Search

Nitrogen-bearing complex organic molecules have been commonly detected in the gas phase but not yet in interstellar ices. This has led to the long-standing question of whether these molecules form in the gas phase or in ices. $\textit{James Webb}$ Space Telescope ($\textit{JWST}$) offers the sensitivity, spectral resolution, and wavelength coverage needed to detect them in ices and investigate whether their abundance ratios are similar in gas and ice. We report the first tentative detection of CH$_3$CN, C$_2$H$_5$CN, and the simple molecule, N$_2$O, based on the CN-stretch band in interstellar ices toward three (HOPS 153, HOPS 370, and IRAS 20126+4104) out of the five protostellar systems observed as part of the Investigating Protostellar Accretion (IPA) GO program with $\textit{JWST}$-NIRSpec. We also provide upper limits for the two other sources with smaller luminosities in the sample. We detect OCN$^-$ in the ices of all sources with typical CH$_3$CN/OCN$^-$ ratios of around 1. Ice and gas column density ratios of the nitrogen-bearing species with respect to each other are better matched than those with respect to methanol, which are a factor of ${\sim}5$ larger in the ices than the gas. We attribute the elevated ice column densities with respect to methanol to the difference in snowline locations of nitrogen-bearing molecules and of methanol, biasing the gas-phase observations toward fewer nitrogen-bearing molecules. Moreover, we find tentative evidence for enhancement of OCN$^-$, CH$_3$CN, and C$_2$H$_5$CN in warmer ices, although formation of these molecules likely starts along with methanol in the cold prestellar phase. Future surveys combining NIRSpec and MIRI, and additional laboratory spectroscopic measurements of C$_2$H$_5$CN ice, are necessary for robust detection and conclusions on the formation history of complex cyanides., Comment: Accepted for publication in A&A

We present the results of a sensitive search for high-velocity gas in interstellar absorption lines associated with the Cygnus Loop supernova remnant (SNR). We examine high-resolution, high signal-to-noise ratio optical spectra of six stars in the Cygnus Loop region with distances greater than ~700 pc. All stars show low-velocity Na I and Ca II absorption. However, only one star, HD 198301, exhibits high-velocity Ca II absorption components, at velocities of +62, +82, and +96 km/s. The distance to this star of ~870 pc helps to constrain the distance to the receding edge of the Cygnus Loop's expanding shock front. One of our targets, HD 335334, was previously thought to exhibit high positive and high negative velocity interstellar Na I and Ca II absorption. This was one factor leading Fesen et al. to derive a distance to the Cygnus Loop of 725 pc. However, we find that HD 335334 is in fact a double-line spectroscopic binary and shows no evidence of high-velocity interstellar absorption. As such, the distance to HD 335334 cannot be used to constrain the distance to the Cygnus Loop. Our detection of Ca II absorption approaching 100 km/s toward HD 198301 is the first conclusive detection of high-velocity absorption from a low ionization species associated with the Cygnus Loop SNR. A large jump in the Na I column density toward BD+31 4218, a star located beyond the northwestern boundary of the Cygnus Loop, helps to constrain the distance to a large molecular cloud complex with which the Cygnus Loop is evidently interacting., Comment: 14 pages, 14 figures, submitted to MNRAS

In this investigation, we present an analysis of the metallicity distribution that pertains to neutral gas in the local Galactic interstellar medium (ISM). We derive relative ISM metallicities for a sample of 84 sight lines probing diffuse atomic and molecular gas within 4 kpc of the Sun. Our analysis is based, in large part, on column density measurements reported in the literature for 22 different elements that are commonly studied in interstellar clouds. We supplement the literature data with new column density determinations for certain key elements and for several individual sight lines important to our analysis. Our methodology involves comparing the relative gas-phase abundances of many different elements for a given sight line to simultaneously determine the strength of dust depletion in that direction and the overall metallicity offset. We find that many sight lines probe multiple distinct gas regions with different depletion properties, which complicates the metallicity analysis. Nevertheless, our results provide clear evidence that the dispersion in the metallicities of neutral interstellar clouds in the solar neighborhood is small ($\sim$0.10 dex) and only slightly larger than the typical measurement uncertainties. We find no evidence for the existence of very low metallicity gas (as has recently been reported by De Cia et al.) along any of the 84 sight lines in our sample. Our results are consistent with a local Galactic ISM that is well mixed and chemically homogeneous., Comment: 34 pages, 14 figures, accepted for publication in ApJ

We present a comprehensive examination of interstellar P and Cl abundances based on an analysis of archival spectra acquired with the Space Telescope Imaging Spectrograph of the Hubble Space Telescope and the Far Ultraviolet Spectroscopic Explorer. Column densities of P II, Cl I, and Cl II are determined for a combined sample of 107 sight lines probing diffuse atomic and molecular gas in the local Galactic interstellar medium (ISM). We reevaluate the nearly linear relationship between the column densities of Cl I and H$_2$, which arises from the rapid conversion of Cl$^+$ to Cl$^0$ in regions where H$_2$ is abundant. Using the observed total gas-phase P and Cl abundances, we derive depletion parameters for these elements, adopting the methodology of Jenkins. We find that both P and Cl are essentially undepleted along sight lines showing the lowest overall depletions. Increasingly severe depletions of P are seen along molecule-rich sight lines. In contrast, gas-phase Cl abundances show no systematic variation with molecular hydrogen fraction. However, enhanced Cl (and P) depletion rates are found for a subset of sight lines showing elevated levels of Cl ionization. An analysis of neutral chlorine fractions yields estimates for the amount of atomic hydrogen associated with the H$_2$-bearing gas in each direction. These results indicate that the molecular fraction in the H$_2$-bearing gas is at least 10% for all sight lines with $\log N({\rm H}_2)\gtrsim18$ and that the gas is essentially fully molecular at $\log N({\rm H}_2)\approx21$., Comment: 44 pages, 21 figures, accepted for publication in ApJ

Photodissociation is one of the main destruction pathways for dicarbon (C$_{2}$) in astronomical environments such as diffuse interstellar clouds, yet the accuracy of modern astrochemical models is limited by a lack of accurate photodissociation cross sections in the vacuum ultraviolet range. C$_{2}$ features a strong predissociative $F\,^1\Pi_u - X\,^1\Sigma_g^+$ electronic transition near 130 nm originally measured in 1969; however, no experimental studies of this transition have been carried out since, and theoretical studies of the $F\,^1\Pi_u$ state are limited. In this work, potential energy curves of excited electronic states of C$_{2}$ are calculated with the aim of describing the predissociative nature of the $F\,^1\Pi_u$ state and providing new ab initio photodissociation cross sections for astrochemical applications. Accurate electronic calculations of 56 singlet, triplet, and quintet states are carried out at the DW-SA-CASSCF/MRCI+Q level of theory with a CAS(8,12) active space and the aug-cc-pV5Z basis set augmented with additional diffuse functions. Photodissociation cross sections arising from the vibronic ground state to the $F\,^1\Pi_u$ state are calculated by a coupled-channel model. The total integrated cross section through the $F\,^1\Pi_u$ $v=0$ and $v=1$ bands is 1.198$\times$10$^{-13} $cm$^2$cm$^{-1}$, giving rise to a photodissociation rate of 5.02$\times$10$^{-10}$ s$^{-1}$ under the standard interstellar radiation field, much larger than the rate in the Leiden photodissociation database. In addition, we report a new $2\,^1\Sigma_u^+$ state that should be detectable via a strong $2\,^1\Sigma_u^+-X\,^1\Sigma_g^+$ band around 116 nm., Comment: 33 pages, 13 figures; Accepted by The Journal of Chemical Physics

The high-resolution B$^1\Sigma^+$ - A$^1\Pi$ (0, 0) and (0, 3) emission bands of the less-abundant $^{13}$C$^{17}$O isotopologue have been investigated by Fourier-transform spectroscopy in the visible region using a Bruker IFS 125HR spectrometer at an accuracy 0.003 cm$^{-1}$. These spectra are combined with high-resolution photoabsorption measurements of the $^{13}$C$^{17}$O B$^1\Sigma^+$ $\leftarrow$ X$^1\Sigma^+$ (0, 0), B$^1\Sigma^+$ $\leftarrow$ X$^1\Sigma^+$ (1, 0) and C$^1\Sigma^+$ $\leftarrow$ X$^1\Sigma^+$ (0, 0) bands recorded with an accuracy of 0.01 cm$^{-1}$ using the vacuum ultraviolet Fourier-transform spectrometer, installed on the DESIRS beamline at the SOLEIL synchrotron. In the studied 17,950 - 22,500 cm$^{-1}$ and 86,800 - 92,100 cm$^{-1}$ regions, 480 transitions have been measured. These new experimental data were combined with data from the C $\to$ A and B $\to$ A systems, previously analyzed in 13C17O. The frequencies of 1003 transitions derived from 12 bands were used to analyze the perturbations between the A$^1\Pi$ ($\nu$ = 0 - 3) levels and rovibrational levels of the d$^3\Delta_i$, e$^3\Sigma^-$, a$'{}^3\Sigma^+$, I$^1\Sigma^-$ and D$^1\Delta$ states as well as to a preliminary investigation of weak irregularities that appear in the B$^1\Sigma^+$ ($\nu$ = 0) level. Deperturbed molecular constants and term values of the A$^1\Pi$ state were obtained. The spin-orbit and L-uncoupling interaction parameters as well as isotopologue-independent spin-orbit and rotation-electronic perturbation parameters were derived., Comment: 37 pages, 8 tables, 7 figures, 91 references

We study four lines of sight that probe the transition from diffuse molecular gas to molecular cloud material in Taurus. Measurements of atomic and molecular absorption are used to infer the distribution of species and the physical conditions toward stars behind the Taurus Molecular Cloud (TMC). New high-resolution spectra at visible and near infrared wavelengths of interstellar Ca II, Ca I, K I, CH, CH^+, C2, CN, and CO toward HD28975 and HD29647 are combined with data at visible wavelengths and published CO results from ultraviolet measurements for HD27778 and HD30122. Gas densities and temperatures are inferred from C2, CN, and CO excitation and CN chemistry. Our results for HD29647 are noteworthy because the CO column density is 10^{18} cm^{-2} while C2 and CO excitation reveals a temperature of 10 K and density about 1000 cm^{-3}, more like conditions found in dark molecular clouds. Similar results arise from our chemical analysis for CN through reactions involving observations of CH, C2, and NH. Enhanced potassium depletion and a reduced CH/H2 column density ratio also suggest the presence of a dark cloud. The directions toward HD27778 and HD30122 probe molecule-rich diffuse clouds, which can be considered CO-dark gas, while the sight line toward HD28975 represents an intermediate case. Maps of dust temperature help refine the description of the material along the four sight lines and provide an estimate of the distance between HD29647 and a clump in the TMC. An Appendix provides results for the direction toward HD26571; this star also probes diffuse molecular gas., Comment: 11 figures, 14 tables, 75 pages; higher quality maps appear in the published version

We present lifetime measurements using beam-foil techniques for radiative transitions from the 3$p^4$($^1S$)4$s$ $^2S_{1/2}$, 3$p^4$($^3P$)5$s$ $^2P_{1/2,3/2}$, and 3$p^4$($^3P$)3$d$ $^2F_{5/2}$ levels in Cl I and the corresponding results of the oscillator strengths for transitions at 1004.68, 1079.88, 1090.73, and 1094.77 \AA, respectively. We compare our experimental results with available theoretical calculations and astronomical observations in an effort to resolve discrepancies among them., Comment: 8 pages, 4 figures

We present results of our Chandra/ACIS observations of the field centered on the fast, runaway O star AE Aur and its bow shock. Previous XMM-Newton observations revealed an X-ray "blob" near the IR arc tracing the bow shock, possibly a nonthermal source consistent with models of Inverse Compton scattering of dust IR photons by electrons accelerated at the shock. The new, subarcsecond resolution Chandra data, while confirming the presence of the XMM-Newton source, clearly indicate that the latter is neither extended nor coincident with the IR arc and strongly suggest it is a background AGN. Motivated by results published for the bow shock of BD+43 3654, we extended our study to the radio domain, by analyzing archival EVLA data. We find no radio emission from the AE Aur bow shock either. The corresponding upper limits for the absorbed (unabsorbed) X-ray flux of 5.9(7.8)x10^-15 erg/cm^2/s (3 sigma) and, in the radio range, of 2 mJy (1.4 GHz), and 0.4 mJy (5.0 GHz), are used to put constraints on model predictions for particle acceleration within the bow shock. In the "classical" framework of Diffusive Shock Acceleration, we find that the predicted X-ray and radio emission by the bow shock is at least two orders of magnitude below the current upper limits, consistent with the systematic non-detections of up to 60 stellar bow shocks. The only exception so far remains that of BD+43 3654, probably the result of its very large mass-loss rate among runaway O stars., Comment: Accepted for publication in ApJ

Photodissociation by ultraviolet radiation is the key destruction pathway for CS in photon-dominated regions, such as diffuse clouds. However, the large uncertainties of photodissociation cross sections and rates of CS, resulting from a lack of both laboratory experiments and theoretical calculations, limit the accuracy of calculated abundances of S-bearing molecules by modern astrochemical models. Here we show a detailed \textit{ab initio} study of CS photodissociation. Accurate potential energy curves of CS electronic states were obtained by choosing an active space CAS(8,10) in MRCI+Q/aug-cc-pV(5+d)Z calculation with additional diffuse functions, with a focus on the \(B\) and \(C\,^1\Sigma^+\) states. Cross sections for both direct photodissociation and predissociation from the vibronic ground state were calculated by applying the coupled-channel method. We found that the \(C-X\) \((0-0)\) transition has extremely strong absorption due to a large transition dipole moment in the Franck-Condon region and the upper state is resonant with several triplet states via spin-orbit couplings, resulting in predissociation to the main atomic products C \((^3P)\) and S \((^1D)\). Our new calculations show the photodissociation rate under the standard interstellar radiation field is \(2.9\ee{-9}\)\,s\(^{-1}\), with a 57\% contribution from \(C-X\) \((0-0)\) transition. This value is larger than that adopted by the Leiden photodissociation and photoionization database by a factor of 3.0. Our accurate \textit{ab initio} calculations will allow more secure determination of S-bearing molecules in astrochemical models., Comment: 23 pages, 14 figures

We report lifetimes, branching fractions, and the resulting oscillator strengths for transitions within the P II multiplet (3s23p2 3P - 3s3p3 3Po) at 1308 {\AA}. These comprehensive beam-foil measurements, which are the most precise set currently available experimentally, resolve discrepancies involving earlier experimental and theoretical results. Interstellar phosphorus abundances derived from {\lambda}1308 can now be interpreted with greater confidence. In the course of our measurements, we also obtained an experimental lifetime for the 3p4s 3P0o level of P IV. This lifetime agrees well with the available theoretical calculation., Comment: 10 pages, 3 figures

Using visible, radio, microwave, and sub-mm data, we study several lines of sight toward stars generally closer than 1 kpc on a component-by-component basis. We derive the component structure seen in absorption at visible wavelengths from Ca II, Ca I, K I, CH, CH$^{+}\!,$ and CN and compare it to emission from H I, CO and its isotopologues, and C$^{+}$ from the GOT C+ survey. The correspondence between components in emission and absorption help create a more unified picture of diffuse atomic and molecular gas in the interstellar medium. We also discuss how these tracers are related to the CO-dark H$_{2}$ gas probed by C$^{+}$ emission and discuss the kinematic connections among the species observed., Comment: To be published in ApJ

Measurements of the lithium isotopic ratio in the diffuse interstellar medium from high-resolution spectra of the LiI {\lambda}6708 resonance doublet have now been reported for a number of lines of sight. The majority of the results for the 7Li/6Li ratio are similar to the Solar System ratio of 12.2 but the line of sight toward o Per, a star near the star-forming region IC 348, gave a ratio of about 2, the expected value for gas exposed to spallation and fusion reactions driven by cosmic rays. To examine the association of IC 348 with cosmic rays more closely, we measured the lithium isotopic ratio for lines of sight to three stars within a few parsecs of o Per. One star, HD 281159, has 7Li/6Li ~ 2 confirming production by cosmic rays. The lithium isotopic ratio toward o Per and HD 281159 together with published analyses of the chemistry of interstellar diatomic molecules suggest that the superbubble surrounding IC 348 is the source of the cosmic rays., Comment: 19 pages, 1 figure and two tables

Lifetime measurements using beam foil techniques for the $5s5p^{2}$ $^{2}D_{3/2,5/2}$ levels in Sn II are presented. The resulting oscillator strengths for transitions at 1699.4, 1831.8 and 1811.2 \AA{} are reported. We also studied these levels with multi-configuration Dirac Hartree-Fock (MCDHF) calculations using a development version of the GRASP2K package. Our experimental and theoretical results are compared with other available studies.

Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for high enough density and molecular fraction before detectable amounts are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds., Comment: 15 pages, 4 figures, to appear in ApJ Letters

We analyzed archival spectra acquired with the Hubble Space Telescope for a study of interstellar C2. Absorption from the electronic transitions, D ^1Sigma^+_u -- X ^1Sigma^+_g (0,0) as well as F ^1Pi_u -- X ^1Sigma^+_g (0,0) and (1,0), was the focus of the study. Our profile syntheses revealed that the lines of the F-X bands were broadened as a result of a perturbation involving the upper levels. Further evidence for the perturbation came from anomalies in line strength and position for the F-X (0,0) band. The perturbation likely arises from a combination of triplet-singlet interactions involving spin-orbit mixing between ^3Pi_u states and F ^1Pi_u and an avoided crossing between the ^3Pi_u states. Tunneling through a potential barrier caused by the 3 and 4 ^1Pi_u states and spin-orbit mixing with other close-lying triplet states of ungerade symmetry are less likely. Except for the broadening, lines in the F-X (1,0) band appear free from anomalies and can be used to study interstellar C2; new results for 10 sight lines are presented., Comment: 17 pages, 3 tables, 3 figures, to appear in ApJ

We present an analysis of 7Li/6Li isotope ratios along four sight lines that probe diffuse molecular gas near the supernova remnant IC 443. Recent gamma-ray observations have revealed the presence of shock-accelerated cosmic rays interacting with the molecular cloud surrounding the remnant. Our results indicate that the 7Li/6Li ratio is lower in regions more strongly affected by these interactions, a sign of recent Li production by cosmic rays. We find that 7Li/6Li ~ 7 toward HD 254755, which is located just outside the visible edge of IC 443, while 7Li/6Li ~ 3 along the line of sight to HD 43582, which probes the interior region of the supernova remnant. No evidence of 7Li synthesis by neutrino-induced spallation is found in material presumably contaminated by the ejecta of a core-collapse supernova. The lack of a neutrino signature in the 7Li/6Li ratios near IC 443 is consistent with recent models of Galactic chemical evolution, which suggest that the nu-process plays only a minor role in Li production., Comment: 7 pages, 4 figures, emulateapj style, accepted for publication in ApJ Letters

An emerging theme in modern astrophysics is the connection between astronomical observations and the underlying physical phenomena that drive our cosmos. Both the mechanisms responsible for the observed astrophysical phenomena and the tools used to probe such phenomena - the radiation and particle spectra we observe - have their roots in atomic, molecular, condensed matter, plasma, nuclear and particle physics. Chemistry is implicitly included in both molecular and condensed matter physics. This connection is the theme of the present report, which provides a broad, though non-exhaustive, overview of progress in our understanding of the cosmos resulting from recent theoretical and experimental advances in what is commonly called laboratory astrophysics. This work, carried out by a diverse community of laboratory astrophysicists, is increasingly important as astrophysics transitions into an era of precise measurement and high fidelity modeling., Comment: 61 pages. 11 figures; to appear in Reports on Progress in Physics

We reanalyzed interstellar Cl I and Cl II spectra acquired with the Copernicus satellite. The directions for this study come from those of Crenny & Federman and sample the transition from atomic to molecular rich clouds where the unique chemistry leading to molecules containing chlorine is initiated. Our profile syntheses relied on up-to-date laboratory oscillator strengths and component structures derived from published high-resolution measurements of K I absorption that were supplemented with Ca II and Na I D results. We obtain self-consistent results for the Cl I lines at 1088, 1097, and 1347 A from which precise column densities are derived. The improved set of results reveals clearer correspondences with H2 and total hydrogen column densities. These linear relationships arise from rapid conversion of Cl^+ to Cl^0 in regions where H2 is present., Comment: 17 pp, 2 tables, and 3 figures, to appear in The Astrophysical Journal

We present a comprehensive survey of boron abundances in diffuse interstellar clouds from observations made with the Space Telescope Imaging Spectrograph (STIS) of the Hubble Space Telescope. Our sample of 56 Galactic sight lines is the result of a complete search of archival STIS data for the B II 1362 resonance line, with each detection confirmed by the presence of absorption from O I 1355, Cu II 1358, and Ga II 1414 (when available) at the same velocity. Five previous measurements of interstellar B II from Goddard High Resolution Spectrograph observations are incorporated in our analysis, yielding a combined sample that more than quadruples the number of sight lines with significant boron detections. Our survey also constitutes the first extensive analysis of interstellar gallium from STIS spectra and expands on previously published results for oxygen and copper. The observations probe both high and low-density diffuse environments, allowing the density-dependent effects of interstellar depletion to be clearly identified in the gas-phase abundance data for each element. In the case of boron, the increase in relative depletion with line-of-sight density amounts to an abundance difference of 0.8 dex between the warm and cold phases of the diffuse interstellar medium. The abundance of boron in warm, low-density gas is found to be B/H = (2.4+/-0.6)*10^-10, which represents a depletion of 60% relative to the meteoritic boron abundance. Beyond the effects of depletion, our survey reveals sight lines with enhanced boron abundances that potentially trace the recent production of 11B, resulting from spallation reactions involving either cosmic rays or neutrinos. Future observations will help to disentangle the relative contributions from the two spallation channels for 11B synthesis., Comment: 42 pages, 18 figures, emulateapj style, accepted for publication in ApJ

We present very high signal-to-noise ratio absorption-line observations of CN and CH+ along 13 lines of sight through diffuse molecular clouds. The data are examined to extract precise isotopologic ratios of 12CN/13CN and 12CH+/13CH+ in order to assess predictions of diffuse cloud chemistry. Our results on 12CH+/13CH+ confirm that this ratio does not deviate from the ambient 12C/13C ratio in local interstellar clouds, as expected if the formation of CH+ involves nonthermal processes. We find that 12CN/13CN, however, can be significantly fractionated away from the ambient value. The dispersion in our sample of 12CN/13CN ratios is similar to that found in recent surveys of 12CO/13CO. For sight lines where both ratios have been determined, the 12CN/13CN ratios are generally fractionated in the opposite sense compared to 12CO/13CO. Chemical fractionation in CO results from competition between selective photodissociation and isotopic charge exchange. An inverse relationship between 12CN/13CN and 12CO/13CO follows from the coexistence of CN and CO in diffuse cloud cores. However, an isotopic charge exchange reaction with CN may mitigate the enhancements in 12CN/13CN for lines of sight with low 12CO/13CO ratios. For two sight lines with high values of 12CO/13CO, our results indicate that about 50 percent of the carbon is locked up in CO, which is consistent with the notion that these sight lines probe molecular cloud envelopes where the transition from C+ to CO is expected to occur. An analysis of CN rotational excitation yields a weighted mean value for T_01(12CN) of 2.754 +/- 0.002 K, which implies an excess over the temperature of the cosmic microwave background of only 29 +/- 3 mK. This modest excess eliminates the need for a local excitation mechanism beyond electron and neutral collisions. The rotational excitation temperatures in 13CN show no excess over the temperature of the CMB., Comment: 27 pages, 21 figures, emulateapj style, accepted for publication in ApJ

We present a comprehensive survey of B abundances in diffuse interstellar clouds from HST/STIS observations along 56 Galactic sight lines. Our sample is the result of a complete search of archival STIS data for the B II resonance line at 1362 angstroms, with each detection confirmed by the presence of absorption from other dominant ions at the same velocity. The data probe a range of astrophysical environments including both high-density regions of massive star formation as well as low-density paths through the Galactic halo, allowing us to clearly define the trend of B depletion onto interstellar grains as a function of gas density. Many extended sight lines exhibit complex absorption profiles that trace both local gas and gas associated with either the Sagittarius-Carina or Perseus spiral arm. Our analysis indicates a higher B/O ratio in the inner Sagittarius-Carina spiral arm than in the vicinity of the Sun, which may suggest that B production in the current epoch is dominated by a secondary process. The average gas-phase B abundance in the warm diffuse ISM is consistent with the abundances determined for a variety of Galactic disk stars, but is depleted by 60 percent relative to the solar system value. Our survey also reveals sight lines with enhanced B abundances that potentially trace recent production of B-11 either by cosmic-ray or neutrino-induced spallation. Such sight lines will be key to discerning the relative importance of the two production routes for B-11 synthesis., Comment: To be published in the proceedings of the IAU Symposium 268, Light Elements in the Universe, C. Charbonnel, M. Tosi, F. Primas & C. Chiappini, eds

We present observations of interstellar rubidium toward o Per, zeta Per, AE Aur, HD 147889, chi Oph, zeta Oph, and 20 Aql. Theory suggests that stable 85Rb and long-lived 87Rb are produced predominantly by high-mass stars, through a combination of the weak s- and r-processes. The 85Rb/87Rb ratio was determined from measurements of the Rb I line at 7800 angstroms and was compared to the solar system meteoritic ratio of 2.59. Within 1-sigma uncertainties all directions except HD 147889 have Rb isotope ratios consistent with the solar system value. The ratio toward HD 147889 is much lower than the meteoritic value and similar to that toward rho Oph A (Federman et al. 2004); both lines of sight probe the Rho Ophiuchus Molecular Cloud. The earlier result was attributed to a deficit of r-processed 85Rb. Our larger sample suggests instead that 87Rb is enhanced in these two lines of sight. When the total elemental abundance of Rb is compared to the K elemental abundance, the interstellar Rb/K ratio is significantly lower than the meteoritic ratio for all the sight lines in this study. Available interstellar samples for other s- and r- process elements are used to help interpret these results., Comment: 24 pages, 3 figures. Accepted for publication in ApJ

We present an analysis of results on absorption from Ca II, Ca I, K I, and the molecules CH+, CH, C2, and CN that probes gas interacting with the supernova remnant IC443. The eleven directions sample material across the visible nebula and beyond its eastern edge. Most of the neutral material, including the diatomic molecules, is associated with the ambient cloud detected via H I and CO emission. Analysis of excitation and chemistry yields gas densities that are typical of diffuse molecular gas. The low density gas probed by Ca II extends over a large range in velocities, from -120 to +80 km/s in the most extreme cases. This gas is distributed among several velocity components, unlike the situation for the shocked molecular clumps, whose emission occurs over much the same range but as very broad features. The extent of the high-velocity absorption suggests a shock velocity of 100 km/s for the expanding nebula., Comment: To be published in ApJ

The runaway star HD34078, initially selected to investigate small scale structure in a foreground diffuse cloud has been shown to be surrounded by highly excited H2. We first search for an association between the foreground cloud and HD34078. Second, we extend previous investigations of temporal absorption line variations (CH, CH+, H2) in order to better characterize them. We have mapped the CO(2-1) emission at 12 arcsec resolution around HD34078's position, using the 30 m IRAM antenna. The follow-up of CH and CH+ absorption lines has been extended over 5 more years. In parallel, CH absorption towards the reddened star Zeta Per have been monitored to check the homogeneity of our measurements. Three more FUSE spectra have been obtained to search for N(H2) variations. CO observations show a pronounced maximum near HD34078's position, clearly indicating that the star and diffuse cloud are associated. The optical spectra confirm the reality of strong, rapid and correlated CH and CH+ fluctuations. On the other hand, N(H2, J=0) has varied by less than 5 % over 4 years. We also discard N(CH) variations towards Zeta Per at scales less than 20 AU. Observational constraints from this work and from 24 micron dust emission appear to be consistent with H2 excitation but inconsistent with steady-state bow shock models and rather suggest that the shell of compressed gas surrounding HD34078, is seen at an early stage of the interaction. The CH and CH+ time variations as well as their large abundances are likely due to chemical structure in the shocked gas layer located at the stellar wind/ambient cloud interface. Finally, the lack of variations for both N(H2, J=0) towards HD34078 and N(CH) towards Zeta Per suggests that quiescent molecular gas is not subject to pronounced small-scale structure., Comment: 19 pages, 15 figures, accepted for publication in A&A

(Abridged) We carried out a comprehensive far-ultraviolet (UV) survey of ^12CO and H_2 column densities along diffuse molecular Galactic sight lines in order to explore in detail the relationship between CO and H_2. We measured new CO abundances from HST spectra, new H_2 abundances from FUSE data, and new CH, CH^+, and CN abundances from the McDonald and European Southern Observatories. A plot of log N(CO) versus log N(H_2) shows that two power-law relationships are needed for a good fit of the entire sample, with a break located at log N(CO, cm^-2) = 14.1 and log N(H_2) = 20.4, corresponding to a change in production route for CO in higher-density gas. Similar logarithmic plots among all five diatomic molecules allow us to probe their relationships, revealing additional examples of dual slopes in the cases of CO versus CH (break at log N = 14.1, 13.0), CH^+ versus H_2 (13.1, 20.3), and CH^+ versus CO (13.2, 14.1). These breaks are all in excellent agreement with each other, confirming the break in the CO versus H_2 relationship, as well as the one-to-one correspondence between CH and H_2 abundances. Our new sight lines were selected according to detectable amounts of CO in their spectra and they provide information on both lower-density (< 100 cm^-3) and higher-density diffuse clouds. The CO versus H_2 correlation and its intrinsic width are shown to be empirically related to the changing total gas density among the sight lines of the sample. We employ both analytical and numerical chemical schemes in order to derive details of the molecular environments. In the low-density gas, where equilibrium-chemistry studies have failed to reproduce the abundance of CH^+, our numerical analysis shows that nonequilibrium chemistry must be employed for correctly predicting the abundances of both CH^+ and CO., Comment: 40 pages in emulateapj style, to appear in the Astrophysical Journal

Recent laboratory measurements for the S^+2 + H2 reaction find a total rate coefficient significantly larger than previously used in theoretical models of X-ray dominated regions (XDRs). While the branching ratio of the products is unknown, one energetically possible route leads to the SH+ molecule, a known XDR diagnostic. In this work, we study the effects of S^+2 on the formation of SH+ and the destruction of S^+2 in XDRs. We find the predicted SH+ column density for molecular gas surrounding an Active Galactic Nucleus (AGN) increases by as much as 2 dex. As long as the branching ratio for S^+2 + H2 -> SH+ + H+ exceeds a few percent, doubly ionized chemistry will be the dominant pathway to SH+, which then initiates the formation of other sulfur-bearing molecules. We also find that the high rate of S^+2 + H2 efficiently destroys S^+2 once H2 forms, while the S^+2 abundance remains high in the atomic hydrogen region. We discuss the possible consequences of S^+2 in the atomic hydrogen region on mid-infrared diagnostics. The enhanced SH+ abundance has important implications in the study of XDRs, while our conclusions for S^+2 could potentially impact the interpretation of Spitzer and SOFIA observations., Comment: 19 pages, 3 figures, Accepted for Publication in ApJ Letters

We examine 20 diffuse and translucent Galactic sight lines and extract the column densities of the ^12CO and ^13CO isotopologues from their ultraviolet A--X absorption bands detected in archival Space Telescope Imaging Spectrograph data with lambda/Deltalambda geq 46,000. Five more targets with Goddard High-Resolution Spectrograph data are added to the sample that more than doubles the number of sight lines with published Hubble Space Telescope observations of ^13CO. Most sight lines have 12-to-13 isotopic ratios that are not significantly different from the local value of 70 for ^12C/^13C, which is based on mm-wave observations of rotational lines in emission from CO and H_2CO inside dense molecular clouds, as well as on results from optical measurements of CH^+. Five of the 25 sight lines are found to be fractionated toward lower 12-to-13 values, while three sight lines in the sample are fractionated toward higher ratios, signaling the predominance of either isotopic charge exchange or selective photodissociation, respectively. There are no obvious trends of the ^12CO-to-^13CO ratio with physical conditions such as gas temperature or density, yet ^12CO/^13CO does vary in a complicated manner with the column density of either CO isotopologue, owing to varying levels of competition between isotopic charge exchange and selective photodissociation in the fractionation of CO. Finally, rotational temperatures of H_2 show that all sight lines with detected amounts of ^13CO pass through gas that is on average colder by 20 K than the gas without ^13CO. This colder gas is also sampled by CN and C_2 molecules, the latter indicating gas kinetic temperatures of only 28 K, enough to facilitate an efficient charge exchange reaction that lowers the value of ^12CO/^13CO., Comment: 1-column emulateapj, 23 pages, 9 figures

We report lifetimes, branching fractions, and the resulting oscillator strengths for transitions within the P II multiplet (3s^23p^2 ^3P - 3s^23p4s ^3P^o) at 1154 A. These beam-foil measurements represent the most comprehensive and precise set currently available experimentally. Comparison with earlier experimental and theoretical results is very good. Since Morton's most recent compilation is based on the earlier body of results, phosphorus abundances for interstellar material in our Galaxy and beyond derived from lambda 1154 do not require any revision., Comment: 10 pages, 2 figures; to be published in ApJ

Three interstellar absorption lines near 1370 A seen toward zeta Oph have been assigned by Watson to Rydberg transitions in the G-X (or 3d-X) band of CH. Our survey of a dozen diffuse interstellar lines of sight shows that the three absorption lines are consistent with the known column densities of CH, by deriving the following oscillator strengths: f(1368.74) = 0.019 +/- 0.003, f(1369.13) = 0.030 +/- 0.005, and f(1370.87) = 0.009 +/- 0.001. We also determined intrinsic line widths that correspond to decay rates of (1.5 +/- 0.6) x 10^11 s^-1, (3.8 +/- 0.7) x 10^11 s^-1, and (1.1 +/- 0.6) x 10^10 s^-1 for lambdalambda 1368, 1369, and 1370, respectively. These rates are significantly higher than those associated with radiative decays, and thus are readily attributable to predissociation of the Rydberg state. A fourth interstellar line near 1271 A has been conjectured by Watson to be the strongest transition in the 4d-X Rydberg band of CH. We detected this line along four sight lines and our spectrum syntheses show that with f(1271.02) = 0.007 +/- 0.002, it is also consistent with the known column densities of CH. In addition, we conducted a search for the F-X band of CH near 1549 A, and successfully discovered two of its absorption features along four sight lines. The astronomical oscillator strengths derived for these features are f(1549.05) = 0.021 +/- 0.006 and f(1549.62) = 0.013 +/- 0.003. Finally, the X Per sight line provided us with an astronomical detection of another CH band, via two D-X features near 1694 A. Comparisons with results of available theoretical calculations for the four CH bands are presented., Comment: 10 pages, emulateapj style

We present high-resolution, high signal to noise absorption-line observations of CN, Ca II, Ca I, CH^+, and CH along twenty lines of sight toward members of the Pleiades. The acquired data enable the most detailed study to date of the interaction between cluster stars and the surrounding interstellar gas. Total equivalent widths are consistent with previous investigations except where weaker features are detected owing to our greater sensitivity. Mean b-values for the molecular species indicate that toward most of the Pleiades CH is associated with the production of CH^+ rather than CN. An analysis of radial velocities reveals a kinematic distinction between ionized atomic gas and molecular and neutral gas. Molecular components are found with velocities in the local standard of rest of either ~ +7 km s^-1 or ~ +9.5 km s^-1, with the higher-velocity components associated with the strongest absorption. Atomic gas traced by Ca II shows a strong central component at v_LSR ~ +7 km s^-1 exhibiting velocity gradients indicative of cloud-cluster interactions. Gas density estimates derived from measured CH/CH^+ column density ratios show good agreement with those inferred from H_2 rotational populations, yielding typical values of n ~ 50 cm^-3. Our models do not include the important time-dependent effects on CH^+ formation which may ultimately be needed to extract physical conditions in these clouds., Comment: 18 pages, 10 figures, emulateapj style, Accepted for publication in ApJ

One of the processes controlling the interstellar CO abundance and the ratio of its isotopologues is photodissociation. Accurate oscillator strengths and predissociation rates for Rydberg transitions are needed for modeling this process. We present results on absorption from the E ^1Pi-X ^1Sigma^+ (1-0) and B ^1Sigma^+-X ^1Sigma^+ (6-0) bands at 1051 and 1002 \AA, respectively, and the vibrational progression W ^1Pi-X ^1Sigma^+ (v'-0) bands with v' = 0 to 3 at 972, 956, 941, and 925 \AA, respectively. The corresponding spectra were acquired at the high resolution (R ~ 30,000) SU5 beam line at the Super ACO Synchrotron in Orsay, France. Spectra were obtained for the ^12C^16O, ^13C^16O, and ^13C^18O isotopologues. These represent the most complete set of measurements available. Comparison is made with earlier results, both empirical and theoretical. While earlier determinations of oscillator strengths based on absorption from synchrotron radiation tend to be somewhat smaller than ours, the suite of measurements from a variety of techniques agree for the most part considering the mutual uncertainties. For the bands studied here, their relative weakness, or their significant line widths arising from predissociation, minimizes potential problems from large optical depths at line center in absorption measurements. Predissociating line widths could generally be extracted from the spectra thanks to the profile simulations used in the analysis. In many cases, these simulations allowed us to consider e and f parity levels separately and to determine the dependence of the width on rotational quantum number, J. Our results are consistent with earlier determinations, especially the widths inferred from laser experiments.

We discuss the abundances of interstellar CH, CH+, and CN in the Magellanic Clouds (MC), derived from spectra of 7 SMC and 13 LMC stars obtained (mostly) with the VLT/UVES. CH and/or CH+ are detected toward 3 SMC and 9 LMC stars; CN is detected toward 2 stars. In the MC, the CH/H2 ratio is comparable to that found for diffuse Galactic molecular clouds in some sight lines, but is lower by factors up to 10-15 in others. The abundance of CH in the MC thus appears to depend on local physical conditions -- and not just on metallicity. The observed relationships between the column density of CH and those of CN, CH+, Na I, and K I in the MC are generally consistent with the trends observed in our Galaxy. Using existing data for the rotational populations of H2, we estimate temperatures, radiation field strengths, and local hydrogen densities for the diffuse molecular gas. Densities estimated from N(CH), assuming that CH is produced via steady-state gas-phase reactions, are considerably higher; much better agreement is found by assuming that the CH is made via the (still undetermined) process(es) responsible for the observed CH+. The UVES spectra also reveal absorption from the diffuse interstellar bands at 5780, 5797, and 6284 A in the MC. On average, the three DIBs are weaker by factors of 7-9 (LMC) and about 20 (SMC), compared to those observed in Galactic sight lines with similar N(H I), and by factors of order 2-6, relative to E(B-V), N(Na I), and N(K I). The detection of several of the ``C2 DIBs'', with strengths similar to those in comparable Galactic sight lines, however, indicates that no single, uniform scaling factor (e.g., one related to metallicity) applies to all DIBs (or all sight lines) in the MC. (abstract abridged), Comment: 59 pages, 15 figures, 10 tables; aastex; accepted to ApJS

To complement the optical absorption-line survey of diffuse molecular gas in Paper I, we obtained and analyzed far ultraviolet H$_2$ and CO data on lines of sight toward stars in Cep OB2 and Cep OB3. Possible correlations between column densities of different species for individual velocity components, not total columns along a line of sight as in the past, were examined and were interpreted in terms of cloud structure. The analysis reveals that there are two kinds of CH in diffuse molecular gas: CN-like CH and CH$^+$-like CH. Evidence is provided that CO is also associated with CN in diffuse molecular clouds. Different species are distributed according to gas density in the diffuse molecular gas. Both calcium and potassium may be depleted onto grains in high density gas, but with different dependences on local gas density. Gas densities for components where CN was detected were inferred from a chemical model. Analysis of cloud structure indicates that our data are generally consistent with the large-scale structure suggested by maps of CO millimeter-wave emission. On small scales, the gas density is seen to vary by factors greater than 5.0 over scales of $\sim$ 10,000 AU. The relationships between column densities of CO and CH with that of H$_2$ along a line of sight show similar slopes for the gas toward Cep OB2 and OB3, but the CO/H$_2$ and CH/H$_2$ ratios tend to differ which we ascribe to variation in average density along the line of sight., Comment: 49 pages, 9 figures, accepted by ApJ

The source of fluorine is not well understood, although core-collapse supernovae, Wolf-Rayet stars, and asymptotic giant branch stars have been suggested. A search for evidence of the nu process during Type II supernovae is presented. Absorption from interstellar F I is seen in spectra of HD 208440 and HD 209339A acquired with the Far Ultraviolet Spectroscopic Explorer. In order to extract the column density for F I from the line at 954 A, absorption from H2 has to be modeled and then removed. Our analysis indicates that for H2 column densities less than about 3 x 10^20 cm^-2, the amount of F I can be determined from lambda 954. For these two sight lines, there is no clear indication for enhanced F abundances resulting from the nu process in a region shaped by past supernovae., Comment: 17 pages, 4 figures, accepted for publication in ApJ

Absorption oscillator strengths have been determined from high-resolution spectra in the 967-972 \AA region of three CO isotopomers for transitions to the Rydberg levels 4{\it p$\pi$}(0), 3{\it d$\pi$}(1) and 4{\it p$\sigma$}(0), as well as to the mixed {\it E(6)} level recently characterized by Eidelsberg et al. (2004). Synchrotron radiation from the Super-ACO electron storage ring at Orsay (LURE) was used as a light source. Oscillator strengths were extracted from the recorded spectra by least-squares fitting of the experimental profiles with synthetic spectra taking into account the homogeneous and heterogeneous interactions of the four levels. Column densities were derived from fits to the 3{\it p$\pi$}(0) absorption band whose oscillator strength is well established. These are the first reported measurements for $^{13}$C$^{18}$O. For $^{12}$C$^{16}$O, our results are consistent with the larger values obtained in the most recent laboratory and astronomical studies., Comment: 9 pages 7 figures 3 tables. Accepted in A&A, date of acceptance 11/05/2004

The isotope ratio, 85Rb/87Rb, places constraints on models of the nucleosynthesis of heavy elements, but there is no precise determination of the ratio for material beyond the Solar System. We report the first measurement of the interstellar Rb isotope ratio. Our measurement of the Rb I line at 7800 A for the diffuse gas toward rho Oph A yields a value of 1.21 +/- 0.30 (1-sigma) that differs significantly from the meteoritic value of 2.59. The Rb/K elemental abundance ratio for the cloud also is lower than that seen in meteorites. Comparison of the 85Rb/K and 87Rb/K ratios with meteoritic values indicates that the interstellar 85Rb abundance in this direction is lower than the Solar System abundance. We attribute the lower abundance to a reduced contribution from the r-process. Interstellar abundances for Kr, Cd, and Sn are consistent with much less r-process synthesis for the solar neighborhood compared to the amount inferred for the Solar System., Comment: 12 pages with 2 figures and 1 table; will appear in ApJ Letters

We used archival data acquired with the Copernicus satellite to reexamine CO column densities because self-consistent oscillator strengths are now available. Our focus is on lines of sight containing modest amounts of molecular species. Our resulting column densities are small enough that self-shielding from photodissociation is not occurring in the clouds probed by the observations. While our sample shows that the column densities of CO and H2 are related, no correspondence with the CH column density is evident. The case for the CH+ column density is less clear. Recent chemical models for these sight lines suggest that CH is mainly a by-product of CH+ synthesis in low density gas. The models are most successful in reproducing the amounts of CO in the densest sight lines. Thus, much of the CO absorption must arise from denser clumps along the line of sight to account for the trend with H2., Comment: 19 pages, 6 figures. Accepted for publication in ApJ

We present high-resolution optical spectra (at ~0.6--1.8 km s-1) of interstellar CN, CH, CH^+, \ion{Ca}{1}, \ion{K}{1}, and \ion{Ca}{2} absorption toward 29 lines of sight in three star-forming regions, \rho Oph, Cep OB2, and Cep OB3. The observations and data reduction are described. The agreement between earlier measurements of the total equivalent widths and our results is quite good. However, our higher resolution spectra reveal complex structure and closely blended components in most lines of sight. The velocity component structure of each species is obtained by analyzing the spectra of the six species for a given sight line together. The tabulated column densities and Doppler parameters of individual components are determined by using the method of profile fitting. Total column densities along lines of sight are computed by summing results from profile fitting for individual components and are compared with column densities from the apparent optical depth method. A more detailed analysis of these data and their implications will be presented in a companion paper., Comment: 66 pages, 15 figures, accepted to ApJS

We report the detection of 11 Rydberg bands of CO in FUSE spectra of the sight line toward HD203374A. Eight of these electronic bands are seen in the interstellar medium for the first time. Our simultaneous fit of five non-Rydberg A-X bands together with the strongest Rydberg band of CO, C-X (0-0), yields a 4-component cloud structure toward the stellar target. With this model we synthesize the other Rydberg bands in order to derive their oscillator strengths. We find that the strength of some bands was underestimated in previously published results from laboratory measurements. The implication is important for theoretical calculations of the abundance of interstellar CO, because its dissociation and self shielding depend on oscillator strengths for these bands., Comment: 11 pages, incl. 1 figure. Accepted for publication in ApJ Letters