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We have developed an atomic magnetometer based on the rubidium isotope 87 Rb and a microfabricated silicon/glass vapor cell for the purpose of qualifying the instrument for space flight during a ride-along opportunity on a sounding rocket. The instrument consists of two scalar magnetic field sensors mounted at 45° angle to avoid measurement dead zones, and the electronics consist of a low-voltage power supply, an analog interface, and a digital controller. The instrument was launched into the Earth's northern cusp from Andøya, Norway on December 8, 2018 on the low-flying rocket of the dual-rocket Twin Rockets to Investigate Cusp Electrodynamics 2 mission. The magnetometer was operated without interruption during the science phase of the mission, and the acquired data were compared favorably with those from the science magnetometer and the model of the International Geophysical Reference Field to within an approximate fixed offset of about 550 nT. Residuals with respect to these data sources are plausibly attributed to offsets resulting from rocket contamination fields and electronic phase shifts. These offsets can be readily mitigated and/or calibrated for a future flight experiment so that the demonstration of this absolute-measuring magnetometer was entirely successful from the perspective of increasing the technological readiness for space flight.

Soil and bedrock weathering and phosphate (P) fertilizers may both contribute to the uranium (U) load of rivers in agricultural regions, but controls over their relative influence are not well known. This study investigates the U sources to rivers in Ohio, United States, part of the Eastern Corn Belt in the Mississippi River watershed. We present a regional picture of seasonal U sources to rivers based on four analyses: 1) a spatial analysis of legacy soil and water data, 2) new measurements of U and carbonate weathering products from rivers at 50 locations across the state collected seasonally over two years, 3) a weekly time series with additional 234 U/ 238 U (n = 5) and 87 Sr/ 86 Sr (n = 5) measurements from an agricultural river, and 4) a mass-balance approach to U addition to the landscape based on reported P fertilizer use. Uranium concentrations in surface waters collected statewide ranged 0.1-21 nM (n = 132), with significantly higher concentrations in the glaciated agricultural portion of the state (mean = 7.3 nM; n = 105) than the non-glaciated portion (mean = 2.0 nM; n = 24). Concentrations in the glaciated region were highest during the spring and summer and decreased during baseflow. In the time-series, concentrations were ~7 nM during baseflow and ~14 nM during intermediate seasonal discharge conditions, indicating a second more surficial endmember source of U in addition to bedrock weathering that is well correlated with other carbonate weathering products. Systematic increases in 87 Sr/ 86 Sr and decreases in 234 U/ 238 U with increasing discharge confirm a changing source of carbonate and U weathering and a third surficial endmember during high discharge events. Our mass balance approach and geochemical analysis suggest that elevated U concentrations are the result of carbonate weathering deep in the soil column during elevated seasonal flow. Further work on U dynamics in agricultural rivers is required to understand mechanism controlling seasonal changes in U concentrations and 234 U/ 238 U in downstream rivers and U flux., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Trace elements sustain biological productivity, yet the significance of trace element mobilization and export in subglacial runoff from ice sheets is poorly constrained at present. Here, we present size-fractionated (0.02, 0.22, and 0.45 µm) concentrations of trace elements in subglacial waters from the Greenland Ice Sheet (GrIS) and the Antarctic Ice Sheet (AIS). Concentrations of immobile trace elements (e.g., Al, Fe, Ti) far exceed global riverine and open ocean mean values and highlight the importance of subglacial aluminosilicate mineral weathering and lack of retention of these species in sediments. Concentrations are higher from the AIS than the GrIS, highlighting the geochemical consequences of prolonged water residence times and hydrological isolation that characterize the former. The enrichment of trace elements (e.g., Co, Fe, Mn, and Zn) in subglacial meltwaters compared with seawater and typical riverine systems, together with the likely sensitivity to future ice sheet melting, suggests that their export in glacial runoff is likely to be important for biological productivity. For example, our dissolved Fe concentration (20,900 nM) and associated flux values (1.4 Gmol y -1 ) from AIS to the Fe-deplete Southern Ocean exceed most previous estimates by an order of magnitude. The ultimate fate of these micronutrients will depend on the reactivity of the dominant colloidal size fraction (likely controlled by nanoparticulate Al and Fe oxyhydroxide minerals) and estuarine processing. We contend that ice sheets create highly geochemically reactive particulates in subglacial environments, which play a key role in trace elemental cycles, with potentially important consequences for global carbon cycling., Competing Interests: The authors declare no competing interest.

Synthetic fertilizer is a potential source of uranium to natural waters, yet evidence is lacking. We analyzed dissolved uranium concentrations in lakes, reservoirs, and rivers in Ohio, USA during the summer of 2017. All water bodies drain areas of extensive agriculture where phosphate-rich fertilizer is applied. Uranium concentrations ranged from 0.3 to 3.9 µg L -1 , with the lowest concentrations observed in the most offshore Lake Erie samples. These results, especially when placed in the context of previous work on both surface and groundwater, suggest that dissolved uranium concentrations in this water emanating from agricultural lands are higher than background, and uranium should be categorized similarly to nitrate and phosphate in that it originates in part from fertilizer application.

Trace metal clean techniques were used to sample and analyze the input of dissolved trace metals, major ions, and dissolved organic carbon (DOC) from a storm sewer along an urban highway in Columbus, OH. The outfall, draining a 3.6 ha sewershed with 100% impermeable surface area, discharges into the Olentangy River. Dissolved Pb (average concentration of 3 nM) and dissolved Zn (average concentration of 127 nM) were found to be much lower in concentration than reported in previous investigations of dissolved metals in urban stormwater runoff. Average concentrations of dissolved Cr (1 microM), Ni (0.087 microM), and Cu (0.33 microM) were similar to those reported in previous studies. The storm sewer is shown to be a significant source of V, Ni, and Zn to the river. The outfall is also a significant source of Na, NH4, Cl, and DOC. The storm sewer input is depleted in NO2 and NO3 as compared to the river, reflecting the highly agricultural land use of the watershed upstream of the sewershed. Input from the storm sewer is also depleted, as compared to the river, with respect to dissolved Mg, Sr, and U with probable sources in the limestone/shale bedrock and glacial till-derived soils in the watershed.

Previous work examining how individuals enter mental health treatment comes either from the health services utilization tradition, which implicitly assumes that clients make decisions to seek care, or from the socio-legal perspective, which examines how clients are forced into care. This paper draws from the Network-Episode Model to systematically consider the different social processes through which people come to enter psychiatric treatment by exploring the "stories" told by individuals making their first major contact with the mental health system. We combine the use of qualitative and quantitative methods to examine data from the Indianapolis Network Mental Health Study, a longitudinal study of individuals in treatment at the largest public and voluntary facilities in the city. We analyze detailed self-reports of how they came to use mental health services, classifying these stories as "choice," "coercion," or "muddling through". Using multinomial logit analyses, we examine how factors such as gender, race and diagnosis shape the types of stories that individuals tell. The preliminary results indicate that fewer than half of the stories (45.9%) match the notion of choice underlying the dominant utilization theories. Almost a quarter of respondents (22.9%) report coercion and nearly one-third (31.2%) tell stories that lack a clear agent. Diagnosis and social networks tap differences in how individuals experience entry into care. Individuals diagnosed with bipolar disorder or who have larger, closer social networks are more likely to tell stories of coercion. We discuss the theoretical, methodological, and clinical implications of findings drawn from this examination of clients' stories.