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2. Stereoselective synthesis of Stannyl enones via palladium-catalyzed and free radical hydrostannation of alkynyl ketones with trineophyltin hydride

Author

Dodero, Veronica I., Koll, Liliana C., Faraoni, M. Belen, Mitchelle, Terence N., and Podesta, Julio C.

Subjects
Organic compounds -- Research, Biological sciences, Chemistry
Abstract

The addition of trineophyltin hydride to alkyonnes under free radical and palladium-catalyzed conditions is studied. Palladium(0)- and palladium (II)-catalyzed hydrostannation of alkynones with trimethyl- and tributyltin hydride carry out the synthesis of alpha-Stannyl enones.

Published
2003

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