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The presence of metronidazole (MNZ) and acetaminophen (ACE) in aquatic environments has raised growing concerns regarding their potential impact on human health. Incorporating various patterns into a photocatalytic material is considered a critical approach to achieving enhanced photocatalytic efficiency in the photocatalysis process. In this study, WO 3 nanoparticles, which were immobilized onto ferromagnetic multi-walled carbon nanotubes that were functionalized using (3-glycidyloxypropyl)trimethoxysilane (FMMWCNTs@GLYMO@WO 3 ), exhibited remarkable efficiency in removing MNZ and ACE (93% and 97%) in only 15 min. In addition, the new visible-light FMMWCNTs@GLYMO@WO 3 nanoparticles as a magnetically separable photocatalyst were characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction analysis (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), EDS-mapping, vibrating sample magnetometry (VSM), thermogravimetric analysis (TGA), diffuse reflectance spectroscopy (DRS), high-performance liquid chromatography (HPLC), and total organic carbon (TOC) due to detailed studies (morphological, structural, magnetic and optical properties) of the photocatalyst. In-depth spectroscopic and microscopic characterization of the newly developed ferromagnetic FMMWCNTs@GLYMO@WO₃ (III) photocatalyst revealed a spherical morphology, with nanoparticle diameters averaging between 23 and 39 nm. Compared to conventional multiwall carbon nanotube and WO₃ photocatalysts, FMMWCNTs@GLYMO@WO₃ (III) demonstrated superior photocatalytic activity. Remarkably, it exhibited excellent reusability, maintaining its efficiency over a minimum of five cycles in the degradation of metronidazole (MNZ) and acetaminophen (ACE)., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Herein, a new visible-light active exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell nanoparticles (NPs) was synthesized as a magnetically separable photocatalyst. For an in-depth understanding of the magnetic photocatalyst's structural, morphological, and optical properties, the products were extensively characterized with FT-IR, XRD, TEM, HRTEM, FESEM, EDS, EDS-mapping, VSM, DRS, EIS, and photocurrent. The photocatalyst was then utilized to degrade Levofloxacin (LEVO) and Indigo Carmine (IC) by visible light at room temperature. The exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs photocatalyst revealed 80% and 95.6% degradation efficiency for Levofloxacin and Indigo Carmine within 25 and 15 min, respectively. In addition, the optimal factors such as concentration, loading of photocatalyst, and pH were also assessed. Levofloxacin degradation mechanistic studies showed that electrons and holes significantly contribute to the photocatalytic process of photocatalyst degradation. In addition, after 5 times regeneration, exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs remained as an excellent magnetic photocatalyst for the eco-friendly degradation of Levofloxacin and Indigo Carmine (76% and 90%), respectively. The superior photocatalytic performance of exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell nanoparticles (NPs) was mostly ascribed to the synergistic advantages of stronger visible light response, larger specific surface area, and the more effective separation and transfer of photogenerated charge carriers. Based on these results, the highly effective magnetic photocatalyst achieved better results than numerous studied catalysts in the literature. The degradation of Levofloxacin and Indigo Carmine under environmentally friendly conditions can be achieved using exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs (V) as an efficient and green photocatalyst. The magnetic photocatalyst was characterized by spectroscopic and microscopic methods, revealing a spherical shape and particle size of 23 nm. Additionally, the magnetic photocatalyst could be separated from the reaction mixture by a magnet without significantly reducing its catalytic activity., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)