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Ultrafast laser processing of transparent materials reveals new phenomena. Reviewed, are recent demonstrations of 5D optical memory, vortex polarization and Airy beam converters employing self-assembled nanostructuring, ultrafast laser calligraphy and polarization writing control using pulses with tilted front.

We report the observation of an anomalous polarization dependent process in an isotropic glass induced by long time stationary irradiation of a high repetition rate near-infrared femtosecond laser. Two distinctive types of polarization dependent microstructures were induced at different irradiation stages. At early stage (a few seconds), a dumbbell-shaped structure elongated perpendicularly to the laser polarization formed at the top of the modified region, which was later erased by further irradiation. At later stage (above 30 s), bubbles filled with O 2 formed by the irradiation, which were distributed along the laser polarization at a distance far beyond the radius of the laser beam. Based on a simple modeling of light reflection on boundaries, a thermal accumulation process was proposed to explain the formation and evolution of the dumbbell-shaped microstructure. The possible factors responsible for polarization dependent distribution of bubbles are discussed, which needs further systematic investigations. The results may be helpful in the development of femtosecond laser microprocessing for various applications.

Polymeric nanofibers containing gold nanorods (GNRs) are aligned in a uniform orientation through electrospinning. The dispersive and absorptive parts of the third-order optical nonlinear optical refractive index of the composite film measured by polarization dependent z-scan method are demonstrated to be anisotropically enhanced. Anisotropic optical response of the aligned GNRs and its connection with the ultrafast electron dynamics are discussed in light of the results of resonant femtosecond pump-probe experiments. The significant appearance of anisotropic nonlinear optical properties of ensembles of GNRs is attributed to the sensitive excitation of longitudinal surface plasmon resonance (LSPR) of highly aligned GNRs. For the macroscopic applications of ensembles of GNRs, such as passive mode-locking and all-optical switching, the experimental results demonstrate that the alignment of GNRs through electrospinning should be very high efficient, and economic.

Surface texturing is demonstrated by the combination of wet etching and ultrafast laser nanostructuring of silica glass. Using potassium hydroxide (KOH) at room temperature as an etchant of laser modified glass, we show the polarization dependent linear increase in retardance reaching a threefold value within 25 hours. The dispersion control of birefringence by the etching procedure led to achromatic behaviour over the entire visible spectral range. The mechanism of enhanced KOH etching selectivity after femtosecond laser exposure is discussed and correlated to the formation of various laser-induced defects, such as silicon-rich oxygen deficiency and color centers.

We demonstrate a technique to generate accelerating Airy beams with a femtosecond laser-imprinted space variant birefringent structure in silica glass. Our approach enables the generation of dual Airy beams with polarization sensitive beam deflection. The produced beam is used for the glass scribing. After the glass-breaking process, a spontaneous self-detachment of a fiber-like structure occurs that can be exploited as an alternative way for fabricating glass cantilevers.

We demonstrate recording and retrieval of the digital document with a nearly unlimited lifetime. The recording process of multiplexed digital data was implemented by femtosecond laser nanostructuring of fused quartz. The storage allows unprecedented parameters including hundreds of terabytes per disc data capacity, thermal stability up to 1000 °C, and virtually unlimited lifetime at room temperature. We anticipate that this demonstration will open a new era of eternal data archiving.

A polarization imaging device based on a femtosecond laser nanostructured birefringent array is demonstrated. The device enables instant measurement of the distribution of the Stokes vectors in the visible spectrum. Polarimetric measurements with radially and circularly polarized light distributions are demonstrated.

The ability of 8 picosecond pulse lasers for three dimensional direct-writing in the bulk of transparent dielectrics is assessed through a comparative study with a femtosecond laser delivering 600 fs pulses. The comparison addresses two main applications: the fabrication of birefringent optical elements and two-step machining by laser exposure and post-processing by chemical etching. Formation of self-organized nano-gratings in glass by ps-pulses is demonstrated. Differential etching between ps-laser exposed regions and unexposed silica is observed. Despite attaining values of retardance (>100 nm) and etching rate (2 μm/min) similar to fs pulses, ps pulses are found unsuitable for bulk machining in silica glass primarily due to the build-up of a stress field causing scattering, cracks and non-homogeneous etching. Additionally, we show that the so-called "quill-effect", that is the dependence of the laser damage from the direction of writing, occurs also for ps-pulse laser machining. Finally, an opposite dependence of the retardance from the intra-pulse distance is observed for fs- and ps-laser direct writing.

The unusual dependence of femtosecond laser writing on the light polarization and direction of raster scanning is demonstrated in silica and chalcogenide glasses. Two different mechanisms contributing to the observed anisotropy are identified: the chevron-shaped stress induced by the sample movement and the pulse front tilt of ultrashort light pulse. Control of anisotropies associated with the spatio-temporal asymmetry of an ultrashort pulse beam and scanning geometry is crucial in the ultrafast laser machining of transparent materials.

We present the first experimental evidence of anisotropic photosensitivity of an isotropic homogeneous medium under uniform illumination. Our experiments reveal fundamentally new type of light induced anisotropy originated from the hidden asymmetry of pulsed light beam with a finite tilt of intensity front. We anticipate that the observed phenomenon, which enables employing mutual orientation of a light polarization plane and pulse front tilt to control interaction of matter with ultrashort light pulses, will open new opportunities in material processing.

We propose a radial polarizer based on light refraction on a transparent isotropic sphere. We demonstrate theoretically and experimentally that the circularly polarized light impinging on the sphere produces double charged optical vortex. The method is applied to generate optical vortices on a small scale using hollow micro-spheres produced by femtosecond laser in fused silica., (© 2011 Optical Society of America)