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1. Development of diastereoselective Birch reduction-alkylation reactions of bi- and tricyclic [beta]-alkoxy-[alpha],[beta]-unsatuarated ketones

Author

Hiroya, Kou, Ichihashi, Yusuke, Furutono, Ai, Inamoto, Kiyofumi, Sakamoto, Takao, and Doi, Takayuki

Subjects
Carbonyl compounds -- Structure, Carbonyl compounds -- Chemical properties, Ketones -- Chemical properties, Oxidation-reduction reaction -- Analysis, Biological sciences, Chemistry
Abstract

Diastereoselective Birch reduction-alkylation reactions of bicyclic [beta]-alkoky-[alpha],[beta]-unsaturated carbonyl compounds and tricyclic analogues are examined. The product from the tricyclic [beta]-alkoxy-[alpha],[beta]-unsaturated carbonyl compound has corresponded to the trichothecene skeleton.

Published
2009

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