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Chirality in tellurium derives from a Peierls distortion driven by strong electron-phonon coupling, making this material a unique candidate for observing a light-induced topological phase transition. By using time- and angle-resolved photoelectron spectroscopy (trARPES), we reveal that upon near-infrared photoexcitation the Peierls gap is modulated by displacively excited coherent phonons with $\mathrm{A_{1g}}$ symmetry as well as chiral-symmetry-breaking $\mathrm{E'_{LO}}$ modes. By comparison with state-of-the-art TDDFT+U calculations, we reveal the microscopic origin of the in-phase oscillations of band edges, due to phonon-induced modulation of the effective Hubbard $U$ term., Comment: 6 pages, 3 figures

Chatbots have become integral to various application domains, including those with safety-critical considerations. As a result, there is a pressing need for methods that ensure chatbots consistently adhere to expected, safe behaviours. In this paper, we introduce RV4Chatbot, a Runtime Verification framework designed to monitor deviations in chatbot behaviour. We formalise expected behaviours as interaction protocols between the user and the chatbot. We present the RV4Chatbot design and describe two implementations that instantiate it: RV4Rasa, for monitoring chatbots created with the Rasa framework, and RV4Dialogflow, for monitoring Dialogflow chatbots. Additionally, we detail experiments conducted in a factory automation scenario using both RV4Rasa and RV4Dialogflow., Comment: In Proceedings FMAS2024, arXiv:2411.13215

This study presents an \textit{ab initio} investigation of the XANES spectra at the aluminum K edge for three compounds: Al$_2$O$_3$, AlF$_3$ and AlCl$_3$, where the Al atoms share the same oxidation state~(III) and are coordinated in an octahedral symmetry. The XANES spectra calculated within the independent-particle approximation reveal significant differences, including shifts in the spectrum onset, variations in the spectral shapes, and the presence of a pre-peak in the case of AlCl$_3$, all in correspondence with the behavior of the PDOS of the absorbing atom in the different materials. The origin of the features stems from the specific band structure of each compound. When electron--hole interactions are taken into account through the solution of the Bethe-Salpeter equation, a series of dark and bright excitons with large binding energies and Frenkel character is obtained. The strong excitonic effects lead to the suppression of the pre-peak in AlCl$_3$ and further accentuate the differences among the three Al K-edge spectra.

The observation of a resonance structure in the opening angle of the electron-positron pairs in the $^{7}$Li(p,\ee) $^{8}$Be reaction was claimed and interpreted as the production and subsequent decay of a hypothetical particle (X17). Similar excesses, consistent with this particle, were later observed in processes involving $^{4}$He and $^{12}$C nuclei with the same experimental technique. The MEG II apparatus at PSI, designed to search for the $\mu^+ \rightarrow \mathrm{e}^+ \gamma$ decay, can be exploited to investigate the existence of this particle and study its nature. Protons from a Cockroft-Walton accelerator, with an energy up to 1.1 MeV, were delivered on a dedicated Li-based target. The $\gamma$ and the e$^{+}$e$^{-}$ pair emerging from the $^8\mathrm{Be}^*$ transitions were studied with calorimeters and a spectrometer, featuring a broader angular acceptance than previous experiments. We present in this paper the analysis of a four-week data-taking in 2023 with a beam energy of 1080 keV, resulting in the excitation of two different resonances with Q-value \SI{17.6}{\mega\electronvolt} and \SI{18.1}{\mega\electronvolt}. No significant signal was found, and limits at \SI{90}{\percent} C.L. on the branching ratios (relative to the $\gamma$ emission) of the two resonances to X17 were set, $R_{17.6} < 1.8 \times 10^{-6} $ and $R_{18.1} < 1.2 \times 10^{-5} $., Comment: 11 pages, 9 figures, submitted to EPJC

We study online Bayesian persuasion problems in which an informed sender repeatedly faces a receiver with the goal of influencing their behavior through the provision of payoff-relevant information. Previous works assume that the sender has knowledge about either the prior distribution over states of nature or receiver's utilities, or both. We relax such unrealistic assumptions by considering settings in which the sender does not know anything about the prior and the receiver. We design an algorithm that achieves sublinear regret with respect to an optimal signaling scheme, and we also provide a collection of lower bounds showing that the guarantees of such an algorithm are tight. Our algorithm works by searching a suitable space of signaling schemes in order to learn receiver's best responses. To do this, we leverage a non-standard representation of signaling schemes that allows to cleverly overcome the challenge of not knowing anything about the prior over states of nature and receiver's utilities. Finally, our results also allow to derive lower/upper bounds on the sample complexity of learning signaling schemes in a related Bayesian persuasion PAC-learning problem.

Modeling the intrinsic alignment (IA) of galaxies poses a challenge to weak lensing analyses. The Dark Energy Survey is expected to be less impacted by IA when limited to blue, star-forming galaxies. The cosmological parameter constraints from this blue cosmic shear sample are stable to IA model choice, unlike passive galaxies in the full DES Y3 sample, the goodness-of-fit is improved and the $\Omega_{m}$ and $S_8$ better agree with the cosmic microwave background. Mitigating IA with sample selection, instead of flexible model choices, can reduce uncertainty in $S_8$ by a factor of 1.5., Comment: Data access available at https://jamiemccullough.github.io/data/blueshear/

We study the Cahn-Hilliard equation with non-degenerate concentration-dependent mobility and logarithmic potential in two dimensions. We show that any weak solution is unique, exhibits propagation of uniform-in-time regularity, and stabilizes towards an equilibrium state of the Ginzburg-Landau free energy for large times. These results improve the state of the art dating back to a work by Barrett and Blowey. Our analysis relies on the combination of enhanced energy estimates, elliptic regularity theory and tools in critical Sobolev spaces.

In the study of algebraic curves with many points over a finite field, a well known general problem is to understanding better the properties of $\mathbb{F}_{q^2}$-maximal curves whose genera fall in the higher part of the spectrum of the genera of all $\mathbb{F}_{q^2}$-maximal curves. This problem is still open for genera smaller than $ \lfloor \frac{1}{6}(q^2-q+4) \rfloor$. In this paper we consider the case of $\mathfrak{g}=\frac{1}{8}(q-1)^2$ where $q\equiv 1\pmod{4}$ and the curve is the Galois cover of the Hermitian curve w.r.t to a cyclic automorphism group of order $4$. Our contributions concern Frobenius embedding, Weierstrass semigroups and automorphism groups.

The number density and redshift evolution of optically selected galaxy clusters offer an independent measurement of the amplitude of matter fluctuations, $S_8$. However, recent results have shown that clusters chosen by the redMaPPer algorithm show richness-dependent biases that affect the weak lensing signals and number densities of clusters, increasing uncertainty in the cluster mass calibration and reducing their constraining power. In this work, we evaluate an alternative cluster proxy, outskirt stellar mass, $M_{\textrm{out}}$, defined as the total stellar mass within a $[50,100]$ kpc envelope centered on a massive galaxy. This proxy exhibits scatter comparable to redMaPPer richness, $\lambda$, but is less likely to be subject to projection effects. We compare the Dark Energy Survey Year 3 redMaPPer cluster catalog with a $M_{\textrm{out}}$ selected cluster sample from the Hyper-Suprime Camera survey. We use weak lensing measurements to quantify and compare the scatter of $M_{\textrm{out}}$ and $\lambda$ with halo mass. Our results show $M_{\textrm{out}}$ has a scatter consistent with $\lambda$, with a similar halo mass dependence, and that both proxies contain unique information about the underlying halo mass. We find $\lambda$-selected samples introduce features into the measured $\Delta \Sigma$ signal that are not well fit by a log-normal scatter only model, absent in $M_{\textrm{out}}$ selected samples. Our findings suggest that $M_{\textrm{out}}$ offers an alternative for cluster selection with more easily calibrated selection biases, at least at the generally lower richnesses probed here. Combining both proxies may yield a mass proxy with a lower scatter and more tractable selection biases, enabling the use of lower mass clusters in cosmology. Finally, we find the scatter and slope in the $\lambda-M_{\textrm{out}}$ scaling relation to be $0.49 \pm 0.02$ and $0.38 \pm 0.09$., Comment: 22 pages, 8 figures, 4 tables, submitted to PRD

We study principal-agent problems where a farsighted agent takes costly actions in an MDP. The core challenge in these settings is that agent's actions are hidden to the principal, who can only observe their outcomes, namely state transitions and their associated rewards. Thus, the principal's goal is to devise a policy that incentives the agent to take actions leading to desirable outcomes. This is accomplished by committing to a payment scheme (a.k.a. contract) at each step, specifying a monetary transfer from the principal to the agent for every possible outcome. Interestingly, we show that Markovian policies are unfit in these settings, as they do not allow to achieve the optimal principal's utility and are constitutionally intractable. Thus, accounting for history in unavoidable, and this begets considerable additional challenges compared to standard MDPs. Nevertheless, we design an efficient algorithm to compute an optimal policy, leveraging a compact way of representing histories for this purpose. Unfortunately, the policy produced by such an algorithm cannot be readily implemented, as it is only approximately incentive compatible, meaning that the agent is incentivized to take the desired actions only approximately. To fix this, we design an efficient method to make such a policy incentive compatible, by only introducing a negligible loss in principal's utility. This method can be generally applied to any approximately-incentive-compatible policy, and it generalized a related approach that has already been discovered for classical principal-agent problems to more general settings in MDPs.

Chemical functionalization of carbon nanodots (CNDs) offers a valuable opportunity to tailor multifunctionality in these nanocarbons, by engineering the composition of their molecular surface. Therefore, it is important to elucidate the type and amount of CNDs functionalization to be able to design their properties accurately. CNDs are often functionalized through amide coupling without validating the degree of functionalization. As a measure of functionalization, the amounts of primary amines via Kaiser test (KT) or imine reactions of the bare CNDs is often considered. However, this may lead to overestimating the degree of functionalization obtained by the pure amide coupling due to different reaction mechanisms and involved intermediates. Herein, four different CNDs prepared by microwave-assisted synthesis from arginine or citric acid with varying amounts of ethylenediamine are presented. We resorted to a combination of physicochemical methods to provide elemental, structural, and optical information. By that, we developed a method to quantify the degree of functionalization by amide coupling and show that the functionalization is lower than one would expect. Comparing experimental optical features of the CNDs with different computed model systems further allows us to provide a more advanced vision of structure-property relationships in these still elusive nanocarbons.

The use of coupled cavities with high quality factor is of undoubted interest for several applications including those concerning quantum sensing and metrology. Here we report on a coupled cavity configuration in which a high $Q$-factor elliptical TESLA-shaped superconducting cavity is coupled with a high permittivity ($\varepsilon_\mathrm{r}$) dielectric resonator. We carried out first tests using a SrTiO$_3$ (STO) resonator at 0.1 GHz, whose permittivity has been observed to reach values higher than 30000 a 0.16 K. The sensitivities of such configurations are discussed both in strong coupling and weak coupling regime. In particular we show that the notch of the coupled system has, as a function of the permittivity, a frequency sensitivity of 2.8 MHz for $\varepsilon_\mathrm{r} \approx 230$. These results highlight the potential of the coupled resonator systems as microwave sensors and are useful for the engineering of high permittivity resonators for applications at cryogenic temperatures., Comment: 10 pages, 9 figures

This study deals with the understanding of hydrogen atom scattering from graphene, a process critical for exploring C-H bond formation and energy transfer during the atom surface collision. In our previous work (J.Chem.Phys \textbf{159}, 194102, (2023)), starting from a cell with 24 carbon atoms treated periodically, we have achieved quantum dynamics (QD) simulations with a reduced-dimensional model (15D) and a simulation in full dimensionality (75D). In the former work, the H atom attacked the top of a single C atom, enabling a comparison of QD simulation results with classical molecular dynamics (cMD). Our approach required the use of sophisticated techniques such as Monte Carlo Canonical Polyadic Decomposition (MCCPD) and Multilayer Multi-Configuration Time-Dependent Hartree (ML-MCTDH), as well as a further development of quantum flux calculations. We could benchmark our calculations by comparison with cMD calculations. We have now refined our method to better mimic experimental conditions. Specifically, rather than sending the H atom to a specific position on the surface, we have employed a plane wave for the H atom in directions parallel to the surface. Key findings for these new simulations include the identification of discrepancies between classical molecular dynamics (cMD) simulations and experiments, which are attributed to both the potential energy surface (PES) and quantum effects. Additionally, the study sheds light on the role of classical collective normal modes during collisions, providing insights into energy transfer processes. The results validate the robustness of our simulation methodologies and highlight the importance of considering quantum mechanical effects in the study of hydrogen-graphene interactions.

We study online learning in \emph{constrained MDPs} (CMDPs), focusing on the goal of attaining sublinear strong regret and strong cumulative constraint violation. Differently from their standard (weak) counterparts, these metrics do not allow negative terms to compensate positive ones, raising considerable additional challenges. Efroni et al. (2020) were the first to propose an algorithm with sublinear strong regret and strong violation, by exploiting linear programming. Thus, their algorithm is highly inefficient, leaving as an open problem achieving sublinear bounds by means of policy optimization methods, which are much more efficient in practice. Very recently, Muller et al. (2024) have partially addressed this problem by proposing a policy optimization method that allows to attain $\widetilde{\mathcal{O}}(T^{0.93})$ strong regret/violation. This still leaves open the question of whether optimal bounds are achievable by using an approach of this kind. We answer such a question affirmatively, by providing an efficient policy optimization algorithm with $\widetilde{\mathcal{O}}(\sqrt{T})$ strong regret/violation. Our algorithm implements a primal-dual scheme that employs a state-of-the-art policy optimization approach for adversarial (unconstrained) MDPs as primal algorithm, and a UCB-like update for dual variables., Comment: arXiv admin note: text overlap with arXiv:2405.14372

We study online learning in constrained Markov decision processes (CMDPs) in which rewards and constraints may be either stochastic or adversarial. In such settings, Stradi et al.(2024) proposed the first best-of-both-worlds algorithm able to seamlessly handle stochastic and adversarial constraints, achieving optimal regret and constraint violation bounds in both cases. This algorithm suffers from two major drawbacks. First, it only works under full feedback, which severely limits its applicability in practice. Moreover, it relies on optimizing over the space of occupancy measures, which requires solving convex optimization problems, an highly inefficient task. In this paper, we provide the first best-of-both-worlds algorithm for CMDPs with bandit feedback. Specifically, when the constraints are stochastic, the algorithm achieves $\widetilde{\mathcal{O}}(\sqrt{T})$ regret and constraint violation, while, when they are adversarial, it attains $\widetilde{\mathcal{O}}(\sqrt{T})$ constraint violation and a tight fraction of the optimal reward. Moreover, our algorithm is based on a policy optimization approach, which is much more efficient than occupancy-measure-based methods.

This work provides a mathematical derivation of a quasi-stationary model for multimode parametric down-conversion, which was presented in [Gatti et al., Sci. Rep. 13, 16786] with heuristic arguments. The model is here derived from the 3D+1 propagation equation of the quantum fields in a nonlinear crystal, and its approximations discussed thoroughly. Thanks to its relative simplicity, and to the fact that it is valid in any gain regime, both at a quantum and classical level, it allows a unified description of disparate experimental observations conducted over the last 20 years, often described in the past by means of limited ad hoc models., Comment: Accepted for publication on Phyl.Trans. of The Royal Soc. A, will appear with DOI 10.1098/rsta.2023.0334. Main ms: 14 pages, 6 figures. Supplementary: 9 pages, 6 figures

Feature-based methods are commonly used to explain model predictions, but these methods often implicitly assume that interpretable features are readily available. However, this is often not the case for high-dimensional data, and it can be hard even for domain experts to mathematically specify which features are important. Can we instead automatically extract collections or groups of features that are aligned with expert knowledge? To address this gap, we present FIX (Features Interpretable to eXperts), a benchmark for measuring how well a collection of features aligns with expert knowledge. In collaboration with domain experts, we propose FIXScore, a unified expert alignment measure applicable to diverse real-world settings across cosmology, psychology, and medicine domains in vision, language and time series data modalities. With FIXScore, we find that popular feature-based explanation methods have poor alignment with expert-specified knowledge, highlighting the need for new methods that can better identify features interpretable to experts.

We present constraints on the $f(R)$ gravity model using a sample of 1,005 galaxy clusters in the redshift range $0.25 - 1.78$ that have been selected through the thermal Sunyaev-Zel'dovich effect (tSZE) from South Pole Telescope (SPT) data and subjected to optical and near-infrared confirmation with the Multi-component Matched Filter (MCMF) algorithm. We employ weak gravitational lensing mass calibration from the Dark Energy Survey (DES) Year 3 data for 688 clusters at $z < 0.95$ and from the Hubble Space Telescope (HST) for 39 clusters with $0.6 < z < 1.7$. Our cluster sample is a powerful probe of $f(R)$ gravity, because this model predicts a scale-dependent enhancement in the growth of structure, which impacts the halo mass function (HMF) at cluster mass scales. To account for these modified gravity effects on the HMF, our analysis employs a semi-analytical approach calibrated with numerical simulations. Combining calibrated cluster counts with primary cosmic microwave background (CMB) temperature and polarization anisotropy measurements from the Planck2018 release, we derive robust constraints on the $f(R)$ parameter $f_{R0}$. Our results, $\log_{10} |f_{R0}| < -5.32$ at the 95 % credible level, are the tightest current constraints on $f(R)$ gravity from cosmological scales. This upper limit rules out $f(R)$-like deviations from general relativity that result in more than a $\sim$20 % enhancement of the cluster population on mass scales $M_\mathrm{200c}>3\times10^{14}M_\odot$., Comment: 21 pages, 6 figures, submitted to Phys. Rev. D

We address the Reynolds-number dependence of the turbulent skin-friction drag reduction induced by streamwise-travelling waves of spanwise wall oscillations. The study relies on direct numerical simulations of drag-reduced flows in a plane open channel at friction Reynolds numbers in the range $1000 \le Re_\tau \le 6000$, which is the widest range considered so far in simulations with spanwise forcing. Our results corroborate the validity of the predictive model proposed by Gatti & Quadrio, J. Fluid Mech. (2016): regardless of the control parameters, the drag reduction decreases monotonically with $Re$, at a rate that depends on the drag reduction itself and on the skin-friction of the uncontrolled flow. We do not find evidence in support of the results of Marusic et al., Nat. Comm. (2021), which instead report by experiments an increase of the drag reduction with $Re$ in turbulent boundary layers, for control parameters that target low-frequency, outer-scaled motions. Possible explanations for this discrepancy are provided, including obvious differences between open channel flows and boundary layers, and possible limitations of laboratory experiments.

This study presents the design, simulation, and experimental characterization of a superconducting transmon qubit circuit prototype for potential applications in dark matter detection experiments. We describe a planar circuit design featuring two non-interacting transmon qubits, one with fixed frequency and the other flux tunable. Finite-element simulations were employed to extract key Hamiltonian parameters and optimize component geometries. The qubit was fabricated and then characterized at $20$ mK, allowing for a comparison between simulated and measured qubit parameters. Good agreement was found for transition frequencies and anharmonicities (within 1\% and 10\% respectively) while coupling strengths exhibited larger discrepancies (30\%). We discuss potential causes for measured coherence times falling below expectations ($T_1\sim\,$1-2 \textmu s) and propose strategies for future design improvements. Notably, we demonstrate the application of a hybrid 3D-2D simulation approach for energy participation ratio evaluation, yielding a more accurate estimation of dielectric losses. This work represents an important first step in developing planar Quantum Non-Demolition (QND) single-photon counters for dark matter searches, particularly for axion and dark photon detection schemes.

Rested and Restless Bandits are two well-known bandit settings that are useful to model real-world sequential decision-making problems in which the expected reward of an arm evolves over time due to the actions we perform or due to the nature. In this work, we propose Graph-Triggered Bandits (GTBs), a unifying framework to generalize and extend rested and restless bandits. In this setting, the evolution of the arms' expected rewards is governed by a graph defined over the arms. An edge connecting a pair of arms $(i,j)$ represents the fact that a pull of arm $i$ triggers the evolution of arm $j$, and vice versa. Interestingly, rested and restless bandits are both special cases of our model for some suitable (degenerated) graph. As relevant case studies for this setting, we focus on two specific types of monotonic bandits: rising, where the expected reward of an arm grows as the number of triggers increases, and rotting, where the opposite behavior occurs. For these cases, we study the optimal policies. We provide suitable algorithms for all scenarios and discuss their theoretical guarantees, highlighting the complexity of the learning problem concerning instance-dependent terms that encode specific properties of the underlying graph structure.

Statistics that capture the directional dependence of the baryon distribution in the cosmic web enable unique tests of cosmology and astrophysical feedback. We use constrained oriented stacking of thermal Sunyaev-Zel'dovich (tSZ) maps to measure the anisotropic distribution of hot gas $2.5-40$ Mpc away from galaxy clusters embedded in massive filaments and superclusters. The cluster selection and orientation (at a scale of $\sim15$ Mpc) use Dark Energy Survey (DES) Year 3 data, while expanded tSZ maps from the Atacama Cosmology Telescope Data Release 6 enable a $\sim3\times$ more significant measurement of the extended gas compared to the technique's proof-of-concept. Decomposing stacks into cosine multipoles of order $m$, we detect a dipole ($m=1$) and quadrupole ($m=2$) at $8-10\sigma$, as well as evidence for $m=4$ signal at up to $6\sigma$, indicating sensitivity to late-time non-Gaussianity. We compare to the Cardinal simulations with spherical gas models pasted onto dark matter halos. The fiducial tSZ data can discriminate between two models that deplete pressure differently in low-mass halos (mimicking astrophysical feedback), preferring higher average pressure in extended structures. However, uncertainty in the amount of cosmic infrared background contamination reduces the constraining power. Additionally, we apply the technique to DES galaxy density and weak lensing to study for the first time their oriented relationships with tSZ. In the tSZ-to-lensing relation, averaged on 7.5 Mpc (transverse) scales, we observe dependence on redshift but not shape or radial distance. Thus, on large scales, the superclustering of gas pressure, galaxies, and total matter is coherent in shape and extent., Comment: 45 pages, 18 figures, submitted to ApJ

We explore linear and non-linear dimensionality reduction techniques for statistical inference of parameters in cosmology. Given the importance of compressing the increasingly complex data vectors used in cosmology, we address questions that impact the constraining power achieved, such as: Are currently used methods effectively lossless? Under what conditions do nonlinear methods, typically based on neural nets, outperform linear methods? Through theoretical analysis and experiments with simulated weak lensing data vectors we compare three standard linear methods and neural network based methods. We propose two linear methods that outperform all others while using less computational resources: a variation of the MOPED algorithm we call e-MOPED and an adaptation of Canonical Correlation Analysis (CCA), which is a method new to cosmology but well known in statistics. Both e-MOPED and CCA utilize simulations spanning the full parameter space, and rely on the sensitivity of the data vector to the parameters of interest. The gains we obtain are significant compared to compression methods used in the literature: up to 30% in the Figure of Merit for $\Omega_m$ and $S_8$ in a realistic Simulation Based Inference analysis that includes statistical and systematic errors. We also recommend two modifications that improve the performance of all methods: First, include components in the compressed data vector that may not target the key parameters but still enhance the constraints on due to their correlations. The gain is significant, above 20% in the Figure of Merit. Second, compress Gaussian and non-Gaussian statistics separately -- we include two summary statistics of each type in our analysis., Comment: 23 pages, 9 figures. Comments welcome. To be submitted to PRD. Implementation examples in https://github.com/98minsu/CosmoCompression/

Using a sample of 2800 galaxy clusters identified in the Dark Energy Survey across the redshift range $0.20 < z < 0.60$, we characterize the hierarchical assembly of Bright Central Galaxies (BCGs) and the surrounding intracluster light (ICL). To quantify hierarchical formation we use the stellar mass - halo mass (SMHM) relation for the BCG+ICL system and incorporate the magnitude gap (M14), the difference in brightness between the BCG (measured within 30kpc) and 4th brightest cluster member galaxy within 0.5 $R_{200,c}$. The inclusion of M14, which traces BCG hierarchical growth, increases the slope and decreases the intrinsic scatter in the SMHM relation, highlighting that it is a latent variable within the BCG+ICL SMHM relation. Moreover, the correlation with M14 decreases at large radii from the BCG's centre. However, the stellar light within the BCG+ICL transition region (30kpc - 80kpc) most strongly correlates with the dark matter halo mass and has a statistically significant correlation with M14. As the light in the transition region and M14 are independent measurements, the transition region may grow as a result of the BCG's hierarchical two-phase formation. Additionally, as M14 and ICL result from hierarchical growth, we use a stacked sample and find that clusters with large M14 values are characterized by larger ICL and BCG+ICL fractions, which illustrates that the merger processes that build the BCG stellar mass also grow the ICL. Furthermore, this may suggest that M14 combined with the ICL fraction can be used as a method to identify dynamically relaxed clusters., Comment: 16 pages, 5 Figures, submitted to MNRAS on 8/30/2024

Grapevine winter pruning is a labor-intensive and repetitive process that significantly influences the quality and quantity of the grape harvest and produced wine of the following season. It requires a careful and expert detection of the point to be cut. Because of its complexity, repetitive nature and time constraint, the task requires skilled labor that needs to be trained. This extended abstract presents the computer vision pipeline employed in project Vinum, using detectron2 as a segmentation network and keypoint visual odometry to merge different observation into a single pointcloud used to make informed pruning decisions.

DarkSide-20k (DS-20k) is a dark matter detection experiment under construction at the Laboratori Nazionali del Gran Sasso (LNGS) in Italy. It utilises ~100 t of low radioactivity argon from an underground source (UAr) in its inner detector, with half serving as target in a dual-phase time projection chamber (TPC). The UAr cryogenics system must maintain stable thermodynamic conditions throughout the experiment's lifetime of >10 years. Continuous removal of impurities and radon from the UAr is essential for maximising signal yield and mitigating background. We are developing an efficient and powerful cryogenics system with a gas purification loop with a target circulation rate of 1000 slpm. Central to its design is a condenser operated with liquid nitrogen which is paired with a gas heat exchanger cascade, delivering a combined cooling power of >8 kW. Here we present the design choices in view of the DS-20k requirements, in particular the condenser's working principle and the cooling control, and we show test results obtained with a dedicated benchmarking platform at CERN and LNGS. We find that the thermal efficiency of the recirculation loop, defined in terms of nitrogen consumption per argon flow rate, is 95 % and the pressure in the test cryostat can be maintained within $\pm$(0.1-0.2) mbar. We further detail a 5-day cool-down procedure of the test cryostat, maintaining a cooling rate typically within -2 K/h, as required for the DS-20k inner detector. Additionally, we assess the circuit's flow resistance, and the heat transfer capabilities of two heat exchanger geometries for argon phase change, used to provide gas for recirculation. We conclude by discussing how our findings influence the finalisation of the system design, including necessary modifications to meet requirements and ongoing testing activities., Comment: 45 pages, 24 figures

Using 1533 type Ia supernovae (SNe Ia) from the five-year sample of the Dark Energy Survey (DES), we investigate the effects of projected galactocentric separation between the SNe and their host galaxies on their light curves and standardization. We show, for the first time, that the difference in SN Ia post-standardization brightnesses between high and low-mass hosts reduces from $0.078\pm0.011$ mag in the full sample to $0.036 \pm 0.018$ mag for SNe Ia located in the outer regions of their host galaxies, while increasing to $0.100 \pm 0.014$ mag for SNe in the inner regions. In these inner regions, the step can be reduced (but not removed) using a model where the $R_V$ of dust along the line-of-sight to the SN changes as a function of galaxy properties. To explain the remaining difference, we use the distributions of the SN Ia stretch parameter to test whether the inferred age of SN progenitors are more varied in the inner regions of galaxies. We find that the proportion of high-stretch SNe Ia in red (older) environments is more prominent in outer regions and that the outer regions stretch distributions are overall more homogeneous compared to inner regions, but conclude that this effect cannot explain the reduction in significance of any Hubble residual step in outer regions. We conclude that the standardized distances of SNe Ia located in the outer regions of galaxies are less affected by their global host galaxy properties than those in the inner regions., Comment: 17 pages, 13 figures

The present state of cosmology is facing a crisis where there is a fundamental disagreement in measurements of the Hubble constant ($H_{0}$), with significant tension between the early and late universe methods. Type Ia supernovae (SNe Ia) are important to measuring $H_{0}$ through the astronomical distance ladder. However, there remains potential to better standardise SN Ia light curves by using known dependencies on host galaxy properties after the standard light curve width and colour corrections have been applied to the peak SN Ia luminosities. To explore this, we use the 5-year photometrically identified SNe Ia sample obtained by the Dark Energy Survey, along with host galaxy spectra obtained by the Australian Dark Energy Survey. Using host galaxy spectroscopy, we find a significant trend with the equivalent width (EW) of the [OII] $\lambda\lambda$ 3727, 29 doublet, a proxy for specific star formation rate, and Hubble residuals. We find that the correlation with [OII] EW is a powerful alternative to the commonly used mass step after initial light curve corrections. We applied our [OII] EW correction to a sample of 20 SN Ia hosted by calibrator galaxies observed using WiFeS, and examined the impact on both the SN Ia absolute magnitude and $H_{0}$. We then explored different [OII] EW corrections and found $H_{0}$ values ranging between $72.80$ to $73.28~\mathrm{km} \mathrm{s}^{-1} \mathrm{Mpc}^{-1}$. Notably, even after using an additional [OII] EW correction, the impact of host galaxy properties in standardising SNe Ia appears limited in reducing the current tension ($\sim$5$\sigma$) with the Cosmic Microwave Background result for $H_{0}$., Comment: 16 pages, 13 figures. Submitting to MNRAS

Characterization of the redshift distribution of ensembles of galaxies is pivotal for large scale structure cosmological studies. In this work, we focus on improving the Self-Organizing Map (SOM) methodology for photometric redshift estimation (SOMPZ), specifically in anticipation of the Dark Energy Survey Year 6 (DES Y6) data. This data set, featuring deeper and fainter galaxies than DES Year 3 (DES Y3), demands adapted techniques to ensure accurate recovery of the underlying redshift distribution. We investigate three strategies for enhancing the existing SOM-based approach used in DES Y3: 1) Replacing the Y3 SOM algorithm with one tailored for redshift estimation challenges; 2) Incorporating $\textit{g}$-band flux information to refine redshift estimates (i.e. using $\textit{griz}$ fluxes as opposed to only $\textit{riz}$); 3) Augmenting redshift data for galaxies where available. These methods are applied to DES Y3 data, and results are compared to the Y3 fiducial ones. Our analysis indicates significant improvements with the first two strategies, notably reducing the overlap between redshift bins. By combining strategies 1 and 2, we have successfully managed to reduce redshift bin overlap in DES Y3 by up to 66$\%$. Conversely, the third strategy, involving the addition of redshift data for selected galaxies as an additional feature in the method, yields inferior results and is abandoned. Our findings contribute to the advancement of weak lensing redshift characterization and lay the groundwork for better redshift characterization in DES Year 6 and future stage IV surveys, like the Rubin Observatory.

Rapid advances in the capabilities of large language models (LLMs) have raised widespread concerns regarding their potential for malicious use. Open-weight LLMs present unique challenges, as existing safeguards lack robustness to tampering attacks that modify model weights. For example, recent works have demonstrated that refusal and unlearning safeguards can be trivially removed with a few steps of fine-tuning. These vulnerabilities necessitate new approaches for enabling the safe release of open-weight LLMs. We develop a method, called TAR, for building tamper-resistant safeguards into open-weight LLMs such that adversaries cannot remove the safeguards even after thousands of steps of fine-tuning. In extensive evaluations and red teaming analyses, we find that our method greatly improves tamper-resistance while preserving benign capabilities. Our results demonstrate that tamper-resistance is a tractable problem, opening up a promising new avenue to improve the safety and security of open-weight LLMs., Comment: Website: https://www.tamper-resistant-safeguards.com

As artificial intelligence systems grow more powerful, there has been increasing interest in "AI safety" research to address emerging and future risks. However, the field of AI safety remains poorly defined and inconsistently measured, leading to confusion about how researchers can contribute. This lack of clarity is compounded by the unclear relationship between AI safety benchmarks and upstream general capabilities (e.g., general knowledge and reasoning). To address these issues, we conduct a comprehensive meta-analysis of AI safety benchmarks, empirically analyzing their correlation with general capabilities across dozens of models and providing a survey of existing directions in AI safety. Our findings reveal that many safety benchmarks highly correlate with upstream model capabilities, potentially enabling "safetywashing" -- where capability improvements are misrepresented as safety advancements. Based on these findings, we propose an empirical foundation for developing more meaningful safety metrics and define AI safety in a machine learning research context as a set of clearly delineated research goals that are empirically separable from generic capabilities advancements. In doing so, we aim to provide a more rigorous framework for AI safety research, advancing the science of safety evaluations and clarifying the path towards measurable progress.

We present galaxy-galaxy lensing measurements using a sample of low surface brightness galaxies (LSBGs) drawn from the Dark Energy Survey Year 3 (Y3) data as lenses. LSBGs are diffuse galaxies with a surface brightness dimmer than the ambient night sky. These dark-matter-dominated objects are intriguing due to potentially unusual formation channels that lead to their diffuse stellar component. Given the faintness of LSBGs, using standard observational techniques to characterize their total masses proves challenging. Weak gravitational lensing, which is less sensitive to the stellar component of galaxies, could be a promising avenue to estimate the masses of LSBGs. Our LSBG sample consists of 23,790 galaxies separated into red and blue color types at $g-i\ge 0.60$ and $g-i< 0.60$, respectively. Combined with the DES Y3 shear catalog, we measure the tangential shear around these LSBGs and find signal-to-noise ratios of 6.67 for the red sample, 2.17 for the blue sample, and 5.30 for the full sample. We use the clustering redshifts method to obtain redshift distributions for the red and blue LSBG samples. Assuming all red LSBGs are satellites, we fit a simple model to the measurements and estimate the host halo mass of these LSBGs to be $\log(M_{\rm host}/M_{\odot}) = 12.98 ^{+0.10}_{-0.11}$. We place a 95% upper bound on the subhalo mass at $\log(M_{\rm sub}/M_{\odot})<11.51$. By contrast, we assume the blue LSBGs are centrals, and place a 95% upper bound on the halo mass at $\log(M_\mathrm{host}/M_\odot) < 11.84$. We find that the stellar-to-halo mass ratio of the LSBG samples is consistent with that of the general galaxy population. This work illustrates the viability of using weak gravitational lensing to constrain the halo masses of LSBGs., Comment: 20 pages, 14 figures

Cosmological analyses with Type Ia Supernovae (SNe Ia) have traditionally been reliant on spectroscopy for both classifying the type of supernova and obtaining reliable redshifts to measure the distance-redshift relation. While obtaining a host-galaxy spectroscopic redshift for most SNe is feasible for small-area transient surveys, it will be too resource intensive for upcoming large-area surveys such as the Vera Rubin Observatory Legacy Survey of Space and Time, which will observe on the order of millions of SNe. Here we use data from the Dark Energy Survey (DES) to address this problem with photometric redshifts (photo-z) inferred directly from the SN light-curve in combination with Gaussian and full p(z) priors from host-galaxy photo-z estimates. Using the DES 5-year photometrically-classified SN sample, we consider several photo-z algorithms as host-galaxy photo-z priors, including the Self-Organizing Map redshifts (SOMPZ), Bayesian Photometric Redshifts (BPZ), and Directional-Neighbourhood Fitting (DNF) redshift estimates employed in the DES 3x2 point analyses. With detailed catalog-level simulations of the DES 5-year sample, we find that the simulated w can be recovered within $\pm$0.02 when using SN+SOMPZ or DNF prior photo-z, smaller than the average statistical uncertainty for these samples of 0.03. With data, we obtain biases in w consistent with simulations within ~1$\sigma$ for three of the five photo-z variants. We further evaluate how photo-z systematics interplay with photometric classification and find classification introduces a subdominant systematic component. This work lays the foundation for next-generation fully photometric SNe Ia cosmological analyses., Comment: 19 pages, 9 figures. Submitting to MNRAS, comments welcome

The X-IFU is one of the two instruments of ATHENA, the next ESA large X-ray observatory. It is a cryogenic spectrometer based on an array of TES microcalorimeters. To reduce the particle background, the TES array works in combination with a Cryogenic AntiCoincidence detector (CryoAC). The CryoAC is a 4-pixel detector, based on ~1 cm2 silicon absorbers sensed by Ir/Au TES. It is required to have a wide energy bandwidth (from 20 keV to ~1 MeV), high efficiency (< 0.014% missed particles), low dead-time (< 1%) and good time-tagging accuracy (10 us at 1 sigma). An end-to-end simulator of the CryoAC detector has been developed both for design and performance assessment, consisting of several modules. First, the in-flight flux of background particles is evaluated by Geant4 simulations. Then, the current flow in the TES is evaluated by solving the electro-thermal equations of microcalorimeters, and the detector output signal is generated by simulating the SQUID FLL dynamics. Finally, the output is analyzed by a high-efficiency trigger algorithm, producing the simulated CryoAC telemetry. Here, we present in detail this end-to-end simulator, and how we are using it to define the new CryoAC baseline configuration in the new Athena context., Comment: Proceeding of the SPIE Astronomical Telescopes + Instrumentation 2024

The moral value of liberty is a central concept in our inference system when it comes to taking a stance towards controversial social issues such as vaccine hesitancy, climate change, or the right to abortion. Here, we propose a novel Liberty lexicon evaluated on more than 3,000 manually annotated data both in in- and out-of-domain scenarios. As a result of this evaluation, we produce a combined lexicon that constitutes the main outcome of this work. This final lexicon incorporates information from an ensemble of lexicons that have been generated using word embedding similarity (WE) and compositional semantics (CS). Our key contributions include enriching the liberty annotations, developing a robust liberty lexicon for broader application, and revealing the complexity of expressions related to liberty across different platforms. Through the evaluation, we show that the difficulty of the task calls for designing approaches that combine knowledge, in an effort of improving the representations of learning systems.

This paper proposes two algorithms to impose seepage boundary conditions in the context of Richards' equation for groundwater flows in unsaturated media. Seepage conditions are non-linear boundary conditions, that can be formulated as a set of unilateral constraints on both the pressure head and the water flux at the ground surface, together with a complementarity condition: these conditions in practice require switching between Neumann and Dirichlet boundary conditions on unknown portions on the boundary. Upon realizing the similarities of these conditions with unilateral contact problems in mechanics, we take inspiration from that literature to propose two approaches: the first method relies on a strongly consistent penalization term, whereas the second one is obtained by an hybridization approach, in which the value of the pressure on the surface is treated as a separate set of unknowns. The flow problem is discretized in mixed form with div-conforming elements so that the water mass is preserved. Numerical experiments show the validity of the proposed strategy in handling the seepage boundary conditions on geometries with increasing complexity.

The dual-phase liquid argon time projection chamber is presently one of the leading technologies to search for dark matter particles with masses below 10 GeV/c$^2$. This was demonstrated by the DarkSide-50 experiment with approximately 50 kg of low-radioactivity liquid argon as target material. The next generation experiment DarkSide-20k, currently under construction, will use 1,000 times more argon and is expected to start operation in 2027. Based on the DarkSide-50 experience, here we assess the DarkSide-20k sensitivity to models predicting light dark matter particles, including Weakly Interacting Massive Particles (WIMPs) and sub-GeV/c$^2$ particles interacting with electrons in argon atoms. With one year of data, a sensitivity improvement to dark matter interaction cross-sections by at least one order of magnitude with respect to DarkSide-50 is expected for all these models. A sensitivity to WIMP--nucleon interaction cross-sections below $1\times10^{-42}$ cm$^2$ is achievable for WIMP masses above 800 MeV/c$^2$. With 10 years exposure, the neutrino fog can be reached for WIMP masses around 5 GeV/c$^2$., Comment: submitted to Nature Communications

We address the challenging problem of dynamically pricing complementary items that are sequentially displayed to customers. An illustrative example is the online sale of flight tickets, where customers navigate through multiple web pages. Initially, they view the ticket cost, followed by ancillary expenses such as insurance and additional luggage fees. Coherent pricing policies for complementary items are essential because optimizing the pricing of each item individually is ineffective. Our scenario also involves a sales constraint, which specifies a minimum number of items to sell, and uncertainty regarding customer demand curves. To tackle this problem, we originally formulate it as a Markov Decision Process with constraints. Leveraging online learning tools, we design a primal-dual online optimization algorithm. We empirically evaluate our approach using synthetic settings randomly generated from real-world data, covering various configurations from stationary to non-stationary, and compare its performance in terms of constraints violation and regret against well-known baselines optimizing each state singularly.

The intermediate scattering function is interpreted as a correlation function of thermal wave packets of the scattering centers perturbed by the scattering particles at different times. A proof of concept is given at the example of ballistic moving centers. The ensuing numerical method is then illustrated at the example of CO adsorbed on Cu(100)., Comment: 8 pages, 2 figures

We present the joint tomographic analysis of galaxy-galaxy lensing and galaxy clustering in harmonic space, using galaxy catalogues from the first three years of observations by the Dark Energy Survey (DES Y3). We utilise the redMaGiC and MagLim catalogues as lens galaxies and the METACALIBRATION catalogue as source galaxies. The measurements of angular power spectra are performed using the pseudo-$C_\ell$ method, and our theoretical modelling follows the fiducial analyses performed by DES Y3 in configuration space, accounting for galaxy bias, intrinsic alignments, magnification bias, shear magnification bias and photometric redshift uncertainties. We explore different approaches for scale cuts based on non-linear galaxy bias and baryonic effects contamination. Our fiducial covariance matrix is computed analytically, accounting for mask geometry in the Gaussian term, and including non-Gaussian contributions and super-sample covariance terms. To validate our harmonic space pipelines and covariance matrix, we used a suite of 1800 log-normal simulations. We also perform a series of stress tests to gauge the robustness of our harmonic space analysis. In the $\Lambda$CDM model, the clustering amplitude $S_8 =\sigma_8(\Omega_m/0.3)^{0.5}$ is constrained to $S_8 = 0.704\pm 0.029$ and $S_8 = 0.753\pm 0.024$ ($68\%$ C.L.) for the redMaGiC and MagLim catalogues, respectively. For the $w$CDM, the dark energy equation of state is constrained to $w = -1.28 \pm 0.29$ and $w = -1.26^{+0.34}_{-0.27}$, for redMaGiC and MagLim catalogues, respectively. These results are compatible with the corresponding DES Y3 results in configuration space and pave the way for harmonic space analyses using the DES Y6 data., Comment: To be submitted to MNRAS

Developing domain-specific conversational agents (CAs) has been challenged by the need for extensive domain-focused data. Recent advancements in Large Language Models (LLMs) make them a viable option as a knowledge backbone. LLMs behaviour can be enhanced through prompting, instructing them to perform downstream tasks in a zero-shot fashion (i.e. without training). To this end, we incorporated structural knowledge into prompts and used prompted LLMs to build domain-specific voice-based CAs. We demonstrate this approach for the specific domain of textile circularity in form of the design, development, and evaluation of TextileBot. We present the design and development of the voice agent TextileBot and also the insights from an in-person user study (N=30) evaluating three variations of TextileBots. We analyse the human-agent interactions, combining quantitative and qualitative methods. Our results suggest that participants engaged in multi-turn conversations, and their perceptions of the three variation agents and respective interactions varied demonstrating the effectiveness of our prompt-based LLM approach. We discuss the dynamics of these interactions and their implications for designing future voice-based CAs. The results show that our method's potential for building domain-specific CAs. Furthermore, most participants engaged in multi-turn conversations, and their perceptions of the three voice agents and respective interactions varied demonstrating the effectiveness of our prompt-based LLM approach. We discuss the dynamics of these interactions and their implications for designing future voice-based CAs.

Pose estimation has promised to impact healthcare by enabling more practical methods to quantify nuances of human movement and biomechanics. However, despite the inherent connection between pose estimation and biomechanics, these disciplines have largely remained disparate. For example, most current pose estimation benchmarks use metrics such as Mean Per Joint Position Error, Percentage of Correct Keypoints, or mean Average Precision to assess performance, without quantifying kinematic and physiological correctness - key aspects for biomechanics. To alleviate this challenge, we develop OpenCapBench to offer an easy-to-use unified benchmark to assess common tasks in human pose estimation, evaluated under physiological constraints. OpenCapBench computes consistent kinematic metrics through joints angles provided by an open-source musculoskeletal modeling software (OpenSim). Through OpenCapBench, we demonstrate that current pose estimation models use keypoints that are too sparse for accurate biomechanics analysis. To mitigate this challenge, we introduce SynthPose, a new approach that enables finetuning of pre-trained 2D human pose models to predict an arbitrarily denser set of keypoints for accurate kinematic analysis through the use of synthetic data. Incorporating such finetuning on synthetic data of prior models leads to twofold reduced joint angle errors. Moreover, OpenCapBench allows users to benchmark their own developed models on our clinically relevant cohort. Overall, OpenCapBench bridges the computer vision and biomechanics communities, aiming to drive simultaneous advances in both areas.

The residuals of the distance moduli of Type Ia supernovae (SN Ia) relative to a Hubble diagram fit contain information about the inhomogeneity of the universe, due to weak lensing magnification by foreground matter. By correlating the residuals of the Dark Energy Survey Year 5 SN Ia sample (DES-SN5YR) with extra-galactic foregrounds from the DES Y3 Gold catalog, we detect the presence of lensing at $6.0 \sigma$ significance. This is the first detection with a significance level above $5\sigma$. Constraints on the effective mass-to-light ratios and radial profiles of dark-matter haloes surrounding individual galaxies are also obtained. We show that the scatter of SNe Ia around the Hubble diagram is reduced by modifying the standardisation of the distance moduli to include an easily calculable de-lensing (i.e., environmental) term. We use the de-lensed distance moduli to recompute cosmological parameters derived from SN Ia, finding in Flat $w$CDM a difference of $\Delta \Omega_{\rm M} = +0.036$ and $\Delta w = -0.056$ compared to the unmodified distance moduli, a change of $\sim 0.3\sigma$. We argue that our modelling of SN Ia lensing will lower systematics on future surveys with higher statistical power. We use the observed dispersion of lensing in DES-SN5YR to constrain $\sigma_8$, but caution that the fit is sensitive to uncertainties at small scales. Nevertheless, our detection of SN Ia lensing opens a new pathway to study matter inhomogeneity that complements galaxy-galaxy lensing surveys and has unrelated systematics., Comment: Submitted to MNRAS

We present $griz$ photometric light curves for the full 5 years of the Dark Energy Survey Supernova program (DES-SN), obtained with both forced Point Spread Function (PSF) photometry on Difference Images (DIFFIMG) performed during survey operations, and Scene Modelling Photometry (SMP) on search images processed after the survey. This release contains $31,636$ DIFFIMG and $19,706$ high-quality SMP light curves, the latter of which contains $1635$ photometrically-classified supernovae that pass cosmology quality cuts. This sample spans the largest redshift ($z$) range ever covered by a single SN survey ($0.1

We report constraints on a variety of non-standard cosmological models using the full 5-year photometrically-classified type Ia supernova sample from the Dark Energy Survey (DES-SN5YR). Both Akaike Information Criterion (AIC) and Suspiciousness calculations find no strong evidence for or against any of the non-standard models we explore. When combined with external probes, the AIC and Suspiciousness agree that 11 of the 15 models are moderately preferred over Flat-$\Lambda$CDM suggesting additional flexibility in our cosmological models may be required beyond the cosmological constant. We also provide a detailed discussion of all cosmological assumptions that appear in the DES supernova cosmology analyses, evaluate their impact, and provide guidance on using the DES Hubble diagram to test non-standard models. An approximate cosmological model, used to perform bias corrections to the data holds the biggest potential for harbouring cosmological assumptions. We show that even if the approximate cosmological model is constructed with a matter density shifted by $\Delta\Omega_m\sim0.2$ from the true matter density of a simulated data set the bias that arises is sub-dominant to statistical uncertainties. Nevertheless, we present and validate a methodology to reduce this bias., Comment: Published to MNRAS on 20 August 2024; v2 updates to the accepted version

Aligning large language models (LLMs) behaviour with human intent is critical for future AI. An important yet often overlooked aspect of this alignment is the perceptual alignment. Perceptual modalities like touch are more multifaceted and nuanced compared to other sensory modalities such as vision. This work investigates how well LLMs align with human touch experiences using the "textile hand" task. We created a "Guess What Textile" interaction in which participants were given two textile samples -- a target and a reference -- to handle. Without seeing them, participants described the differences between them to the LLM. Using these descriptions, the LLM attempted to identify the target textile by assessing similarity within its high-dimensional embedding space. Our results suggest that a degree of perceptual alignment exists, however varies significantly among different textile samples. For example, LLM predictions are well aligned for silk satin, but not for cotton denim. Moreover, participants didn't perceive their textile experiences closely matched by the LLM predictions. This is only the first exploration into perceptual alignment around touch, exemplified through textile hand. We discuss possible sources of this alignment variance, and how better human-AI perceptual alignment can benefit future everyday tasks.