Search

Emission spectra and diagnostic spectral features of a diverse range of ablated meteorite samples with a known composition are presented. We aim to provide a reference spectral dataset to improve our abilities to classify meteoroid composition types from meteor spectra observations. The data were obtained by ablating meteorite samples in high-enthalpy plasma wind tunnel facilities recreating conditions characteristic of low-speed meteors. Near-UV to visible-range (320 - 800 nm) emission spectra of 22 diverse meteorites captured by a high-resolution Echelle spectrometer were analyzed to identify the characteristic spectral features of individual meteorite groups. The same dataset captured by a lower-resolution meteor spectrograph was applied to compare the meteorite data with meteor spectra observations. Spectral modeling revealed that the emitting meteorite plasma was characterized by temperatures of 3700 - 4800 K, similar to the main temperature component of meteors. The studied line intensity variations were found to trace the differences in the original meteorite composition and thus can be used to constrain the individual meteorite classes. We demonstrate that meteorite composition types, including ordinary chondrites, carbonaceous chondrites, various achondrites, stony-iron and iron meteorites, can be spectrally distinguished by measuring relative line intensities of Mg I, Fe I, Na I, Cr I, Mn I, Si I, H I, CN, Ni I, and Li I. Additionally, we confirm the effect of the incomplete evaporation of refractory elements Al, Ti, and Ca, and the presence of minor species Co I, Cu I, and V I.

In June 1976, a pristine meteorite stone weighing approximately 1 kg, fully covered with a fresh black fusion crust, was collected on a mountain road in the high-altitude Alpine environment. The recovery took place while clearing the remnants of a snow avalanche, 2 km northwest of Ischgl in Austria. Subsequent to its retrieval, the specimen remained in the finder's private residence without undergoing any scientific examination or identification until 2008, when it was brought to the University of Innsbruck. The sample was classified as a well-preserved LL6 chondrite, with a W0 weathering grade, implying a relatively short time between the meteorite fall and its retrieval. To investigate the potential connection between the Ischgl meteorite and a recorded fireball event, we have reviewed all documented fireballs ever photographed by German fireball camera stations. This examination led us to identify the fireball EN241170 observed in Germany by ten different European Network stations on the night of November 23/24, 1970, as the most likely candidate. We employed state-of-the-art techniques to reconstruct the fireball's trajectory, and to reproduce both its luminous and dark flight phases in detail. We find that the determined strewn field and the generated heat map closely align with the recovery location of the Ischgl meteorite. Furthermore, the measured radionuclide data reported here indicate that the pre-atmospheric size of the Ischgl meteoroid is consistent with the mass estimate inferred from our deceleration analysis along the trajectory. Our findings strongly support the conclusion that the Ischgl meteorite originated from the EN241170 fireball, effectively establishing it as a confirmed meteorite fall. This discovery enables to determine, along with the physical properties, also the heliocentric orbit and cosmic history of the Ischgl meteorite., Comment: Accepted for publication in Meteoritics & Planetary Science

Fragments of small solar system bodies entering Earth's atmosphere have possibly been important contributors of organic compounds to the early Earth. The cyano radical (CN) emission from meteors is considered as potentially one of the most suitable markers of organic compounds in meteoroids, however, its detection in meteor spectra has been thus far unsuccessful. With the aim to improve our abilities to identify CN emission in meteor observations and use its spectral features to characterize the composition of incoming asteroidal meteoroids, we present a detailed analysis of CN emission from high-resolution spectra of 22 laboratory simulated meteors including ordinary, carbonaceous, and enstatite chondrites, as well as a large diversity of achondrites (i.e., ureilite, aubrite, lunar, martian, howardite, eucrite, and diogenite), mesosiderite, and iron meteorites. We describe the variations of CN emission from different classes of asteroidal meteor analogues, its correlation and time evolution relative to other major meteoroid components. We demonstrate that CN can be used as a diagnostic spectral feature of carbonaceous and carbon-rich meteoroids, while most ordinary chondrites show no signs of CN. Our results point out strong correlation between CN and H emission and suggest both volatile features are suitable to trace contents of organic matter and water molecules present within meteoroids. For the application in lower resolution meteor observations, we demonstrate that CN can be best recognized in the early stages of ablation and for carbon-rich materials by measuring relative intensity ratio of CN band peak to the nearby Fe I-4 lines.

The hydrogen emission from meteors is assumed to originate mainly from the meteoroid composition, making it a potential tracer of H$_{2}$O molecules and organic compounds. H$\alpha$ line was previously detected in individual fireballs, but its variation in a larger meteor dataset and dependency on the dynamical origin and physical properties have not yet been studied. Here we investigate the relative intensity of H$\alpha$ within 304 meteor spectra observed by the AMOS network. We demonstrate that H$\alpha$ emission is favored in faster meteors ($v_i >>$ 30 km s$^{-1}$) which form the high-temperature spectral component. H$\alpha$ was found to be a characteristic spectral feature of cometary meteoroids with $\sim$ 92% of all meteoroids with detected H$\alpha$ originating from Halley-type and long-period orbits. Our results suggest that hydrogen is being depleted from meteoroids with lower perihelion distances (q $<$ 0.4 au). No asteroidal meteoroids with detected H emission were found. However, using spectral data from simulated ablation of different meteorite types, we show that H emission from asteroidal materials can occur, and apparently correlates with their water and organic matter content. Strongest H emission was detected from carbonaceous chondrites (CM and CV) and achondrites (ureilite and aubrite), while it was lacking in most ordinary chondrites. The detection of H$\alpha$ in asteroidal meteoroids could be used to identify meteoroids of carbonaceous or achondritic composition. Overall, our results suggest that H$\alpha$ emission correlates with the emission of other volatiles (Na and CN) and presents a suitable tracer of water and organic matter in meteoroids.

In meteor physics the luminous efficiency ${\tau}$ is used to convert the meteor's magnitude to the corresponding meteoroid's mass. However, lack of sufficiently accurate verification methods or adequate laboratory tests leave this parameter to be controversially discussed. In this work meteor/fireball data obtained by the Fireball Recovery and InterPlanetary Observation Network (FRIPON) was used to calculate the masses of the pre-atmospheric meteoroids which could in turn be compared to the meteor brightnesses to assess their luminous efficiencies. For that, deceleration-based formulas for the mass computation were used. We have found ${\tau}$-values, as well as the shape change coefficients, of 294 fireballs with determined masses in the range of $10^{-6}$ kg - $100$ kg. The derived ${\tau}$-values have a median of ${\tau}_{median}$ = 2.17 %. Most of them are on the order of 0.1 % - 10 %. We present how our values were obtained, compare them with data reported in the literature, and discuss several methods. A dependence of ${\tau}$ on the pre-atmospheric velocity of the meteor, $v_e$, is noticeable with a relation of ${\tau}=0.0023 \cdot v_e^{2.3}$. The higher luminous efficiency of fast meteors could be explained by the higher energy released. Fast meteoroids produce additional emission lines that radiate more efficiently in specific wavelengths due to the appearance of the so-called second component of higher temperature. Furthermore, a dependence of ${\tau}$ on the initial meteoroid mass, $M_e$, was found, with negative linear behaviour in log-log space: ${\tau}=0.48 \cdot M_e^{-0.47}$. This implies that the radiation of smaller meteoroids is more efficient.

The geochemistry and textural associations of chondritic phosphate minerals can provide insights into the geological histories of parental asteroids, but the processes governing their formation and deformation remain poorly constrained. Here, we present a quantitative assessment of phosphorus-bearing mineral textures in the three variously-shocked lithologies (light, dark, and melt) of the Chelyabinsk (LL5) ordinary chondrite using scanning electron microscope, electron microprobe, cathodoluminescence, and electron backscatter diffraction techniques. Phase associations, microtextures, and microstructures of phosphates are extremely variable within and between the differently-shocked lithologies investigated in the Chelyabinsk meteorite. We observe continuously strained as well as recrystallized, strain-free phosphate populations. Recrystallized grains (with strain-free subdomains) are present only in the more intensely shocked dark lithology, indicating that phosphate growth in Chelyabinsk predates the development of primary shock-metamorphic textures. This disruption event is also recorded by complete melting of portions of the meteorite to produce the shock-melt lithology, which contains a population of phosphorus-rich olivine grains. We interpret the textures and phase associations of Chelyabinsk to have resulted from initial phosphate growth via metasomatic olivine replacement, followed by major deformation during an early shock-melting impact and a subsequent minor shock event. This minor event appears to have generated a sub-population of phosphates that display patchy CL textures, in both the light and dark lithology. Finally, we propose a new classification scheme to describe various types of Phosphorus-Olivine-Assemblages (Type I-III POAs), which can be used to classify shock metamorphic events and define the associated physicochemical processes., Comment: Accepted in Meteoritics and Planetary Science

Accessory mineral geochronometers such as zircon, monazite, baddeleyite, and xenotime are increasingly being recognized for their ability to preserve diagnostic microstructural evidence of hypervelocity processes. However, little is known about the response of titanite to shock metamorphism, even though it is a widespread accessory phase and U-Pb geochronometer. Here we report two new mechanical twin modes in titanite within shocked granitoids from the Chicxulub impact structure, Mexico. Titanite grains in the newly acquired International Ocean Discovery Program Site expedition 364 M0077A core preserve multiple sets of polysynthetic twins, most commonly with composition planes (K1), = ~{1̅11}, and shear direction (η1) = <110>, and less commonly with the mode K1 = {130}, η1 = ~<522>. In some grains, {130} deformation bands have formed concurrently with shock twins, indicating dislocation glide with Burgers vector b = [341] can be active at shock conditions. Twinning of titanite in these modes, the presence of planar deformation features in shocked quartz, and lack of diagnostic shock microstructures in zircon in the same samples highlights the utility of titanite as a shock indicator for a shock pressure range between ~12 and ~17 GPa. Given the challenges of identifying ancient impact evidence on Earth and other bodies, microstructural analysis of titanite is here demonstrated to be a new avenue for recognizing impact deformation in materials where other impact evidence may be erased, altered, or did not manifest due to low shock pressure.