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Metal halide perovskites exhibit a fairly linear increase of the bandgap with increasing temperature, when crystallized in a tetragonal or cubic phase. In general, both thermal expansion and electron-phonon interaction effects contribute equally to this variation of the gap with temperature. Herein, we have disentangled both contributions in the case of colloidal CsPbBr$_3$ nanocrystals (NCs) by means of photoluminescence (PL) measurements as a function of temperature (from 80 K to ambient) and hydrostatic pressure (from atmospheric to ca. 1 GPa). At around room temperature, CsPbBr$_3$ NCs also show a linear increase of the bandgap with temperature with a slope similar to that of the archetypal methylammonium lead iodide (MAPbI$_3$) perovskite. This is somehow unexpected in view of the recent observations in mixed-cation Cs$_x$MA$_{1-x}$PbI$_3$ single crystals with low Cs content, for which Cs incorporation caused a reduction by a factor of two in the temperature slope of the gap. This effect was ascribed to an anomalous electron-phonon interaction induced by the coupling with vibrational modes admixed with the Cs translational dynamics inside the cage voids. Thus, no trace of anomalous coupling is found in CsPbBr$_3$ NCs. In fact, we show that the linear temperature renormalization exhibited by the gap of CsPbBr$_3$ NCs is shared with most metal halide perovskites, due to a common bonding/antibonding and atomic orbital character of the electronic band-edge states. In this way, we provide a deeper understanding of the gap temperature dependence in the general case when the A-site cation dynamics is not involved in the electron-phonon interaction., Comment: 29 pages, including 4 figures, a long table and 2 pages of Supporting Information

Weakly magnetized shock waves are paramount to a large diversity of environments, including supernova remnants, blazars, and binary-neutron-star mergers. Understanding the distribution of energy between electrons and ions within these astrophysical shock waves spanning a wide spectrum of velocities is a long-standing challenge. In this study, we present a unified model for the downstream electron temperature within unmagnetized shock waves. Encompassing velocities from Newtonian to relativistic, we probe regimes representative of the gradual deceleration of the forward shock in the late gamma-ray burst afterglow phase, such as GRB 170817A. In our model, heating results from an ambipolar electric field generated by the difference in inertia between electrons and ions, coupled with rapid electron scattering in the decelerating turbulence. Our findings demonstrate that the electron temperature consistently represents $10\%$ of the incoming ion kinetic energy in the shock front frame over the full range of shock velocities., Comment: Proceedings of HEPRO VIII (Paris 2023)

The energy partition in high Mach number collisionless shock waves is central to a wide range of high-energy astrophysical environments. We present a new theoretical model for electron heating that accounts for the energy exchange between electrons and ions at the shock. The fundamental mechanism relies on the difference in inertia between electrons and ions, resulting in differential scattering of the particles off a decelerating magnetically-dominated microturbulence across the shock transition. We show that the self-consistent interplay between the resulting ambipolar-type electric field and diffusive transport of electrons leads to efficient heating in the magnetic field produced by the Weibel instability in the high-Mach number regime and is consistent with fully kinetic simulations., Comment: 10 pages, 6 figures, 1 table; Accepted for publication in Physical Review Letters

In recent years, the field of metal-halide perovskite emitters has rapidly emerged as a new community in solid-state lighting. Their exceptional optoelectronic properties have contributed to the rapid rise in external quantum efficiencies (EQEs) in perovskite light-emitting diodes (PeLEDs) from <1% (in 2014) to approaching 30% (in 2023) across a wide range of wavelengths. However, several challenges still hinder their commercialization, including the relatively low EQEs of blue/white devices, limited EQEs in large-area devices, poor device stability, as well as the toxicity of the easily accessible lead components and the solvents used in the synthesis and processing of PeLEDs. This roadmap addresses the current and future challenges in PeLEDs across fundamental and applied research areas, by sharing the community's perspectives. This work will provide the field with practical guidelines to advance PeLED development and facilitate more rapid commercialization., Comment: 103 pages, 29 figures. This is the version of the article before peer review or editing, as submitted by an author to Journal of Physics: Photonics. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it

Collisionless shock waves in supernova remnants and the solar wind heat electrons less effectively than they heat ions, as is predicted by kinetic simulations. However, the values of T$_e$/T$_p$ inferred from the H alpha profiles of supernova remnant shocks behave differently as a function of Mach number or Alfv\'{e}n Mach number than what is measured in the solar wind or predicted by simulations. Here we determine T$_e$/T$_p$ for supernova remnant shocks using H alpha profiles, shock speeds from proper motions, and electron temperatures from X-ray spectra. We also improve the estimates of sound speed and Alfv\'{e}n speed used to determine Mach numbers. We find that the H alpha determinations are robust and that the discrepancies among supernova remnant shocks, solar wind shocks and computer-simulated shocks remain. We discuss some possible contributing factors, including shock precursors, turbulence and varying preshock conditions.

The radiation drag in photon-rich environments of cosmic explosions can seed kinetic instabilities by inducing velocity spreads between relativistically streaming plasma components. Such microturbulence is likely imprinted on the breakout signals of radiation-mediated shocks. However, large-scale, transverse magnetic fields in the deceleration region of the shock transition can suppress the dominant kinetic instabilities by preventing the development of velocity separations between electron-positron pairs and a heavy ion species. We use a one-dimensional (1D) five-fluid radiative transfer code to generate self-consistent profiles of the radiation drag force and plasma composition in the deceleration region. For increasing magnetization, our models predict rapidly growing pair multiplicities and a substantial radiative drag developing self-similarly throughout the deceleration region. We extract the critical magnetization parameter $\sigma_{c}$, determining the limiting magnetic field strength at which a three-species plasma can develop kinetic instabilities before reaching the isotropized downstream. For a relativistic, single ion plasma drifting with $\gamma_{u} = 10$ in the upstream of a relativistic radiation-mediated shock, we find the threshold $\sigma_{c}\approx 10^{-7}$ for the onset of microturbulence. Suppression of plasma instabilities in the case of multi-ion composition would likely require much higher values of $\sigma_{c}$. Identifying high-energy signatures of microturbulence in shock-breakout signals and combining them with the magnetization limits provided in this work will allow a deeper understanding of the magnetic environment of cosmic explosions like supernovae, gamma-ray bursts, and neutron star binary mergers., Comment: 12 pages, 11 figures, Accepted for publication by MNRAS

We study the onset of electron heating in intense laser-solid interactions and its impact on the spectral quality of radiation pressure accelerated ions in both hole boring and light sail regimes. Two- and three-dimensional particle-in-cell (PIC) simulations are performed over a wide range of laser and target parameters and reveal how the pulse duration, profile, polarization, and target surface stability control the electron heating, the dominant ion acceleration mechanisms, and the ion spectra. We find that the onset of strong electron heating is associated with the growth of the Rayleigh-Taylor-like instability at the front surface and must be controlled to produce high-quality ion beams, even when circularly polarized lasers are employed. We define a threshold condition for the maximum duration of the laser pulse that allows mitigation of electron heating and radiation pressure acceleration of narrow energy spread ion beams. The model is validated by three-dimensional PIC simulations, and the few experimental studies that reported low energy spread radiation pressure accelerated ion beams appear to meet the derived criteria. The understanding provided by our work will be important in guiding future experimental developments, for example for the ultrashort laser pulses becoming available at state-of-the-art laser facilities, for which we predict that proton beams with ~150 - 250 MeV, ~30% energy spread, and a total laser-to-proton conversion efficiency of ~20% can be produced., Comment: 20 (25) pages, 10 figures

Ongoing progress in laser and accelerator technology opens new possibilities in high-field science, notably to investigate the largely unexplored strong-field quantum electrodynamics (SFQED) regime where electron-positron pairs can be created directly from light-matter or even light-vacuum interactions. Laserless strategies such as beam-beam collisions have also been proposed to access the nonperturbative limit of SFQED. Here we report on a concept to probe SFQED by harnessing the interaction between a high-charge, ultrarelativistic electron beam and a solid conducting target. When impinging onto the target surface, the beam self fields are reflected, partly or fully, depending on the beam shape; in the rest frame of the beam electrons, these fields can exceed the Schwinger field, thus triggering SFQED effects such as quantum nonlinear inverse Compton scattering and nonlinear Breit-Wheeler electron-positron pair creation. Through reduced modeling and kinetic numerical simulations, we show that this single-beam setup can achieve interaction conditions similar to those envisioned in beam-beam collisions, but in a simpler and more controllable way owing to the automatic overlap of the beam and driving fields. This scheme thus eases the way to precision studies of SFQED and is also a promising milestone towards laserless studies of nonperturbative SFQED.

The generation of compact, high-energy ion beams is one of the most promising applications of intense laser-matter interactions, but the control of the beam spectral quality remains an outstanding challenge. We show that in radiation pressure acceleration of a thin solid target the onset of electron heating is determined by the growth of the Rayleigh-Taylor-like instability at the front surface and must be controlled to produce ion beams with high spectral quality in the light sail regime. The growth rate of the instability imposes an upper limit on the laser pulse duration and intensity to achieve high spectral beam quality and we demonstrate that under this optimal regime, the maximum peak ion beam energy per nucleon is independent of target density, composition, and laser energy (transverse spot size). Our predictions are validated by two- and three-dimensional particle-in-cell simulations, which indicate that for recent and upcoming experimental facilities using ultrashort ($\lesssim 25$ fs) laser pulses it is possible to produce $100 - 300$ MeV proton beams with $\sim 30\%$ energy spread and high laser-to-proton energy conversion efficiency., Comment: 6 pages, 6 figures

While the long-term vision of the advanced accelerator community is aimed at addressing the challenges of future collider technology, it is critical that the community takes advantage of the opportunity to make large societal impact through its near-term applications. In turn, enabling robust applications strengthens the quality, control, and reliability of the underlying accelerator infrastructure. The white paper contributions that are solicited here will summarize the near-term applications ideas presented by the advanced accelerator community, assessing their potential impact, discussing scientific and technical readiness of concepts, and providing a timeline for implementation., Comment: contribution to Snowmass 2021

Plasma wakefield acceleration (PWFA) has shown illustrious progress and resulted in an impressive demonstration of tens of GeV particle acceleration in meter-long single structures. To reach even higher energies in the 1 TeV to 10 TeV range, a promising scheme is channeling acceleration in solid-density plasmas within crystals or nanostructures. The E336 experiment studies the beam-nanotarget interaction with the highly compressed electron bunches available at the FACET-II accelerator. These studies furthermore involve an in-depth research on dynamics of beam-plasma instabilities in ultra-dense plasma, its development and suppression in structured media like carbon nanotubes and crystals, and its potential use to transversely modulate the electron bunch., Comment: submitted to Snowmass'2021 Accelerator Frontier (AF6), 16 pages, 9 Figs

Relativistic radiation mediated shocks (RRMS) likely form in prodigious cosmic explosions. The structure and emission of such shocks is regulated by copious production of electron-positron pairs inside the shock transition layer. It has been pointed out recently that substantial abundance of positrons inside the shock leads to a velocity separation of the different plasma constituents, which is expected to induce a rapid growth of plasma instabilities. In this paper, we study the hierarchy of plasma microinstabilities growing in an electron-ion plasma loaded with pairs and subject to a radiation force. Linear stability analysis indicates that such a system is unstable to the growth of various plasma modes which ultimately become dominated by a current filamentation instability driven by the relative drift between the ions and the pairs. These results are validated by particle-in-cell simulations that further probe the nonlinear regime of the instabilities, and the pair-ion coupling in the microturbulent electromagnetic field. Based on this analysis, we derive a reduced transport equation for the particles via pitch angle scattering in the microturbulence and demonstrate that it can couple the different species and lead to nonadiabatic compression via a Joule-like heating. The heating of the pairs and, conceivably, the formation of nonthermal distributions, arising from the microturbulence, can affect the observed shock breakout signal in ways unaccounted for by current single-fluid models., Comment: 12 pages, 9 figures

Plasma streaming instabilities play an important role in magnetic field amplification and particle acceleration in relativistic shocks and their environments. However, in the far shock precursor region where accelerated particles constitute a highly relativistic and dilute beam, streaming instabilities typically become inefficient and operate at very small scales when compared to the gyroradii of the beam particles. We report on a plasma cavitation instability that is driven by dilute relativistic beams and can increase both the magnetic field strength and coherence scale by orders of magnitude to reach near-equipartition values with the beam energy density. This instability grows after the development of the Weibel instability and is associated with the asymmetric response of background leptons and ions to the beam current. The resulting net inductive electric field drives a strong energy asymmetry between positively and negatively charged beam species. Large-scale particle-in-cell simulations are used to verify analytical predictions for the growth and saturation level of the instability and indicate that it is robust over a wide range of conditions, including those associated with pair-loaded plasmas. These results can have important implications for the magnetization and structure of shocks in gamma-ray bursts, and more generally for magnetic field amplification and asymmetric scattering of relativistic charged particles in plasma astrophysical environments., Comment: 10 pages, 5 figures. Accepted by ApJL

An extended thermal particle boundary condition is devised to more efficiently and accurately model laser-plasma interactions in overdense plasmas. Particle-in-cell simulations of such interactions require many particles per cell, and a large region of background plasma is often necessary to correctly mimic a semi-infinite plasma and avoid electron refluxing from a truncated plasma. For long-pulse lasers of many picoseconds, such constraints can become prohibitively expensive. Here, an extended particle boundary condition (absorber) is designed that instantaneously stops and re-emits energetic particles streaming toward the simulation boundary over a defined region, allowing sufficient time and space for a suitably cool return current to develop in the background plasma. Tunable parameters of the absorber are explained, and simulations using the absorber with a 3-ps laser are shown to accurately reproduce those of a causally separated boundary while requiring only 20% the number of particles., Comment: 12 pages, 9 figures

An electron or electron-positron beam streaming through a plasma is notoriously prone to micro-instabilities. For a dilute ultrarelativistic infinite beam, the dominant instability is a mixed mode between longitudinal two-stream and transverse filamentation modes, with a phase velocity oblique to the beam velocity. A spatiotemporal theory describing the linear growth of this oblique mixed instability is proposed, which predicts that spatiotemporal effects generally prevail for finite-length beams, leading to a significantly slower instability evolution than in the usually assumed purely temporal regime. These results are accurately supported by particle-in-cell (PIC) simulations. Furthermore, we show that the self-focusing dynamics caused by the plasma wakefields driven by finite-width beams can compete with the oblique instability. Analyzed through PIC simulations, the interplay of these two processes in realistic systems bears important implications for upcoming accelerator experiments on ultrarelativistic beam-plasma interactions.

Laser-ablated high-energy-density (HED) plasmas offer a promising route to study astrophysically relevant processes underlying collisionless shock formation, magnetic field amplification, and particle acceleration in the laboratory. Using large-scale, multi-dimensional particle-in-cell simulations, we explore the interpenetration of laser-ablated counter-streaming plasmas for realistic experimental flow profiles. We find that the shock formation and its structure are substantially different from those of more idealized and commonly considered uniform flows: shock formation can be up to 10 times faster due to the transition from small-angle scattering to magnetic reflection and the shock front develops strong corrugations at the ion gyroradius scale. These findings have important consequences for current experimental programs and open exciting prospects for studying the microphysics of turbulent collisionless shocks with currently available high-energy laser systems., Comment: 9 pages, 9 figures

Novel emergent phenomena are expected to occur under conditions exceeding the QED critical electric field, where the vacuum becomes unstable to electron-positron pair production. The required intensity to reach this regime, $\sim10^{29}\,\mathrm{Wcm^{-2}}$, cannot be achieved even with the most intense lasers now being planned/constructed without a sizeable Lorentz boost provided by interactions with ultrarelativistic particles. Seeded laser-laser collisions may access this strong-field QED regime at laser intensities as low as $\sim10^{24}\,\mathrm{Wcm^{-2}}$. Counterpropagating e-beam--laser interactions exceed the QED critical field at still lower intensities ($\sim10^{20}\,\mathrm{Wcm^{-2}}$ at $\sim10\,\mathrm{GeV}$). Novel emergent phenomena are predicted to occur in the "QED plasma regime", where strong-field quantum and collective plasma effects play off one another. Here the electron beam density becomes a decisive factor. Thus, the challenge is not just to exceed the QED critical field, but to do so with high quality, approaching solid-density electron beams. Even though laser wakefield accelerators (LWFA) represent a very promising research field, conventional accelerators still provide orders of magnitude higher charge densities at energies $\gtrsim10\,\mathrm{GeV}$. Co-location of extremely dense and highly energetic electron beams with a multi-petawatt laser system would therefore enable seminal research opportunities in high-field physics and laboratory astrophysics. This white paper elucidates the potential scientific impact of multi-beam capabilities that combine a multi-PW optical laser, high-energy/density electron beam, and high-intensity x rays and outlines how to achieve such capabilities by co-locating a 3-10 PW laser with a state-of-the-art linear accelerator., Comment: 3 pages

Magnetic field amplification by relativistic streaming plasma instabilities is central to a wide variety of high-energy astrophysical environments as well as to laboratory scenarios associated with intense lasers and electron beams. We report on a new secondary nonlinear instability which arises for relativistic dilute electron beams after the saturation of the linear Weibel instability. This instability grows due to the transverse magnetic pressure associated with the beam current filaments, which cannot be quickly neutralized due to the inertia of background ions. We show that it can amplify the magnetic field strength and spatial scale by orders of magnitude, leading to large-scale plasma cavities with strong magnetic field and to very efficient conversion of the beam kinetic energy into magnetic energy. The instability growth rate, saturation level, and scale length are derived analytically and shown to be in good agreement with fully-kinetic simulations., Comment: 6 pages, 4 figures, submitted to Physical Review Letters

The binary Monte Carlo (MC) collision algorithm is a standard and robust method to include binary Coulomb collision effects in particle-in-cell (PIC) simulations of plasmas. Here, we show that the coupling between PIC and MC algorithms can give rise to (nonphysical) numerical heating of the system, that significantly exceeds that observed when these algorithms operate independently. We argue that this deleterious effect results from an inconsistency between the particle motion associated with MC-collisions and the work performed by the collective electromagnetic field on the PIC grid. This inconsistency manifests as the (artificial) stochastic production of electromagnetic energy, which ultimately heats the plasma particles. The MC-induced numerical heating can significantly impact the evolution of the simulated system for long simulation times ($\gtrsim 10^3$ collision periods, for typical numerical parameters). We describe the source of the MC-induced numerical heating analytically and discuss strategies to minimize it.

Magnetic reconnection is a fundamental plasma process that is thought to play a key role in the production of nonthermal particles associated with explosive phenomena in space physics and astrophysics. Experiments at high-energy-density facilities are starting to probe the microphysics of reconnection at high Lundquist numbers and large system sizes. We have performed particle-in-cell (PIC) simulations to explore particle acceleration for parameters relevant to laser-driven reconnection experiments. We study particle acceleration in large system sizes that may be produced soon with the most energetic laser drivers available, such as at the National Ignition Facility. In these conditions, we show the possibility of reaching the multi-plasmoid regime, where plasmoid acceleration becomes dominant. Our results show the transition from \textit{X} point to plasmoid-dominated acceleration associated with the merging and contraction of plasmoids that further extend the maximum energy of the power-law tail of the particle distribution for electrons. We also find for the first time a system-size-dependent emergence of nonthermal ion acceleration in driven reconnection, where the magnetization of ions at sufficiently large sizes allows them to be contained by the magnetic field and energized by direct \textit{X} point acceleration. For feasible experimental conditions, electrons and ions can attain energies of $\epsilon_{max,e} / k_{B} T_{e} > 100$ and $\epsilon_{max,i} / k_{B} T_{i} > 1000$. Using PIC simulations with binary Monte Carlo Coulomb collisions we study the impact of collisionality on plasmoid formation and particle acceleration. The implications of these results for understanding the role reconnection plays in accelerating particles in space physics and astrophysics are discussed.