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2. Dative Bonding in Quasimetallatranes Containing Group 15 Donors (Y = N, P, and As) and Group 14 Acceptors (M = Si, Ge, Sn, and Pb)

Author

Bakry, Aamy A., Fanelli, Matthew G., Zeldin, Martel, Donald, Kelling J., and Parish, Carol A.

Abstract

Metallatranes and their analogous fused ring [3.3.0] bicyclic compounds, quasimetallatranes, have emerged as fascinating molecular systems with intriguing structural, bonding, and conformational properties. We present a comprehensive investigation aimed at unraveling the nature of dative bonding and exploring the conformational flexibility of these compounds. We extensively characterize the dative bond between the metal center and the electron pair donor, using a range of modeling techniques. Our analyses involve structural optimizations, molecular orbital examinations, and covalency ratio calculations, which provide a thorough understanding of the bonding interactions responsible for the stability of these systems. The results confirmed the presence of dative bonds, supported by the close proximity between the metal and the electron-donating group, and the observation of overlapping electron density. Our studies reveal a correlation between the size of the electron-donor and the coordinating metal atom, and the strength of the dative interaction, as indicated by the bond length and the Wiberg bond indices. This bond strength, in turn, influences the conformational preferences adopted by these compounds. This investigation sheds light on the fundamental aspects of the fused ring [3.3.0] bicyclic quasimetallatrane compounds and offers valuable insights into their unique properties.

Published
2024
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6. Author response: S-adenosylmethionine synthases specify distinct H3K4me3 populations and gene expression patterns during heat stress

Author

Godbole, Adwait A, primary, Gopalan, Sneha, additional, Nguyen, Thien-Kim, additional, Munden, Alexander L, additional, Lui, Dominique S, additional, Fanelli, Matthew J, additional, Vo, Paula, additional, Lewis, Caroline A, additional, Spinelli, Jessica B, additional, Fazzio, Thomas G, additional, and Walker, Amy K, additional

Published
2023
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19. Blastic plasmacytoid dendritic cell neoplasm with absolute monocytosis at presentation

Author

Hou, Steve, Jaworski,Joseph, Swami,Vanlila, Heintzelman,Rebecca, Cusack,Carrie, Chung,Christina, Peck,Jeremy, Fanelli,Matthew, Styler,Michael, and Rizk,Sanaa

Subjects
Pathology and Laboratory Medicine International, hemic and lymphatic diseases
Abstract

Joseph M Jaworski,1,2 Vanlila K Swami,1 Rebecca C Heintzelman,1 Carrie A Cusack,3 Christina L Chung,3 Jeremy Peck,3 Matthew Fanelli,3 Micheal Styler,4 Sanaa Rizk,4 J Steve Hou1 1Department of Pathology and Laboratory Medicine, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA; 2Department of Pathology, Mercy Fitzgerald Hospital, Darby, PA, USA; 3Department of Dermatology, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA; 4Department of Hematology/Oncology, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA Abstract: Blastic plasmacytoid dendritic cell neoplasm is an uncommon malignancy derived from precursors of plasmacytoid dendritic cells. Nearly all patients present initially with cutaneous manifestations, with many having extracutaneous disease additionally. While response to chemotherapy initially is effective, relapse occurs in most, with a leukemic phase ultimately developing. The prognosis is dismal. While most of the clinical and pathologic features are well described, the association and possible prognostic significance between peripheral blood absolute monocytosis (>1.0 K/µL) and blastic plasmacytoid dendritic cell neoplasm have not been reported. We report a case of a 68-year-old man who presented with a rash for 4–5 months. On physical examination, there were multiple, dull-pink, indurated plaques on the trunk and extremities. Complete blood count revealed thrombocytopenia, absolute monocytosis of 1.7 K/µL, and a negative flow cytometry study. Biopsy of an abdominal lesion revealed typical features of blastic plasmacytoid dendritic cell neoplasm. Patients having both hematologic and nonhematologic malignancies have an increased incidence of absolute monocytosis. Recent studies examining Hodgkin and non-Hodgkin lymphoma patients have suggested that this is a negative prognostic factor. The association between blastic plasmacytoid dendritic cell neoplasm and absolute monocytosis has not been described and may, in fact, have prognostic value. Keywords: blastic, plasmacytoid, dendritic, monocytosis

Published
2015

23. Blastic plasmacytoid dendritic cell neoplasm with absolute monocytosis at presentation

Author

Jaworski,Joseph, Swami,Vanlila, Heintzelman,Rebecca, Cusack,Carrie, Chung,Christina, Peck,Jeremy, Fanelli,Matthew, Styler,Michael, Rizk,Sanaa, Hou,J Steve, Jaworski,Joseph, Swami,Vanlila, Heintzelman,Rebecca, Cusack,Carrie, Chung,Christina, Peck,Jeremy, Fanelli,Matthew, Styler,Michael, Rizk,Sanaa, and Hou,J Steve

Abstract

Joseph M Jaworski,1,2 Vanlila K Swami,1 Rebecca C Heintzelman,1 Carrie A Cusack,3 Christina L Chung,3 Jeremy Peck,3 Matthew Fanelli,3 Micheal Styler,4 Sanaa Rizk,4 J Steve Hou1 1Department of Pathology and Laboratory Medicine, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA; 2Department of Pathology, Mercy Fitzgerald Hospital, Darby, PA, USA; 3Department of Dermatology, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA; 4Department of Hematology/Oncology, Hahnemann University Hospital/Drexel University College of Medicine, Philadelphia, PA, USA Abstract: Blastic plasmacytoid dendritic cell neoplasm is an uncommon malignancy derived from precursors of plasmacytoid dendritic cells. Nearly all patients present initially with cutaneous manifestations, with many having extracutaneous disease additionally. While response to chemotherapy initially is effective, relapse occurs in most, with a leukemic phase ultimately developing. The prognosis is dismal. While most of the clinical and pathologic features are well described, the association and possible prognostic significance between peripheral blood absolute monocytosis (>1.0 K/µL) and blastic plasmacytoid dendritic cell neoplasm have not been reported. We report a case of a 68-year-old man who presented with a rash for 4–5 months. On physical examination, there were multiple, dull-pink, indurated plaques on the trunk and extremities. Complete blood count revealed thrombocytopenia, absolute monocytosis of 1.7 K/µL, and a negative flow cytometry study. Biopsy of an abdominal lesion revealed typical features of blastic plasmacytoid dendritic cell neoplasm. Patients having both hematologic and nonhematologic malignancies have an increased incidence of absolute monocytosis. Recent studies examining Hodgkin and non-Hodgkin lymphoma patients have suggested that this is a negative prognostic factor. The associa

Published
2015

24. Treatment of Skin Disease Previous Edition Contributors

Author

Abrouk, Michael, Accordino, Robert E., Admani, Shehla, Adriaans, Beverly, Agarwal, Sanjay, Ahad, Tashmeeta, Ahmed, Imtiaz, Akhavan, Arash, Al Quran, Hanadi Abdallah, Albert, Sandra, Alberta-Wszolek, Lauren, Allen, Caroline, Allen, Robert A., Al-Qari, Haltham, Al-Suwaidan, Sami, Alwan, Wisam, Amini, Sadegh, Angit, Caroline, Anhalt, Grant J., Anyanwu, Cynthia O., Aouthmany, Mouhammad, Asch, Sarah, Ashourian, Neda, Ashton, Richard, Aslam, Arif M., Bader, Eanas, Bain, E. Eugene, III, Bakkour, Waseem, Bala, Harini Rajgopal, Balasubramaniam, Periasamy, Baltz, Julia, Banerjee, Abhijit, Bank, Ali, Bardhan, Ajoy, Bartlett, Brenda L., Bartsch, Megan, Basu, Tanya N., Belazarian, Leah, Bello, Ysabel M., Benton, E. Claire, Berbis, Philippe, Berger, Jeffrey, Berkowitz, Eric, Bernhard, Jeffrey D., Bernstein, Daniel, Bewley, Anthony, Bhushan, Monica, Bialy, Tracy, Bibi, Yuval, Bilsland, David J., Blackwell, Verity, Bornstein, Elana, Borysiewicz, Catherine, Bos, Jan D., Bowman, Paul H., Brauner, Gary J., Brooke, Rebecca C.C., Bruce, Alison J., Buchholz, Robin, Burd, Robert M., Burge, Susan M., Byrd-Miles, Katina, Campbell, Caren, Carruthers, Robert, Carucci, John A., Castelo-Soccio, Leslie, Cave, Bridgette, Centurion, Santiago A., Chachkin, Samuel L., Chadwick, Preston W., Chalmers, Robert J.G., Chang, Yuchl C., Chayavichitsilp, Pamela, Chen, Chen “Mary”, Cheung, Lawrence, Zhen Chiang, Nicole Yi, Chiaravalloti, Anthony J., Chong, Alvin H., Chu, Anthony C., Clark, Sheila M., Clayton, Timothy H., Cliff, Sandeep H., Cockrell, Clay J., Conrad, Nicole, Cooper, Susan M., Correnti, Christina M., Council, M. Laurin, Cowper, Shawn E., Cox, Neil H., Craven, Nicholas M., Creamer, Daniel, Cunliffe, William, Curry, Mary L., Dalton, Jack F., Dasgeb, Bahar, Davis, Rosie, Dawber, Rodney, Deng, Min, Desai, Avani D., Desai, Nisha C., Devlin, Georgina, Diamantis, Stephanie A., Diaz, Camilo, Dick, Sarah E., DiRusso, Lori M., Doctoroff, Alexander, Dortzbach, Kathryn, Dowd, Pauline, Drage, Lisa A., Dyche, Jacqueline A., Eke, Ure, Ellis, Natalie N., Emer, Jason J., Eminger, Lindsay A., Ensanyat, Shaheen H., Faergemann, Jan, Falabella, Anna F., Fanelli, Matthew, Farquharson, Nina R., Farsani, Terry T., Feingold, Anat, Felner, Alyssa M., Ferguson, James, Fernández, Geover, Ferzli, Pascal G., Fiandeiro, Pamela, Firoz, Elnaz F., Fischer, Michael, Fitzpatrick, James E., Fleischmayer, Raul, Frankel, Stacey, Friedlander, Philip, Fuchs, Brian S., Gagna, Claude E., Levine, Erika Gaines, Galan, Anjela, Galaria, Noreen Ahmad, Gamboni, Sarah E., Gardner, Loma S., Garg, Amit, Garza, Reed M., Gelfand, Joel M., Geller, Lauren, Gelmetti, Carlo M., Ghazi, Elizabeth, Ghunawat, Sneha, Ghura, Harvinder, Gibbs, Sam, Gibson, Gillian E., Goldenberg, Gary, Gonzales, Darrell W., Goodfield, Mark J.D., Gordon, Marsha L., Gordon, Patricia Mary, Gordon, Rachel A., Grabell, Daniel A., Graham-Brown, Robin A.C., Greaves, Malcolm W., Green, Justin J., Grelck, Kurt W., Griffiths, Christopher E.M., Gropper, Jaime R., Gruber, Pascale, Guidry, Jacqueline A., Gupta, Arpeta, Gupta, Girish, Gurtman, Alejandra, Hadi, Ahmed S., Hafejee, Abdul, Hague, Joanne, Haimowitz, Julia E., Handfield-Jones, Susan E., Zhu, Tian Hao, Harper, Natasha, Harper, John, Harris, Ronald M., Harrison, Shannon, Hatch, Michael M., Hawk, John L.M., Heagerty, Adrian H.M., Fernandez, Kristen Heins, Helms, Amy E., Henderson, Catriona A., Henry, Patricia A., Higgins, Claire L., Higgins†, Elisabeth M., Hodulik, Sarah, Hönigsmann, Herbert, Houk, Laura, Houpt, Karen R., Hruza, George J., Hui, Andrea, Humphreys, Frances, Huo, Ran, Hwang, Linda Y., Ilchyshyn, Andrew, Ilyas, Erum N., Ismail, Dina, Jablonska, Stefania, Javed, Aysha, Jing, Wei, Jolliffe, Victoria, Jones, Stephen K., Jorizzo, Joseph L., Junkins-Hopkins, Jacqueline M., Kaffenberger, Jessica, Kamenshchikov, Aleksey, Kannee, Carmen E., Kantor, Jonathan, Kasparis, Christos, Kaur, Manjit, Kaye, Keith, Kazlow, Dana, Keefe, Martin, Kellen, Roselyn, Khan, Murtaza, Kia, Kevin F., Skelsey, Maral Kibarian, Kihiczak, George G., Kim, Ho Jin, Kim, Sam, Kirby, Brian, Kirtschig, Gudula, Klein, Rachel S., Kleinerman, Rebecca, Kleydman, Kate, Kluk, Justine, Knopp, Eleanor A., Knowles, Sandra R., Kohorst, John J., Kopf, Alfred W., Korman, Neil J., Krafchik, Bernice R., Krishnan, Anjeli, Krupnick, Amy, Kupetsky, Erine A., Lamba, Sumedha, Lambert, W Clark, Langmuir, Peter, Langtry, James A.A., Larian, Amir A., Larocca, Cecilia A., Lawrence, Clifford M., Layton, Alison, Lee, Andrew D., Lee, Chai Sue, Lee, Robert E., Lessin, Stuart R., Levin, Joshua M., Levin, Robin M., Li, Hong, Liu, Kristina J., Loftus, Frances, Loosemore, Michael P., Lui, Edward, Lushniak, Boris D., Macedo, Chrystalla, Maderal, Andrea D., Mailhot, Jeffrey, Majewski, Slawomir, Majmudar, Vallari, Mann, Ranon, Manning, Jamie R., Mansouri, Yasaman, Margolis, David J., Markoff, Sarah, Marks, Ronald, Marmur, Ellen S., Marraiki, Najat A.Y., Marsden, Jeremy R., Marsland, Alexander, Martin-Clavijo, Agustin, Martinez, Anna, Matiz, Catalina, McAllister, Susan Coutinho, McDonagh, Andrew J.G., McFadden, John, McGinnis, Karen S., McKenna, Dermot B., McKerrow, Kevin, Mehmi, Manjeet, Mendonca, Corinna, Metz, Brandie J., Millard, Leslie G., Miller, James E., Miller, Jason H., Millett, Christian R., Milligan, Alex, Mimouni, Daniel, Minni, John, Mirza, Sultan A., Molin, Sonja, Montie, Dwayne, Morales-Burgos, Adisbeth, Morel, Patrice, Morison, Warwick L., Mortimer, Peter S., Motley, Richard J., Mowad, Christen M., Mowbray, Megan, Muncaster, Anna E., Murakawa, George J., Murray, Stuart C., Nabatian, Adam S., Nalluri, Rajani, Nasca, Maria R., Nawas, Zeena Y., Nayeemuddin, Farzana, Nazarlan, Rachel, Neill, Sallie, Newton-Bishop, Julia, Shim, Tang Ngee, Nguyen, Adam V., Nguyer, Patricia, Nousari, Carlos H., O’Brien, Jack C., O’Donoghue, Nuala, O’Driscoll, John B., O’Shea, Sally Jane, Ogboll, Malobl, Ogden, Stephanie, Owen, Caroline M., Paller, Amy, Palmer, Roy A., Pan, Michael, Panting, Katherine, Pappas-Taffer, Lisa, Patalay, Rakesh, Patel, Gopi, Patel, Nisha C., Paul, Jose, Payette, Michael, Piliang, Melissa Peck, Peck, Gary L., Pena, Sandra, Peranteau, Jarad, Pereira, Frederick A., Perkins, William, Perlis, Clifford S., Piraccini, Bianca Maria, Pittelkow, Mark, Pop, Samantha R., Porcu, Pierluigi, Pote, Amy, Powell, James B., Prok, Lori D., Pyle, Tia M., Qazaz, Surod, Rajkomar, Vikram, Rajpar, Sajjad F., Ramirez, Claudia C., Rapini, Ronald P., Ravitskiy, Larisa, Reddick, Tanya, Regula, Christie G., Reynolds, Rachel V., Richard, Elisabeth, Roberts, Brandie J., Roberts, David T., Rogers, Roy S., III, Rogge, Megan, Roling, Daniel, Rosenfeld, David, Payne, Christopher Rowland, Rubin, Adam I., Rubin, Courtney, Rudikoff, Donald, Ruzicka, Thomas, Sahu, Malini, Salvaggio, Heather L., Samimi, Sara, Sanchez, Miguel R., Sapadin, Allen, Scarff, Cate, Schachner, Lawrence A., Scheinfeld, Noah, Schlosser, Bethanee J., Schofield, Olivia M.V., Kirby, Joslyn Sciacca, Segal, Elana T., Selkin, Bryan A., Sexton, Daniel J., Seymour, Jamie, Shaver, Christine M., Shergil, Bav, Siegel, Julia, Silverman, Robert, Singer, Elisha, Singh, Saurabh, Sladden, Chris, Sladden, Michael, Smith, Andrew G., Smucker, Joanne E., Somani, Najwa, Sommerlad, Mary, Soon, Christine, Sopkovich, Jennifer A., Spencer, James M., Spielvogel, Richard L., Stalkup, Jennifer R., Staughton, Richard C.D., Stege, Helger, Sterling, Jane C., Stibich, Adam S., Suchin, Elliot, Suchin, Karen, Summey, Brett T., Jr, Takwale, Anita, Talhari, Carolina, Tan, Jianyou, Tan, Mei-Hing, Tarlow, Mordechai M., Taylor, Lynsey, Telfer, Nicholas R., Ter Poorten, Maryanna C., Thai, Keng-Ee, Thiers, Bruce H., Thomas, Lucy J., Thomson, Michelle A., Thornton, Cody R., Tobin, Anne-Marie, Tremaine, Anne Marie, Tripp, Jackie M., Tristani-Firouzi, Payam, Tsatsou, Fragkiski, Tucker, William F.G., Udkoff, Jeremy, Unger, Robin H., Unger, Walter P., Utz, Sarah, Valbuena, Martha C., Vangipuram, Ramya, Veitch, David, Venning, Vanessa, Versteeg, Sarah G., Vidal, Claudia Irene, Viera, Martha, Vlachou, Christina, Waldorf, Heidi A., Wali, Gorav N., Wallach, Frances, Wan, Joy, Ward, Jon R., Weidmann, Anja K., Wesley, Carlos K., West, Dennis, Wharton, James R., Whittaker, Sean J., Wiener, Adam H., Wilkin, Nathaniel K., Williams, Jason, Boucher, Kari Williamson, Winhoven, Sandra M., Wiss, Karen, Witkowski†, Joseph A., Wojnarowska, Fenella, Wong Millsop, Jillian W., Wong, Henry K., Woodall, Timothy, Wriston, Cooper C., Wu, Benedict C., Wulkan, Adam, Yates, Victoria M., Lam, Wing Yin, Young, Helen S., Zaghloul, Sameh S., Zeichner, Joshua A., Zell, Deborah, and Zouboulis, Christos C.

Published
2022
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29. Blastic plasmacytoid dendritic cell neoplasm with absolute monocytosis at presentation.

Author

Jaworski, Joseph M., Swami, Vanlila K., Heintzelman, Rebecca C., Cusack, Carrie A., Chung, Christina L., Peck, Jeremy, Fanelli, Matthew, Styler, Micheal, Rizk, Sanaa, and Hou, J. Steve

Subjects
DENDRITIC cells, MONOCYTOSIS, THROMBOCYTOPENIA, CANCER chemotherapy, FLOW cytometry
Abstract

Blastic plasmacytoid dendritic cell neoplasm is an uncommon malignancy derived from precursors of plasmacytoid dendritic cells. Nearly all patients present initially with cutaneous manifestations, with many having extracutaneous disease additionally. While response to chemotherapy initially is effective, relapse occurs in most, with a leukemic phase ultimately developing. The prognosis is dismal. While most of the clinical and pathologic features are well described, the association and possible prognostic significance between peripheral blood absolute monocytosis (>1.0 K/μL) and blastic plasmacytoid dendritic cell neoplasm have not been reported. We report a case of a 68-year-old man who presented with a rash for 4-5 months. On physical examination, there were multiple, dull-pink, indurated plaques on the trunk and extremities. Complete blood count revealed thrombocytopenia, absolute monocytosis of 1.7 K/μL, and a negative flow cytometry study. Biopsy of an abdominal lesion revealed typical features of blastic plasmacytoid dendritic cell neoplasm. Patients having both hematologic and nonhematologic malignancies have an increased incidence of absolute monocytosis. Recent studies examining Hodgkin and non-Hodgkin lymphoma patients have suggested that this is a negative prognostic factor. The association between blastic plasmacytoid dendritic cell neoplasm and absolute monocytosis has not been described and may, in fact, have prognostic value. [ABSTRACT FROM AUTHOR]

Published
2015
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30. List of Contributors

Author

Abdullah, Anthony, Admani, Shehla, Ahmed, Imtiaz, Hammadi, Anwar Al, Allen, Caroline P., Allen, Robert A., Ameen, Mahreen, Amini, Sadegh, Anderson, Bryan E., Anhalt, Grant J., Anyanwu, Cynthia O., Aouthmany, Mouhammad, Aslam, Arif M., Bain, E. Eugene, III, Baker, Donald J., Bakkour, Waseem, Banach, David, Baran, Robert L., Barkham, Melissa C., Basu, Tanya N., Bello, Ysabel M., Benton, Emma, Bergfeld, Wilma F., Berkowitz, Eric, Berman, Brian, Bernhard, Jeffrey D., Berth-Jones, John, Bewley, Anthony, Bhate, Chinmoy, Bhatia, Bhavnit K., Blume, Jonathan E., Brauner, Gary J., Brodell, Robert T., Brown, Marc D., Burd, Robert M., Burdick, Anne E., Burge, Susan M., Callen, Jeffrey P., Camacho, Ivan D., Campbell, Caren, Caplivski, Daniel, Cappell, Mitchell S., Carucci, John A., Casey, Genevieve A., Castelo-Soccio, Leslie, Chadwick, Preston W., Chalmers, Robert J.G., Chan, Loi-Yuen, Chan, Lawrence S., Chayavichitsilp, Pamela, Chen, Jennifer K., Child, Fiona J., Chu, Anthony C., Clayton, Timothy H., Cohen, Steven R., Cooper, Elizabeth A., Cooper, Susan M., Coulson, Ian, Cowper, Shawn E., Craven, Nicholas M., Creamer, Daniel, Cruz, Ponciano D., Jr, Cunningham, Carol, Cusack, Carrie Ann R., Davis, Mark D.P., Davis, Rosie, Dawe, Robert S., D'Cruz, David P., de Berker, David, DeHoratius, Danielle M., Desai, Nisha C., DiGiovanna, John J., Doctoroff, Alexander, Eichenfield, Lawrence F., Eisen, Drore, Eke, Ure, Elston, Dirk M., Emanuel, Patrick O.M., Emer, Jason J., Eminger, Lindsay A., Ensanyat, Shaheen H., Falabella, Anna F., Fanelli, Matthew, Farquharson, Nina R., Farsani, Terry T., Fett, Nicole, Fiandeiro, Pamela, Finlay, Andrew Y., Firoz, Bahar F., Firoz, Elnaz F., Fitzpatrick, James E., Flischel, Amy E., Freedman, Derek, Friedlander, Philip, Friedman, Adam, Fuchs, Brian S., Fukaya, Eri, Fuller, L. Claire, Gach, Joanna E., Galan, Anjela, Gamboni, Sarah E., Gardner, Loma S., Garg, Amit, Garza, Reed M., Gelfand, Joel M., Gelmetti, Carlo, Goldberg, Leonard H., Goodfield, Mark J.D., Gordon, Marsha L., Gordon, Rachel A., Graham-Brown, Robin A.C., Grattan, Clive E.H., Greaves, Malcolm W., Green, Justin J., Grelck, Kurt W., Griffiths, Christopher E.M., Gropper, Charles A., Gropper, Jaime R., Guidry, Jacqueline A., Gupta, Aditya K., Hadi, Ahmed S., Hadi, Suhail M., Hairston, Bethany R., Halpern, Analisa Vincent, Halverstam, Caroline, Handfield-Jones, Susan E., Harrison, Shannon, Heagerty, Adrian H.M., Hebert, Adelaide A., Helms, Stephen E., Hexsel, Camile L., Hexsel, Doris M., Heymann, Warren R., Higgins, Elisabeth M., High, Whitney A., Hönigsmann, Herbert, Horenstein, Marcelo G., Hui, Andrea, Humphreys, Frances, Huo, Ran, Ibbotson, Sally H., Ibrahim, Sherrif F., Ilchyshyn, Andrew, Jablonska, Stefania, Jacobe, Heidi T., James, William D., Javed, Aysha, Jemec, Gregor B.E., Johnston, Graham A., Jones, Stephen K., Junkins-Hopkins, Jacqueline M., Jurecka, Wolfgang, Kaffenberger, Jessica A., Kanelleas, Antonios, Kasparis, Christos, Katugampola, Ruwani P., Katz, Bruce E., Keefe, Martin, Khan, Murtaza, Khorasani, Hooman, Kia, Kevin F., Kihiczak, George G., Kim, Ellen J., Kirby, Brian, Kirby, Joslyn S., Klein, Rachel S., Kleydman, Kate, Kluk, Justine, Knowles, Sandra R., Koch, Dimitra, Koo, John Y.M., Kopp, Sandra A., Korman, Neil J., Kraemer, Kenneth H., Krafchik, Bernice R., Krakowski, Andrew C., Krishnamurthy, Karthik, Kvernebo, Knut, Lacuesta, Maricarr Pamela M., Landero, James Lee, Lam, Charlene, Langtry, James A.A., Larian, Amir A., Lawlor, Frances, Lawrence, Clifford M., Lawrence, Naomi, Lebwohl, Mark G., Lebwohl, Oscar, Lee, Robert E., Lehman, Julia S., Lessin, Stuart R., Levitt, Jacob O., Lewis, Fiona M., Loosemore, Michael P., Luger, Thomas A., Lushniak, Boris D., Lyon, Calum C., Macedo, Chrystalla, Mailhot, Jeffrey, Majewski, Slawomir, Mallett, Richard B., Manders, Steven M., Mann, Ranon, Mansouri, Yasaman, Margolis, David J., Markoff, Sarah, Markowitz, Orit, Marmur, Ellen S., Marraiki, Najat A.Y., Marsden, Jeremy R., Martin-Clavijo, Agustin, Maruthappu, Thiviyani, Mays, Rana Majd, McCall, Calvin O., McDonagh, Andrew J.G., McElligott, Sean C., Merika, Eirini E., Micali, Giuseppe, Millard, Leslie G., Millett, Christian R., Milligan, Alex, Mimouni, Daniel, Mirowski, Ginat W., Molin, Sonja, Mookerjee, Anuradha Lele, Morales-Burgos, Adisbeth, Morison, Warwick L., Mørk, Cato, Morton, Laurel M., Motley, Richard J., Mowbray, Megan, Muldoon, Eavan G., Muncaster, Anna E., Murakawa, George J., Murase, Jenny E., Murdoch, Michele E., Nalluri, Rajani, Needham, Glen R., Neldner, Kenneth H., Newell, Glenn C., Newsham, John, Newton-Bishop, Julia, Nixon, Rosemary L., Nousari, Carlos H., Ogden, Stephanie, Owen, Caroline M., Owen, Cindy E., Pacha, Omar, Palmer, Roy A., Parish, Jennifer L., Parish, Lawrence Charles, Patel, Gopi, Peck, Gary L., Pereira, Frederick A., Perkins, William, Perlis, Clifford S., Petersen, Erik T., Phelps, Robert G., Phillips, Tania J., Piraccini, Bianca Maria, Poh-Fitzpatrick, Maureen B., Porcu, Pierluigi, Powell, James B., Powers, Jennifer Gloeckner, Prok, Lori D., Ratnavel, Ravi, Recica, Hilmi F., Regan, Thomas D., Regula, Christie G., Reutemann, Patricia, Revuz, Jean, Reynolds, Rachel V., Richard, Elisabeth G., Richard, Gabriele, Rigel, Darrell S., Robles, Wanda Sonia, Romano, Michael, Rook, Alain H., Rosen, Ted, Payne, Christopher Rowland, Rustin, Malcolm H.A., Ruzicka, Thomas, Salvaggio, Heather L., Samimi, Sara, Sanchez, Miguel, Schachner, Lawrence A., Schadt, Courtney R., Scheinfeld, Noah, Schlosser, Bethanee J., Schnur, Rhonda E., Schofield, Olivia M.V., Schwartz, Robert A., Scott, Michelle, Selkin, Bryan A., Seymour, Jamie, Shea, Christopher R., Shear, Neil H., Shim, Tang Ngee, Shimizu, Hiroshi, Sidhu, Harleen K., Silverman, Robert A., Simpson, Fiona C., Singer, Elisha, Sladden, Christopher, Sladden, Michael, Smith, Janellen, Somani, Najwa, Sommer, Lacy L., Soon, Christine, Soter, Nicholas A., Spencer, James M., Staughton, Richard C.D., Stechschulte, Sarah A., Sterling, Jane C., Sunderkötter, Cord, Szczecinska, Weronika, Taibjee, Saleem M., Tallon, Ben, Tamura, Deborah, Tan, Eunice, Tang, William Y-M, Telfer, Nicholas R., Thiers, Bruce H., Thornton, Cody R., Tobin, Anne-Marie, Tomson, Nevianna, Torgerson, Rochelle R., Tosti, Antonella, Tsatsou, Fragkiski, Tsuji-Abe, Yukiko, Tucker, William F.G., Turker, Dana, Tyring, Stephen K., Unger, Robin H., Unger, Walter P., van de Kerkhof, Peter C.M., Van Voorhees, Abby S., Venning, Vanessa, Viera, Martha, Vittorio, Carmela C., Vivehanantha, Sivanie, Vleugels, Ruth Ann, Waldorf, Heidi A., Wallengren, Joanna, Walls, Brooke M., Wanat, Karolyn A., Weichert, Gabriele, Weidmann, Anja K., Weinberg, Jeffrey M., Wentworth, Ashley B., Werth, Victoria P., Wesley, Carlos K., White, Lucile E., Whittaker, Sean J., Wiener, Adam H., Wilkin, Jonathan K., Wilkin, Nathaniel K., Williams, Jason D.L., Wiss, Karen, Witkowski, Joseph A., Wong, Henry K., Wong Millsop, Jillian W., Wright, Andrew L., Wriston, Cooper C., Wulkan, Adam, Zaenglein, Andrea L., Zaghloul, Sameh S., Zaki, Irshad, Zeichner, Joshua A., Zeitouni, Nathalie, Zone, John J., and Zouboulis, Christos C.

Published
2014
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31. Media Networks, Inc

Author

Fanelli, Matthew

Subjects
Media Networks Inc. -- Officials and employees, Marketing industry -- Officials and employees, Advertising, marketing and public relations, Mass communications, Appointments, resignations and dismissals, Officials and employees
Abstract

Matthew Fanelli was named director of digital media at Media Networks, Inc., a local advertising subsidiary of Time Inc. Fanelli was most recently online advertising director for The Journal News [...]

Published
2007

32. Mechanisms for the Reactionof Thiophene and Methylthiophenewith Singlet and Triplet Molecular Oxygen.

Author

Song, Xinli, Fanelli, Matthew G., Cook, Justin M., Bai, Furong, and Parish, Carol A.

Subjects
*THIOPHENES, *OXYGEN, *CHEMICAL reactions, *POTENTIAL energy surfaces, *HYDROGEN, *HIGH temperatures
Abstract

Mechanisms for the reaction of thiophene and 2-methylthiophenewith molecular oxygen on both the triplet and singlet potential energysurfaces (PESs) have been investigated using ab initio methods. Geometriesof various stationary points involved in the complex reaction routesare optimized at the MP2/6-311(d, p) level. The barriers and energiesof reaction for all product channels were refined using single-pointcalculations at the G4MP2 level of theory. For thiophene, CCSD(T)single point energies were also determined for comparison with theG4MP2 energies. Thiophene and 2-methylthiophene were shown to reactwith O2via two types of mechanisms, namely, direct hydrogenabstraction and addition/elimination. The barriers for reaction withtriplet oxygen are all significantly large (i.e., >30 kcal mol–1), indicating that the direct oxidation of thiopheneby ground state oxygen might be important only in high temperatureprocesses. Reaction of thiophene with singlet oxygen via a 2 4 cycloadditionleading to endoperoxides is the most favorable channel. Moreover,it was found that alkylation of the thiophene ring (i.e., methyl-substitutedthiophene) is capable of lowering the barrier height for the additionpathway. The implication of the current theoretical results may shednew light on the initiation mechanisms for combustion of asphaltenes. [ABSTRACT FROM AUTHOR]

Published
2012
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33. Geographic Distribution of Foot and Ankle Orthopaedic Surgeons Throughout the United States.

Author

Hui Zhang, Fanelli, Matthew G., Cush, Coleman, Wagner, Benjamin, Grandizio, Louis C., Young, Amanda, Maddineni, Bhumika, and Cush, Gerard J.

Subjects
ORTHOPEDIC surgery, ORTHOPEDISTS, UROLOGICAL surgery, MEDICAL referrals
Abstract

Introduction/Purpose: Orthopaedic Surgery has become increasingly subspecialized since fellowships were established in the 1970s. Previous investigations within hand and urologic surgery have demonstrated an uneven geographic distribution within these subspecialties. Economic factors can influence surgeon distribution within a particular geographic region. At present, the geographic distribution of orthopaedic foot and ankle (OFA) surgeons in the US is poorly defined. The purpose of this investigation is to determine the geographic distribution of OFA surgeons in the US. We hypothesize that there will be substantial differences in OFA surgeon density throughout the US and that economic factors may play a role in access to subspecialty OFA care. Methods: A current membership list was obtained from the American Orthopaedic Foot & Ankle Society (AOFAS). Active AOFAS members were categorized relative to states and US House of Representatives Congressional Districts. Using publicly available census data, we recorded the population within each state and district as well as the percentage of families and people with income below the federally defined poverty level. Descriptive statistics were utilized for demographic information. The relationship between income level and the number of surgeons was determined using a Pearson correlation. These data were used to generate OFA surgeons per capita at a state and congressional district level. This information was also used to generate choropleth maps comparing surgeon density and poverty. Results: We identified a list of 1,103 active AOFAS members with 1,311 practice addresses. There was an average of 21.2 OFA surgeons per state. There was an average of 0.38 and 0.40 OFA surgeons per 100,000 people in each state and congressional district respectively. The District of Columbia, VT, WY, and NE had the highest OFA surgeon density. WV, KY, NM, RI had the lowest density. 75 congressional districts had no OFA surgeons. There was a statistically significant negative relationship demonstrating that regions with higher levels of poverty had fewer OFA surgeons, with a Pearson correlation coefficient of -0.14, (P-value = 0.008). This relationship is further illustrated in Figure 1. Conclusion: There is wide geographic variation of OFA surgeon density throughout the US. Regions with higher levels of poverty have less access to OFA surgeons compared to regions with lower poverty levels. Understanding these trends may aid in developing both recruitment and referal strategies for complex foot and ankle care in underserved regions. [ABSTRACT FROM AUTHOR]

Published
2020
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34. LETTERS TO THE EDITOR.

Author

ENTIN, STEPHEN J., MCCULLOUGH, PAUL, MCNALLY, DONAL, FANELLI, MATTHEW, RHODES, STEVE, MUSCAT, BOB, DEVRIES, LARRY G., PARKS, BILL, GUIDOTTI, TEE L., BOEDY, ALEX, and PUGH, CATHERINE E.

Subjects
*TAXATION
Abstract

Several letters to the editor are presented in response to articles "My Tax Overhaul to Unleash 4% Growth" and "The Bush Growth Plan," by Jeb Bush in the September 9 and 10 issues.

Published
2015

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