1. Microwave conductivity of metal complexes TTF[M(dmit)2]2 (M=Pd, Ni)
- Author
-
A.V. Schchepak, G.L. Osipyan, V. M. Pchelkin, I. B. Vendik, and V.V. Kuznetsov
- Subjects
Permittivity ,Stereochemistry ,Chemistry ,Mechanical Engineering ,Metals and Alloys ,Analytical chemistry ,Dielectric ,Atmospheric temperature range ,Conductivity ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Metal ,Mechanics of Materials ,Electrical resistivity and conductivity ,visual_art ,Materials Chemistry ,visual_art.visual_art_medium ,Metal–insulator transition ,Microwave - Abstract
The highly conducting TTF [M(dmit) 2 ] 2 compounds with M= Pd, Ni have been investigated at microwaves. The temperature dependence of real and imaginary part of conductivity was measured from T=77K to 300 K. The Ni salt remains metallic, while the Pd salt reveals at f=2GHz a metal-insulator transition at T p =260K with the negative dielectric constant below T p . The non-linear microwave conductivity of Pd salt was observed in the temperature range 105÷200K, while the Ni salt exhibited the linear conductivity. The results observed can not be accounted for in the framework of known model approach of the collective CDW transport.
- Published
- 1993