Search

Using density functional theory calculations with spin-orbit coupling (SOC), we report on the temperature-dependent thermodynamical properties of Pb: electrical resistivity, thermal expansion (TE), heat capacity, bulk modulus and its pressure derivative. For the former, we employed the state-of-the-art ab initio Boltzmann Transport Equation formalism, and we calculated the effect of TE. In accordance with previous work, we show that SOC improves the description of the phonon dispersion and the resistivity. We argue that this is caused by a joint mutual effect of an increase in the electronic nesting and an increase in the electron-phonon coupling. Interestingly, including TE incorporates non-linearity into the resistivity at high temperatures, whose magnitude depends on whether SOC is included or not. We suggest that mechanisms beyond the quasi-harmonic approximation should be considered to get a better description of Pb with SOC at high temperatures., Comment: 19 pages, 10 figures

Analyzing and finding anomalies in multi-dimensional datasets is a cumbersome but vital task across different domains. In the context of financial fraud detection, analysts must quickly identify suspicious activity among transactional data. This is an iterative process made of complex exploratory tasks such as recognizing patterns, grouping, and comparing. To mitigate the information overload inherent to these steps, we present a tool combining automated information highlights, Large Language Model generated textual insights, and visual analytics, facilitating exploration at different levels of detail. We perform a segmentation of the data per analysis area and visually represent each one, making use of automated visual cues to signal which require more attention. Upon user selection of an area, our system provides textual and graphical summaries. The text, acting as a link between the high-level and detailed views of the chosen segment, allows for a quick understanding of relevant details. A thorough exploration of the data comprising the selection can be done through graphical representations. The feedback gathered in a study performed with seven domain experts suggests our tool effectively supports and guides exploratory analysis, easing the identification of suspicious information.

Understanding phonon and charge propagation in superconducting devices plays an important role in both performing low-threshold dark matter searches and limiting correlated errors in superconducting qubits. The Geant4 Condensed Matter Physics (G4CMP) package, originally developed for the Cryogenic Dark Matter Search (CDMS) experiment, models charge and phonon transport within silicon and germanium detectors and has been validated by experimental measurements of phonon caustics, mean charge-carrier drift velocities, and heat pulse propagation times. In this work, we present a concise framework for expanding the capabilities for phonon transport to a number of other novel substrate materials of interest to the dark matter and quantum computing communities, including sapphire (Al$_{2}$O$_{3}$), gallium arsenide (GaAs), lithium fluoride (LiF), calcium tungstate (CaWO$_{4}$), and calcium fluoride (CaF$_{2}$). We demonstrate the use of this framework in generating phonon transport properties of these materials and compare these properties with experimentally-determined values where available., Comment: 18 pages, 13 figures, 6 Tables

The design and optimization of laser-Compton x-ray systems based on compact distributed charge accelerator structures can enable micron-scale imaging of disease and the concomitant production of beams of Very High Energy Electrons (VHEEs) capable of producing FLASH-relevant dose rates. The physics of laser-Compton x-ray scattering ensures that the scattered x-rays follow exactly the trajectory of the incident electrons, thus providing a route to image-guided, VHEE FLASH radiotherapy. The keys to a compact architecture capable of producing both laser-Compton x-rays and VHEEs are the use of X-band RF accelerator structures which have been demonstrated to operate with over 100 MeV/m acceleration gradients. The operation of these structures in a distributed charge mode in which each radiofrequency (RF) cycle of the drive RF pulse is filled with a low-charge, high-brightness electron bunch is enabled by the illumination of a high-brightness photogun with a train of UV laser pulses synchronized to the frequency of the underlying accelerator system. The UV pulse trains are created by a patented pulse synthesis approach which utilizes the RF clock of the accelerator to phase and amplitude modulate a narrow band continuous wave (CW) seed laser. In this way it is possible to produce up to 10 {\mu}A of average beam current from the accelerator. Such high current from a compact accelerator enables production of sufficient x-rays via laser-Compton scattering for clinical imaging and does so from a machine of "clinical" footprint. At the same time, the production of 1000 or greater individual micro-bunches per RF pulse enables > 10 nC of charge to be produced in a macrobunch of < 100 ns. The design, construction, and test of the 100-MeV class prototype system in Irvine, CA is also presented., Comment: 28 pages, 13 figures, 2 tables

Accurately predicting carrier mobility in strongly anharmonic solids necessitates a precise characterization of lattice dyndamics as a function of temperature. We achieve consistency with experimental electron mobility data for bulk KTaO$_3$ and SrTiO$_3$ above 150 K by refining the Boltzmann transport equations. This refinement includes incorporating temperature-dependent anharmonic phonon eigenfrequencies and eigenmodes into the electron-phonon interaction tensor, while maintaining the derivatives of the Kohn-Sham potential as computed in density functional perturbation theory. Using efficient machine-learned force fields and the stochastic self-consistent harmonic approximation, we accurately compute the dynamical matrices. At room temperature, the calculated mobility for SrTiO$_3$ exceeds experimental values by an order of magnitude, whereas the overestimation for KTaO$_3$ is way less pronounced. This discrepancy is explained through the more significant electron mass renormalization near the conduction band bottom due to anharmonic electron-phonon coupling and the presence of local disorder in SrTiO$_3$.

We present our optical observations and multi-wavelength analysis of the GRB\,200613A detected by \texttt{Fermi} satellite. Time-resolved spectral analysis of the prompt $\gamma$-ray emission was conducted utilizing the Bayesian block method to determine statistically optimal time bins. Based on the Bayesian Information Criterion (BIC), the data generally favor the Band+Blackbody (short as BB) model. We speculate that the main Band component comes from the Blandford-Znajek mechanism, while the additional BB component comes from the neutrino annihilation process. The BB component becomes significant for a low-spin, high-accretion rate black hole central engine, as evidenced by our model comparison with the data. The afterglow light curve exhibits typical power-law decay, and its behavior can be explained by the collision between the ejecta and constant interstellar medium (ISM). Model fitting yields the following parameters: $E_{K,iso} = (2.04^{+11.8}_{-1.50})\times 10^{53}$ erg, $\Gamma_0=354^{+578}_{-217}$, $p=2.09^{+0.02}_{-0.03}$, $n_{18}=(2.04^{+9.71}_{-1.87})\times 10^{2}$ cm$^{-3}$, $\theta_j=24.0^{+6.50}_{-5.54}$ degree, $\epsilon_e=1.66^{+4.09}_{-1.39})\times 10^{-1}$ and $\epsilon_B=(7.76^{+48.5}_{-5.9})\times 10^{-6}$. In addition, we employed the public Python package \texttt{Prospector} perform a spectral energy distribution (SED) modeling of the host galaxy. The results suggest that the host galaxy is a massive galaxy ($\log(M_\ast / M_\odot)=11.75^{+0.10}_{-0.09}$) with moderate star formation rate ($\mbox{SFR}=22.58^{+13.63}_{-7.22} M_{\odot}$/yr). This SFR is consistent with the SFR of $\sim 34.2 M_{\odot}$ yr$^{-1}$ derived from the [OII] emission line in the observed spectrum., Comment: 30 pages, 16 figures, accepted by ApJ

(2060) Chiron is a large centaur that has been reported active on multiple occasions including during aphelion passage. Studies of Chirons coma during active periods have resulted in the detection of C(triple)N and CO outgassing. Significant work remains to be undertaken to comprehend the activation mechanisms on Chiron and the parent molecules of the gas phases detected. This work reports the study of the ices on Chirons surface and coma and seeks spectral indicators of volatiles associated with the activity. Additionally, we discuss how these detections could be related to the activation mechanism for Chiron and, potentially, other centaurs. In July 2023, the James Webb Space Telescope (JWST) observed Chiron when it was active near its aphelion. We present JWST/NIRSpec spectra from 0.97 to 5.27 microns with a resolving power of 1000, and compare them with laboratory data for identification of the spectral bands. We report the first detections on Chiron of absorption bands of several volatile ices, including CO2, CO, C2H6, C3H8, and C2H2. We also confirm the presence of water ice in its amorphous state. A key discovery arising from these data is the detection of fluorescence emissions of CH4, revealing the presence of a gas coma rich in this hyper-volatile molecule, which we also identify to be in non-local thermal equilibrium (nonLTE). CO2 gas emission is also detected in the fundamental stretching band at 4.27 microns. We argue that the presence of CH4 emission is the first proof of the desorption of CH4 due to a density phase transition of amorphous water ice at low temperature in agreement with the estimated temperature of Chiron during the JWST observations (61 K). Detection of photolytic and proton irradiation products of CH4 and CO2 on the surface, in the coma ice grains, or in the ring material is also detected via a forest of absorption features from 3.5 to 5.3 microns., Comment: 4 figures in paper plus 2 more in the appendix. Accepted as A&A Letter

This article presents constraints on dark-matter-electron interactions obtained from the first underground data-taking campaign with multiple SuperCDMS HVeV detectors operated in the same housing. An exposure of 7.63 g-days is used to set upper limits on the dark-matter-electron scattering cross section for dark matter masses between 0.5 and 1000 MeV/$c^2$, as well as upper limits on dark photon kinetic mixing and axion-like particle axioelectric coupling for masses between 1.2 and 23.3 eV/$c^2$. Compared to an earlier HVeV search, sensitivity was improved as a result of an increased overburden of 225 meters of water equivalent, an anticoincidence event selection, and better pile-up rejection. In the case of dark-matter-electron scattering via a heavy mediator, an improvement by up to a factor of 25 in cross-section sensitivity was achieved., Comment: 7 pages + title and references, 4 figures, and 1 table

Cryogenic calorimetric experiments to search for neutrinoless double-beta decay ($0\nu\beta\beta$) are highly competitive, scalable and versatile in isotope. The largest planned detector array, CUPID, is comprised of about 1500 individual Li$_2^{100}$MoO$_{4}$ detector modules with a further scale up envisioned for a follow up experiment (CUPID-1T). In this article, we present a novel detector concept targeting this second stage with a low impedance TES based readout for the Li$_2$MoO$_{4}$ absorber that is easily mass-produced and lends itself to a multiplexed readout. We present the detector design and results from a first prototype detector operated at the NEXUS shallow underground facility at Fermilab. The detector is a 2-cm-side cube with 21$\,$g mass that is strongly thermally coupled to its readout chip to allow rise-times of $\sim$0.5$\,$ms. This design is more than one order of magnitude faster than present NTD based detectors and is hence expected to effectively mitigate backgrounds generated through the pile-up of two independent two neutrino decay events coinciding close in time. Together with a baseline resolution of 1.95$\,$keV (FWHM) these performance parameters extrapolate to a background index from pile-up as low as $5\cdot 10^{-6}\,$counts/keV/kg/yr in CUPID size crystals. The detector was calibrated up to the MeV region showing sufficient dynamic range for $0\nu\beta\beta$ searches. In combination with a SuperCDMS HVeV detector this setup also allowed us to perform a precision measurement of the scintillation time constants of Li$_2$MoO$_{4}$. The crystal showed a significant fast scintillation emission with O(10$\,\mu$s) time-scale, more than an order below the detector response of presently considered light detectors suggesting the possibility of further progress in pile-up rejection through better light detectors in the future.

Halide perovskites emerged as a revolutionary family of high-quality semiconductors for solar energy harvesting and energy-efficient lighting. There is mounting evidence that the exceptional optoelectronic properties of these materials could stem from unconventional electron-phonon couplings, and it has been suggested that the formation of polarons and self-trapped excitons could be key to understanding such properties. By performing first-principles simulations with unprecedented detail across the length scales, here we show that halide perovskites harbor a uniquely rich variety of polaronic species, including small polarons, large polarons, and charge density waves, and we explain a variety of experimental observations. We find that these emergent quasiparticles support topologically nontrivial phonon fields with quantized topological charge, making them the first non-magnetic analog of the helical Bloch points found in magnetic skyrmion lattices.

We measure space- and time-correlated charge jumps on a four-qubit device, operating 107 meters below the Earth's surface in a low-radiation, cryogenic facility designed for the characterization of low-threshold particle detectors. The rock overburden of this facility reduces the cosmic ray muon flux by over 99% compared to laboratories at sea level. Combined with 4$\pi$ coverage of a movable lead shield, this facility enables quantifiable control over the flux of ionizing radiation on the qubit device. Long-time-series charge tomography measurements on these weakly charge-sensitive qubits capture discontinuous jumps in the induced charge on the qubit islands, corresponding to the interaction of ionizing radiation with the qubit substrate. The rate of these charge jumps scales with the flux of ionizing radiation on the qubit package, as characterized by a series of independent measurements on another energy-resolving detector operating simultaneously in the same cryostat with the qubits. Using lead shielding, we achieve a minimum charge jump rate of 0.19$^{+0.04}_{-0.03}$ mHz, almost an order of magnitude lower than that measured in surface tests, but a factor of roughly eight higher than expected based on reduction of ambient gammas alone. We operate four qubits for over 22 consecutive hours with zero correlated charge jumps at length scales above three millimeters., Comment: 12 pages, 6 figures, 4 tables. Minor update to the measured gamma flux ratio (Page 4 and Supplemental Section F) in the LMO detector, from 23 to 20. Typos corrected, references added. Extraneous .tex files have been removed that were causing errors with the "HTML (experimental)" arxiv feature

We have developed a calibration system based on a micro-electromechanical systems (MEMS) mirror that is capable of delivering an optical beam over a wavelength range of 180 -- 2000 nm (0.62 -- 6.89 eV) in a sub-Kelvin environment. This portable, integrated system can steer the beam over a $\sim$3 cm $\times$ 3 cm area on the surface of any sensor with a precision of $\sim$100 $\mu$m, enabling characterization of device response as a function of position. This fills a critical need in the landscape of calibration tools for sub-Kelvin devices, including those used for dark matter detection and quantum computing. These communities have a shared goal of understanding the impact of ionizing radiation on device performance, which can be pursued with our system. This paper describes the design of the first-generation calibration system and the results from successfully testing its performance at room temperature and 20 mK., Comment: 17 pages, 7 figures, submitted to SPIE

Convection-permitting models (CPMs) enable the representation of meteorological variables at horizontal high resolution spatial scales (higher than 4 km), where convection plays a significant role. Physical schemes need to be evaluated considering factors in the studied region such as orography and climate variability. This study investigates the sensitivity of the WRF model as CPM to the use of different physics schemes on Andalusia, a complex orography region in southern Iberian Peninsula (IP). A set of 1-year WRF simulations was completed based on two one-way nested domains: the parent domain (d01) spanning the entire IP with 5 km spatial resolution and the nested domain (d02) for the region of Andalusia at 1 km of spatial resolution. 12 physic schemes were examined from combinations of microphysics (MP) schemes including THOMPSON, WRF single moment 6-class (WSM6), and WRF single moment 7-class (WSM7), and different options for the convection in d01, the Grell 3D (G3), Grell-Freitas (GF), Kain-Fritsch (KF), and deactivated cumulus parameterization (OFF). The simulated precipitation and 2-m temperature for the year 2018, a very wet year, were compared with observational datasets to determine the optimal WRF configuration, including point-to-point and station-point comparisons at different time aggregations. In general, greater differences were shown when comparing the results of convection schemes in d01. Simulations completed with GF or OFF presented better performance compared to the reference datasets. Concerning the MP, although THOMPSON showed a better fit in high mountain areas, it generally presents a worse agreement with the reference datasets. In terms of temperature, the results were very similar and, therefore, the selection of the best configuration was based mainly on the precipitation results with the WSM7-GF scheme being suitable for Andalusia region.

The nature of the minute-to-hour long Fast X-ray Transients (FXTs) localised by telescopes such as Chandra, Swift, and XMM-Newton remains mysterious, with numerous models suggested for the events. Here, we report multi-wavelength observations of EP240315a, a 1600 s long transient detected by the Einstein Probe, showing it to have a redshift of z=4.859. We measure a low column density of neutral hydrogen, indicating that the event is embedded in a low-density environment, further supported by direct detection of leaking ionising Lyman-continuum. The observed properties are consistent with EP240315a being a long-duration gamma-ray burst, and these observations support an interpretation in which a significant fraction of the FXT population are lower-luminosity examples of similar events. Such transients are detectable at high redshifts by the Einstein Probe and, in the (near) future, out to even larger distances by SVOM, THESEUS, and Athena, providing samples of events into the epoch of reionisation., Comment: 41 pages, 7 figures, submitted

Layered halide perovskites have emerged as potential alternatives to three-dimensional halide perovskites due to their improved stability and larger material phase space, allowing fine-tuning of structural, electronic, and optical properties. However, their charge carrier mobilities are significantly smaller than that of three-dimensional halide perovskites, which has a considerable impact on their application in optoelectronic devices. Here, we employ state-of-the-art ab initio approaches to unveil the electron-phonon mechanisms responsible for the diminished transport properties of layered halide perovskites. Starting from a prototypical ABX$_{3}$ halide perovskite, we model the case of $n=1$ and $n=2$ layered structures and compare their electronic and transport properties to the three-dimensional reference. The electronic and phononic properties are investigated within density functional theory (DFT) and density functional perturbation theory (DFPT), while transport properties are obtained via the ab initio Boltzmann transport equation. The vibrational modes contributing to charge carrier scattering are investigated and associated with polar-phonon scattering mechanisms arising from the long-range Fr\"ohlich coupling and deformation potential scattering processes. Our investigation reveals that the lower mobilities in layered systems primarily originates from the increased electronic density of states at the vicinity of the band edges, while the electron-phonon coupling strength remains similar. Such increase is caused by the dimensionality reduction and the break in octahedra connectivity along the stacking direction. Our findings provide a fundamental understanding of the electron-phonon coupling mechanisms in layered perovskites and highlight the intrinsic limitations of the charge carrier transport in these materials.

In recent years, the lack of a conclusive detection of WIMP dark matter at the 10 GeV/c$^{2}$ mass scale and above has encouraged development of low-threshold detector technology aimed at probing lighter dark matter candidates. Detectors based on Cooper-pair-breaking sensors have emerged as a promising avenue for this detection due to the low (meV-scale) energy required for breaking a Cooper pair in most superconductors. Among them, devices based on superconducting qubits are interesting candidates for sensing due to their observed sensitivity to broken Cooper pairs. We have developed an end-to-end G4CMP-based simulation framework and have used it to evaluate performance metrics of qubit-based devices operating in a gate-based "energy relaxation" readout scheme, akin to those used in recent studies of qubit sensitivity to ionizing radiation. We find that for this readout scheme, the qubit acts as a phonon sensor with an energy threshold ranging down to $\simeq$0.4 eV for near-term performance parameters., Comment: 17 pages, 10 figures

Various dark matter search experiments employ phonon-based crystal detectors operated at cryogenic temperatures. Some of these detectors, including certain silicon detectors used by the SuperCDMS Collaboration, are able to achieve single-charge sensitivity when a voltage bias is applied across the detector. The total amount of phonon energy measured by such a detector is proportional to the number of electron-hole pairs created by the interaction. However, crystal impurities and surface effects can cause propagating charges to either become trapped inside the crystal or create additional unpaired charges, producing non-quantized measured energy as a result. A new analytical model for describing these detector response effects in phonon-based crystal detectors is presented. This model improves upon previous versions by demonstrating how the detector response, and thus the measured energy spectrum, is expected to differ depending on the source of events. We use this model to extract detector response parameters for SuperCDMS HVeV detectors, and illustrate how this robust modelling can help statistically discriminate between sources of events in order to improve the sensitivity of dark matter search experiments., Comment: 19 pages, 7 figures

Microcalorimeters that leverage microwave kinetic inductance detectors to read out phonon signals in the particle-absorbing target, referred to as kinetic inductance phonon-mediated (KIPM) detectors, offer an attractive detector architecture to probe dark matter (DM) down to the fermionic thermal relic mass limit. A prototype KIPM detector featuring a single aluminum resonator patterned onto a 1-gram silicon substrate was operated in the NEXUS low-background facility at Fermilab for characterization and evaluation of this detector architecture's efficacy for a dark matter search. An energy calibration was performed by exposing the bare substrate to a pulsed source of 470 nm photons, resulting in a baseline resolution on the energy absorbed by the phonon sensor of $2.1\pm0.2$ eV, a factor of two better than the current state-of-the-art, enabled by millisecond-scale quasiparticle lifetimes. However, due to the sub-percent phonon collection efficiency, the resolution on energy deposited in the substrate is limited to $\sigma_E=318 \pm 28$ eV. We further model the signal pulse shape as a function of device temperature to extract quasiparticle lifetimes, as well as the observed noise spectra, both of which impact the baseline resolution of the sensor.

The transparent conducting oxide SnO2 is a wide bandgap semiconductor that is easily n-type doped and widely used in various electronic and optoelectronic applications. Experimental reports of the electron mobility of this material vary widely depending on the growth conditions and doping concentrations. In this work, we calculate the electron mobility of SnO2 from first principles to examine the temperature- and doping-concentration dependence, and to elucidate the scattering mechanisms that limit transport. We include both electron-phonon scattering and electron-ionized impurity scattering to accurately model scattering in a doped semiconductor. We find a strongly anisotropic mobility that favors transport in the direction parallel to the c-axis. At room temperature and intrinsic carrier concentrations, the low-energy polar-optical phonon modes dominate scattering, while ionized-impurity scattering dominates above 10^18 cm^-3., Comment: 24 pages, 3 figures in main text, 6 figures in supplementary material

Heat transfer at the interface between two materials is becoming increasingly important as the size of electronic devices shrinks. Most studies concentrate on the interfacial thermal conductance between either crystalline-crystalline or amorphous-amorphous materials. Here, we investigate the interfacial thermal conductance at crystalline-amorphous interfaces using non-equilibrium molecular dynamics simulations. Specifically, gold and two different materials, silicon and silica, in both their crystalline and amorphous structures, have been considered. The findings reveal that the interfacial thermal conductance between amorphous structures and gold is significantly higher as compared to crystalline structures for both planar and rough interfaces ($\approx$ 152 MW/(m$^2$K) for gold-amorphous silicon and $\approx$ 56 MW/(m$^2$K) for gold-crystalline silicon). We explain this increase by two factors~:~the relative commensurability between amorphous silicon/silica and gold leads to enhanced bonding and cross-correlations of atomic displacements at the interface, contributing to enhance phonon elastic transmission. Inelastic phonon transmission is also enhanced due to the relative larger degree of anharmonicity characterizing gold-amorphous silicon/silica. We also show that all the vibrational modes that participate to interfacial heat transfer are delocalized and use the Ioffe-Regel (IR) criterion to separate the contributions of propagating~(propagons) and non-propagating modes~(diffusons). In particular, we demonstrate that, while at gold-amorphous silicon interfaces elastic phonon scattering involves propagons and inelastic phonon scattering involves a mixture of propagons and diffusons, in gold-amorphous silica, all modes transmitting energy at the interface are diffusons.

The local field potential (LFP) is as a measure of the combined activity of neurons within a region of brain tissue. While biophysical modeling schemes for LFP in cortical circuits are well established, there is a paramount lack of understanding regarding the LFP properties along the states assumed in cortical circuits over long periods. Here we use a symbolic information approach to determine the statistical complexity based on Jensen disequilibrium measure and Shannon entropy of LFP data recorded from the primary visual cortex (V1) of urethane-anesthetized rats and freely moving mice. Using these information quantifiers, we find consistent relations between LFP recordings and measures of cortical states at the neuronal level. More specifically, we show that LFP's statistical complexity is sensitive to cortical state (characterized by spiking variability), as well as to cortical layer. In addition, we apply these quantifiers to characterize behavioral states of freely moving mice, where we find indirect relations between such states and spiking variability.

Coherent elastic neutrino-nucleus scattering (CE$\nu$NS) offers a valuable approach in searching for physics beyond the Standard Model. The Ricochet experiment aims to perform a precision measurement of the CE$\nu$NS spectrum at the Institut Laue-Langevin nuclear reactor with cryogenic solid-state detectors. The experiment plans to employ an array of cryogenic thermal detectors, each with a mass around 30 g and an energy threshold of sub-100 eV. The array includes nine detectors read out by Transition-Edge Sensors (TES). These TES based detectors will also serve as demonstrators for future neutrino experiments with thousands of detectors. In this article we present an update in the characterization and modeling of a prototype TES detector., Comment: Submitted to LTD20 proceeding

Scaling superconducting digital circuits requires fundamental changes in the current material set and fabrication process. The transition to 300 mm wafers and the implementation of advanced lithography are instrumental in facilitating mature CMOS processes, ensuring uniformity, and optimizing the yield. This study explores the properties of NbxTi(1-x)N films fabricated by magnetron DC sputtering on 300 mm Si wafers. As a promising alternative to traditional Nb in device manufacturing, NbxTi(1-x)N offers numerous advantages, including enhanced stability and scalability to smaller dimensions, in both processing and design. As a ternary material, NbxTi(1-x)N allows engineering material parameters by changing deposition conditions. The engineered properties can be used to modulate device parameters through the stack and mitigate failure modes. We report characterization of NbxTi(1-x)N films at less than 2% thickness variability, 2.4% Tc variability and 3% composition variability. The films material properties such as resistivity (140-375 {\Omega}cm) and critical temperature Tc (4.6 K - 14.1 K) are correlated with stoichiometry and morphology of the films. Our results highlight the significant influence of deposition conditions on crystallographic texture along the films and its correlation with Tc., Comment: 8 pages 8 figures

Advanced Persistent Threats (APTs) represent the most threatening form of attack nowadays since they can stay undetected for a long time. Adversary emulation is a proactive approach for preparing against these attacks. However, adversary emulation tools lack the anti-detection abilities of APTs. We introduce Laccolith, a hypervisor-based solution for adversary emulation with anti-detection to fill this gap. We also present an experimental study to compare Laccolith with MITRE CALDERA, a state-of-the-art solution for adversary emulation, against five popular anti-virus products. We found that CALDERA cannot evade detection, limiting the realism of emulated attacks, even when combined with a state-of-the-art anti-detection framework. Our experiments show that Laccolith can hide its activities from all the tested anti-virus products, thus making it suitable for realistic emulations.

We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 $\mu$m. Quaoar was also observed at 10x higher spectral resolution from 0.97 to 3.16 $\mu$m using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C$_2$H$_6$), as well as acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), H$_2$O, and possibly minor CO$_2$. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H$_2$O features and CO$_2$ complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H$_2$O features, a feature at 3.2 $\mu$m possibly due to HCN, and CO$_2$ ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH$_4$). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 $\mu$m indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs., Comment: 32 pages, 9 figures, 5 tables, accepted for publication in Icarus

Dwarf planets Eris and Makemake have surfaces bearing methane ice of unknown origin. D/H ratios were recently determined from James Webb Space Telescope (JWST) observations of Eris and Makemake, giving us new clues to decipher the origin of methane. Here, we develop geochemical models to test if the origin of methane could be primordial, derived from CO$_2$ or CO ("abiotic"), or sourced by organics ("thermogenic"). We find that primordial methane is inconsistent with the observational data, whereas both abiotic and thermogenic methane can have D/H ratios that overlap the observed ranges. This suggests that Eris and Makemake either never acquired a significant amount of methane during their formation, or their original inventories were removed and then replaced by a source of internally produced methane. Because producing abiotic or thermogenic methane likely requires temperatures above ~150{\deg}C, we infer that Eris and Makemake have rocky cores that underwent substantial radiogenic heating. Their cores may still be warm/hot enough to make methane. This heating could have driven hydrothermal circulation at the bottom of an ice-covered ocean to generate abiotic methane, and/or metamorphic reactions involving accreted organic matter could have occurred in response to heating in the deeper interior, generating thermogenic methane. Additional analyses of relevant thermal evolution model results and theoretical predictions of the D/H ratio of methane in the solar nebula support our findings of elevated subsurface temperatures and an apparent lack of primordial methane on Eris and Makemake. It remains an open question whether their D/H ratios may have evolved subsequent to methane outgassing. Recommendations are given for future activities to further test proposed scenarios of abiotic and thermogenic methane production on Eris and Makemake, and to explore these worlds up close., Comment: Accepted by Icarus, 43 pages, 8 figures, 1 table

James Webb Space Telescope's NIRSpec infrared imaging spectrometer observed the outer solar system dwarf planets Eris and Makemake in reflected sunlight at wavelengths spanning 1 through 5 microns. Both objects have high albedo surfaces that are rich in methane ice, with a texture that permits long optical path lengths through the ice for solar photons. There is evidence for N2 ice absorption around 4.2 um on Eris, though not on Makemake. No CO ice absorption is seen at 4.67 um on either body. For the first time, absorption bands of two heavy isotopologues of methane are observed at 2.615 um (13CH4), 4.33 um (12CH3D), and 4.57 um (12CH3D). These bands enable us to measure D/H ratios of (2.5 +/- 0.5) x 10-4 and (2.9 +/- 0.6) x 10-4, along with 13C/12C ratios of 0.012 +/- 0.002 and 0.010 +/- 0.003 in the surface methane ices of Eris and Makemake, respectively. The measured D/H ratios are much lower than that of presumably primordial methane in comet 67P/Churyumov-Gerasimenko, but they are similar to D/H ratios in water in many comets and larger outer solar system objects. This similarity suggests that the hydrogen atoms in methane on Eris and Makemake originated from water, indicative of geochemical processes in past or even ongoing hot environments in their deep interiors. The 13C/12C ratios are consistent with commonly observed solar system values, suggesting no substantial enrichment in 13C as could happen if the methane currently on their surfaces was the residue of a much larger inventory that had mostly been lost to space. Possible explanations include geologically recent outgassing from the interiors as well as processes that cycle the surface methane inventory to keep the uppermost surfaces refreshed.