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Low-temperature electronic properties of rare-earth intermetallics are substantially influenced by the symmetry and magnitude of the crystal electric field. The direct spectroscopic analysis of crystal field splitting can be challenging, especially in low-dimensional systems, because it requires both high spectral resolution and pronounced sensitivity. We demonstrate the eligibility of electronic Raman spectroscopy for this purpose by the direct determination of the $4f$ level splitting in ultra-thin ordered CePt$_5$ films down to 1.7 nm thickness on Pt(111). Crystal field excitations of Ce $4f$ electrons give rise to Raman peaks with energy shifts up to $\approx$ 25 meV. Three distinct peaks occur which we attribute to inequivalent Ce sites, located (i) at the interface to the substrate, (ii) next to the Pt-terminated surface, and (iii) in the CePt$_5$ layers in between. The well-resolved Raman signatures allow us to identify a reduced crystal field splitting at the interface and an enhancement at the surface, highlighting its strong dependence on the local atomic environment., Comment: 5 pages, 4 figures

We study the chemical ordering in Bi$_2$Te$_{3-x}$Se$_x$ grown by molecular beam epitaxy on Si substrates. We produce films in the full composition range from x = 0 to 3, and determine their material properties using energy dispersive X-ray spectroscopy, X-ray diffraction and Raman spectroscopy. By fitting the parameters of a kinetic growth model to these results, we obtain a consistent description of growth at a microscopic level. Our main finding is that despite the incorporation of Se in the central layer being much more probable than that of Te, the formation of a fully ordered Te-Bi-Se-Bi-Te layer is prevented by kinetic of the growth process. Indeed, the Se concentration in the central layer of Bi$_2$Te$_2$Se$_1$ reaches a maximum of only $\approx$ 75% even under ideal growth conditions. A second finding of our work is that the intensity ratio of the 0 0 12 and 0 0 6 X-ray reflections serves as an experimentally accessible quantitative measure of the degree of ordering in these films., Comment: Accepted for publication in Journal of Physics: Condensed Matter (JPCM)

Photoluminescence spectra of a (001)-Cd0.99Mn0.01Te quantum well were taken with linear-polarization resolution and using an in-plane magnetic field. Because the quantum well contained a two-dimensional electron gas, the spectra consisted of several features. Since the quantum well layer was formed by a diluted magnetic semiconductor, the spectra showed pronounced polarization-dependent transformations when the in-plane magnetic field was applied. In the magnetic field, a 90-degrees rotation of the sample about the surface normal axis resulted in a clearly different spectrum, meaning that the nominally equivalent [110] and [1-10] directions in the sample are not equivalent in fact. But, remarkably, the additional 90-degrees rotations of both the polarizer and the analyzer restored the initial spectrum. This combined invariance regarding simultaneous 90-degrees rotation of the sample and reversal of the polarization configuration was known earlier for spin-flip Raman spectra only. Our present observations are interpreted in terms of the mixing of valence subbands leading to the pseudo-isotropic g-factor of the ground-state holes., Comment: 7 pages, 3 figures

The excitations of a two-dimensional electron gas in quantum wells with intermediate carrier density (~10^{11} cm^{-2}), i.e., between the exciton-trion- and the Fermi-Sea range, are so far poorly understood. We report on an approach to bridge this gap by a magneto-photoluminescence study of modulation-doped (Cd,Mn)Te quantum well structures. Employing their enhanced spin splitting, we analyzed the characteristic magnetic-field behavior of the individual photoluminescence features. Based on these results and earlier findings by other authors, we present a new approach for understanding the optical transitions at intermediate densities in terms of four-particle excitations, the Suris tetrons, which were up to now only predicted theoretically. All characteristic photoluminescence features are attributed to emission from these quasi-particles when attaining different final states., Comment: 12 pages, 3 figures