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International audience; The south east basin of France shelters deep CO2 reservoirs often studied with the aim of better constraining geological CO2 storage operations. Here we present new soil gas data, completing an existing dataset (CO2, 222Rn, 4He), together with mineralogical and physical characterisations of soil columns, in an attempt to better understand the spatial distribution of gas concentrations in the soils and to rule on the sealed character of the CO2 reservoir at present time. Anomalous gas concentrations were found but did not appear to be clearly related to geological structures that may drain deep gases up to the surface, implying a dominant influence of near surface processes as indicated by carbon isotope ratios. Coarse grained, quartz-rich soils favoured the existence of high CO2 concentrations. Fine grained clayey soils preferentially favoured the existence of 222Rn but not CO2. Soil formations did not act as barriers preventing gas migrations in soils, either due to water content or due to mineralogical composition. No abundant leakage from the Montmiral reservoir can be highlighted by the measurements, even near the exploitation well. As good correlation between CO2 and 222Rn concentrations still exist, it is suggested that 222Rn migration is also CO2 dependent in non-leaking areas e diffusion dominated systems.

The measurement of gas concentrations and fluxes in the soil and atmosphere is a powerful tool for monitoring geological carbon capture and storage (CCS) sites because the analyses are made directly in the biosphere in which we live. These methods can be used to both find and accurately quantifying leaks, and are visible and tangible data for public and ecosystem safety. To be most reliable and accurate, however, the measurements must be interpreted in the context of natural variations in gas concentration and flux. Such baseline data vary both spatially and temporally due to natural processes, and a clear understanding of their values and distributions is critical for interpreting near-surface gas monitoring techniques. The best example is CO2 itself, as the production of this gas via soil respiration can create a wide range of concentrations and fluxes that must be separated from, and not confused with, CO2 that may leak towards the surface from a storage reservoir. The present article summarizes baseline studies performed by the authors at various sites having different climates and geological settings from both Europe and North America, with focus given to the range of values that can result from near surface processes and how different techniques or data processing approaches can be used to help distinguish a leakage signal from an anomalous, shallow biogenic signal.

The south east basin of France shelters deep CO₂ reservoirs often studied with the aim of better constraining geological CO₂ storage operations. Here we present new soil gas data, completing an existing dataset (CO₂, ²²²Rn, ⁴He), together with mineralogical and physical characterisations of soil columns, in an attempt to better understand the spatial distribution of gas concentrations in the soils and to rule on the sealed character of the CO₂ reservoir at present time. Anomalous gas concentrations were found but did not appear to be clearly related to geological structures that may drain deep gases up to the surface, implying a dominant influence of near surface processes as indicated by carbon isotope ratios. Coarse grained, quartz-rich soils favoured the existence of high CO₂ concentrations. Fine grained clayey soils preferentially favoured the existence of ²²²Rn but not CO₂. Soil formations did not act as barriers preventing gas migrations in soils, either due to water content or due to mineralogical composition. No abundant leakage from the Montmiral reservoir can be highlighted by the measurements, even near the exploitation well. As good correlation between CO₂ and ²²²Rn concentrations still exist, it is suggested that ²²²Rn migration is also CO₂ dependent in non-leaking areas--diffusion dominated systems.