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Building-integrated photovoltaic (BIPV) glazing systems with intelligent window technologies enhance building energy efficiency by generating electricity and managing daylighting. This study explores advanced BIPV glazing, focusing on building-integrated concentrating photovoltaic (BICPV) systems. BICPV integrates concentrating optics, such as holographic films, luminescent solar concentrators (LSC), Fresnel lenses, and compound parabolic concentrators (CPCs), with photovoltaic cells. Notable results include achieving 17.9% electrical efficiency using cylindrical holographic optical elements and crystalline silicon cells at a 3.5× concentration ratio. Dielectric CPCs showed 97.7% angular acceptance efficiency in simulations and 94.4% experimentally, increasing short-circuit current and maximum power by 87.0% and 96.6%, respectively, across 0° to 85° incidence angles. Thermochromic hydrogels and thermotropic smart glazing systems demonstrated significant HVAC energy savings. Large-area 1 m2 PNIPAm-based thermotropic window outperformed conventional double glazing in Singapore. The thermotropic parallel slat transparent insulation material (TT PS-TIM) improved energy efficiency by up to 21.5% compared to double glazing in climates like London and Rome. Emerging dynamic glazing technologies combine BIPV with smart functions, balancing transparency and efficiency. Photothermally controlled methylammonium lead iodide PV windows achieved 68% visible light transmission, 11.3% power conversion efficiency, and quick switching in under 3 min. Polymer-dispersed liquid crystal smart windows provided 41–68% visible transmission with self-powered operation. [ABSTRACT FROM AUTHOR]

Solar walls provide transformative solutions by harnessing solar energy to generate electricity, improve thermal comfort, and reduce energy consumption and emissions, contributing to zero-energy buildings and mitigating climate change. In hot and humid regions, solar walls can reduce indoor temperatures by 30% to 50%, significantly improving energy efficiency. Optimizing the performance of solar walls includes factors such as glazing, shading, solar orientation, ventilation, and catalytic techniques, allowing them to be adapted to different climates. Innovative solar wall variants that include photovoltaic panels, water storage, and phase-change materials offer multifunctionality and sustainability in building design and are in line with global energy efficiency and environmentally conscious goals. In addition, innovative solar wall variants that combine photovoltaic panels, water storage, and phase-change materials promise even more sustainability in building design. These multifunctional solar wall systems can efficiently heat, cool, and generate energy, further reducing a building's environmental impact. Solar walls have the potential to significantly reduce heating energy consumption; align with global goals for energy-efficient, environmentally conscious, and climate-responsive building design; and offer dynamic and adaptable solutions for sustainable architecture. [ABSTRACT FROM AUTHOR]