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We investigate the detectability of atmospheric spectral features of Earth-like planets in the habitable zone (HZ) around M dwarfs with the future James Webb Space Telescope (JWST). We use a coupled 1D climate-chemistry-model to simulate the influence of a range of observed and modelled M-dwarf spectra on Earth-like planets. The simulated atmospheres served as input for the calculation of the transmission spectra of the hypothetical planets, using a line-by-line spectral radiative transfer model. To investigate the spectroscopic detectability of absorption bands with JWST we further developed a signal-to-noise ratio (S/N) model and applied it to our transmission spectra. High abundances of CH$_4$ and H$_2$O in the atmosphere of Earth-like planets around mid to late M dwarfs increase the detectability of the corresponding spectral features compared to early M-dwarf planets. Increased temperatures in the middle atmosphere of mid- to late-type M-dwarf planets expand the atmosphere and further increase the detectability of absorption bands. To detect CH$_4$, H$_2$O, and CO$_2$ in the atmosphere of an Earth-like planet around a mid to late M dwarf observing only one transit with JWST could be enough up to a distance of 4 pc and less than ten transits up to a distance of 10 pc. As a consequence of saturation limits of JWST and less pronounced absorption bands, the detection of spectral features of hypothetical Earth-like planets around most early M dwarfs would require more than ten transits. We identify 276 existing M dwarfs (including GJ 1132, TRAPPIST-1, GJ 1214, and LHS 1140) around which atmospheric absorption features of hypothetical Earth-like planets could be detected by co-adding just a few transits. We show that using transmission spectroscopy, JWST could provide enough precision to be able to partly characterise the atmosphere of Earth-like TESS planets around mid to late M dwarfs., Comment: 18 pages, 10 figures

Earth-like planets orbiting M-dwarfs are prominent future targets when searching for life outside the solar system. We apply our newly developed Coupled Atmosphere Biogeochemistry model to investigate the coupling between the biosphere, geosphere and atmosphere to gain deeper insight into the atmospheric evolution of Earth-like planets orbiting M-dwarfs. Our main goal is to understand better atmospheric processes affecting biosignatures and climate on such worlds. Furthermore, this is the first study to our knowledge which applies an automated chemical pathway analysis quantifying the production and destruction pathways of O$_2$ for an Earth-like planet with an Archean O$_2$ abundance orbiting in the habitable zone of the M-dwarf AD Leo. Results suggest that the main production arises in the upper atmosphere from CO$_2$ photolysis followed by catalytic HO$_x$ reactions. The strongest destruction does not take place in the troposphere, as was the case in Gebauer et al. (2017) for an early-Earth analog planet around the Sun, but instead in the middle atmosphere where H$_2$O photolysis is the strongest. This result was driven by the strong Lyman-$\alpha$-radiation output of AD Leo, which efficiently photolyzes H$_2$O. Results further suggest that early Earth-like atmospheres of planets orbiting an M-dwarf like AD Leo are in absolute terms less destructive for atmospheric O$_2$ than for early-Earth analog planets around the Sun despite higher concentrations of reduced gases such as e.g. H$_2$, CH$_4$ and CO. Hence the net primary productivity (NPP) required to produce the same amount of atmospheric O$_2$ at the surface is reduced. This implies that a possible Great Oxidation event, analogous to that on Earth, would have occurred earlier in time in analog atmospheres around M-dwarfs., Comment: 40 pages, 22 figures, 2 tables, peer-review Version, final publication is available from Mary Ann Liebert, Inc., publishers http://doi.org/10.1089/ast.2017.1723

Understanding the evolution of Earth and potentially habitable Earth-like worlds is essential to fathom our origin in the Universe. The search for Earth-like planets in the habitable zone and investigation of their atmospheres with climate and photochemical models is a central focus in exoplanetary science. Taking the evolution of Earth as a reference for Earth-like planets, a central scientific goal is to understand what the interactions were between atmosphere, geology, and biology on early Earth. The Great Oxidation Event (GOE) in Earth's history was certainly caused by their interplay, but the origin and controlling processes of this occurrence are not well understood, the study of which will require interdisciplinary, coupled models. In this work, we present results from our newly developed Coupled Atmosphere Biogeochemistry model in which atmospheric O$_2$ concentrations are fixed to values inferred by geological evidence. Applying a unique tool, ours is the first quantitative analysis of catalytic cycles that governed O$_2$ in early Earth's atmosphere near the GOE. Complicated oxidation pathways play a key role in destroying O$_2$, whereas in the upper atmosphere, most O$_2$ is formed abiotically via CO$_2$ photolysis. The O$_2$ bistability found by Goldblatt et al. (2006) is not observed in our calculations likely due to our detailed CH$_4$ oxidation scheme. We calculate increased CH$_4$ with increasing O$_2$ during the GOE. For a given atmospheric surface flux, different atmospheric states are possible; however, the net primary productivity (NPP) of the biosphere that produces O$_2$ is unique. Mixing, CH$_4$ fluxes, ocean solubility, and mantle/crust properties strongly affect NPP and surface O$_2$ fluxes. Regarding exoplanets, different "states" of O$_2$ could exist for similar biomass output. Strong geological activity could lead to false negatives for life., Comment: 72 pages, 28 figures, 7 tables

Spectral characterization of Super-Earth atmospheres for planets orbiting in the Habitable Zone of M-dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of atmospheric biosignatures (species associated with life). Our work applies a global-mean radiative-convective-photochemical column model assuming a planet with an Earth-like biomass and planetary development. We investigated planets with gravities of 1g and 3g and a surface pressure of one bar around central stars with spectral classes from M0 to M7. The spectral signals of the calculated planetary scenarios have been presented by Rauer et al. (2011). The main motivation of the present work is to perform a deeper analysis of the chemical processes in the planetary atmospheres. We apply a diagnostic tool, the Pathway Analysis Program, to shed light on the photochemical pathways that form and destroy biosignature species. Ozone is a potential biosignature for complex- life. An important result of our analysis is a shift in the ozone photochemistry from mainly Chapman production (which dominates in the terrestrial stratosphere) to smog-dominated ozone production for planets in the Habitable Zone of cooler (M5-M7)-class dwarf stars. This result is associated with a lower energy flux in the UVB wavelength range from the central star, hence slower planetary atmospheric photolysis of molecular oxygen, which slows the Chapman ozone production., Comment: 53 pages, 7 figures, manuscript accepted at "Astrobiology" Journal

We report here that the equation for H2O Rayleigh scattering was incorrectly stated in the original paper [arXiv:1009.5814]. Instead of a quadratic dependence on refractivity r, we accidentally quoted an r^4 dependence. Since the correct form of the equation was implemented into the model, scientific results are not affected., Comment: accepted to Astronomy&Astrophysics

The M-type star Gliese 581 is orbited by at least one terrestrial planet candidate in the habitable zone, i.e. GL 581 d. Orbital simulations have shown that additional planets inside the habitable zone of GL 581 would be dynamically stable. Recently, two further planet candidates have been claimed, one of them in the habitable zone. In view of the ongoing search for planets around M stars which is expected to result in numerous detections of potentially habitable Super-Earths, we take the GL 581 system as an example to investigate such planets. In contrast to previous studies of habitability in the GL 581 system, we use a consistent atmospheric model to assess surface conditions and habitability. Furthermore, we perform detailed atmospheric simulations for a much larger subset of potential planetary and atmospheric scenarios than previously considered. A 1D radiative-convective atmosphere model is used to calculate temperature and pressure profiles of model atmospheres, which we assumed to be composed of molecular nitrogen, water, and carbon dioxide. In these calculations, key parameters such as surface pressure and CO2 concentration as well as orbital distance and planetary mass are varied. Results imply that surface temperatures above freezing could be obtained, independent of the here considered atmospheric scenarios, at an orbital distance of 0.117 AU. For an orbital distance of 0.146 AU, CO2 concentrations as low as 10 times the present Earth's value are sufficient to warm the surface above the freezing point of water. At 0.175 AU, only scenarios with CO2 concentrations of 5% and 95% were found to be habitable. Hence, an additional Super-Earth planet in the GL 581 system in the previously determined dynamical stability range would be considered a potentially habitable planet., Comment: 5 pages, 4 figures, accepted in Astronomy&Astrophysics

Atmospheric temperature and mixing ratio profiles of terrestrial planets vary with the spectral energy flux distribution for different types of M-dwarf stars and the planetary gravity. We investigate the resulting effects on the spectral appearance of molecular absorption bands, that are relevant as indicators for potential planetary habitability during primary and secondary eclipse for transiting terrestrial planets with Earth-like biomass emissions. Atmospheric profiles are computed using a plane-parallel, 1D climate model coupled with a chemistry model. We then calculate simulated spectra using a line-by-line radiative transfer model. We find that emission spectra during secondary eclipse show increasing absorption of methane, water and ozone for planets orbiting quiet M0-M3 dwarfs and the active M-type star AD Leo compared to solar type central stars. However, for planets orbiting very cool and quiet M dwarfs (M4 to M7), increasing temperatures in the mid-atmosphere lead to reduced absorption signals, making the detection of molecules more difficult in such scenarios. Transmission spectra during primary eclipse show strong absorption features of CH4, N2O and H2O for planets orbiting quiet M0-M7 stars and AD Leo. The N2O absorption of an Earth-sized planet orbiting a quiet M7 star can even be as strong as the CO2 signal. However, ozone absorption decreases for planets orbiting such cool central stars due to chemical effects in the atmosphere. To investigate the effect on the spectroscopic detection of absorption bands with potential future satellite missions, we compute signal-to-noise-ratios (SNR) for a James Webb Space Telescope (JWST)-like aperture telescope., Comment: accepted in A&A

The planetary system around the M star Gliese 581 contains at least three close-in potentially low-mass planets, GL 581 c, d, and e. In order to address the question of the habitability of GL 581 d, we performed detailed atmospheric modeling studies for several planetary scenarios. A 1D radiative-convective model was used to calculate temperature and pressure profiles of model atmospheres, assumed to be composed of molecular nitrogen, water, and carbon dioxide. The model allows for changing surface pressures caused by evaporation/condensation of water and carbon dioxide. Furthermore, the treatment of the energy transport has been improved in the model to account in particular for high CO2, high-pressure Super-Earth conditions. For four high-pressure scenarios of our study, the resulting surface temperatures were above 273 K, indicating a potential habitability of the planet. These scenarios include three CO2-dominated atmospheres (95% CO2 concentration with 5, 10, and 20 bar surface pressure) and a high-pressure CO2-enriched atmosphere (5% CO2 concentration with 20 bar surface pressure). For all other considered scenarios, the calculated GL 581 d surface temperatures were below the freezing point of water, suggesting that GL 581 d would not be habitable then. The results for our CO2-dominated scenarios confirm very recent model results by Wordsworth et al. (2010). However, our model calculations imply that also atmospheres that are not CO2-dominated (i.e., 5% vmr instead of 95% vmr) could result in habitable conditions for GL 581 d., Comment: accepted for publication in Astronomy&Astrophysics 18 pages, 10 figures, 7 tables, corrected typo in eq. 3 for H2O Rayleigh scattering (this version, 31.1.2013)

The effects of multi-layered clouds in the atmospheres of Earth-like planets orbiting different types of stars are studied. The radiative effects of cloud particles are directly correlated with their wavelength-dependent optical properties. Therefore the incident stellar spectra may play an important role for the climatic effect of clouds. We discuss the influence of clouds with mean properties measured in the Earth's atmosphere on the surface temperatures and Bond albedos of Earth-like planets orbiting different types of main sequence dwarf stars., Comment: accepted for publication in A&A