84 results on '"Forero‐Saboya, Juan"'
Search Results
2. A Hydridoaluminate Additive Producing a Protective Coating on Ni‐Rich Cathode Materials in Lithium‐Ion Batteries.
- Author
-
Forero‐Saboya, Juan, Moiseev, Ivan A., Vlara, Marina‐Lamprini, Foix, Dominique, Deschamps, Michael, Abakumov, Artem M., Tarascon, Jean‐Marie, and Mariyappan, Sathiya
- Subjects
- *
ENERGY density , *PROTECTIVE coatings , *TRANSITION metals , *SURFACE impedance , *SURFACE reconstruction - Abstract
To enhance the energy density of Li‐ion batteries, high‐capacity and high‐voltage cathode materials are needed. Recently, Ni‐rich layered oxides have attracted attention as they can offer ≈200 mAh g−1 when cycled up to 4.3 V. However, cycling these materials in their full capacity range often leads to excessive reactivity with the electrolyte, resulting in particle cracking, transition metal dissolution, and oxygen loss. In this study, the use of lithium hydridoaluminates as electrolyte additives is explored for lithium‐ion batteries based on nickel‐rich cathode materials. Being mild reducing agents, these additives act as HF scavengers, avoiding transition metal dissolution from the cathode. Additionally, their oxidation results in the formation of an Al‐rich protective layer on the cathode, which dampens the surface reactivity, preventing surface reconstruction and impedance build‐up. This study further stresses the important role of the cathode‐electrolyte interface phenomena on the capacity degradation of Ni‐rich cathode materials and provides a novel avenue for controlling this reactivity, thus extending their cycling life. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
3. Towards dry and contaminant free Ca(BF4)2-based electrolytes for Ca plating
- Author
-
Forero-Saboya, Juan D., Lozinšek, Matic, and Ponrouch, Alexandre
- Published
- 2020
- Full Text
- View/download PDF
4. A novel calcium fluorinated alkoxyaluminate salt as a next step towards Ca metal anode rechargeable batteries
- Author
-
Slovenian Research Agency, European Commission, Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Forero Saboya, Juan [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Dominko, Robert [0000-0002-6673-4459], Bitenc, Jan [0000-0002-0109-8121], Pavčnik, Tjaša, Forero Saboya, Juan, Ponrouch, Alexandre, Robba, Ana, Dominko, Robert, Bitenc, Jan, Slovenian Research Agency, European Commission, Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Forero Saboya, Juan [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Dominko, Robert [0000-0002-6673-4459], Bitenc, Jan [0000-0002-0109-8121], Pavčnik, Tjaša, Forero Saboya, Juan, Ponrouch, Alexandre, Robba, Ana, Dominko, Robert, and Bitenc, Jan
- Abstract
Ca metal anode rechargeable batteries are seen as a sustainable high-energy density and high-voltage alternative to the current Li-ion battery technology due to the low redox potential of Ca metal and abundance of Ca. Electrolytes are key enablers on the path towards next-generation battery systems. Within this work, we synthesize a new calcium tetrakis(hexafluoroisopropyloxy) aluminate salt, Ca[Al(hfip)4]2, and benchmark it versus the state-of-the-art boron analogue Ca[B(hfip)4]2. The newly developed aluminate-based electrolyte exhibits improved performance in terms of conductivity, Ca plating/stripping efficiency, and oxidative stability as well as Ca battery cell performance. A marked improvement of 0.5 V higher oxidative stability can pave the path towards high-voltage Ca batteries. A critical issue of solvent quality during salt synthesis is identified as well as solvent decomposition at the Ca metal/electrolyte interface, which leads to passivation of the Ca metal anode. However, the new aluminate salt with preferable electrochemical properties over the existing boron analogue opens up a new area for future Ca battery research based on aluminium compounds.
- Published
- 2023
5. Aqua-tri-fluorido-boron-1,3-dioxolan-2-one (1/2)
- Author
-
European Research Council, European Commission, Slovenian Research Agency, Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Radan, Kristian [0000-0003-4554-3976], Forero Saboya, Juan [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Lozinšek, Matic [0000-0002-1864-4248], Radan, Kristian, Forero Saboya, Juan, Ponrouch, Alexandre, Lozinšek, Matic, European Research Council, European Commission, Slovenian Research Agency, Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Radan, Kristian [0000-0003-4554-3976], Forero Saboya, Juan [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Lozinšek, Matic [0000-0002-1864-4248], Radan, Kristian, Forero Saboya, Juan, Ponrouch, Alexandre, and Lozinšek, Matic
- Abstract
The crystal structure of the co-crystal of aqua-tri-fluorido-boron with two ethyl-ene carbonate (systematic name: 1,3-dioxolan-2-one) mol-ecules, BF3H2O·2OC(OCH2)2, was determined by low-temperature single-crystal X-ray diffraction. The co-crystal crystallizes in the ortho-rhom-bic space group P212121 with four formula units per unit cell. The asymmetric unit consists of an aqua-tri-fluorido-boron mol-ecule and two ethyl-ene carbonate mol-ecules, connected by O-H⋯O=C hydrogen bonds. This crystal structure is an inter-esting example of a superacidic BF3H2O species co-crystallized with an organic carbonate.
- Published
- 2023
6. Influence of Formation Temperature on Cycling Stability of Sodium-Ion Cells: A Case Study of Na3V2(PO4)2F3|HC Cells
- Author
-
Forero-Saboya, Juan, primary, Desai, Parth, additional, Healy Corominas, Roman, additional, Raymundo-Piñero, Encarnacion, additional, Canizarès, Aurélien, additional, Foix, Dominique, additional, Tarascon, Jean-Marie, additional, and Mariyappan, Sathiya, additional
- Published
- 2023
- Full Text
- View/download PDF
7. A Guanidium Salt as a Chaotropic Agent for Aqueous Battery Electrolytes
- Author
-
Brown, John, primary, Forero-Saboya, Juan, additional, Baptise, Benoît, additional, Karlsmo, Martin, additional, Rousse, Gwenaëlle, additional, and Grimaud, Alexis, additional
- Published
- 2023
- Full Text
- View/download PDF
8. Elucidation of the redox activity of Ca2MnO3.5 and CaV2O4 in calcium batteries using operando XRD: charge compensation mechanism and reversibility
- Author
-
European Commission, Ministerio de Ciencia, Innovación y Universidades (España), Recio Poo, Miguel [0000-0001-5297-3865], Rozier, Patrick [0000-0002-7879-4344], Forero Saboya, Juan D. [0000-0002-3403-6066], Fauth, François [0000-0001-9465-3106], Palacín, M. Rosa [0000-0001-7351-2005], Black, Ashley P., Frontera, Carlos, Torres, Arturo, Recio Poo, Miguel, Rozier, Patrick, Forero Saboya, Juan, Fauth, François, Urones Garrote, Esteban, Arroyo de Dompablo, M. Elena, Palacín, M. Rosa, European Commission, Ministerio de Ciencia, Innovación y Universidades (España), Recio Poo, Miguel [0000-0001-5297-3865], Rozier, Patrick [0000-0002-7879-4344], Forero Saboya, Juan D. [0000-0002-3403-6066], Fauth, François [0000-0001-9465-3106], Palacín, M. Rosa [0000-0001-7351-2005], Black, Ashley P., Frontera, Carlos, Torres, Arturo, Recio Poo, Miguel, Rozier, Patrick, Forero Saboya, Juan, Fauth, François, Urones Garrote, Esteban, Arroyo de Dompablo, M. Elena, and Palacín, M. Rosa
- Abstract
Ca2MnO3.5 and CaV2O4 were found to be potentially interesting as positive electrode materials for calcium metal-based high-energy density batteries with DFT-predicted average voltages of 3.7 V and 2.5 V and energy barriers for Ca migration of 1.1 eV and 0.6 eV, respectively. Both compounds were prepared by solid state reaction under reducing atmospheres. Optimum conditions to achieve Ca2MnO3.5 comprised the reduction of Ca2MnO4 under NH3 gas at 420⁰C with a flow rate of 1200 ml/min while CaV2O4 was achieved by reduction of CaV2O6 at 700 ⁰C under H2 flow. Electrochemical oxidation of Ca2MnO3.5 in lithium or calcium cells resulted in the formation of an orthorhombic phase with cell parameter (a= 5.2891(1), b= 10.551(2), c= 12.1422(1)). Operando synchrotron radiation diffraction experiments indicate that the charge compensation mechanism is not related to Ca2+ extraction but to intercalation of F− (originated from electrolyte salt decomposition) into the anion vacancy position, as confirmed by EELS and EDS. This process was found to be irreversible. In the case of CaV2O4, oxidation induces the electrochemical extraction of calcium with the formation of an orthorhombic phase (space group Pbnm) with cell parameters a = 10.72008(9) Å, b = 9.20213(2) Å and c = 2.89418(3) Å. The process was also investigated via operando synchrotron radiation diffraction, with the oxidized phase being found to reintercalate Ca2+ ions upon reduction, with the formation of a solid solution. Preliminary cycling tests reveals a decrease in the polarization after the first cycle and call for further investigation of this system.
- Published
- 2022
9. Interfaces and Interphases in Ca and Mg Batteries
- Author
-
European Commission, Agencia Estatal de Investigación (España), Ministerio de Ciencia, Innovación y Universidades (España), Forero Saboya, Juan [0000-0002-3403-6066], Johansson, Patrik [0000-0002-9907-117X], Palacín, M. Rosa [0000-0001-7351-2005], Ponrouch, Alexandre [0000-0002-8232-6324], Forero Saboya, Juan, Tchitchekova , Deyana S., Johansson, Patrik, Palacín, M. Rosa, Ponrouch, Alexandre, European Commission, Agencia Estatal de Investigación (España), Ministerio de Ciencia, Innovación y Universidades (España), Forero Saboya, Juan [0000-0002-3403-6066], Johansson, Patrik [0000-0002-9907-117X], Palacín, M. Rosa [0000-0001-7351-2005], Ponrouch, Alexandre [0000-0002-8232-6324], Forero Saboya, Juan, Tchitchekova , Deyana S., Johansson, Patrik, Palacín, M. Rosa, and Ponrouch, Alexandre
- Abstract
The development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the technological development of these batteries is the low efficiency of plating/stripping at the negative electrode, which relates to several factors that have not yet been looked at systematically; the nature/concentration of the electrolyte, which determines the mass transport of electro-active species (cation complexes) toward the electrode; the possible presence of passivation layers, which may hinder ionic transport and hence limit electrodeposition; and the mechanisms behind the charge transfer leading to nucleation/growth of the metal. Different electrolytes are investigated for Mg and Ca, with the presence/absence of chlorides in the formulation playing a crucial role in the cation desolvation. From a R&D point-of-view, proper characterization alongside modeling is crucial to understand the phenomena determining the mechanisms of the plating/stripping processes. The state-of-the-art is here presented together with a short perspective on the influence of the cation solvation also on the positive electrode and finally an attempt to define guidelines for future research in the field.
- Published
- 2022
10. Elucidation of the redox activity of Ca2MnO3. 5 and CaV2O4 in calcium batteries using operando XRD: charge compensation mechanism and reversibility
- Author
-
Black, Ashley, Frontera, Carlos, Torres, Arturo, Recio-Poo, Miguel, Rozier, Patrick, Forero-Saboya, juan, Faith, Francois, Urones-Garrote, Esteban, Arroyo De Dompablo, María Elena, Palacin, M. Rosa, Black, Ashley, Frontera, Carlos, Torres, Arturo, Recio-Poo, Miguel, Rozier, Patrick, Forero-Saboya, juan, Faith, Francois, Urones-Garrote, Esteban, Arroyo De Dompablo, María Elena, and Palacin, M. Rosa
- Abstract
Depto. de Química Inorgánica, Fac. de Ciencias Químicas, TRUE, pub
- Published
- 2023
11. Mastering the synergy between Na3V2(PO4)2F3 electrode and electrolyte: A must for Na-ion cells
- Author
-
Desai, Parth, primary, Forero-Saboya, Juan, additional, Meunier, Valentin, additional, Rousse, Gwenaëlle, additional, Deschamps, Michael, additional, Abakumov, Artem M., additional, Tarascon, Jean-Marie, additional, and Mariyappan, Sathiya, additional
- Published
- 2023
- Full Text
- View/download PDF
12. Mastering the synergy between Na 3 V 2 (PO 4 ) 2 F 3 electrode and electrolyte: A must for Na-ion cells
- Author
-
Desai, Parth, Forero-Saboya, Juan, Meunier, Valentin, Rousse, Gwenaëlle, Deschamps, Michael, Abakumov, Artem M., Tarascon, Jean-Marie, Mariyappan, Sathiya, Collège de France - Chaire Chimie du solide et énergie, Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Réseau sur le stockage électrochimique de l'énergie (RS2E), Université de Nantes (UN)-Aix Marseille Université (AMU)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Collège de France (CdF (institution))-Université de Picardie Jules Verne (UPJV)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université de Pau et des Pays de l'Adour (UPPA)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), and Université Grenoble Alpes (UGA)-Université Grenoble Alpes (UGA)
- Subjects
hard carbon poisoning ,high temperature cycling ,Renewable Energy, Sustainability and the Environment ,transition metal dissolution ,surface coating ,Energy Engineering and Power Technology ,[CHIM]Chemical Sciences ,General Materials Science ,Na-ion batteries transition metal dissolution hard carbon poisoning surface coating high temperature cycling ,Na-ion batteries - Abstract
International audience; Sodium-ion batteries are emerging as suitable energy storage devices for special applications such as high-power devices with the advantages of being cheaper and more sustainable than the Li-ion equivalents. The sodium ion cells consisting of polyanionic Na 3 V 2 (PO 4) 2 F 3-hard carbon electrodes exhibit high power rate capabilities but limited cycle life, especially at high temperatures. To circumvent this drawback we herein conducted in-depth analyses of the origins of structural degradations occurring in Na 3 V 2 (PO 4) 2 F 3 electrodes upon long cycling. Vanadium dissolution with associated parasitic reactions is identified as one of the major reasons for cell failure. Its amount varies depending on the electrolyte, with NaTFSI-based electrolyte showing the least vanadium dissolution as the TFSI-anion decomposes without producing acidic impurities, in contrast to the Na-PF 6-based electrolyte. The dissolved vanadium species undergoes oxidation and reduction processes at the Na 3 V 2 (PO 4) 2 F 3 and HC electrodes, respectively, with the electrochemical signature of these processes being used as a fingerprint to identify state of health of the 18650 cells. Having found that surface reactivity is the primary cause of vanadium dissolution we provide methods to mitigate it by combining surface coating and optimized electrolyte formulation.
- Published
- 2023
- Full Text
- View/download PDF
13. Aquatrifluoridoboron–1,3-dioxolan-2-one (1/2)
- Author
-
Radan, Kristian, primary, Forero-Saboya, Juan, additional, Ponrouch, Alexandre, additional, and Lozinšek, Matic, additional
- Published
- 2023
- Full Text
- View/download PDF
14. A novel calcium fluorinated alkoxyaluminate salt as a next step towards Ca metal anode rechargeable batteries
- Author
-
Pavčnik, Tjaša, primary, Forero-Saboya, Juan D., additional, Ponrouch, Alexandre, additional, Robba, Ana, additional, Dominko, Robert, additional, and Bitenc, Jan, additional
- Published
- 2023
- Full Text
- View/download PDF
15. A guanidium salt as a chaotropic agent for aqueous battery electrolytes.
- Author
-
Brown, John, Forero-Saboya, Juan, Baptiste, Benoît, Karlsmo, Martin, Rousse, Gwenaëlle, and Grimaud, Alexis
- Subjects
- *
AQUEOUS electrolytes , *SALT crystals , *SALT , *INFRARED spectroscopy , *HYDROGEN bonding - Abstract
This study investigates a salt design principle for aqueous battery electrolytes by combining chaotropic ions, guanidium cations (Gdm) and bis(trifluoromethanesulfonyl)imide anions (TFSI), forming GdmTFSI. This salt's crystal structure was solved via single-crystal X-ray diffraction and characterized using Fourier-transform infrared spectroscopy. Study reveals that GdmTFSI salt disrupts the hydrogen bonding network of aqueous solutions, impacting water reactivity at electrochemical interfaces. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
16. Mastering the synergy between Na3V2(PO4)2F3 electrode and electrolyte: A must for Na-ion cells
- Author
-
Mariyappan, Sathiya, primary, Desai, Parth, additional, Forero-Saboya, Juan, additional, Meunier, Valentin, additional, Rousse, Gwenaëlle, additional, Deschamps, Michael, additional, Abakumov, Artem, additional, and Tarascon, Jean-Marie, additional
- Published
- 2022
- Full Text
- View/download PDF
17. Boron‐Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Battery
- Author
-
Bodin, Charlotte, primary, Forero Saboya, Juan, additional, Jankowski, Piotr, additional, Radan, Kristian, additional, Foix, Dominique, additional, Courrèges, Cécile, additional, Yousef, Ibraheem, additional, Dedryvère, Rémi, additional, Davoisne, Carine, additional, Lozinšek, Matic, additional, and Ponrouch, Alexandre, additional
- Published
- 2022
- Full Text
- View/download PDF
18. Boron-Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Battery
- Author
-
European Commission, European Research Council, Ministerio de Ciencia, Innovación y Universidades (España), Agence Nationale de la Recherche (France), Slovenian Research Agency, Alistore, Wroclaw Centre for Networking and Supercomputing, Jankowski, Piotr [0000-0003-0178-8955], Ponrouch, Alexandre [0000-0002-8232-6324], Bodin, Charlotte, Forero Saboya, Juan, Jankowski, Piotr, Radan, Kristian, Foix, Dominique, Courrèges, Cécile, Yousef, Ibraheem, Dedryvère, Rémi, Davoisne, Carine, Lozinšek, Matic, Ponrouch, Alexandre, European Commission, European Research Council, Ministerio de Ciencia, Innovación y Universidades (España), Agence Nationale de la Recherche (France), Slovenian Research Agency, Alistore, Wroclaw Centre for Networking and Supercomputing, Jankowski, Piotr [0000-0003-0178-8955], Ponrouch, Alexandre [0000-0002-8232-6324], Bodin, Charlotte, Forero Saboya, Juan, Jankowski, Piotr, Radan, Kristian, Foix, Dominique, Courrèges, Cécile, Yousef, Ibraheem, Dedryvère, Rémi, Davoisne, Carine, Lozinšek, Matic, and Ponrouch, Alexandre
- Abstract
Calcium-metal batteries have received growing attention recently after several studies reporting successful metal plating and stripping with organic electrolytes. Given the low redox potential of metallic calcium, its surface is commonly covered by a passivation layer grown by the accumulation of electrolyte decomposition products. The presence of borate species in this layer has been shown to be a key parameter allowing for Ca2+ migration and favoring Ca electrodeposition. Here, boron-based additives are evaluated in order to tune the SEI composition, morphology, and properties. The decomposition of a BF3-based additive is studied at different potentiostatic steps and the resulting SEI layer was thoroughly characterized. SEI growth mechanism is proposed based on both experimental data and DFT calculations pointing at the formation of boron-crosslinked polymeric matrices. Several boron-based adducts are explored as SEI-forming additives for calcium-metal batteries paving the way to very rich chemistry leading to Ca2+ conducting SEI.
- Published
- 2022
19. Elucidation of the redox activity of Ca2MnO3.5 and CaV2O4 in calcium batteries using operando XRD: charge compensation mechanism and reversibility
- Author
-
Black, Ashley P., primary, Frontera, Carlos, additional, Torres, Arturo, additional, Recio-Poo, Miguel, additional, Rozier, Patrick, additional, Forero-Saboya, Juan D., additional, Fauth, François, additional, Urones-Garrote, Esteban, additional, Arroyo-de Dompablo, M. Elena, additional, and Palacín, M. Rosa, additional
- Published
- 2022
- Full Text
- View/download PDF
20. Interfaces and Interphases in Ca and Mg Batteries
- Author
-
Forero‐Saboya, Juan D., primary, Tchitchekova, Deyana S., additional, Johansson, Patrik, additional, Palacín, M. Rosa, additional, and Ponrouch, Alexandre, additional
- Published
- 2021
- Full Text
- View/download PDF
21. A boron-based electrolyte additive for calcium electrodeposition
- Author
-
Forero-Saboya, Juan, Bodin, Charlotte, and Ponrouch, Alexandre
- Published
- 2021
- Full Text
- View/download PDF
22. Boron‐Based Functional Additives Enable Solid Electrolyte Interphase Engineering in Calcium Metal Battery.
- Author
-
Bodin, Charlotte, Forero Saboya, Juan, Jankowski, Piotr, Radan, Kristian, Foix, Dominique, Courrèges, Cécile, Yousef, Ibraheem, Dedryvère, Rémi, Davoisne, Carine, Lozinšek, Matic, and Ponrouch, Alexandre
- Subjects
SOLID electrolytes ,CALCIUM ,METALS ,REDUCTION potential ,ADDITIVES ,ELECTROPLATING - Abstract
Calcium‐metal batteries have received growing attention recently after several studies reporting successful metal plating and stripping with organic electrolytes. Given the low redox potential of metallic calcium, its surface is commonly covered by a passivation layer grown by the accumulation of electrolyte decomposition products. The presence of borate species in this layer has been shown to be a key parameter allowing for Ca2+ migration and favoring Ca electrodeposition. Here, boron‐based additives are evaluated in order to tune the SEI composition, morphology, and properties. The decomposition of a BF3‐based additive is studied at different potentiostatic steps and the resulting SEI layer was thoroughly characterized. SEI growth mechanism is proposed based on both experimental data and DFT calculations pointing at the formation of boron‐crosslinked polymeric matrices. Several boron‐based adducts are explored as SEI‐forming additives for calcium‐metal batteries paving the way to very rich chemistry leading to Ca2+ conducting SEI. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
23. Cation Solvation and Physico-Chemical Properties of Ca Battery Electrolytes
- Author
-
European Research Council, Ministerio de Economía, Industria y Competitividad (España), Swedish Energy Agency, Consejo Superior de Investigaciones Científicas (España), Ponrouch, Alexandre [0000-0002-8232-6324], Forero-Saboya, Juan [0000-0002-3403-6066], Johansson, Patrick [0000-0002-9907-117X], Forero Saboya, Juan, Marchante, Elena, Neves de Araújo, Rafael Barros, Monti, Damien, Johansson, Patrik, Ponrouch, Alexandre, European Research Council, Ministerio de Economía, Industria y Competitividad (España), Swedish Energy Agency, Consejo Superior de Investigaciones Científicas (España), Ponrouch, Alexandre [0000-0002-8232-6324], Forero-Saboya, Juan [0000-0002-3403-6066], Johansson, Patrick [0000-0002-9907-117X], Forero Saboya, Juan, Marchante, Elena, Neves de Araújo, Rafael Barros, Monti, Damien, Johansson, Patrik, and Ponrouch, Alexandre
- Abstract
Divalent cation based batteries are being considered as potential high energy density storage devices. The optimization of electrolytes for these technologies is, however, still largely lacking. Recent demonstration of the feasibility of Ca and Mg plating and stripping in the presence of a passivation layer or an artificial interphase has paved the way for more diverse electrolyte formulations. Here we exhaustively evaluate several Ca based electrolytes with different salts, solvents and concentrations, via measuring physico-chemical properties and using vibrational spectroscopy. Some comparisons with Mg and Li based electrolytes are made in order to highlight the unique properties of the Ca2+ cation. The Ca-salt solubility is found to be a major issue, calling for development of new highly dissociative salts. Nonetheless, reasonable salt solubility and dissociation was achieved using TFSI, BF4 and triflate anion based electrolytes and high permittivity solvents such as EC, PC, gBL and DMF. The local Ca2+ coordination is concentration dependent and rather complex, possibly involving bidentate coordination and participation of the nitrogen atom of DMF. The ionicity and the degree of ion-pair formation were both investigated and found to be strongly dependent on the nature of the cation, solvent donicity and salt concentration. The large ion-ion interaction energies of the contact ion-pairs, confirmed by DFT calculations, are expected to play a major role in the interfacial processes, and thus we here provide electrolyte design strategies to engineer the cation solvation and possibly improve the power performance of divalent battery systems.
- Published
- 2019
24. Methods and Protocols for reliable electrochemical testing in post Li batteries (Na, K, Mg and Ca)
- Author
-
European Research Council, Ministerio de Economía, Industria y Competitividad (España), Generalitat de Catalunya, Consejo Superior de Investigaciones Científicas (España), Forero-Saboya, Juan D. [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Dugas, Romain, Forero Saboya, Juan, Ponrouch, Alexandre, European Research Council, Ministerio de Economía, Industria y Competitividad (España), Generalitat de Catalunya, Consejo Superior de Investigaciones Científicas (España), Forero-Saboya, Juan D. [0000-0002-3403-6066], Ponrouch, Alexandre [0000-0002-8232-6324], Dugas, Romain, Forero Saboya, Juan, and Ponrouch, Alexandre
- Abstract
While less mature than Li-ion battery, technologies based on Na, K, Mg and Ca are attracting more and more attention from the battery community. New material (cathode, anode or electrolyte) testing for these post Li systems commonly involves the use of an electrochemical setup called half-cell in which metal counter and reference electrodes are used. Here we firstly describe the different issues that become critical when moving away from Li with respect to the cell hardware (cell design, current collector, separator, insulator) and the nature of counter and reference electrodes. Workarounds are given and a versatile setup is proposed to run reliable electrochemical tests for post Li battery materials in general, in a broad range of electrolyte compositions.
- Published
- 2019
25. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, primary, Armstrong, A Robert, additional, Alptekin, Hande, additional, Amores, Marco A, additional, Au, Heather, additional, Barker, Jerry, additional, Boston, Rebecca, additional, Brant, William R, additional, Brittain, Jake M, additional, Chen, Yue, additional, Chhowalla, Manish, additional, Choi, Yong-Seok, additional, Costa, Sara I R, additional, Crespo Ribadeneyra, Maria, additional, Cussen, Serena A, additional, Cussen, Edmund J, additional, David, William I F, additional, Desai, Aamod V, additional, Dickson, Stewart A M, additional, Eweka, Emmanuel I, additional, Forero-Saboya, Juan D, additional, Grey, Clare P, additional, Griffin, John M, additional, Gross, Peter, additional, Hua, Xiao, additional, Irvine, John T S, additional, Johansson, Patrik, additional, Jones, Martin O, additional, Karlsmo, Martin, additional, Kendrick, Emma, additional, Kim, Eunjeong, additional, Kolosov, Oleg V, additional, Li, Zhuangnan, additional, Mertens, Stijn F L, additional, Mogensen, Ronnie, additional, Monconduit, Laure, additional, Morris, Russell E, additional, Naylor, Andrew J, additional, Nikman, Shahin, additional, O’Keefe, Christopher A, additional, Ould, Darren M C, additional, Palgrave, R G, additional, Poizot, Philippe, additional, Ponrouch, Alexandre, additional, Renault, Stéven, additional, Reynolds, Emily M, additional, Rudola, Ashish, additional, Sayers, Ruth, additional, Scanlon, David O, additional, Sen, S, additional, Seymour, Valerie R, additional, Silván, Begoña, additional, Sougrati, Moulay Tahar, additional, Stievano, Lorenzo, additional, Stone, Grant S, additional, Thomas, Chris I, additional, Titirici, Maria-Magdalena, additional, Tong, Jincheng, additional, Wood, Thomas J, additional, Wright, Dominic S, additional, and Younesi, Reza, additional
- Published
- 2021
- Full Text
- View/download PDF
26. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A. Robert, Alptekin, Hande, Amores, Marco A., Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R., Brittain, Jake M., Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I. R., Crespo Ribadeneyra, Maria, Cussen, Serena A., Cussen, Edmund J., David, William I. F., Desai, Aamod, V, Dickson, Stewart A. M., Eweka, Emmanuel, I, Forero-Saboya, Juan D., Grey, Clare P., Griffin, John M., Gross, Peter, Hua, Xiao, Irvine, John T. S., Johansson, Patrik, Jones, Martin O., Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg, V, Li, Zhuangnan, Mertens, Stijn F. L., Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E., Naylor, Andrew J., Nikman, Shahin, O'Keefe, Christopher A., Ould, Darren M. C., Palgrave, R. G., Poizot, Philippe, Ponrouch, Alexandre, Renault, Steven, Reynolds, Emily M., Rudola, Ashish, Sayers, Ruth, Scanlon, David O., Sen, S., Seymour, Valerie R., Silvan, Begona, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S., Thomas, Chris, I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J., Wright, Dominic S., Younesi, Reza, Tapia-Ruiz, Nuria, Armstrong, A. Robert, Alptekin, Hande, Amores, Marco A., Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R., Brittain, Jake M., Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I. R., Crespo Ribadeneyra, Maria, Cussen, Serena A., Cussen, Edmund J., David, William I. F., Desai, Aamod, V, Dickson, Stewart A. M., Eweka, Emmanuel, I, Forero-Saboya, Juan D., Grey, Clare P., Griffin, John M., Gross, Peter, Hua, Xiao, Irvine, John T. S., Johansson, Patrik, Jones, Martin O., Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg, V, Li, Zhuangnan, Mertens, Stijn F. L., Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E., Naylor, Andrew J., Nikman, Shahin, O'Keefe, Christopher A., Ould, Darren M. C., Palgrave, R. G., Poizot, Philippe, Ponrouch, Alexandre, Renault, Steven, Reynolds, Emily M., Rudola, Ashish, Sayers, Ruth, Scanlon, David O., Sen, S., Seymour, Valerie R., Silvan, Begona, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S., Thomas, Chris, I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J., Wright, Dominic S., and Younesi, Reza
- Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid-electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
- Published
- 2021
- Full Text
- View/download PDF
27. A boron-based electrolyte additive for calcium electrodeposition
- Author
-
European Research Council, European Commission, Ministerio de Economía, Industria y Competitividad (España), Forero Saboya, Juan, Bodin, Charlotte, Ponrouch, Alexandre, European Research Council, European Commission, Ministerio de Economía, Industria y Competitividad (España), Forero Saboya, Juan, Bodin, Charlotte, and Ponrouch, Alexandre
- Abstract
In recent years, several organic electrolytes have been reported allowing calcium metal electrodeposition. In all cases, some degree of passivation on the surface of the calcium electrode was reported. Following a recent report on borate-based passivation layer playing a crucial role for Ca plating in electrolyte solutions containing Ca(BF4)2, here we report the use of a boron-containing additive. The presence of this additive allows Ca plating and stripping using a Ca(TFSI)2 containing electrolyte, which otherwise lead to the formation of a fully Ca2+ blocking passivation layer.
- Published
- 2021
28. 2021 roadmap for sodium-ion batteries
- Author
-
Alistore, European Commission, Swedish Research Council, Swedish Energy Agency, Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning, Ministerio de Economía, Industria y Competitividad (España), Faraday Institution, Austrian Science Fund, Innovate UK, Tapia Ruiz, Nuria, Forero Saboya, Juan, Ponrouch, Alexandre, Younesi, Reza, Alistore, European Commission, Swedish Research Council, Swedish Energy Agency, Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning, Ministerio de Economía, Industria y Competitividad (España), Faraday Institution, Austrian Science Fund, Innovate UK, Tapia Ruiz, Nuria, Forero Saboya, Juan, Ponrouch, Alexandre, and Younesi, Reza
- Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
- Published
- 2021
29. Solid Electrolyte Interphase for Ca Metal Batteries
- Author
-
Bodin, Charlotte, primary, Forero-Saboya, Juan, additional, Davoisne, Carine, additional, Dedryvere, Remi, additional, Yousef, Ibraheem, additional, and Ponrouch, Alexandre, additional
- Published
- 2021
- Full Text
- View/download PDF
30. On the Parameters Affecting Calcium Plating and Stripping from Organic Electrolytes – Cases of Electrolyte Optimization
- Author
-
Forero-Saboya, Juan, primary and Ponrouch, Alexandre, additional
- Published
- 2021
- Full Text
- View/download PDF
31. Towards Dry and Contaminant Free Ca(BF4)2 Based Electrolyte for Ca Metal Anode Based Batteries
- Author
-
Forero-Saboya, Juan, primary and Ponrouch, Alexandre, additional
- Published
- 2020
- Full Text
- View/download PDF
32. Electrolyte, Solvation Shell and Interphase for Ca and Mg Metal Anode Based Batteries
- Author
-
Forero-Saboya, Juan, primary and Ponrouch, Alexandre, additional
- Published
- 2020
- Full Text
- View/download PDF
33. Interfaces and Interphases in Ca and Mg Batteries.
- Author
-
Forero‐Saboya, Juan D., Tchitchekova, Deyana S., Johansson, Patrik, Palacín, M. Rosa, and Ponrouch, Alexandre
- Subjects
NEGATIVE electrode ,ENERGY density ,ENERGY development ,CHARGE transfer ,REDUCTION potential ,ELECTROPLATING ,PASSIVATION - Abstract
The development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the technological development of these batteries is the low efficiency of plating/stripping at the negative electrode, which relates to several factors that have not yet been looked at systematically; the nature/concentration of the electrolyte, which determines the mass transport of electro‐active species (cation complexes) toward the electrode; the possible presence of passivation layers, which may hinder ionic transport and hence limit electrodeposition; and the mechanisms behind the charge transfer leading to nucleation/growth of the metal. Different electrolytes are investigated for Mg and Ca, with the presence/absence of chlorides in the formulation playing a crucial role in the cation desolvation. From a R&D point‐of‐view, proper characterization alongside modeling is crucial to understand the phenomena determining the mechanisms of the plating/stripping processes. The state‐of‐the‐art is here presented together with a short perspective on the influence of the cation solvation also on the positive electrode and finally an attempt to define guidelines for future research in the field. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
34. Understanding the nature of the passivation layer enabling reversible calcium plating
- Author
-
European Research Council, European Commission, Ministerio de Economía, Industria y Competitividad (España), National Research Foundation Singapore, Forero Saboya, Juan, Davoisne, Carine, Dedryvère, Rémi, Yousef, Ibraheem, Canepa, Pieremanuele, Ponrouch, Alexandre, European Research Council, European Commission, Ministerio de Economía, Industria y Competitividad (España), National Research Foundation Singapore, Forero Saboya, Juan, Davoisne, Carine, Dedryvère, Rémi, Yousef, Ibraheem, Canepa, Pieremanuele, and Ponrouch, Alexandre
- Abstract
As for other multivalent systems, the interface between the calcium (Ca) metal anode and the electrolyte is of paramount importance for reversible plating/stripping. Here, we combined experimental and theoretical approaches to unveil the potential solid electrolyte interphase (SEI) components enabling facile Ca plating. Borates compounds, in the form of cross-linked polymers are suggested as divalent conducting component. A pre-passivation protocol with such SEI is demonstrated and allows to broaden the possibility for electrolyte formulation. We also demonstrated a 10-fold increase in Ca plating kinetics by tuning the cation solvation structure in the electrolyte limiting the degree of contact ion pair.
- Published
- 2020
35. Understanding the nature of the passivation layer enabling reversible calcium plating
- Author
-
Forero-Saboya, Juan, primary, Davoisne, Carine, additional, Dedryvère, Rémi, additional, Yousef, Ibraheem, additional, Canepa, Pieremanuele, additional, and Ponrouch, Alexandre, additional
- Published
- 2020
- Full Text
- View/download PDF
36. Methods and Protocols for Reliable Electrochemical Testing in Post-Li Batteries (Na, K, Mg, and Ca)
- Author
-
Dugas, Romain, primary, Forero-Saboya, Juan D., additional, and Ponrouch, Alexandre, additional
- Published
- 2019
- Full Text
- View/download PDF
37. Water-in-Bisalt Electrolyte with Record Salt Concentration and Widened Electrochemical Stability Window
- Author
-
Forero-Saboya, Juan, primary, Hosseini-Bab-Anari, Elham, additional, Abdelhamid, Muhammad E., additional, Moth-Poulsen, Kasper, additional, and Johansson, Patrik, additional
- Published
- 2019
- Full Text
- View/download PDF
38. Study of SEI Components Enabling Calcium Metal Plating and Stripping
- Author
-
Forero-Saboya, Juan, primary, Yousef, Ibraheem, additional, Davoisne, Carine, additional, Dedryvère, Rémi, additional, Canepa, Pieremanuele, additional, and Ponrouch, Alexandre, additional
- Published
- 2019
- Full Text
- View/download PDF
39. Water-in-Bisalt Electrolyte with Record Salt Concentration and Widened Electrochemical Stability Window
- Author
-
Forero Saboya, Juan, Hosseini-Bab-Anari, Elham, Abdelhamid, Muhammad E., Moth-Poulsen, Kasper, Johansson, Patrik, Forero Saboya, Juan, Hosseini-Bab-Anari, Elham, Abdelhamid, Muhammad E., Moth-Poulsen, Kasper, and Johansson, Patrik
- Published
- 2019
40. Solvent-free lithium and sodium containing electrolytes based on pseudo-delocalized anions
- Author
-
Forero-Saboya, Juan, primary, Hosseini-Bab-Anari, Elham, additional, Abdelhamid, Muhammad E., additional, Moth-Poulsen, Kasper, additional, and Johansson, Patrik, additional
- Published
- 2019
- Full Text
- View/download PDF
41. Sodium systems – Low temperature (LIB equivalent) | Sodium-ion conductive nonaqueous electrolytes
- Author
-
Forero-Saboya, Juan and Mariyappan, Sathiya
- Published
- 2013
- Full Text
- View/download PDF
42. Influence of Formation Temperature on Cycling Stability of Sodium-Ion Cells: A Case Study of Na3V2(PO4)2F3 | HC Cells.
- Author
-
Forero-Saboya, Juan, Desai, Parth, Raymundo-Piñero, Encarnacion, Canizares, Aurélien, Foix, Dominique, Mariyappan, Sathiya, and Tarascon, Jean-Marie
- Published
- 2023
- Full Text
- View/download PDF
43. Towards Dry and Contaminant Free Ca(BF4)2 Based Electrolyte for Ca Metal Anode Based Batteries.
- Author
-
Forero-Saboya, Juan and Ponrouch, Alexandre
- Published
- 2020
- Full Text
- View/download PDF
44. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
45. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
46. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
47. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
48. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
49. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
50. 2021 roadmap for sodium-ion batteries
- Author
-
Tapia-Ruiz, Nuria, Armstrong, A Robert, Alptekin, Hande, Amores, Marco A, Au, Heather, Barker, Jerry, Boston, Rebecca, Brant, William R, Brittain, Jake M, Chen, Yue, Chhowalla, Manish, Choi, Yong-Seok, Costa, Sara I R, Crespo Ribadeneyra, Maria, Cussen, Serena A, Cussen, Edmund J, David, William I F, Desai, Aamod V, Dickson, Stewart A M, Eweka, Emmanuel I, Forero-Saboya, Juan D, Grey, Clare P, Griffin, John M, Gross, Peter, Hua, Xiao, Irvine, John T S, Johansson, Patrik, Jones, Martin O, Karlsmo, Martin, Kendrick, Emma, Kim, Eunjeong, Kolosov, Oleg V, Li, Zhuangnan, Mertens, Stijn F L, Mogensen, Ronnie, Monconduit, Laure, Morris, Russell E, Naylor, Andrew J, Nikman, Shahin, O’Keefe, Christopher A, Ould, Darren M C, Palgrave, R G, Poizot, Philippe, Ponrouch, Alexandre, Renault, Stéven, Reynolds, Emily M, Rudola, Ashish, Sayers, Ruth, Scanlon, David O, Sen, S, Seymour, Valerie R, Silván, Begoña, Sougrati, Moulay Tahar, Stievano, Lorenzo, Stone, Grant S, Thomas, Chris I, Titirici, Maria-Magdalena, Tong, Jincheng, Wood, Thomas J, Wright, Dominic S, and Younesi, Reza
- Subjects
energy materials ,Roadmap ,batteries ,13. Climate action ,anodes ,sodium ion ,electrolytes ,7. Clean energy ,cathodes - Abstract
Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid–electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.