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We present spatially resolved H$\alpha$ properties of 21 type 1 AGN host galaxies at z$\sim$2 derived from the SUPER survey. These targets were observed with the adaptive optics capabilities of the SINFONI spectrograph, a near-infrared integral field spectrograph, that provided a median spatial resolution of 0.3 arcsec ($\sim$2 kpc). We model the H$\alpha$ emission line profile in each pixel to investigate whether it traces gas in the narrow line region or if it is associated with star formation. To do this, we first investigate the presence of resolved H$\alpha$ emission by removing the contribution of the AGN PSF. We find extended H$\alpha$ emission in sixteen out of the 21 type 1 AGN host galaxies (76%). Based on the BPT diagnostics, optical line flux ratios and the line widths (FWHM), we show that the H$\alpha$ emission in five galaxies is ionised by the AGN (30%), in four galaxies by star formation (25%) and for the rest (45%), the ionisation source is unconstrained. Two galaxies show extended H$\alpha$ FWHM $>$600 km/s, which is interpreted as a part of an AGN-driven outflow. Morphological and kinematic maps of H$\alpha$ emission in targets with sufficient signal-to-noise ratio suggest the presence of rotationally supported disks in six galaxies and possible presence of companions in four galaxies. In two galaxies, we find an anti-correlation between the locations of extended H$\alpha$ emission and [OIII]-based ionised outflows, indicating possible negative feedback at play. However, in the majority of galaxies, we do not find evidence of outflows impacting H$\alpha$ based star formation., Comment: 16 pages, 11 figures, 2 tables, accepted for publication in MNRAS; Appendix = 2 tables and 3 figures

Undisturbed galaxy clusters are characterized by a massive and large elliptical galaxy at their center, i.e. the Brightest Cluster Galaxy (BCG). How these central galaxies form is still debated. According to most models, a typical epoch for their assembly is z~1-2. We have performed a detailed multi-wavelength analysis of the core of XDCPJ0044.0-2033 (XDCP0044), one of the most massive and densest galaxy clusters currently known at redshift z~1.6, whose central galaxy population shows high star formation compared to lower-z clusters and an X-ray AGN located close to its center. SINFONI J-, H- and KMOS YJ-, H- bands spectroscopic data have been analyzed, together with deep archival HST photometric data in F105W, F140W, and F160W bands, Chandra X-ray, radio JVLA data at 1-2 GHz, and ALMA band-6 observations. In the central region of the cluster (~70x70 kpc^2), 2 systems of interacting galaxies have been identified and studied (Complex A and B), with a total of 7 confirmed cluster members. These galaxies show perturbed morphologies and 3 of them show signs of AGN activity. In particular, 2 type-1 AGN with typical broad lines have been found at the center of each complex (both of them X-ray obscured and highly accreting; Eddington ratio ~0.5), while a type-2 AGN has been discovered in Complex A. The AGN at the center of Complex B is also detected in X-ray while the other 2 are spatially related to radio emission. The 3 AGN provide one of the closest AGN triple at z>1 revealed so far with a minimum(maximum) projected distance of ~10(40) kpc. The observation of high star formation, merger signatures and nuclear activity in the core of XDCP0044 suggests that all these processes are key ingredients in shaping the nascent BCG. According to our data, XDCP0044 could form a typical massive galaxy of 10^12 Msun, hosting a Black Hole of 2x10^8-10^9 Msun, in a time scale of the order of ~2.5 Gyrs., 15 pages, 10 figures, 5 tables. Accepted to MNRAS in 2020 August 14

Improving our understanding of the nuclear properties of high-Eddington-ratio (λEdd) active galactic nuclei (AGN) is necessary since at this regime the radiation pressure is expected to affect the structure and efficiency of the accretion disc-corona system. This may cause departures from the typical nuclear properties of low-λEdd AGN, which have been largely studied so far. We present here the X-ray spectral analysis of 14 radio-quiet, λEdd ≳ 1 AGN at 0.4 ≤ z ≤ 0.75, observed with XMM-Newton. Optical/UV data from simultaneous Optical Monitor observations have also been considered. These quasars were selected to have relatively high values of black hole mass (MBH ∼ 108 − 8.5 M⊙) and bolometric luminosity (Lbol ∼ 1046 erg s−1) in order to complement previous studies of high-λEdd AGN at lower MBH and Lbol. We studied the relation between λEdd and other key X-ray spectral parameters, such as the photon index (Γ) of the power-law continuum, the X-ray bolometric correction (kbol, X), and the optical/UV-to-X-ray spectral index (αox). Our analysis reveals that, despite the homogeneous optical and supermassive black hole accretion properties, the X-ray properties of these high-λEdd AGN are quite heterogeneous. We indeed measured values of Γ between 1.3 and 2.5, at odds with the expectations based on previously reported Γ − λEdd relations, for which Γ ≥ 2 would be a ubiquitous hallmark of AGN with λEdd ∼ 1. Interestingly, we found that ∼30% of the sources are X-ray weak, with an X-ray emission about a factor of ∼10 − 80 fainter than that of typical AGN at similar UV luminosities. The X-ray weakness seems to be intrinsic and not due to the presence of absorption along the line of sight to the nucleus. This result may indicate that high-λEdd AGN commonly undergo periods of intrinsic X-ray weakness. Furthermore, results from follow-up monitoring with Swift of one of these X-ray weak sources suggest that these periods can last for several years. © ESO 2022., This work is based on observations obtained with XMM-Newton, an ESA science mission with instruments and contributions directly funded by ESA Member States and NASA. Part of this work is based on archival data, software and online services provided by the Space Science Data Center – ASI. This work has been partially supported by the ASI-INAF program I/004/11/4. ML acknowledges financial support from the PhD programme in Astronomy, Astrophysics and Space Science supported by MIUR (Ministero dell’Istruzione, dell’Università e della Ricerca). EP, LZ, FT, SB, AL and GV acknowledge financial support under ASI/INAF contract 2017-14-H.0. EP, SB, MB and GV acknowledge support from PRIN MIUR project “Black Hole winds and the Baryon Life Cycle of Galaxies: the stone-guest at the galaxy evolution supper”, contract #2017PH3WAT. AdO acknowledges financial support from the State Agency for Research of the Spanish MCIU through the project PID2019-106027GB-C41 and the “Center of Excellence Severo Ochoa” award to the Instituto de Astrofísica de Andalucía (SEV-2017-0709). RM acknowledges the financial support of INAF (Istituto Nazionale di Astrofisica), Osservatorio Astronomico di Roma, ASI (Agenzia Spaziale Italiana) under contract to INAF: ASI 2014-049-R.0 dedicated to SSDC. CR acknowledges support from the Fondecyt Iniciacion grant 11190831.

Hyper-luminous Quasi-Stellar Objects (QSOs) represent the ideal laboratory to investigate Active Galactic Nuclei (AGN) feedback mechanism since their formidable energy release causes powerful winds at all scales and thus the maximum feedback is expected. We aim at deriving the mean Spectral Energy Distribution (SED) of a sample of 85 WISE-SDSS Selected Hyper-luminous (WISSH) quasars. Since the SED provides a direct way to investigate the AGN structure, our goal is to understand if quasars at the bright end of the luminosity function have peculiar properties compared to the bulk of the population. We built a mean intrinsic SED after correcting for the dust extinction, absorption and emission lines and intergalactic medium absorption. We also derived bolometric, IR band and monochromatic luminosities together with bolometric corrections at lambda = 5100 A and 3 micron. We define a new relation for the 3 micron bolometric correction. We find that the mean SED of hyper-luminous WISSH QSOs is different from that of less luminous sources, i.e. a relatively lower X-ray emission and a near and mid IR excess which can be explained assuming a larger dust contribution. WISSH QSOs have stronger emission from both warm and very hot dust, the latter being responsible for shifting the typical dip of the AGN SED from 1.3 to 1.1 micron. We also derived the mean SEDs of two sub-samples created according to the presence of Broad Absorption Lines and equivalent width of CIV line. We confirm that BALs are X-ray weak and that they have a reddened UV-optical continuum. We also find that BALs tend to have stronger emission from the hot dust component. This analysis suggests that hyper-luminous QSOs have a peculiar SED compared to less luminous objects. It is therefore critical to use SED templates constructed exclusively from very bright quasars samples when dealing with particularly luminous sources., Comment: Accepted for publication in A&A. 20 pages, 15 figures

We report on the variability of a multi-component broad absorption line (BAL) system observed in the hyper-luminous quasar J1538+0855 at z=3.6. Observations from SDSS, VLT, LBT and Subaru telescopes taken at five different epochs, spanning 17 yr in the observed frame, are presented. We detect three (A, B, C) CIV variable troughs exhibiting extreme velocities ($\sim$40,000-54,000 km s$^{-1}$) similar to the ultra-fast outflows (UFOs) typically observed in the X-ray spectra. The A component of the BAL UFO ($\rm v_{ufo}$ $\sim$0.17 c) shows strength variations, while B ($\rm v_{ufo}$ $\sim$0.15 c) and C ($\rm v_{ufo}$ $\sim$0.13 c) components show changes both in shape and strength, appearing and disappearing at different epochs. In addition, during the last observation on June 2021 the entire BAL system disappears. The variability trends observed during the first two epochs (1.30 yr rest-frame) in the CIV, SiIV, OVI and NV absorption spectral regions are the same for B and C troughs, while the A component of the BAL varies independently. This suggests a change in the ionization state of the absorbing gas for B and C components and tangential motion for the A component, as causes of this temporal behavior. Accordingly, it is possible to provide an upper limit for distance of the gas responsible for the A component of $R\rm_{out}^{A}$$\le$58 pc, and in turn, a kinetic power of $\dot{E}\rm_{K,ufo}$ $\le$5.2 $\times$ 10$^{44}$ erg s$\rm^{-1}$. We also obtain $R\rm_{out}^{B,C}$ $\le$2.7 kpc for B and C components, which implies an upper limit estimation of $\dot{E}\rm_{K,ufo}$ $\le$2.1$\times$10$^{46}$ erg s$\rm^{-1}$ and $\dot{E}\rm_{K,ufo}$ $\le$1.4$\times$10$^{46}$ erg s$\rm^{-1}$, respectively. Future spectral monitoring with high-resolution instruments is mandatory to accurately constrain physical properties of the BAL UFO discovered in the UV spectrum of J1538+0855., Comment: Accepted for publication in A&A

We report on a long (250 ks) NuSTAR observation of the bright quasar RBS 1055 performed in March 2021, and archival XMM-Newton pointings (185 ks) taken in July 2014. An optical spectrum of the source taken with the Double Spectrograph at the Palomar Observatory, quasi-simultaneous with the NuSTAR observations, is also analyzed. We find that the two-coronae model, in which a warm and hot corona coexist, well reproduces its broad band spectrum, with temperatures kT$_e=0.12^{+0.08}_{-0.03}$ keV, kT$_e=30^{+40}_{-10}$ keV and Thomson optical depths $\tau$=30$_{-10}^{+15}$ and $\tau$=3.0$_{-1.4}^{+1.0}$ for the former and the latter component, respectively. We confirm the presence of an intense Fe K$\alpha$ emission line (EW=55$\pm$6 eV) and, when a toroidal model is considered for reproducing the Compton reflection, a Compton-thin solution with N$_{\rm H}=(3.2^{+0.9}_{-0.8})\times10^{23}$ cm$^{-2}$ for the circumnuclear reflector is found. The analysis of the optical spectrum reveals a likely peculiar configuration of our line of sight with respect to the nucleus, and the presence of a broad [O III] component, tracing outflows in the NLR, with a velocity shift $v=$1500$\pm100$ km s$^{-1}$, leading to a mass outflow rate $\dot{M}_{\rm out}=25.4\pm1.5$ M$_{\odot}$ yr$^{-1}$ and outflow kinetic power $\dot{E}_{\rm kin}$/L$_{\rm Bol}$ $\sim$0.33%. We estimate the BH mass to be in the range 2.8$\times$10$^{8}$-1.2$\times$10$^{9}$ M$_{\odot}$, according to different BLR emission lines, with an average value of =6.5$\times$10$^{8}$ M$_{\odot}$. With an Fe K$\alpha$ which is 3$\sigma$ above the value predicted from the EW-L$_{2-10\ \rm keV}$ relation and an extreme source brightness at 2 keV (a factor 10-15 higher than the one expected from the optical/UV), RBS 1055 confirms to be an outlier in the X-rays, compared to other objects in the same luminosity and redshift range., Comment: 11 pages, 10 figures, 4 tables. Accepted for publication in Astronomy & Astrophysics

We present SIPGI, a spectroscopic pipeline to reduce optical/near-infrared data from slit-based spectrographs. SIPGI is a complete spectroscopic data reduction environment which retains the high level of flexibility and accuracy typical of the standard "by-hand" reduction methods but is characterized by a significantly higher level of efficiency. This is obtained by exploiting three main concepts: $i)$ the instrument model: at the core of the data reduction is an analytic description of the main calibration relations (e.g. spectra location and wavelength calibration) that can be easily checked and adjusted on data using a graphical tool; $ii)$ a built-in data organizer that classifies the data, together with a graphical interface that helps in providing the recipes with the correct input; $iii)$ the design and flexibility of the reduction recipes: the number of tasks required to perform a complete reduction is minimized, while preserving the possibility of verifying the accuracy of the main stages of data-reduction process with provided tools. The current version of SIPGI manages data from the MODS and LUCI spectrographs mounted at the Large Binocular Telescope, and it is our plan to extend SIPGI to support other through-slit spectrographs. Meanwhile, to allow using the same approach based on the instrument model with other instruments, we have developed SpectraPy, a spectrograph independent Python library working on through-slit spectra. In its current version, SpectraPy produces two-dimensional wavelength calibrated spectra corrected by instrument distortions. The current release of SIPGI and its documentation can by downloaded from http://pandora.lambrate.inaf.it/sipgi/, while SpectraPy can be found at http://pandora.lambrate.inaf.it/SpectraPy/., Comment: 13 pages, 8 figures. This article has been published in MNRAS: Gargiulo et al., 2022. Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved

VANDELS is an ESO Public Spectroscopic Survey designed to build a sample of high signal to noise, medium resolution spectra of galaxies at redshift between 1 and 6.5. Here we present the final Public Data Release of the VANDELS Survey, comprising 2087 redshift measurements. We give a detailed description of sample selection, observations and data reduction procedures. The final catalogue reaches a target selection completeness of 40% at iAB = 25. The high Signal to Noise ratio of the spectra (above 7 in 80% of the spectra) and the dispersion of 2.5�� allowed us to measure redshifts with high precision, the redshift measurement success rate reaching almost 100%. Together with the redshift catalogue and the reduced spectra, we also provide optical mid-IR photometry and physical parameters derived through SED fitting. The observed galaxy sample comprises both passive and star forming galaxies covering a stellar mass range 8.3< Log(M*/Msolar), 16 pages, 13 figures, accepted for publication in Astronomy & Astrophysics

We study the impact of AGN ionised outflows on star formation in high-redshift AGN hosts, by combining NIR IFS observations, mapping the H$\alpha$ emission and [OIII] outflows, with matched-resolution observations of the rest-frame FIR emission. We present high-resolution ALMA Band 7 observations of eight X-ray selected AGN at z~2 from the SUPER sample, targeting the rest-frame ~260 um continuum at ~2 kpc (0.2'') resolution. We detected 6 out of 8 targets with S/N>10 in the ALMA maps, with continuum flux densities F = 0.27-2.58 mJy and FIR half-light radii Re = 0.8-2.1 kpc. The FIR Re of our sample are comparable to other AGN and star-forming galaxies at a similar redshift from the literature. However, we find that the mean FIR size in X-ray AGN (Re = 1.16+/- 0.11 kpc) is slightly smaller than in non-AGN (Re = 1.69+/-0.13 kpc). From SED fitting, we find that the main contribution to the 260 um flux density is dust heated by star formation, with < 4% contribution from AGN-heated dust and < 1% from synchrotron emission. The majority of our sample show different morphologies for the FIR (mostly due to reprocessed stellar emission) and the ionised gas emission (H$\alpha$ and [OIII], mostly due to AGN emission). This could be due to the different locations of dust and ionised gas, the different sources of the emission (stars and AGN), or the effect of dust obscuration. We are unable to identify any residual H$\alpha$ emission, above that dominated by AGN, that could be attributed to star formation. Under the assumption that the FIR emission is a reliable tracer of obscured star formation, we find that the obscured star formation activity in these AGN host galaxies is not clearly affected by the ionised outflows. However, we cannot rule out that star formation suppression is happening on smaller spatial scales than the ones we probe with our observations (< 2 kpc) or on different timescales., Comment: 32 pages, 13 figures. Accepted for publication in A&A

The most standard scenario for the evolution of massive galaxies across cosmic time assumes a correspondence based on the interplay between active galactic nuclei (AGN) feedback, which injects large amounts of energy into the host environment, and galaxy mergers, with their ability to trigger massive star formation events and accretion onto supermassive black holes. Interacting systems hosting AGN are useful laboratories for obtaining key insights into both phenomena. In this context, we present an analysis of the optical spectral properties of IRAS 20210+1121 (I20210), a merging system at z = 0.056. According to X-ray data, this object comprises two interacting galaxies, each hosting an obscured AGN. The optical spectra confirm the presence of AGN features in both galaxies. In particular, we are able to provide a Seyfert classification for I20210 North. The spectrum of I20120 South shows broad blueshifted components associated with the most intense emission lines that indicate the presence of an ionized outflow, for which we derive a maximum velocity of ∼2000 km s-1, an extension of ∼2 kpc, and a mass rate of ∼0.6 M⊙ yr-1. We also report the existence of an ionized nebular component with v ∼ 1000 km s-1 at ∼6.5 kpc southwards of I20210 South, which can be interpreted as disrupted gas ejected from the host galaxy by the action of the outflow. I20120 therefore exhibits a double obscured AGN, with one of them showing evidence of ongoing events for AGN-powered outflows. Future spatially resolved spectroscopy will allow for an accurate mapping of the gas kinematics in this AGN pair and evaluate the impact of the outflow on both the interstellar medium and the galaxy environment. © ESO 2021., GV, EP, CV, MB, CF and FF acknowledge support from PRIN MIUR project "Black Hole winds and the Baryon Life Cycle of Galaxies: the stone-guest at the galaxy evolution supper", contract #2017PH3WAT. GV also acknowledges financial support from Premiale 2015 MITic (PI: B. Garilli). CRA acknowledges financial support from the Spanish Ministry of Science, Innovation and Universities (MCIU) under grant with reference RYC-2014-15779, from the European Union's Horizon 2020 research and innovation programme under Marie Skodowska-Curie grant agreement No 860744 (BiD4BESt), from the State Research Agency (AEI-MCINN) of the Spanish MCIU under grants "Feeding and feedback in active galaxies" with reference PID2019-106027GB-C42, "Feeding, feedback and obscuration in active galaxies" with reference AYA2016-76682-C3-2-P, and "Quantifying the impact of quasar feedback on galaxy evolution (QSOFEED)" with reference EUR2020-112266. CRA also acknowledges support from the Consejeria de Economia, Conocimiento y Empleo del Gobierno de Canarias and the European Regional Development Fund (ERDF) under grant with reference ProID2020010105 and from IAC project P/301404, financed by the Ministry of Science and Innovation, through the State Budget and by the Canary Islands Department of Economy, Knowledge and Employment, through the Regional Budget of the Autonomous Community. Based on observations made with the Italian Telescopio Nazionale Galileo (TNG) operated on the island of La Palma by the Fundacion Galileo Galilei of the INAF (Istituto Nazionale di Astrofisica) at the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias. IRAF is distributed by the National Optical Astronomy Observatories, which is operated by the Association of Universities for Research in Astronomy, Inc. (AURA) under cooperative agreement with the National Science Foundation., With funding from the Spanish government through the Severo Ochoa Centre of Excellence accreditation SEV-2017-0709.

The Planck satellite has identified more than 2000 protocluster candidates with extreme star formation rates (SFRs). Here, we present the spectroscopic identification of a Planck-selected protocluster located in the Cosmos field, PHz G237.01+42.50 (G237). G237 contains a galaxy overdensity of 31 spectroscopically identified galaxies at z~2.16 (significant at 5.4 sigma) in a 10'x11' region. The overdensity contains two substructures or protoclusters at ~2.16 and 2.195 with estimated halo masses at z=0 of ~(5-6)x10^14 Msun. The overdensity total SFR, ~4000 Msun/yr, is higher than predicted by simulations but much smaller than the SFR derived from the Planck data. The analysis of the Herschel data, in combination with the available ancillary data, shows that such a difference is due to an effect of source alignment along the line of sight that produces a 5 sigma overdensity of red Herschel sources in the field. We analyze the members' UV spectra and UV-far-infrared spectral energy distributions to derive their SFR, stellar mass, and metallicity. Galaxy members include blue star-forming galaxies and AGN with SFRs and stellar masses consistent with the main sequence. AGN, identified through optical spectroscopy or X-ray data, represent a significant fraction (20+/-10%) of all members of the protocluster at z=2.16, and they are powerful enough to produce radiative feedback. The core of this protocluster, besides being denser, includes members that are, on average, more massive and star-forming and contains a larger fraction of AGN and Herschel-detected galaxies than the full sample, suggesting an environmental effect on galaxy growth. A comparison between G237 and other protoclusters in the literature at similar redshifts reveals some common traits and differences that reflect both observational biases and a diversity in intrinsic properties that is not yet fully understood., Comment: (40 pages, 28 figures) Accepted for publication in A&A

We present a study of optically-selected Type II AGN at 0.5 < z < 0.9 from the VIPERS and VVDS surveys, to investigate the connection between AGN activity and physical properties of their host galaxies. The host stellar mass is estimated through spectral energy distribution fitting with the CIGALE code, and star formation rates are derived from the [OII]$\lambda$3727 $\r{A}$ line luminosity. We find that 49% of the AGN host galaxies are on or above the main sequence (MS), 40% lie in the sub-MS locus, and 11% in the quiescent locus. Using the [OIII]$\lambda$5007 $\r{A}$ line luminosity as a proxy of the AGN power, we find that at fixed AGN power Type II AGN host galaxies show a bimodal behaviour: systems with host galaxy stellar mass 10$^{10}$ M$_{\odot}$) show a lower level of star formation (low-SF Type II AGN). At all stellar masses, the offset from the MS is positively correlated with the AGN power. We interpret this correlation as evidence of co-evolution between the AGN and the host, possibly due to the availability of cold gas. In the most powerful AGN with host galaxies below the MS we find a hint, though weak, of asymmetry in the [OIII] line profile, likely due to outflowing gas, consistent with a scenario in which AGN feedback removes the available gas and halts the star formation in the most massive hosts., Comment: Accepted for publication in A&A

Context. Sources at the brightest end of the quasi-stellar object (QSO) luminosity function, during the peak epoch in the history of star formation and black hole accretion (z ∼ 2-4, often referred to as "Cosmic noon") are privileged sites to study the cycle of feeding & feedback processes in massive galaxies. Aims. We aim to perform the first systematic study of cold gas properties in the most luminous QSOs, by characterising their host-galaxies and environment. These targets exhibit indeed widespread evidence of outflows at nuclear and galactic scales. Methods. We analyse ALMA, NOEMA and JVLA observations of the far-infrared continuum, CO and [CII] emission lines in eight QSOs (bolometric luminosity LBol ≳ 3 × 1047 erg s-1) from the WISE-SDSS selected hyper-luminous (WISSH) QSOs sample at z ∼ 2.4-4.7. Results. We report a 100% emission line detection rate and a 80% detection rate in continuum emission, and we find CO emission to be consistent with the steepest CO ladders observed so far. Sub-millimetre data reveal presence of (one or more) bright companion galaxies around ∼80% of WISSH QSOs, at projected distances of ∼6-130 kpc. We observe a variety of sizes for the molecular gas reservoirs (∼1.7-10 kpc), mostly associated with rotating disks with disturbed kinematics. WISSH QSOs typically show lower CO luminosity and higher star formation efficiency than infrared matched, z ∼ 0-3 main-sequence galaxies, implying that, given the observed SFR ∼170-1100 M⊙ yr-1, molecular gas is converted into stars in ≲ 50 Myr. Most targets show extreme dynamical to black-hole mass ratios Mdyn/MBH ∼ 3-10, two orders of magnitude smaller than local relations. The molecular gas fraction in the host-galaxies of WISSH is lower by a factor of ∼10-100 than in star forming galaxies with similar M∗. Conclusions. Our analysis reveals that hyper-luminous QSOs at Cosmic noon undergo an intense growth phase of both the central super-massive black hole and of the host-galaxy. These systems pinpoint the high-density sites where giant galaxies assemble, where we show that mergers play a major role in the build-up of the final host-galaxy mass. We suggest that the observed low molecular gas fraction and short depletion timescale are due to AGN feedback, whose presence is indicated by fast AGN-driven ionised outflows in all our targets. © ESO 2020., This paper makes use of the following ALMA data: ADS/JAO.ALMA#2013.1.00417.S, ADS/JAO.ALMA#2019.1.01070.S, ADS/JAO.ALMA#2015.1.01602.S, ADS/JAO.ALMA#2016.1.00718.S, ADS/JAO. ALMA#2016.1.01515.S, ADS/JAO.ALMA#2018.1.01806.S. ALMA is a partnership of ESO (representing its member states), NSF (USA) and NINS (Japan), together with NRC (Canada), MOST and ASIAA (Taiwan), and KASI (Republic of Korea), in cooperation with the Republic of Chile. The Joint ALMA Observatory is operated by ESO, AUI/NRAO and NAOJ. This work is based on observations carried out under project number S17BW and W17DT with the IRAM NOEMA Interferometer. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain). We are grateful to the anonymous referee for useful feedback which helped us to improve the paper. We thank Dr. Y. Wang for providing us with SUBARU images of J0209-0005 and Dr. P. Santini for useful discussion about SFE in high-z galaxies. MBi, MBr, CF, FF, AM, EP acknowledge support from PRIN MIUR project "Black Hole winds and the Baryon Life Cycle of Galaxies: the stone-guest at the galaxy evolution supper", contract #2017PH3WAT. MBi, CF and FF acknowledge support from INAF under PRIN SKA/CTA FORECaST and PRIN MAINSTREAM 2018 "Black hole winds and the baryon cycle". EP, LZ and MBi acknowledge financial support under ASI-INAF contract 2017-14-H.0. GB acknowledges financial support under the INTEGRAL ASI-INAF agreement 2019-35-HH.0 MPT acknowledges financial support from the State Agency for Research of the Spanish MCIU through the Center of Excellence Severo Ochoa award to the Instituto de Astrofisica de Andalucia (SEV-2017-0709) and through grant PGC2018-098915-B-C21 (MCI/AEI/FEDER, UE). RM acknowledges ERC Advanced Grant 695671 "QUENCH" and support by the Science and Technology Facilities Council (STFC). GVe acknowledges support from CONICYT Basal-CATA AFB-170002 and FONDECYT Postdoctorado 3200802 grants. CC acknowledges support from the Royal Society. MP is supported by the Programa Atraccion de Talento de la Comunidad de Madrid via grant 2018-T2/TIC-11715. GVi acknowledges financial support from Premiale 2015 MITiC (PI B. Garilli).

We present a detailed study of ionized outflows in a large sample of ~650 hard X-ray detected AGN. Using optical spectroscopy from the BAT AGN Spectroscopic Survey (BASS) we are able to reveal the faint wings of the [OIII] emission lines associated with outflows covering, for the first time, an unexplored range of low AGN bolometric luminosity at low redshift (z~0.05). We test if and how the incidence and velocity of ionized outflow is related to AGN physical parameters: black hole mass, gas column density, Eddington Ratio, [OIII], X-ray, and bolometric luminosities. We find a higher occurrence of ionized outflows in type 1.9 (55%) and type 1 AGN (46%) with respect to type 2 AGN (24%). While outflows in type 2 AGN are evenly balanced between blue and red velocity offsets with respect to the [OIII] narrow component, they are almost exclusively blueshifted in type 1 and type 1.9 AGN. We observe a significant dependence between the outflow occurrence and accretion rate, which becomes relevant at high Eddington ratios (> -1.7). We interpret such behaviour in the framework of covering factor-Eddington ratio dependence. We don't find strong trends of the outflow maximum velocity with AGN physical parameters, as an increase with bolometric luminosity can be only identified when including samples of AGN at high luminosity and high redshift taken from literature., Accepted for publication in MNRAS, 15 pages, 19 figures, 1 table

During the last years, Ly$\alpha$ nebulae have been routinely detected around high-z, radio-quiet quasars (RQQs) thanks to the advent of sensitive integral field spectrographs. Constraining the physical properties of the Ly$\alpha$ nebulae is crucial for a full understanding of the circum-galactic medium (CGM), which is a venue of feeding and feedback processes. The most luminous quasars are privileged test-beds to study these processes, given their large ionizing fluxes and dense CGM environments in which they are expected to be embedded. We aim at characterizing the rest-frame UV emission lines in the CGM around a hyper-luminous, broad emission line, RQQ at z~3.6, that exhibits powerful outflows at both nuclear and host galaxy scales. We analyze VLT/MUSE observations of the quasar J1538+08 and perform a search for extended UV emission lines to characterize its morphology, emissivity, kinematics and metal content. We report the discovery of a very luminous ($\sim2 \times10^{44}~erg~s^{-1}$), giant Ly$\alpha$ nebula and a likely associated extended CIV nebula. The Ly$\alpha$ nebula emission exhibits moderate blueshift compared with the quasar systemic redshift and large average velocity dispersion ($\sigma_{v}$ ~700 $km~s^{-1}$) across the nebula, while the CIV nebula shows $\sigma_{v}$~$350~km~s^{-1}$. The Ly$\alpha$ line profile exhibits a significant asymmetry towards negative velocity values at 20-30 kpc south of the quasar and is well parameterized by two Gaussian components: a narrow ($\sigma$~$470~km~s^{-1}$) systemic one plus a broad ($\sigma$~1200 $km~s^{-1}$), blueshifted (~1500 $km~s^{-1}$) one. Our analysis of the MUSE observation of J1538+08 reveals metal-enriched CGM around this hyper-luminous quasar and our detection of blueshifted emission in the line profile of the Ly$\alpha$ nebula suggests that powerful nuclear outflows can propagate through the CGM over tens of kpc., Comment: 14 pages, 16 figures, 2 tables. Accepted for publication in A&A Journal

Aims. The SINFONI survey for Unveiling the Physics and Effect of Radiative feedback (SUPER) was designed to conduct a blind search for AGN-driven outflows on X-ray-selected AGNs at redshift z∼2 with high (∼2 kpc) spatial resolution, and to correlate them with the properties of their host galaxy and central black hole. The main aims of this paper are: (a) to derive reliable estimates for the masses of the black holes and accretion rates for the Type-1 AGNs in this survey; and (b) to characterise the properties of the AGN-driven winds in the broad line region (BLR). Methods. We analysed rest-frame optical and UV spectra of 21 Type-1 AGNs. We used Hα, Hβ, and MgII line profiles to estimate the masses of the black holes. We used the blueshift of the CIV line profile to trace the presence of winds in the BLR. Results. We find that the Hα and Hβ line widths are strongly correlated, as is the line continuum luminosity at 5100 Å with Hα line luminosity, resulting in a well-defined correlation between black hole masses estimated from Hα and Hβ. Using these lines, we estimate that the black hole masses for our objects are in the range Log (MBH/M·) = 8.4-10.8 and are accreting at λEdd = 0.04-1.3. Furthermore, we confirm the well-known finding that the CIV line width does not correlate with the Balmer lines and the peak of the line profile is blueshifted with respect to the [OIII]-based systemic redshift. These findings support the idea that the CIV line is tracing outflowing gas in the BLR for which we estimated velocities up to ∼4700 km s-1. We confirm the strong dependence of the BLR wind velocity on the UV-to-X-ray continuum slope, the bolometric luminosity, and Eddington ratio. We infer BLR mass outflow rates in the range 0.005-3 M· yr-1, revealing a correlation with the bolometric luminosity consistent with that observed for ionised winds in the narrow line region (NLR), and X-ray winds detected in local AGNs, and kinetic power ∼10-7-10-4 × LBol. The coupling efficiencies predicted by AGN-feedback models are much higher than the values reported for the BLR winds in the SUPER sample; although it should be noted that only a fraction of the energy injected by the AGN into the surrounding medium is expected to become kinetic power in the outflow. Finally, we find an anti-correlation between the equivalent width of the [OIII] line and the CIV velocity shift, and a positive correlation between this latter parameter and [OIII] outflow velocity. These findings, for the first time in an unbiased sample of AGNs at z∼2, support a scenario where BLR winds are connected to galaxy-scale detected outflows, and are therefore capable of affecting the gas in the NLR located at kiloparsec scale distances., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

Feedback from AGN is thought to be key in shaping the life cycle of their host galaxies by regulating star-formation activity. Therefore, to understand the impact of AGN on star formation, it is essential to trace the molecular gas out of which stars form. In this paper we present the first systematic study of the CO properties of AGN hosts at z~2 for a sample of 27 X-ray selected AGN spanning two orders of magnitude in AGN bolometric luminosity (Lbol= 10^44.7-10^46.9 erg/s) by using ALMA Band 3 observations of the CO(3-2) transition (~1" angular resolution). To search for evidence of AGN feedback on the CO properties of the host galaxies, we compared our AGN with a sample of inactive (i.e., non-AGN) galaxies from the PHIBSS survey with similar redshift, stellar masses, and SFRs. We used the same CO transition as a consistent proxy for the gas mass for the two samples in order to avoid systematics involved when assuming conversion factors. By adopting a Bayesian approach to take upper limits into account, we analyzed CO luminosities as a function of stellar masses and SFRs, as well as the ratio LCO(3-2)/M* (proxy for the gas fraction). The two samples show statistically consistent trends in the LCO(3-2)-Lfir and LCO(3-2)-M* planes. However, there are indications that AGN feature lower CO(3-2) luminosities (0.4-0.7 dex) than inactive galaxies at the 2-3sigma level when we focus on the subset of parameters where the results are better constrained and on the distribution of the mean LCO(3-2)/M*. Therefore, even by conservatively assuming the same excitation factor r31, we would find lower molecular gas masses in AGN, and assuming higher r31 would exacerbate this difference. We interpret our result as a hint of the potential effect of AGN activity (e.g., radiation and outflows), which may be able to heat, excite, dissociate, and/or deplete the gas reservoir of the host galaxies. (abridged), Comment: Key figures: 2, 3, 4. 22 pages, 9 figures (5 in appendices), 3 tables. Accepted for publication in A&A

The SINFONI survey for Unveiling the Physics and Effect of Radiative feedback (SUPER) aims at tracing and characterizing ionized gas outflows and their impact on star formation in a statistical sample of X-ray selected Active Galactic Nuclei (AGN) at z$\sim$2. We present the first SINFONI results for a sample of 21 Type-1 AGN spanning a wide range in bolometric luminosity (log $\mathrm{L_{bol}}$ = 45.4-47.9 erg/s). The main aims of this paper are determining the extension of the ionized gas, characterizing the occurrence of AGN-driven outflows, and linking the properties of such outflows with those of the AGN. We use Adaptive Optics-assisted SINFONI observations to trace ionized gas in the extended narrow line region using the [OIII]5007 line. We classify a target as hosting an outflow if its non-parametric velocity of the [OIII] line, $\mathrm{w_{80}}$, is larger than 600 km/s. We study the presence of extended emission using dedicated point-spread function (PSF) observations, after modelling the PSF from the Balmer lines originating from the Broad Line Region. We detect outflows in all the Type-1 AGN sample based on the $\mathrm{w_{80}}$ value from the integrated spectrum, which is in the range 650-2700 km/s. There is a clear positive correlation between $\mathrm{w_{80}}$ and the AGN bolometric luminosity (99% correlation probability), but a weaker correlation with the black hole mass (80% correlation probability). A comparison of the PSF and the [OIII] radial profile shows that the [OIII] emission is spatially resolved for $\sim$35% of the Type-1 sample and the outflows show an extension up to $\sim$6 kpc. The relation between maximum velocity and the bolometric luminosity is consistent with model predictions for shocks from an AGN driven outflow. The escape fraction of the outflowing gas increase with the AGN luminosity, although for most galaxies, this fraction is less than 10%., Accepted for publication in A&A, 34 pages, 14 figures and 5 tables

We present the discovery of copious molecular gas in the halo of cid_346, a $z=2.2$ quasar studied as part of the SINFONI survey for Unveiling the Physics and Effect of Radiative feedback (SUPER). New Atacama Compact Array (ACA) CO(3-2) observations detect a much higher flux (by a factor of $14\pm5$) than measured on kiloparsec scales ($r\lesssim8$ kpc) using previous snapshot Atacama Large Millimeter/submillimeter Array data. Such additional CO(3-2) emission traces a structure that extends out to $r\sim200$ kpc in projected size, as inferred through direct imaging and confirmed by an analysis of the uv visibilities. This is the most extended molecular circumgalactic medium (CGM) reservoir that has ever been mapped. It shows complex kinematics, with an overall broad line profile (FWHM $= 1000$ km/s) that is skewed towards redshifted velocities up to at least $v\sim1000$ km/s. Using the optically thin assumption, we estimate a strict lower limit for the total molecular CGM mass observed by ACA of $M_{mol}^{CGM}>10^{10}~M_{\odot}$. There is however room for up to $M^{CGM}_{mol}\sim 1.7\times 10^{12}$ $M_{\odot}$, once optically thick CO emission with $\alpha_{\rm CO}=3.6$ $\rm M_{\odot}~(K~km~s^{-1}~pc^2)^{-1}$ and $L^{\prime}_{CO(3-2)}/L^{\prime}_{CO(1-0)}=0.5$ are assumed. Since cid_346 hosts quasar-driven ionised outflows and since there is no evidence of merging companions or an overdensity, we suggest that outflows may have played a crucial rule in seeding metal-enriched, dense gas on halo scales. However, the origin of such an extended molecular CGM remains unclear., Comment: Accepted for publication in A&A Letters. 9 pages and 9 figures including Appendix. Version updated after language editing

The WISSH quasars project aims at studying the nuclear and host galaxy properties of the most luminous quasars ($L_{bol}>10^{47}$ erg/s, $1.8, Comment: Accepted for publication on A&A

Theoretical models of galaxy formation suggest that the presence of an active galactic nucleus (AGN) is required to regulate the growth of its host galaxy through feedback mechanisms, produced by e.g. AGN-driven outflows. Although such outflows are common both at low and high redshift, a comprehensive picture is still missing. The peak epoch of galaxy assembly (1, Comment: 28 pages, 8 figures, 5 tables. Accepted for publication in A&A

It is the twentieth anniversary of the publication of the seminal papers by Magorrian et al. and Silk & Rees which, along with other related work, ignited an explosion of publications connecting active galactic nuclei (AGN)-driven outflows to galaxy evolution. With a surge in observations of AGN outflows, studies are attempting to directly test AGN feedback models using the outflow properties. With a focus on outflows traced by optical and CO emission lines, we discuss significant challenges which greatly complicate this task from both an observational and theoretical perspective. We highlight observational uncertainties involved, and the assumptions required, when deriving kinetic coupling efficiencies (i.e., outflow kinetic power as a fraction of AGN luminosity) from typical observations. Based on recent models we demonstrate that extreme caution should taken when comparing observationally-derived kinetic coupling efficiencies to coupling efficiencies from fiducial feedback models., Authors' version (all referee comments addressed). 7 pages + references. Published in Nature Astronomy

We present the analysis of the rest-frame optical-to-UV spectrum of APM 08279+5255, a well-known lensed broad absorption line (BAL) quasar at $z = 3.911$. The spectroscopic data are taken with the optical DOLoRes and near-IR NICS instruments at TNG, and include the previously unexplored range between C III] $\lambda$1910 and [O III] $\lambda\lambda$4959,5007. We investigate the possible presence of multiple BALs by computing "balnicity" and absorption indexes (i.e. BI, BI$_0$ and AI) for the transitions Si IV $\lambda$1400, C IV $\lambda$1549, Al III $\lambda$1860 and Mg II $\lambda$2800. No clear evidence for the presence of absorption features is found in addition to the already known, prominent BAL associated to C IV, which supports a high-ionization BAL classification for APM 08279+5255. We also study the properties of the [O III], H$\beta$ and Mg II emission lines. We find that [O III] is intrinsically weak ($F_{\rm [OIII]}/F_{\rm H\beta} \lesssim 0.04$), as it is typically found in luminous quasars with a strongly blueshifted C IV emission line ($\sim$2500 km s$^{-1}$ for APM 08279+5255). We compute the single-epoch black hole mass based on Mg II and H$\beta$ broad emission lines, finding $M_{\rm BH} = (2 \div 3) \times 10^{10}\mu^{-1}$ M$_\odot$, with the magnification factor $\mu$ that can vary between 4 and 100 according to CO and rest-frame UV-to-mid-IR imaging respectively. Using a Mg II equivalent width (EW)-to-Eddington ratio relation, the EW$_{\rm MgII} \sim 27$ \AA\ measured for APM 08279+5255 translates into an Eddington ratio of $\sim$0.4, which is more consistent with $\mu=4$. This magnification factor also provides a value of $M_{\rm BH}$ that is consistent with recent reverberation-mapping measurements derived from C IV and Si IV., Comment: 10 pages, 4 figures, 4 tables, accepted for publication in A&A

We present an ALMA high-resolution observation of the 840 um continuum and [CII] line emission in the WISE-SDSS selected hyper-luminous (WISSH) QSO J1015+0020 at z~4.4. Our analysis reveals an exceptional overdensity of [CII]-emitting companions with a very small (, Accepted

We perform a survey of the X-ray properties of 41 objects from the WISE/SDSS selected Hyper-luminous (WISSH) quasars sample, composed by 86 broad-line quasars (QSOs) with bolometric luminosity $L_{Bol}\geq 2\times 10^{47}\,erg\, s^{-1}$, at z~2-4. All but 3 QSOs show unabsorbed 2-10 keV luminosities $L_{2-10}\geq10^{45} \,erg \,s^{-1}$. Thanks to their extreme radiative output across the Mid-IR-to-X-ray range, WISSH QSOs offer the opportunity to significantly extend and validate the existing relations involving $L_{2-10}$. We study $L_{2-10}$ as a function of (i) X-ray-to-Optical (X/O) flux ratio, (ii) mid-IR luminosity ($L_{MIR}$), (iii) $L_{Bol}$ as well as (iv) $\alpha_{OX}$ vs. the 2500$\mathring{A}$ luminosity. We find that WISSH QSOs show very low X/O(9.5). This enables a more robust modeling of the $\Gamma-M_{BH}$ relation by increasing the statistics at high masses. We derive a flatter $\Gamma$ dependence than previously found over the broad range 5, Comment: 20 pages, 14 Figures. Accepted for publication on A&A

Studying the coupling between the energy output produced by the central quasar and the host galaxy is fundamental to fully understand galaxy evolution. Quasar feedback is indeed supposed to dramatically affect the galaxy properties by depositing large amounts of energy and momentum into the ISM. In order to gain further insights on this process, we study the SEDs of sources at the brightest end of the quasar luminosity function, for which the feedback mechanism is supposed to be at its maximum. We model the rest-frame UV-to-FIR SEDs of 16 WISE-SDSS Selected Hyper-luminous (WISSH) quasars at 1.8 < z < 4.6 disentangling the different emission components and deriving physical parameters of both the nuclear component and the host galaxy. We also use a radiative transfer code to account for the contribution of the quasar-related emission to the FIR fluxes. Most SEDs are well described by a standard combination of accretion disk+torus and cold dust emission. However, about 30% of them require an additional emission component in the NIR, with temperatures peaking at 750K, which indicates the presence of a hotter dust component in these powerful quasars. We measure extreme values of both AGN bolometric luminosity (LBOL > 10^47 erg/s) and SFR (up to 2000 Msun/yr). A new relation between quasar and star-formation luminosity is derived (LSF propto LQSO^(0.73)) by combining several Herschel-detected quasar samples from z=0 to 4. Future observations will be crucial to measure the molecular gas content in these systems, probe the impact between quasar-driven outflows and on-going star-formation, and reveal the presence of merger signatures in their host galaxies., 19 pages, 12 figures; Accepted for publication in Astronomy & Astrophysics on June 13, 2017

We have performed a high sensitivity observation of the UFO/BAL quasar APM 08279+5255 at z=3.912 with NOEMA at 3.2 mm, aimed at detecting fast moving molecular gas. We report the detection of blueshifted CO(4-3) with maximum velocity (v95\%) of $-1340$ km s$^{-1}$, with respect to the systemic peak emission, and a luminosity of $L' = 9.9\times 10^9 ~\mu^{-1}$ K km s$^{-1}$ pc$^{-2}$ (where $\mu$ is the lensing magnification factor). We discuss various scenarios for the nature of this emission, and conclude that this is the first detection of fast molecular gas at redshift $>3$. We derive a mass flow rate of molecular gas in the range $\rm \dot M=3-7.4\times 10^3$ M$_\odot$/yr, and momentum boost $\dot P_{OF} / \dot P_{AGN} \sim 2-6$, therefore consistent with a momentum conserving flow. For the largest $\dot P_{OF}$ the scaling is also consistent with a energy conserving flow with an efficiency of $\sim$10-20\%. The present data can hardly discriminate between the two expansion modes. The mass loading factor of the molecular outflow $\eta=\dot M_{OF}/SFR$ is $>>1$. We also detect a molecular emission line at a frequency of 94.83 GHz, corresponding to a rest frame frequency of 465.8 GHz, which we tentatively identified with the cation molecule $\rm N_2H^+$(5-4), which would be the first detection of this species at high redshift. We discuss the alternative possibility that this emission is due to a CO emission line from the, so far undetected, lens galaxy. Further observations of additional transitions of the same species with NOEMA can discriminate between the two scenarios., Comment: Accepted for publication on Astronomy & Astrophysics

Models and observations suggest that both power and effects of AGN feedback should be maximised in hyper-luminous (L_Bol>10^47 erg/s) quasars, i.e. objects at the brightest end of the AGN luminosity function. We present the first results of a multi-wavelength observing program, focusing on a sample of WISE/SDSS selected hyper-luminous (WISSH) broad-line quasars at z~1.5-5. The WISSH quasars project has been designed to reveal the most energetic AGN-driven outflows, estimate their occurrence at the peak of quasar activity and extend the study of correlations between outflows and nuclear properties up to poorly-investigated extreme AGN luminosities (L_Bol~10^47 -10^48 erg/s). We present NIR, long-slit LBT/LUCI1 spectroscopy of five WISSH quasars at z~2.3-3.5 showing prominent [OIII] emission lines with broad (FWHM~1200-2200 km/s) and skewed profiles. The luminosities of the broad [OIII] wings are the highest measured so far (L_[OIII]^broad >~5x10^44 erg/s) and reveal the presence of powerful ionised outflows with mass outflow rates Mdot >~1700 M_Sun/yr and kinetic powers Edot >~10^45 erg/s. Although these estimates are affected by large uncertainties, due to the use of [OIII] as tracer of ionized outflows and the very basic outflow model we assume, these results suggest that the AGN is highly efficient in pushing outwards large amounts of ionised gas in our targets. The mechanical outflow luminosities for WISSH quasars correspond to higher fractions (~1-3%) of L_Bol than those derived for lower L_Bol AGN. Our targets host very massive (M_BH>~2x10^9 M_Sun) black holes which are still accreting at a high rate (i.e. a factor of ~0.4-3 of the Eddington limit). These findings demonstrate that WISSH quasars offer the opportunity of probing the extreme end of both luminosity and SMBH mass functions and revealing powerful ionised outflows able to affect the evolution of their host galaxies., 18 pages, 11 figures, A&A accepted

Feedback from accreting SMBHs is often identified as the main mechanism responsible for regulating star-formation in AGN host galaxies. However, the relationships between AGN activity, radiation, winds, and star-formation are complex and still far from being understood. We study scaling relations between AGN properties, host galaxy properties and AGN winds. We then evaluate the wind mean impact on the global star-formation history, taking into account the short AGN duty cycle with respect to that of star-formation. We first collect AGN wind observations for 94 AGN with detected massive winds at sub-pc to kpc spatial scales. We then fold AGN wind scaling relations with AGN luminosity functions, to evaluate the average AGN wind mass-loading factor as a function of cosmic time. We find strong correlations between the AGN molecular and ionised wind mass outflow rates and the AGN bolometric luminosity. The power law scaling is steeper for ionised winds (slope 1.29+/-0.38) than for molecular winds (0.76+/-0.06), meaning that the two rates converge at high bolometric luminosities. The molecular gas depletion timescale and the molecular gas fraction of galaxies hosting powerful AGN winds are 3-10 times shorter and smaller than those of main-sequence galaxies with similar SFR, stellar mass and redshift. These findings suggest that, at high AGN bolometric luminosity, the reduced molecular gas fraction may be due to the destruction of molecules by the wind, leading to a larger fraction of gas in the atomic ionised phase. The AGN wind mass-loading factor $\eta=\dot M_{OF}/SFR$ is systematically higher than that of starburst driven winds. Our analysis shows that AGN winds are, on average, powerful enough to clean galaxies from their molecular gas only in massive systems at z, This work was supported by ASI/INAF contract I/009/10/0 and INAF PRIN 2011, 2012 and 2014. MB acknowledges support from the FP7 Career Integration Grant “eEASy” (CIG 321913). LZ acknowledges support from ASI/INAF grant I/037/12/0. CF acknowledges funding from the European Union Horizon 2020 research and innovation programme under the Marie SklodowskaCurie grant agreement No 664931. CC acknowledges funding from the European Union Horizon 2020 research and innovation programme under the Marie SklodowskaCurie grant agreement No 664931 and support from Swiss National Science Foundation Grants PP00P2 138979 and PP00P2 166159. RM acknowledges the ERC Advanced Grant 695671 QUENCH and support from the Science and Technology Facilities Council (STFC).

Synthetic Na-zeolites (NaA, NaX, NaAX) were investigated as tanning agents in leather production from sheepskin and calfskin pelts. It was found in laboratory scale testing that the combined use of zeolite and chrome sulphate results in both higher float exhaustion and higher shrinkage temperatures in shorter time than in conventional chrome tannage. The best results were obtained with zeolite NaA. The operating conditions were optimized with respect to chrome and zeolite concentration, tanning bath pH and pelt weight/bath volume ratio. The analysed Si/Al ratio in the leather is about 1.1, similar to that of NaA zeolite. The promoting effect of zeolite A in chrome tanning has been confirmed on pilot scale: higher tanning rate as well as higher float exhaustion were found. Mechanical properties of the finished leathers, such as tensile strength, elongation, tearing strength and ball bursting are similar or better when compared with chrome usually tanned leather.

Winds accelerated by active galactic nuclei (AGNs) are invoked in the most successful models of galaxy evolution to explain the observed physical and evolutionary properties of massive galaxies. Winds are expected to deposit energy and momentum into the interstellar medium (ISM), thus regulating both star formation and supermassive black hole (SMBH) growth. We undertook a multiband observing program aimed at obtaining a complete census of winds in a sample of WISE/SDSS selected hyper-luminous (WISSH) quasars (QSOs) at z ≈ 2–4. We analyzed the rest-frame optical (i.e. LBT/LUCI and VLT/SINFONI) and UV (i.e. SDSS) spectra of 18 randomly selected WISSH QSOs to measure the SMBH mass and study the properties of winds both in the narrow line region (NLR) and broad line region (BLR) traced by blueshifted or skewed [OIII] and CIV emission lines, respectively. These WISSH QSOs are powered by SMBH with masses ≳109 M⊙ accreting at 0.4 < λEdd < 3.1. We found the existence of two subpopulations of hyper-luminous QSOs characterized by the presence of outflows at different distances from the SMBH. One population (i.e. [OIII] sources) exhibits powerful [OIII] outflows, a rest-frame equivalent width (REW) of the CIV emission REWCIV ≈ 20–40 Å, and modest CIV velocity shift (vCIVpeak) with respect to the systemic redshift (vCIVpeak −1). The second population (i.e. Weak [OIII] sources), representing ~70% of the analyzed WISSH QSOs, shows weak or absent [OIII] emission and an extremely large blueshifted CIV emission (vCIVpeak up to ~8000 km s−1 and REWCIV OIII] QSOs (Ėkin ~ 1044−45 erg s−1). We also investigated the dependence of these CIV winds on fundamental AGN parameters such as bolometric luminosity (LBol), Eddington ratio (λEdd), and UV-to-X-ray continuum slope (αOX). We found a strong correlation with LBol and an anti-correlation with αOX whereby the higher the luminosity, the steeper the ionizing continuum described by means of αOX and the larger the blueshift of the CIV emission line. Finally, the observed dependence vCIVpeak ∝ LBol0.28 ± 0.04 is consistent with a radiatively-driven-winds scenario, where a strong UV continuum is necessary to launch the wind and a weakness of the X-rayemission is fundamental to prevent overionization of the wind itself.