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High-fluoride dentifrice can be used to manage dental erosion; however, little is known about it effect on root dentine previously demineralized. This study evaluated the effect of high-fluoride treatment on dentin de/remineralization exposed to an erosion challenge in vitro.Sound and demineralized dentine blocks were submitted to a 5-days-erosive challenge in soft drink (4/day during 90 s) and treated with fluoride solutions (0, 1,100, or 5,000 µg F/mL). After this, the percentage of surface hardness loss (%SHL) or recovery (%SHR) was calculated. Data were analyzed by one-way ANOVA and Tukey post hoc test with p fixed at 5%.High-fluoride treatment was able to reduce dentine remineralization and increase mineral recovery of previously demineralized dentine compared to other treatments tested (High-fluoride treatment was able to increase the remineralization and reduce the demineralization of root dentine submitted to an erosive challenge in vitro, being an option for the erosion prevention/treatment.

Este trabalho tem como primeiro objetivo enquadrar o setor da publicidade exterior em Portugal na atualidade, nomeadamente rever os problemas do setor no presente. No âmbito da análise do meio outdoor na atualidade, apresenta-se uma lista dos novos meios que estão a ser introduzidos no setor, como consequência da introdução da inovação e do investimento dos operadores da Publicidade Exterior em Portugal.

Workshop: An opportunity for international cooperation on atmospheric sciences, Lisboa, 2015 (Comunicação). N/A

Workshop: An opportunity for international cooperation on atmospheric sciences, Lisboa, 2015 (Comunicação). Aerosols are an important constituent of the atmospheric boundary layer. Aerosol particles provide surfaces for heterogeneous chemical processes, they also act as a condensation sink for atmospheric trace species. In the marineatmosphere originate from a variety of production and transformation processes that includes sea spray aerosol produced at the sea surface through the interactions between wind and surface waves (Liss and Johnson, 2013). N/A

European Geosciences Union (EGU), General Assembly. Viena, Austria, 07 - 12 April 2013. Here, we present an overview of gas and aerosol data measured at the Pico Mountain Station. The primary objective of these measurements are to enhance our knowledge of anthropogenic and biomass burning emissions from North America and their relative impact on atmospheric composition and radiative forcing in the free troposphere of the North Atlantic.

European Geosciences Union (EGU), General Assembly. Viena, Austria, 07 - 12 April 2013. Non-methane hydrocarbons (NMHC) covering the C2 to C7 volatility range have been monitored at the Pico Mountain Observatory, Pico Island, Azores, Portugal, since 2004. The Observatory is located at 2225 m a.s.l. in the caldera of the Pico Mountain volcano, and during most times receives lower free tropospheric air that has been transported across the North Atlantic. The 7-year NMHC record has been analyzed for seasonal behavior of photochemical processing, atmospheric transport time, and source region using ratios of NMHC species as indicators of photochemical aging and HYSPLIT model outputs. Transport conditions resulting in elevated and low NMHC conditions were specifically studied to investigate seasonal pollution transport in the North Atlantic region.

4th Atmospheric System Research (ASR), Science Team Meeting. Potomac, Maryland, March 18-21, 2013. The Pico Mountain Observatory is located at an altitude of 2225 meters above sea level in the summit caldera of the Pico volcano in the Azores, Portugal (38.47°N, 28.40°W). The scientific value of the station stems from the fact that this is the only permanent free-tropospheric monitoring station in the central North Atlantic, with negligible influence from local sources and that frequently samples air from the North American continent. Thus, it is an ideal site for studying long-range transported pollution. The station started operating in 2001 with a focus on gaseous species (e.g., ozone, carbon monoxide, nitrogen oxides, and non-methane hydrocarbons) and aerosol particles that absorb light (black carbon [BC] and aerosol dust). The absorbing aerosol mass concentrations, in units of equivalent black carbon mass concentrations, have been monitored using a seven-wavelength aethalometer (Magee scientific model AE31). Ancillary measurements at the station include meteorological parameters such as temperature, relative humidity, pressure, wind direction, and speed. Due to the harsh environmental conditions at the site, most measurements have been performed during the summer seasons. In the summer of 2012, new aerosol instrumentation and samplers were installed at the station. The new equipment includes a three-wavelength nephelometer (Ecotech model Aurora 3000) that measure aerosol scattering and backscattering fraction, a set of four high-volume samplers for the collection and chemical analysis of aerosol, a sequential sampler to collect aerosols on membranes and grids, and an optical particle counter. Membranes and grids are analysed offline with scanning and transmission electron microscopy to study morphological properties and elemental composition of the aged aerosols. In this poster we will discuss some of the analysis of the decadal BC mass concentration data, as well as some analysis of the new aerosol data with a focus on aerosol optical properties and morphology. Analysis of these properties is important for a better understanding of aerosol’s life cycle and ageing during their transport over the Atlantic, with implications on aerosol radiative properties and climate science.

45th annual Fall Meeting, AGU. San Francisco, California, 3-7 December. The Pico Mountain Observatory is located in the summit caldera of the Pico mountain, an inactive volcano on the Pico Island in the Azores, Portugal (38.47°N, 28.40°W, Altitude 2225m asl). The Azores are often impacted by polluted outflows from the North American continent and local sources have been shown to have a negligible influence at the observatory. The value of the station stems from the fact that this is the only permanent mountaintop monitoring station in the North Atlantic that is typically located above the marine boundary layer (average MBL heights are below 1200 m and rarely exceed 1300 m) and often receives air characteristic of the lower free troposphere. Measurements of black carbon (BC) mass have been carried out at the station since 2001, mostly in the summer seasons. Here we discuss the BC decadal dataset (2001-2011) collected at the site by using a seven-wavelength AE31 Magee Aethalometer. Measured BC mass and computed Angstrom exponent (AE) values were analysed to study seasonal and diurnal variations. There was a large day-to-day variability in the BC values due to varied meteorological conditions that resulted in different diurnal patterns for different months. The daily mean BC at this location ranged between 0 and ~430 ngm-3, with the most frequently occurring value in the range 0-100 ngm-3. The overall mean for the 10 year period is ~24 ngm-3, with a coefficient of variation of 150%. The BC values exhibited a consistent annual trend being low in winter months and high in summer months, barring year to year variations. To differentiate between BC and other absorbing particles, we analyzed the wavelength dependence of aerosol absorption coefficient and determined a best-fit exponent i.e., the Ångström exponent, for the whole dataset. Visible Ångström exponent (AE: 470-520-590-660 nm) values ranged between 0 and 3.5, with most frequently occurring values in the range 0.85 to 1.25. By making use of the aethalometer light attenuation measurements at different wavelengths and Hysplit back trajectories, we divided the data into two categories. One for periods characterized by AE values close to 1; these periods are typically correlated with back trajectories originating from Canada, North America or northern Europe, indicating the dominance of BC on the light attenuation. Another characterized by AE values substantially different from 1; these periods correlated with back trajectories originating from dust-prone regions (e.g., the Sahara desert).The above measurements, with the aid of ancillary satellite and ground-based measurements will be employed in estimating the radiaitve effects of BC in the North Atlantic.

AAAR 31st Annual Conference. Minneapolis, Minnesota, October 8-12, 2012. In this poster we discuss a limited subset of the aerosol measurements performed at the Pico Mountain Observatory. The Black Carbon (BC) mass shows a clear seasonal pattern over a ten-years period. The 2012 scattering measurements show highly variable signals with events with high scattering and periods of very low aerosol loading. Dust events are clearly captured by the aethalometer, as well the nephelometer Ångström exponents. Particles have various shapes, and mixing states, and soot particles typically are very compacted.

AAAR 31st Annual Conference. Minneapolis, Minnesota, October 8-12, 2012. The Pico Mountain Observatory is located at 2225 m amsl on an inactive volcano at Pico Island in the Azores archipelago in the North Atlantic ~3900 km east and downwind of North America (38º28'15''N; 28º24’'14''W). The unique location of the Observatory enables sampling of free tropospheric air transported over long, intercontinental distances and is rarely affected by local emissions. The Observatory is affected mainly by North American outflow after its trans-Atlantic transport. Therefore, its location is ideal for observations of long-range transported pollutants emitted from anthropogenic and biogenic continental sources. The composition of continental pollution outflow is altered during transport by mixing, chemical reactions, phase changes, and removal processes. Thus, the properties of aerosol and trace gases in downwind regions are impacted by the outflow of pollutants, their chemical transformation, and sinks. In previous work, the sampled air-mass measurements (including CO, O3, NOx, NOy, NMHC, black carbon and aerosol optical size) and the simulations of their dispersion indicated outflow of North American tropospheric ozone and its precursors. Although the measurements have been crucial in explaining the evolution of North American gaseous pollution, little is known regarding the nature of the aged aerosol. New work is currently underway at the Observatory to provide chemical characterization of the intercepted free tropospheric aerosols. Here, we show the preliminary results of the free tropospheric aerosol composition and its physical properties. Samples were collected using high-volume filter samplers with quartz filters and analyzed for organic and elemental carbon (OC and EC, respectively). We compare the observed OC and EC values to the collocated measurements of gas- and particle-phase species, meteorological parameters and to the values found in current literature. We highlight the future work in which we will select filter samples based on the arrival of highly polluted air masses from anthropological or biomass burning emissions for further detailed analysis.

III Encontro Nacional de História das Ciências e da Tecnologia. O Centro de Estudos de História e Filosofia da Ciência, organiza o 3.º Encontro Nacional de História da Ciência e da Técnica, sob o tema «Ciência, Crise e Mudança» que tem lugar na Universidade de Évora, nos dias 26, 27 e 28 de Setembro de 2012. O Primeiro Encontro Nacional de História da Ciência teve lugar em 21 e 22 Julho de 2009, no seguimento do programa de estímulo ao de¬senvolvimento da História da Ciência em Portugal e de valorização do património cultural e científico do País, lançado pelo Ministério da Ciência, Tecnologia e Ensino Superior (MCTES) em 31 de Janeiro desse ano. A sua organização coube a investigadores do Instituto de História Contemporânea (IHC), da FCSH da UNL, e do Centro Científico e Cultural de Macau (CCCM), em cujas instalações se realizou. De en¬tre as conclusões do Encontro, destacou-se a de realizar periodicamen¬te novos Encontros Nacionais, a serem organizados de forma rotativa por diferentes centros e núcleos de investigadores. Na sequência deste Primeiro Encontro, o Centro Interuniversitário de História das Ciências e da Tecnologia (CIUHCT) organizou, entre 26 e 28 de Julho de 2010, o II Encontro, dedicado ao tema “Comunicação das Ciências e da Tecnologia em Portugal: Agentes, Meios e Audiências”. Cabe agora ao CEHFCi cumprir o que foi decidido no final deste Encontro. Na situação económica e política que hoje vivemos torna-se particularmente urgente aprofundar o estudo e o debate sobre a interação entre a Sociedade, a Ciência e a sua História. Coordenação Científica e Executiva do encontro estiveram a cargo de dois investigadores CEHFCi: Maria de Fátima Nunes, José Pedro Sousa Dias

European Aerosol Conference. Granada, Spain, 2-7 September 2012. > huge amounts of mineral dust are emitted every year from the Sahara desert to the atmosphere; > optical parameters of mineral aerosols determine the direct interaction of solar and terrestrial radiation in the atmosphere through scattering and absorption; > mineral dust has a great impact on cloud formation leading to additional indirect radiation effects; > The dense haze from dust events is also known to affect visibility.

International Congresso on Environmental Health (ICEH 2012). Lisboa, 29 Maio – 1 Junho.

3th Atmospheric Science Research (ASR), Science Team Meeting. Arlington, Virginia, March 12-16, 2012. Pico is a small island (447 km2) in the archipelago of the Azores, Portugal, in the North Atlantic Ocean. The island has a very steep inactive volcano. An atmospheric monitoring station (Pico Mountain Observatory) was established close to the summit of the volcano by the late Dr. Richard Honrath and colleagues in 2001. The station, far from persistent local sources, is located near the northern cliff of the summit caldera at an altitude of 2225 meters. The station altitude is typically well above the boundary layer during summertime, when average marine boundary-layer heights are below 1200 meters and rarely exceed 1300 meters. Air masses reaching the station are often transported from North America and seldom from Europe or North Africa. The station’s uniqueness and significance lie in its location that allows study of the transport and evolution of gases and aerosols from North America in the free troposphere. Until recently, the focus was on the measurement and analysis of trace gases (ozone, carbon monoxide, non-methane hydrocarbons, nitrogen oxides) and light-absorbing aerosol (black carbon and iron oxide). Aerosol light attenuation has been measured at the site since 2001 using a seven-wavelengths aethalometer. An optical particle sizer was installed at the site in 2010 and has been running in parallel to the aethalometer for two seasons. A three-wavelength nephelometer, to measure the aerosol total- and back-scattering, and aerosol samplers for morphological and chemical analysis will be installed at the site in 2012. Our goal is to enhance the observatory monitoring capabilities for aerosol research. The objectives of this new research program are to: (a) assess background as well as specific event tropospheric aerosol properties, (b) compare aerosol and gases measurements with model outputs, and (c) use the data collected to provide satellite validation. This research is anticipated to enhance our understanding of the interactions between tropospheric aerosols, clouds, and climate by allowing, for example, the analysis of North American outflows and seasonal changes, the assessment of different source regions, the estimation of aerosol radiative forcing above marine clouds and in clear sky, and the study of the relative contribution of anthropogenic versus biomass burning emissions. In this poster we present a preliminary analysis of the black carbon and aerosol size data in conjunction with retroplume model analysis.

8th International Aerosol Conference. Helsinki, Finland, August 29-September 3, 2010. Aerosol light absorption is an important parameter for the assessment of the radiation budget of the atmosphere. Filter based absorption photometers, e.g. the Aethalometer and the Particle Soot Absorption Photometer (PSAP) have been available for several years. Multiple scattering of light in the filter medium and the presence of scattering particles result in a measured attenuation coefficient, which is different from the absorption coefficient of airborne particles. Correction schemes have to be determined experimentally using reference methods (e.g. photoacoustic photometers or extinction minus scattering). Often used correction schemes are described in Bond et al. (1999) and Virkkula et al. (2005) for PSAP and in Weingaartner et al. (2003) for Aethalometer. In the frameworks of EUSAAR a workshop for testing existing and developing new correction schemes has been conducted in 2009 at the Leibniz Institute for Tropospheric Research in Leipzig.

International Aerosol Conference 2010. Helsinki, Finland, August 29-September 3. Develop methodologies to compensate for apparent absorption caused by scattering dueto the use of filter matrix support.

Green Islands Open Session, Ponta Delgada, Spring 2010.

Symposium on Atmospheric Chemistry and Physics at Mountain Sites. Interlaken, Switzerland, 8-10 June 2010. Aerosol samples were collected using an aethalometer (AE31) from 15 July 2001 to the present at the Pico Mountain site in Pico island, Azores, Portugal (38.470ºN; 28.404ºW and 2225 m above mean see level). The aethalometer was setup to integrate the aerosol samples for 24 h period for most of the cases, with the exception of the period between July 2002 and July 2003 were it was leaved to change the integration sample spot only after 75% attenuation level. [...].

10th BSRN Science and Review Workshop. De Bilt, The Netherlands, 7-11 July 2008. A preliminary analysis of AOD results from sun-photometer measurements collected at Jose Agostinho Observatory at Angra do Heroísmo (Terceira Island, the Azores) was presented. The observational period ranges from August 2004 to December 2007, using a SP02 sun-photometer at wavelengths 412, 500, 675, and 862 nm, coupled to a 2AXP sun-tracker. The sampling interval is 5 s and data is filtered for cloud contamination in a time window of 10 minutes. Most AOD 500 nm values are below 0.3, showing a small variation during the day; frequency distribution shows a typical right skew distribution. Alpha and beta Angstrom coefficients were also computed and analyzed in the same way. Alpha values are generally positive and lower than 4, while beta values are below 1.5. AOD results from the AERONET station at Horta Observatory (Faial Island, the Azores) were also used and compared with Angra data. AOD and Angstrom coefficients were also analyzed with wind results from the automatic weather station located at both observatories. Results show different wind distributions due to different exposures; however, systematic higher AOD values are found at Horta. The proximity of the two sites indicates that these differences are more likely due to different instruments and processing methods used.

MCM9 UV Conference. Davos, Switzerland, 17-20 September 2007. The UV Index (UVI) is a public-oriented meteorological kind of information about the damaging ultraviolet radiation at the ground (Vaniceck et al., 1999). Its use begins to be so popular as temperatures highs, wind chill, fire risk index, air quality index and other meteorological indexes and parameters. A UVI scale was already defined by WHO (WHO, 2002) in order to provide a correspondence between UVI levels and protective measures to avoid damaging effects on humans. However, UVI is usually given in integer units, so the required precision for the public must be less or equal than 0.5 UVI units. While UV dependence on ozone is well understood and easily to model, clouds dependence is more difficult do model and its effect on daily variability is also important. In addition, atmospheric UV measurements are more expensive than global radiation measurements and therefore fewer. However, global radiation is much less dependent on ozone and its variability depends basically on clouds. Therefore, global radiation measurements can be used to correct a simple radioactive transfer model for clear sky conditions with respect to the actual cloudiness. The scope of this work is to find an approach to derive UVI from actual global radiation and ozone measurements with acceptable error for public awareness.