermal engine, refrigerator, heater and thermal accelerator) is provided: in this context we show in fact that the different regimes only depend upon a limited number of parameters (essentially the ratios of the energy gaps associated with the local Hamiltonians of the parts of the network which are in direct thermal contact with the baths)., Comment: 21 pages, 6 figures. One column format

The two-way capacities of quantum channels determine the ultimate entanglement and secret-key distribution rates achievable by two distant parties that are connected by a noisy transmission line, in absence of quantum repeaters. Since repeaters will likely be expensive to build and maintain, a central open problem of quantum communication is to understand what performances are achievable without them. In this paper, we find a new lower bound on the energy-constrained and unconstrained two-way quantum and secret-key capacities of all phase-insensitive bosonic Gaussian channels, namely thermal attenuator, thermal amplifier, and additive Gaussian noise, which are realistic models for the noise affecting optical fibres or free-space links. Ours is the first nonzero lower bound on the two-way quantum capacity in the parameter range where the (reverse) coherent information becomes negative, and it shows explicitly that entanglement distribution is always possible when the channel is not entanglement breaking. This completely solves a crucial open problem of the field, namely, establishing the maximum excess noise which is tolerable in continuous-variable quantum key distribution. In addition, our construction is fully explicit, i.e. we devise and optimise a concrete entanglement distribution and distillation protocol that works by combining recurrence and hashing protocols, Comment: 51 pages, 12 figures

We introduce a theoretical scheme to prepare a pure Bell singlet state of two bosonic qubits, in a way that is robust under the action of arbitrary local noise. Focusing on a photonic platform, the proposed procedure employs passive optical devices and a polarization-insensitive, non-absorbing, parity check detector in an iterative process which achieves determinism asymptotically with the number of repetitions. Distributing the photons over two distinct spatial modes, we further show that the elements of the related basis composed of maximally entangled states can be divided in two groups according to an equivalence based on passive optical transformations. We demonstrate that the parity check detector can be used to connect the two sets of states. We thus conclude that the proposed protocol can be employed to prepare any pure state of two bosons which are maximally entangled in either the internal degree of freedom (Bell states) or the spatial mode (NOON states)., Comment: 5 pages, 3 figures

We consider the problem of devising a suitable Quantum Error Correction (QEC) procedures for a generic quantum noise acting on a quantum circuit. In general, there is no analytic universal procedure to obtain the encoding and correction unitary gates, and the problem is even harder if the noise is unknown and has to be reconstructed. The existing procedures rely on Variational Quantum Algorithms (VQAs) and are very difficult to train since the size of the gradient of the cost function decays exponentially with the number of qubits. We address this problem using a cost function based on the Quantum Wasserstein distance of order 1 ($QW_1$). At variance with other quantum distances typically adopted in quantum information processing, $QW_1$ lacks the unitary invariance property which makes it a suitable tool to avoid to get trapped in local minima. Focusing on a simple noise model for which an exact QEC solution is known and can be used as a theoretical benchmark, we run a series of numerical tests that show how, guiding the VQA search through the $QW_1$, can indeed significantly increase both the probability of a successful training and the fidelity of the recovered state, with respect to the results one obtains when using conventional approaches.

Quantum batteries are energy-storing devices, governed by quantum mechanics, that promise high charging performance thanks to collective effects. Due to its experimental feasibility, the Dicke battery - which comprises $N$ two-level systems coupled to a common photon mode - is one of the most promising designs for quantum batteries. Here, we use reinforcement learning to optimize the charging process of a Dicke battery either by modulating the coupling strength, or the system-cavity detuning. We find that the extractable energy (ergotropy) and quantum mechanical energy fluctuations (charging precision) can be greatly improved with respect to standard charging strategies. Notably, the collective speedup of the charging time can be preserved even when nearly fully charging the battery., Comment: 6+9 pages, 7 figures

Achieving quantum-enhanced performances when measuring unknown quantities requires developing suitable methodologies for practical scenarios, that include noise and the availability of a limited amount of resources. Here, we report on the optimization of sub-standard quantum limit Bayesian multiparameter estimation in a scenario where a subset of the parameters describes unavoidable noise processes in an experimental photonic sensor. We explore how the optimization of the estimation changes depending on which parameters are either of interest or are treated as nuisance ones. Our results show that optimizing the multiparameter approach in noisy apparata represents a significant tool to fully exploit the potential of practical sensors operating beyond the standard quantum limit for broad resources range.

We introduce a new regularization of the Redfield equation based on a replacement of the Kossakowski matrix with its closest positive semidefinite neighbor. Unlike most of the existing approaches, this procedure is capable of retaining the time dependence of the Kossakowski matrix, leading to a completely positive divisible quantum process. Using the dynamics of an exactly-solvable three-level open system as a reference, we show that our approach performs better during the transient evolution, if compared to other approaches like the partial secular master equation or the universal Lindblad equation. To make the comparison between different regularization schemes independent from the initial states, we introduce a new quantitative approach based on the Choi-Jamiolkowski isomorphism., Comment: Final published version. 18 pages, 3 figures

We present a theoretical analysis of the energy recovery efficiency for quantum batteries composed of many identical quantum cells undergoing noise. While the possibility of using quantum effects to speed up the charging processes of batteries have been vastly investigated, In order to traslate these ideas into working devices it is crucial to assess the stability of the storage phase in the quantum battery elements when they are in contact with environmental noise. In this work we formalize this problem introducing a series of operationally well defined figures of merit (the work capacitances and the Maximal Asymptotic Work/Energy Ratios) which gauge the highest efficiency one can attain in recovering useful energy from quantum battery models that are formed by large collections of identical and independent elements (quantum cells or q-cells). Explicit evaluations of such quantities are presented for the case where the energy storing system undergoes through dephasing and depolarizing noise., Comment: 18 pages, 5 figures

Robust and tunable topological Josephson junctions (TJJs) are highly desirable platforms for investigating the anomalous Josephson effect and topological quantum computation applications. Experimental demonstrations have been done in hybrid superconducting-two dimensional topological insulator (2DTI) platforms, sensitive to magnetic disorder and interactions with phonons and other electrons. In this work, we propose a robust and electrostatically tunable TJJ by combining the physics of the integer quantum Hall (IQH) regime and of superconductors. We provide analytical insights about the corresponding Andreev bound state spectrum, the Josephson current and the anomalous current. We demonstrate the existence of protected zero-energy crossings, that can be controlled through electrostatic external gates. This electrostatic tunability has a direct advantage to compensate for non-ideal interfaces and undesirable reflections that may occur in any realistic samples. TJJs in the IQH regime could be realized in graphene and other 2D materials. They are of particular relevance towards scalable and robust Andreev-qubit platforms, and also for efficient phase batteries.

We investigate the optimal charging processes for several models of quantum batteries, finding how to maximize the energy stored in a given battery with a finite-time modulation of a set of external fields. We approach the problem using advanced tools of optimal control theory, highlighting the universality of some features of the optimal solutions, for instance the emergence of the well-known Bang-Bang behavior of the time-dependent external fields. The technique presented here is general, and we apply it to specific cases in which the energy is both pumped into the battery by external forces (direct charging) or transferred into it from an external charger (mediated charging). In this article we focus on particular systems that consist of coupled qubits and harmonic oscillators, for which the optimal charging problem can be explicitly solved using a combined analytical-numerical approach based on our optimal control techniques. However, our approach can be applied to more complex setups, thus fostering the study of many-body effects in the charging process., Comment: 17 pages, 5 figures

We introduce a new set of quantum channels: resonant multilevel amplitude damping (ReMAD) channels. Among other instances, they can describe energy dissipation effects in multilevel atomic systems induced by the interaction with a zero-temperature bosonic environment. At variance with the already known class of multilevel amplitude damping (MAD) channels, this new class of maps allows the presence of an environment unable to discriminate transitions with identical energy gaps. After characterizing the algebra of their composition rules, by analyzing the qutrit case, we show that this new set of channels can exhibit degradability and antidegradability in vast regions of the allowed parameter space. There we compute their quantum capacity and private classical capacity. We show that these capacities can be computed exactly also in regions of the parameter space where the channels aren't degradable nor antidegradable.

We investigate the problem of finding the local analogue of the ergotropy, that is the maximum work that can be extracted from a system if we can only apply local unitary transformation acting on a given subsystem. In particular, we provide a closed formula for the local ergotropy in the special case in which the local system has only two levels, and give analytic lower bounds and semidefinite programming upper bounds for the general case. As non-trivial examples of application, we compute the local ergotropy for a atom in an electromagnetic cavity with Jaynes-Cummings coupling, and the local ergotropy for a spin site in an XXZ Heisenberg chain, showing that the amount of work that can be extracted with an unitary operation on the coupled system can be greater than the work obtainable by quenching off the coupling with the environment before the unitary transformation., Comment: 10 pages, 1 figure

We propose a special relativistic framework for quantum mechanics. It is based on introducing a Hilbert space for events. Events are taken as primitive notions (as customary in relativity), whereas quantum systems (e.g. fields and particles) are emergent in the form of joint probability amplitudes for position and time of events. Textbook relativistic quantum mechanics and quantum field theory can be recovered by dividing the event Hilbert spaces into space and time (a foliation) and then conditioning the event states onto the time part. Our theory satisfies the full Poincare' symmetry as a `geometric' unitary transformation, and possesses observables for space (location of an event) and time (position in time of an event)., Comment: Years of hard work

In this paper we address a special case of "sloppy" quantum estimation procedures which happens in the presence of intertwined parameters. A collection of parameters are said to be intertwined when their imprinting on the quantum probe that mediates the estimation procedure, is performed by a set of linearly dependent generators. Under this circumstance the individual values of the parameters can not be recovered unless one tampers with the encoding process itself. An example is presented by studying the estimation of the relative time-delays that accumulate along two parallel optical transmission lines. In this case we show that the parameters can be effectively untwined by inserting a sequence of balanced beam splitters (and eventually adding an extra phase shift on one of the lines) that couples the two lines at regular intervals in a setup that remind us a generalized Hong-Ou-Mandel (GHOM) interferometer. For the case of two time delays we prove that, when the employed probe is the frequency-correlated biphoton state, the untwining occurs in correspondence of exclusive zero-coincidence (EZC) point. Furthermore we show the statistical independence of two time delays and the optimality of the quantum Fisher information at the EZC point. Finally we prove the compatibility of this scheme by checking the weak commutativity condition associated with the symmetric logarithmic derivative operators., Comment: 20 pages, 8 figures

Is quantum communication possible over an optical fibre with transmissivity $\lambda\leq 1/2$ ? The answer is well known to be negative if the environment with which the incoming signal interacts is initialised in a thermal state. However, in [PRL 125:110504, 2020] the quantum capacity was found to be always bounded away from zero for all $\lambda>0$, a phenomenon dubbed "die-hard quantum communication" (D-HQCOM), provided that the initial environment state can be chosen appropriately (depending on $\lambda$). Here we show an even stronger version of D-HQCOM in the context of entanglement-assisted classical communication: entanglement assistance and control of the environment enable communication with performance at least equal to that of the ideal case of absence of noise, even if $\lambda>0$ is arbitrarily small. These two phenomena of D-HQCOM have technological potential provided that we are able to control the environment. How can we achieve this? Our second main result answers this question. Here we provide a fully consistent protocol to activate the phenomena of D-HQCOM without directly accessing the environment state. This is done by sending over the channel "trigger signals", i.e. signals which do not encode information, prior to the actual communication, with the goal of modifying the environment in an advantageous way. This is possible thanks to the memory effects which arise when the sender feeds signals separated by a sufficiently short temporal interval. Our results may offer a concrete scheme to communicate across arbitrarily long optical fibres, without using quantum repeaters. As a by-product of our analysis, we derive a simple Kraus representation of the thermal attenuator exploiting the associated Lindblad master equation., Comment: 38 pages, 12 figures. The present paper serves as the companion to the paper [F. A. Mele, L. Lami, and V. Giovannetti. Restoring quantum communication efficiency over high loss optical fibres. Preprint arXiv:2204.13128, 2022], by providing proofs of the results stated there and additional developments. In v3 minor typos have been fixed

In the absence of quantum repeaters, quantum communication proved to be nearly impossible across optical fibres longer than $\gtrsim 20\text{ km}$ due to the drop of transmissivity below the critical threshold of $1/2$. However, if the signals fed into the fibre are separated by a sufficiently short time interval, memory effects must be taken into account. In this paper we show that by properly accounting for these effects it is possible to devise schemes that enable unassisted quantum communication across arbitrarily long optical fibres at a fixed positive qubit transmission rate. We also demonstrate how to achieve entanglement-assisted communication over arbitrarily long distances at a rate of the same order of the maximum achievable in the unassisted noiseless case., Comment: 19 pages, 2 figures. The full technical details, proofs and additional developments are deferred to the companion paper [F. A. Mele, L. Lami, and V. Giovannetti. Quantum optical communication in the presence of strong attenuation noise. Preprint arXiv:2204.13129, 2022]. In v3 minor typos have been fixed

We analyze the capability of discriminating the statistical nature of a thermal bath by exploiting the interaction with an additional environment. We first shows that, at difference with the standard scenario where the additional environment is not present, the modified evolution induced by the mere presence of the extra bath allows to improve the discrimination task. We then also consider the possibility of continuously monitoring the additional environment and we discuss in detail how to obtain improved performances in the discrimination by considering different kinds of interaction, i.e. different jump operators, and different monitoring strategies corresponding to continuous homodyne and photo-detection. Our strategy can be in principle implemented in a circuit QED setup and paves the way to further developments of quantum probing via continuous monitoring.

Technologies operating on the basis of quantum mechanical laws and resources such as phase coherence and entanglement are expected to revolutionize our future. Quantum technologies are often divided into four main pillars: computing, simulation, communication, and sensing & metrology. Moreover, a great deal of interest is currently also nucleating around energy-related quantum technologies. In this Perspective, we focus on advanced superconducting materials, van der Waals materials, and moir\'e quantum matter, summarizing recent exciting developments and highlighting a wealth of potential applications, ranging from high-energy experimental and theoretical physics to quantum materials science and energy storage., Comment: 19 pages, 4 figures, 215 references, Perspective article on solid-state quantum technologies

The presence of correlations in the input state of a non-interacting many-body quantum system can lead to an increase in the amount of work we can extract from it under global unitary processes (ergotropy). The present work explore such effect on translationally invariant systems relaying on the Matrix Product Operator formalism to define a measure of how much they are correlated. We observe that in the thermodynamic limit of large number of sites, complete work extraction can be attained for relatively small correlation strength (a reduction of a 2 factor in dB unit). Most importantly such an effect appears not to be associated with the presence of quantum correlations (e.g. entanglement) in the input state (classical correlation sources), and to be attainable by only using incoherent ergotropy. As a byproduct of our analysis we also present a rigorous formulation of the heuristic typicality argument first formulated in [Alicki and Fannes, 2013], which gives the maximum work extractable for a set of many identical quantum systems in the asymptotic limit., Comment: 21 pages, 5 figures

Adopting quantum resources for parameter estimation discloses the possibility to realize quantum sensors operating at a sensitivity beyond the standard quantum limit. Such approach promises to reach the fundamental Heisenberg scaling as a function of the employed resources $N$ in the estimation process. Although previous experiments demonstrated precision scaling approaching Heisenberg-limited performances, reaching such regime for a wide range of $N$ remains hard to accomplish. Here, we show a method which suitably allocates the available resources reaching Heisenberg scaling without any prior information on the parameter. We demonstrate experimentally such an advantage in measuring a rotation angle. We quantitatively verify Heisenberg scaling for a considerable range of $N$ by using single-photon states with high-order orbital angular momentum, achieving an error reduction greater than $10$ dB below the standard quantum limit. Such results can be applied to different scenarios, opening the way to the optimization of resources in quantum sensing.

We present an extensive introduction to quantum collision models (CMs), also known as repeated interactions schemes: a class of microscopic system-bath models for investigating open quantum systems dynamics whose use is currently spreading in a number of research areas. Through dedicated sections and a pedagogical approach, we discuss the CMs definition and general properties, their use for the derivation of master equations, their connection with quantum trajectories, their application in non-equilibrium quantum thermodynamics, their non-Markovian generalizations, their emergence from conventional system-bath microscopic models and link to the input-output formalism. The state of the art of each involved research area is reviewed through dedicated sections. The article is supported by several complementary appendices, which review standard concepts/tools of open quantum systems used in the main text with the goal of making the material accessible even to readers possessing only a basic background in quantum mechanics. The paper could also be seen itself as a friendly, physically intuitive, introduction to fundamentals of open quantum systems theory since most main concepts of this are treated such as quantum maps, Lindblad master equation, steady states, POVMs, quantum trajectories and stochastic Schrodinger equation., Comment: 159 pages, 20 figures. Extensive pedagogical review on quantum collision models (aka repeated interactions schemes)

We consider the problem of discriminating quantum states, where the task is to distinguish two different quantum states with a complete classical knowledge about them, and the problem of classifying quantum states, where the task is to distinguish two classes of quantum states where no prior classical information is available but a finite number of physical copies of each classes are given. In the case the quantum states are represented by coherent states of light, we identify intermediate scenarios where partial prior information is available. We evaluate an analytical expression for the minimum error when the quantum states are opposite and a prior on the amplitudes is known. Such a threshold is attained by complex POVM that involve highly non-linear optical procedure. A suboptimal procedure that can be implemented with current technology is presented that is based on a modification of the conventional Dolinar receiver. We study and compare the performance of the scheme under different assumptions on the prior information available.

We present a novel mapping for studying 2D many-body quantum systems by solving an effective, one-dimensional long-range model in place of the original two-dimensional short-range one. In particular, we address the problem of choosing an efficient mapping from the 2D lattice to a 1D chain that optimally preserves the locality of interactions within the TN structure. By using Matrix Product States (MPS) and Tree Tensor Network (TTN) algorithms, we compute the ground state of the 2D quantum Ising model in transverse field with lattice size up to $64\times64$, comparing the results obtained from different mappings based on two space-filling curves, the snake curve and the Hilbert curve. We show that the locality-preserving properties of the Hilbert curve leads to a clear improvement of numerical precision, especially for large sizes, and turns out to provide the best performances for the simulation of 2D lattice systems via 1D TN structures., Comment: 17 pages, 13 figures

We study the transferring of useful energy (work) along a transmission line that allows for partial preservation of quantum coherence. As a figure of merit we adopt the maximum values that ergotropy, total ergotropy, and non-equilibrium free-energy attain at the output of the line for an assigned input energy threshold. For Phase-Invariant Bosonic Gaussian Channels (BGCs) models, we show that coherent inputs are optimal. For (one-mode) not Phase-Invariant BGCs we solve the optimization problem under the extra restriction of Gaussian input signals., Comment: 6+12 pages, 1+4 figures

We study the problem of testing identity of a collection of unknown quantum states given sample access to this collection, each state appearing with some known probability. We show that for a collection of $d$-dimensional quantum states of cardinality $N$, the sample complexity is $O(\sqrt{N}d/\epsilon^2)$, {with a matching lower bound, up to a multiplicative constant}. The test is obtained by estimating the mean squared Hilbert-Schmidt distance between the states, thanks to a suitable generalization of the estimator of the Hilbert-Schmidt distance between two unknown states by B\u{a}descu, O'Donnell, and Wright (https://dl.acm.org/doi/10.1145/3313276.3316344)., Comment: 23+6 pages, 1 figure

We present upper bounds on the quantum and private capacity of single-mode, phase-insentitive Bosonic Gaussian Channels based on degradable extensions. Our findings are state-of-the-art in the following parameter regions: low temperature and high transmissivity for the thermal attenuator, low temperature for additive Gaussian noise, high temperature and intermediate amplification for the thermal amplifier., Comment: 5+4 pages, 3 figures. Typos corrected, improved presentation