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We explore a pure optical method for enantioselective orientation of chiral molecules by means of laser fields with twisted polarization. Several field implementations are considered, including a pair of delayed cross-polarized laser pulses, an optical centrifuge, and polarization shaped pulses. The underlying classical orientation mechanism common for all these fields is discussed, and its operation is demonstrated for a range of chiral molecules of various complexity: hydrogen thioperoxide (${\rm HSOH}$), propylene oxide (${\rm CH_{3}CHCH_{2}O}$) and ethyl oxirane (${\rm CH_{3}CH_{2}CHCH_{2}O}$). The presented results demonstrate generality, versatility and robustness of this optical method for manipulating molecular enantiomers in the gas phase.

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable molecular axis, but also induces a directed torque along this axis, which results in the transient orientation of the molecules. The asymmetric molecules are chiral in nature and different molecular enantiomers experience the orienting action in opposite directions causing out-of-phase oscillation of their dipole moments. The resulting microwave radiation was recently suggested to be used for analysis/discrimination of chiral molecular mixtures. We reveal the mechanism behind this laser induced orientation effect, show that it is classical in nature, and envision further applications of light with skewed polarization., Comment: 8 pages, 5 figures

We present what is probably the simplest classical system featuring the echo phenomenon - a collection of randomly oriented free rotors with dispersed rotational velocities. Following excitation by a pair of time-delayed impulsive kicks, the mean orientation/alignment of the ensemble exhibits multiple echoes and fractional echoes. We elucidate the mechanism of the echo formation by kick-induced filamentation of phase space, and provide the first experimental demonstration of classical alignment echoes in a thermal gas of CO_2 molecules excited by a pair of femtosecond laser pulses.

The effects of laser-induced prealignment on the deflection of paramagnetic molecules by inhomogeneous static magnetic field are studied. Depending on the relevant Hund's coupling case of the molecule, two different effects were identified: either suppression of the deflection by laser pulses (Hund's coupling case (a) molecules, such as ClO), or a dramatic reconstruction of the broad distribution of the scattering angles into several narrow peaks (for Hund's coupling case (b) molecules, such as O2 or NH). These findings are important for various applications using molecular guiding, focusing and trapping with the help of magnetic fields.

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we demonstrate that one may efficiently control the deflection process with the help of short and strong femtosecond laser pulses. In particular the deflection process may by turned-off by a proper excitation, and the angular dispersion of the deflected molecules can be substantially reduced. We study the problem both classically and quantum mechanically, taking into account the effects of strong deflecting field on the molecular rotations. In both treatments we arrive at the same conclusions. The suggested control scheme paves the way for many applications involving molecular focusing, guiding, and trapping by inhomogeneous fields.

We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like features in the distribution of the scattering angle. Moreover, by preshaping molecular angular distribution with the help of short and strong femtosecond laser pulses, one may efficiently control the scattering process, manipulate the average deflection angle and its distribution, and reduce substantially the angular dispersion of the deflected molecules. We provide quantum and classical treatment of the deflection process. The effects of strong deflecting field on the scattering of rotating molecules are considered by the means of the adiabatic invariants formalism. This new control scheme opens new ways for many applications involving molecular focusing, guiding and trapping by optical and static fields.

We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like features in the distribution of the scattering angle. Moreover, by pre-shaping molecular angular distribution with the help of short and strong femtosecond laser pulses, one may efficiently control the scattering process, manipulate the average deflection angle and its distribution, and reduce substantially the angular dispersion of the deflected molecules. This opens new ways for many applications involving molecular focusing, guiding and trapping by optical and static fields., Comment: 4 pages, 4 figures

We consider laser alignment of ortho and para spin isomers of water molecules by using strong and short off-resonance laser pulses. A single pulse is found to create a distinct transient alignment and antialignment of the isomeric species. We suggest selective alignment of one isomeric species (leaving the other species randomly aligned) by a pair of two laser pulses., Comment: 6 pages, 4 figures, 3 tables

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle pulse. The laser pulse induces transient anti-alignment in the plane orthogonal to the field polarization, while the half-cycle pulse leads to the orientation. We identify two qualitatively different enhancement mechanisms depending on the pulse order, and optimize their effects using classical and quantum models both at zero and non-zero temperature.

We show that field-free molecular orientation induced by a half-cycle pulse may be considerably enhanced by an additional laser pulse inducing molecular anti-alignment. Two qualitatively different enhancement mechanisms are identified depending on the pulse order, and their effects are optimized with the help of quasi-classical as well as fully quantum models.

We study the linearized Bogoliubov excitation spectrum of infinitely long anharmonically trapped Bose-Einstein condensates, with the aim of overcoming inhomogeneous broadening. We compare the Bogoliubov spectrum of a harmonic trap with that of a theoretical flat-bottom trap and find a dramatic reduction in the inhomogeneous broadening of the lineshape of Bogoliubov excitations. While the Bragg excitation spectrum for a condensate in a harmonic trap supports a number of radial modes, the flat trap is found to significantly support just one mode. We also study the excitation spectrum of realistic anharmonic traps with potentials of finite power dependence on the radial coordinate. We observe a correlation between the number of radial modes and the number of bound states in the effective potential of the quasi-particles. Finally we compare a full numerical Gross-Pitaevskii simulation of a finite-length condensate to our model of infinite, linearized Gross-Pitaevskii excitations. We conclude that our model captures the essential physics., Comment: 6 figures

We report on a measurement of splitting in the excitation spectrum of a condensate driven by an optical travelling wave. Experimental results are compared to a numerical solution of the Gross Pitaevskii equation, and analyzed by a simple two level model and by the more complete band theory, treating the driving beams as an optical lattice. In this picture, the splitting is a manifestation of the energy gap between neighboring bands that opens on the boundary of the Brillouin zone., Comment: 5 pages, 5 figures

We propose and demonstrate an echo method to reduce the inhomogeneous linewidth of Bogoliubov excitations, in a harmonically-trapped Bose-Einstein condensate. Our proposal includes the transfer of excitations with momentum +q to -q using a double two photon Bragg process, in which a substantial reduction of the inhomogeneous broadening is calculated. Furthermore, we predict an enhancement in the method's efficiency for low momentum due to many-body effects. The echo can also be implemented by using a four photon process, as is demonstrated experimentally., Comment: 4 pages, 5 figures

We report on a series of measurements of decoherence and wavepacket dephasing between two colliding, strongly coupled, identical Bose-Einstein condensates. We measure, in the strong excitation regime, a suppression of the mean-field shift, compared to the shift which is observed for a weak excitation. This suppression is explained by applying the Gross-Pitaevskii energy functional. By selectively counting only the non-decohered fraction in a time of flight image we observe oscillations for which both inhomogeneous and Doppler broadening are suppressed, in quantitative agreement with a full Gross-Pitaevskii equation simulation. If no post selection is used, the decoherence rate due to collisions can be extracted, and is in agreement with the local density average calculated rate., Comment: 4 pages, 5 figures