Search

This study examined the influence of different wastewater treatment processes on the physicochemical properties of Alginate-Like Exopolymers (ALE) extracted from waste sludge. Sludge samples were collected from wastewater treatment plants (WWTPs) processing both combined industrial and domestic wastewater, as well as domestic wastewater alone. Among the processes studied, aerobic granular sludge (AGS) produced the highest ALE yield (352 ± 50 mg/g-VSsludge), significantly exceeding that from membrane bioreactor (170 ± 41 mg/g-VSsludge) and conventional activated sludge (<130 mg/g-VSsludge). AGS-derived ALE also had the highest uronic acid content (224 ± 14.5 mg/g-VSsludge), with mannuronic acids playing a critical role in enhancing hydrogel cohesion and stability. The results showed that the distinct microbial consortium in the AGS system, including the presence of Pseudomonas alcaligenes , was strongly associated with increased ALE production. This establishes a novel link between microbial community composition and ALE yield. These insights are crucial for optimizing resource recovery in AGS systems and underscore the potential of ALE for various industrial applications. [ABSTRACT FROM AUTHOR]

The quest for sustainable and functional food packaging materials has led researchers to explore biopolymers such as pullulan, which has emerged as a notable candidate for its excellent film-forming and anti-fogging properties. This study introduces an innovative anti-fog coating by combining pullulan with poly (acrylic acid sodium salt) to enhance the display of packaged food in high humidity environments without impairing the sealing performance of the packaging material—two critical factors in preserving food quality and consumers' acceptance. The research focused on varying the ratios of pullulan to poly (acrylic acid sodium salt) and investigating the performance of this formulation as an anti-fog coating on bioriented polypropylene (BOPP). Contact angle analysis showed a significant improvement in BOPP wettability after coating deposition, with water contact angle values ranging from ~60° to ~17° for formulations consisting only of poly (acrylic acid sodium salt) (P0) or pullulan (P100), respectively. Furthermore, seal strength evaluations demonstrated acceptable performance, with the optimal formulation (P50) achieving the highest sealing force (~2.7 N/2.5 cm) at higher temperatures (130 °C). These results highlight the exceptional potential of a pullulan-based coating as an alternative to conventional packaging materials, significantly enhancing anti-fogging performance. [ABSTRACT FROM AUTHOR]

A new molecularly imprinted electrochemical sensor was proposed to determine 4,4′-methylene diphenyl diamine (MDA) using molecularly imprinted polymer–multiwalled carbon nanotubes modified glassy carbon electrode (MIP/MWCNTs/GCE). GCE was coated by MWCNTs (MWCNTs/GCE) because of their antifouling qualities and in order to improve the sensor sensitivity. To make the whole sensor, a polymeric film made up of chitosan nanoparticles was electrodeposited by the cyclic voltammetry method on the surface of MWCNTs/GCE in the presence of MDA as a template. Different parameters such as scan cycles, elution time, incubation time, molar ratio of template molecules to functional monomers, and pH were optimized to increase the performance of the MIP sensor. With a detection limit of 15 nM, a linear response to MDA was seen in the concentration range of 0.5–100 µM. The imprinting factor (IF) of the proposed sensor was also calculated at around 3.66, demonstrating the extremely high recognition performance of a MIP/MWCNT-modified electrode. Moreover, the sensor exhibited good reproducibility and selectivity. Finally, the proposed sensor was efficiently used to determine MDA in real samples with satisfactory recoveries ranging from 94.10% to 106.76%. [ABSTRACT FROM AUTHOR]

In this work, we present the development of bionanocomposite coatings on poly(ethylene terephthalate) (PET) with outstanding oxygen barrier properties. Pullulan and graphene oxide (GO) were used as main polymer phase and nanobuilding block (NBB), respectively. The oxygen barrier performance was investigated at different filler volume fractions (φ) and as a function of different relative humidity (RH) values. Noticeably, the impermeable nature of GO was reflected under dry conditions, in which an oxygen transmission rate (OTR, mL·m-2·24 h-1) value below the detection limit of the instrument (0.01 mL·m-2·24 h-1) was recorded, even for ' as low as 0.0004. A dramatic increase of the OTR values occurred in humid conditions, such that the barrier performance was totally lost at 90% RH (the OTR of coated PET films was equal to the OTR of bare PET films). Modelling of the experimental OTR data by Cussler's model suggested that the spatial ordering of GO sheets within the main pullulan phase was perturbed because of RH fluctuations. In spite of the presence of the filler, all the formulations allowed the obtainment of final materials with haze values below 3%, the only exception being the formulation with the highest loading of GO (φ ≈ 0.03). The mechanisms underlying the experimental observations are discussed. [ABSTRACT FROM AUTHOR]