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Erbium-doped \ch{TiO2} materials are promising candidates for advancing quantum technologies, necessitating a thorough understanding of their electronic and crystal structures to tailor their properties and enhance coherence times. This study explored epitaxial erbium-doped rutile \ch{TiO2} films deposited on r-sapphire substrates using molecular beam epitaxy. Photoluminescence excitation spectroscopy demonstrated decreasing fluorescence lifetimes with erbium doping, indicating limited coherence times. Lattice distortions associated with \ch{Er^{3+}} were probed by X-ray absorption spectroscopy, indicating that erbium primarily occupies \ch{Ti^{4+}} sites and influences oxygen vacancies. Significant lattice distortions in the higher-order shells and full coordination around erbium suggest that additional defects are likely prevalent in these regions. These findings indicate that defects contribute to limited coherence times by introducing alternative decay pathways, leading to shorter fluorescence lifetimes., Comment: 8 pages, 13 figures, 3 tables

In rare earth nickelates (RENiO$_3$), electron-lattice coupling drives a concurrent metal-to-insulator and bond disproportionation phase transition whose microscopic origin has long been the subject of active debate. Of several proposed mechanisms, here we test the hypothesis that pairs of self-doped ligand holes spatially condense to provide local spin moments that are antiferromagnetically coupled to Ni spins. These singlet-like states provide a basis for long-range bond and spiral spin order. Using magnetic resonant X-ray scattering on NdNiO$_3$ thin films, we observe the chiral nature of the spin-disproportionated state, with spin spirals propagating along the crystallographic (101)$_\mathrm{ortho}$ direction. These spin spirals are found to preferentially couple to X-ray helicity, establishing the presence of a hitherto-unobserved macroscopic chirality. The presence of this chiral magnetic configuration suggests a potential multiferroic coupling between the noncollinear magnetic arrangement and improper ferroelectric behavior as observed in prior studies on NdNiO$_3$ (101)$_\mathrm{ortho}$ films and RENiO$_3$ single crystals. Experimentally constrained theoretical double-cluster calculations confirm the presence of an energetically stable spin-disproportionated state with Zhang-Rice singlet-like combinations of Ni and ligand moments., Comment: 6 pages, 4 figures

Both magnetism and spin-orbit coupling in systems with broken inversion symmetry lift the spin degeneracy of electronic bands, but the consequences of interplay between these mechanisms remain poorly understood. Here, we show that ultrathin transition ferromagnet-heavy metal bilayers exhibit anomalous temperature- and electric bias-dependent behaviors in the vicinity of the Curie temperature, inconsistent with the usual Weiss magnetism. Characterization by several complementary techniques and analysis of the dependence on composition reveal that these effects originate from interfacial spin-orbit interaction, which results in the emergence of a state with distinct magnetic and magnetoelectronic properties that can be described as Rashba magnetism. Our findings open a new route for the characterization and control of spin-orbit phenomena in heterostructures enabling the development of efficient spin-orbitronic devices., Comment: 6 pages, 4 figures, comments are welcome

Adaptive networks can sense and adjust to dynamic environments to optimize their performance. Understanding their nanoscale responses to external stimuli is essential for applications in nanodevices and neuromorphic computing. However, it is challenging to image such responses on the nanoscale with crystallographic sensitivity. Here, the evolution of nanodomain networks in (PbTiO3)n/(SrTiO3)n superlattices was directly visualized in real space as the system adapts to ultrafast repetitive optical excitations that emulate controlled neural inputs. The adaptive response allows the system to explore a wealth of metastable states that were previously inaccessible. Their reconfiguration and competition were quantitatively measured by scanning x-ray nanodiffraction as a function of the number of applied pulses, in which crystallographic characteristics were quantitatively assessed by assorted diffraction patterns using unsupervised machine-learning methods. The corresponding domain boundaries and their connectivity were drastically altered by light, holding promise for light-programmable nanocircuits in analogy to neuroplasticity. Phase-field simulations elucidate that the reconfiguration of the domain networks is a result of the interplay between photocarriers and transient lattice temperature. The demonstrated optical control scheme and the uncovered nanoscopic insights open opportunities for remote control of adaptive nanoscale domain networks.

Schools are increasingly engaging in career-connected learning to increase career exposure and skill development. But focusing on skills alone will fall short, particularly if schools hope to address long-standing opportunity gaps. Awareness of possible careers and access to jobs depends not only on learning and achievement, but on personal and professional relationships that serve as gateways to career opportunities. Opportunity sits at the intersection of students' human capital--what they know and can do--and their social capital--who they know and can depend on for support and access. To launch a career, students need more than skills--they also need people willing to take a bet on their potential. With the aim of helping leaders implement effective, equitable strategies for building students' social capital, this report offers field-tested considerations for piloting social capital building within existing career pathways initiatives. The observations draw from an 18-month pilot during which the authors leveraged their social capital playbook to provide direct support to a group of three intermediary organizations--Education Strategy Group, Generation Schools Network, and Hawai'i P-20--collectively supporting 20 sites in the K-12 career pathways space. In the course of the pilot, the authors sought to understand how schools and nonprofits can make social capital building an explicit, effective, and equitable component of existing career-connected learning models.

A central paradigm of non-equilibrium physics concerns the dynamics of heterogeneity and disorder, impacting processes ranging from the behavior of glasses to the emergent functionality of active matter. Understanding these complex mesoscopic systems requires probing the microscopic trajectories associated with irreversible processes, the role of fluctuations and entropy growth, and the timescales on which non-equilibrium responses are ultimately maintained. Approaches that illuminate these processes in model systems may enable a more general understanding of other heterogeneous non-equilibrium phenomena, and potentially define ultimate speed and energy cost limits for information processing technologies. Here, we apply ultrafast single shot x-ray photon correlation spectroscopy to resolve the non-equilibrium, heterogeneous, and irreversible mesoscale dynamics during a light-induced phase transition. This approach defines a new way of capturing the nucleation of the induced phase, the formation of transient mesoscale defects at the boundaries of the nuclei, and the eventual annihilation of these defects, even in systems with complex polarization topologies. A non-equilibrium response spanning >10 orders of magnitude in timescales is observed, with multistep behavior similar to the plateaus observed in supercooled liquids and glasses. We show how the observed time-dependent long-time correlations can be understood in terms of the stochastic dynamics of domain walls, encoded in effective waiting-time distributions with power-law tails. This work defines new possibilities for probing the non-equilibrium and correlated dynamics of disordered and heterogeneous media.

Would another origin of life resemble Earth's biochemical use of amino acids? Here we review current knowledge at three levels: 1) Could other classes of chemical structure serve as building blocks for biopolymer structure and catalysis? Amino acids now seem both readily available to, and a plausible chemical attractor for, life as we don't know it. Amino acids thus remain important and tractable targets for astrobiological research. 2) If amino acids are used, would we expect the same L-alpha-structural subclass used by life? Despite numerous ideas, it is not clear why life favors L-enantiomers. It seems clearer, however, why life on Earth uses the shortest possible (alpha-) amino acid backbone, and why each carries only one side chain. However, assertions that other backbones are physicochemically impossible have relaxed into arguments that they are disadvantageous. 3) Would we expect a similar set of side chains to those within the genetic code? Not only do many plausible alternatives exist and evidence exists for both evolutionary advantage and physicochemical constraint for those encoded by life. Overall, as focus shifts from amino acids as a chemical class to specific side chains used by post-LUCA biology, the probable role of physicochemical constraint diminishes relative to that of biological evolution. Exciting opportunities now present themselves for laboratory work and computing to explore how changing the amino acid alphabet alters the universe of protein folds. Near-term milestones include: a) expanding evidence about amino acids as attractors within chemical evolution; b) extending characterization of other backbones relative to biological proteins; c) merging computing and laboratory explorations of structures and functions unlocked by xeno peptides., Comment: Submitted to Life (ISSN 2075-1729), 26 pages (without references), 8 figures, 1 table, 1 box

Rare-earth ion dopants in solid-state hosts are ideal candidates for quantum communication technologies such as quantum memory, due to the intrinsic spin-photon interface of the rare-earth ion combined with the integration methods available in the solid-state. Erbium-doped cerium oxide (Er:CeO$_2$) is a particularly promising platform for such a quantum memory, as it combines the telecom-wavelength (~1.5 $\mu$m) 4f-4f transition of erbium, a predicted long electron spin coherence time supported by CeO$_2$, and is also near lattice-matched to silicon for heteroepitaxial growth. In this work, we report on the epitaxial growth of Er:CeO$_2$ thin films on silicon using molecular beam epitaxy (MBE), with controlled erbium concentration down to 2 parts per million (ppm). We carry out a detailed microstructural study to verify the CeO$_2$ host structure, and characterize the spin and optical properties of the embedded Er$^{3+}$ ions. In the 2-3 ppm Er regime, we identify EPR linewidths of 245(1) MHz, optical inhomogeneous linewidths of 9.5(2) GHz, optical excited state lifetimes of 3.5(1) ms, and spectral diffusion-limited homogenoeus linewidths as narrow as 4.8(3) MHz in the as-grown material. We test annealing of the Er:CeO$_2$ films up to 900 deg C, which yields modest narrowing of the inhomogeneous linewidth by 20% and extension of the excited state lifetime by 40%. We have also studied the variation of the optical properties as a function of Er doping and find that the results are consistent with the trends expected from inter-dopant charge interactions., Comment: 15 pages, 6 figures (including supplemental information)

The current challenge to realizing continuously tunable magnetism lies in our inability to systematically change properties such as valence, spin, and orbital degrees of freedom as well as crystallographic geometry. Here, we demonstrate that ferromagnetism can be externally turned on with the application of low-energy helium implantation and subsequently erased and returned to the pristine state via annealing. This high level of continuous control is made possible by targeting magnetic metastability in the ultra-high conductivity, non-magnetic layered oxide PdCoO2 where local lattice distortions generated by helium implantation induce emergence of a net moment on the surrounding transition metal octahedral sites. These highly-localized moments communicate through the itinerant metal states which triggers the onset of percolated long-range ferromagnetism. The ability to continuously tune competing interactions enables tailoring precise magnetic and magnetotransport responses in an ultra-high conductivity film and will be critical to applications across spintronics., Comment: https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.3c01065

Efforts to invest in students' networks--either to bolster support or expand professional opportunities--should start with a deep understanding of and appreciation for the networks of which they are already members. Recognizing and respecting students' inherent resources and cultural wealth is what this report refers to as an asset-based approach. Luckily, a host of innovative organizations focused on more equitably building and maintaining students' social capital are doing just that. This report describes the profound potential of these organizations' approaches to mapping and mobilizing students' existing social networks, and details emerging strategies and tools that schools should consider. To surface these examples, the authors interviewed and convened program leaders from a variety of schools, nonprofits, and social enterprises. These leaders have all endeavored to help students map out, reflect on, and mobilize their existing networks in some form or fashion. Because deficit-based approaches may be more common among institutions serving low-income students, first-generation students, and students of color, the majority of the programs interviewed explicitly focus on serving students from these backgrounds, with strategies attuned to their students' racial and cultural identities. This paper explores the research behind relationship mapping and the basic tenets of building a relationship map. To illustrate how and when schools can use relationship mapping to serve a variety of short- and long-term goals, it highlights examples of current programs. Finally, it offers recommendations for furthering the vision and unlocking the potential of relationship mapping.

Technology moves towards ever faster switching between different electronic and magnetic states of matter. Manipulating properties at terahertz rates requires accessing the intrinsic timescales of electrons (femtoseconds) and associated phonons (10s of femtoseconds to few picoseconds), which is possible with short-pulse photoexcitation. Yet, in many Mott insulators, the electronic transition is accompanied by the nucleation and growth of percolating domains of the changed lattice structure, leading to empirical time scales dominated by slow coarsening dynamics. Here, we use time-resolved X-ray diffraction and reflectivity measurements to investigate the photoinduced insulator-to-metal transition in an epitaxially strained thin film Mott insulator Ca2RuO4. The dynamical transition occurs without observable domain formation and coarsening effects, allowing the study of the intrinsic electronic and lattice dynamics. Above a fluence threshold, the initial electronic excitation drives a fast lattice rearrangement, followed by a slower electronic evolution into a metastable non-equilibrium state. Microscopic calculations based on time-dependent dynamical mean-field theory and semiclassical lattice dynamics within a recently published equilibrium energy landscape picture explain the threshold-behavior and elucidate the delayed onset of the electronic phase transition in terms of kinematic constraints on recombination. Analysis of satellite scattering peaks indicates the persistence of a strain-induced nano-texture in the photoexcited film. This work highlights the importance of combined electronic and structural studies to unravel the physics of dynamic transitions and elucidates the role of strain in tuning the timescales of photoinduced processes.

We present Ly $\alpha$ imaging of 45 low redshift star-forming galaxies observed with the Hubble Space Telescope. The galaxies have been selected to have moderate to high star formation rates using far-ultraviolet (FUV) luminosity and \ha equivalent width criteria, but no constraints on Ly $\alpha$ luminosity. We employ a pixel stellar continuum fitting code to obtain accurate continuum subtracted Ly $\alpha$, H $\alpha$ and H $\beta$ maps. We find that Ly $\alpha$ is less concentrated than FUV and optical line emission in almost all galaxies with significant Ly $\alpha$ emission. We present global measurements of Ly $\alpha$ and other quantities measured in apertures designed to capture all of the Ly $\alpha$ emission. We then show how the escape fraction of Ly $\alpha$ relates to a number of other measured quantities (mass, metallicity, star formation, ionisation parameter, and extinction). We find that the escape fraction is strongly anti-correlated with nebular and stellar extinction, weakly anti-correlated with stellar mass, but no conclusive evidence for correlations with other quantities. We show that Ly $\alpha$ escape fractions are inconsistent with common dust extinction laws, and discuss how a combination of radiative transfer effects and clumpy dust models can help resolve the discrepancies. We present a star formation rate calibration based on Ly $\alpha$ luminosity, where the equivalent width of Ly $\alpha$ is used to correct for non-unity escape fraction, and show that this relation provides a reasonably accurate SFR estimate. We also show stacked growth curves of Ly $\alpha$ for the galaxies that can be used to find aperture loss fractions at a given physical radius., Comment: 48 pages, 21 figures, accepted for publication in The Astrophysical Journal Supplement Series. Multipanel figures for all 45 galaxies will be available in the online version of the published paper (and here: https://stockholmuniversity.box.com/s/ghvnvjyhxts64hpbqh90uwcj5dlczlhm ). Data products will be available as a MAST HLSP soon (placeholder DOI: 10.17909/pbe1-m743)

Lanthanides in the trivalent oxidation state are typically described using an ionic picture that leads to localized magnetic moments. The hierarchical energy scales associated with trivalent lanthanides produce desirable properties for e.g., molecular magnetism, quantum materials, and quantum transduction. Here, we show that this traditional ionic paradigm breaks down for praseodymium in the 4+ oxidation state. Synthetic, spectroscopic, and theoretical tools deployed on several solid-state Pr4+ oxides uncover the unusual participation of 4f orbitals in bonding and the anomalous hybridization of the 4f1 configuration with ligand valence electrons, analogous to transition metals. The resulting competition between crystal-field and spin-orbit-coupling interactions fundamentally transforms the spin-orbital magnetism of Pr4+, which departs from the Jeff =1/2 limit and resembles that of high-valent actinides. Our results show that Pr4+ ions are in a class on their own, where the hierarchy of single-ion energy scales can be tailored to explore new correlated phenomena in quantum materials., Comment: 9 pages, 4 figures, and SI (47 pages)

Exploiting the emerging nanoscale periodicities in epitaxial, single-crystal thin films is an exciting direction in quantum materials science: confinement and periodic distortions induce novel properties. The structural motifs of interest are ferroelastic, ferroelectric, multiferroic, and, more recently, topologically protected magnetization and polarization textures. A critical step towards heterostructure engineering is understanding their nanoscale structure, best achieved through real-space imaging. X-ray Bragg coherent diffractive imaging visualizes sub-picometer crystalline displacements with tens of nanometers spatial resolution. Yet, it is limited to objects spatially confined in all three dimensions and requires highly coherent, laser-like x-rays. Here we lift the confinement restriction by developing real-space imaging of periodic lattice distortions: we combine an iterative phase retrieval algorithm with unsupervised machine learning to invert the diffuse scattering in conventional x-ray reciprocal-space mapping into real-space images of polar and elastic textures in thin epitaxial films. We first demonstrate our imaging in PbTiO3/SrTiO3 superlattices to be consistent with published phase-field model calculations. We then visualize strain-induced ferroelastic domains emerging during the metal-insulator transition in Ca2RuO4 thin films. Instead of homogeneously transforming into a low-temperature structure (like in bulk), the strained Mott insulator splits into nanodomains with alternating lattice constants, as confirmed by cryogenic scanning transmission electron microscopy. Our study reveals the type, size, orientation, and crystal displacement field of the nano-textures. The non-destructive imaging of textures promises to improve models for their dynamics and enable advances in quantum materials and microelectronics.

The quasi-two-dimensional van der Waals magnet Fe$_{5-\delta}$GeTe$_2$ has emerged as a promising platform for electronic and spintronic functionalities at room temperature, owing to its large ferromagnetic ordering temperature $T_{\text{C}}$ $\sim$ 315 K. Interestingly, by cobalt (Co) substitution of iron in F5GT, $i.e.$ $({\text{Fe}}_{1-x}{\text{Co}}_x)_{5-\delta}{\text{GeTe}}_2$ (Co-F5GT), not only can its magnetic transition temperature be further enhanced, but the magnetic and structural ground states can also be tuned. Specifically, an antiferromagnetic (AFM) order is induced beyond the Co doping level $x \ge 0.4$. Here, we investigate the magnetic properties of a Co-F5GT single crystal at $x = 0.45(1)$, by utilizing the element specific, resonant magnetic x-ray scattering technique. Our study reveals an A-type, Ising-like AFM ground state, with a transition temperature $T_{\text{N}}$ $\sim$ 340 K. In addition, our work unveils an important contribution from Co magnetic moments to the magnetic order. The application of the in-plane magnetic fields gradually polarize the spin moments along the field direction, but without inducing incommensurate spin texture(s)., Comment: 7 pages with 5 figures. Submitted on June/2022

Magnetism in topological materials creates phases exhibiting quantized transport phenomena with applications in spintronics and quantum information. The emergence of such phases relies on strong interaction between localized spins and itinerant states comprising the topological bands, and the subsequent formation of an exchange gap. However, this interaction has never been measured in any intrinsic magnetic topological material. Using a multimodal approach, this exchange interaction is measured in MnBi2Te4, the first realized intrinsic magnetic topological insulator. Interrogating nonequilibrium spin dynamics, itinerant bands are found to exhibit a strong exchange coupling to localized Mn spins. Momentum-resolved ultrafast electron scattering and magneto-optic measurements reveal that itinerant spins disorder via electron-phonon scattering at picosecond timescales. Localized Mn spins, probed by resonant X-ray scattering, disorder concurrently with itinerant spins, despite being energetically decoupled from the initial excitation. Modeling the results using atomistic simulations, the exchange coupling between localized and itinerant spins is estimated to be >100 times larger than superexchange interactions. This implies an exchange gap of >25 meV should occur in the topological surface states. By directly quantifying local-itinerant exchange coupling, this work validates the materials-by-design strategy of utilizing localized magnetic order to create and manipulate magnetic topological phases, from static to ultrafast timescales.

Alumni networks are part of the bill of goods that colleges and universities sell to students. But according to a Strada-Gallup Alumni Survey, only 9% of college graduates reported that their alumni network was helpful or very helpful in the job market. That startling statistic says a lot about how poorly most institutions actually perform when it comes to systematically connecting alumni and students in reliable, scalable ways. Endowment-supported institutions have long-held, elaborate strategies in place to "engage" alumni to mine their financial capital. But if the Strada-Gallup alumni survey is any clue, they--and their peer institutions with smaller or no endowments--could be doing more to successfully activate alumni's social capital. That social capital has immense potential to drive improvements in students' experiences while on campus, and to bolster graduates' long-term return on investment (ROI) in a degree. With the right tools and models, postsecondary institutions could enlist alumni to deliberately equip college-goers with career skills and professional networks. This report highlights innovative companies and models that are emerging to help postsecondary players harness their alumni networks in new ways, and provides an analysis of five ways that rethinking alumni connections could fulfill postsecondary education's promise. The tools and models highlighted in this paper reflect the fact that it's networks--not just degrees--that lead to jobs. Alumni networks are a critical resource as postsecondary programs look to enrich the student experience, particularly with an eye towards boosting graduates' ROI.