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We studied the Zuccale Fault on Elba Island, Northern Apennines, to unravel the complex deformation history that is responsible for the remarkable architectural complexity of the fault. The ZF is characterized by a patchwork of at least six distinct, now tightly juxtaposed Brittle Structural Facies (BSF), that is, volumes of deformed rock characterized by a given fault rock type, texture, color, composition, and age of formation. ZF fault rocks vary from massive cataclasite to foliated ultracataclasite, from clay-rich gouge to highly sheared talc phyllonite. Understanding the current spatial juxtaposition of these BSF’s requires tight constraints on their age of formation during the ZF life span to integrate current fault geometries and characteristics over the time dimension of faulting. We present new K-Ar gouge dates obtained from three samples from two different BSF’s. Two top-to-the E foliated gouge and talc phyllonite samples document faulting in the Aquitanian (c. 22 Ma), constraining E-vergent shearing along the ZF already in the earliest Miocene. A third sample constrains later faulting along the exclusively brittle, flat-lying principal slip surface to < c. 5 Ma. The new structural and geochronological results reveal an unexpectedly long faulting history spanning a ca. 20 Ma long time interval in the framework of the evolution of the Northern Apennines. The current fault architecture is highly heterogeneous as it formed at very different times under different environmental conditions during this prolonged history. We propose that the ZF started as an Aquitanian thrust which then became selectively reactivated by early Pliocene out-of-sequence thrusting during the progressive structuring of the Northern Apennines wedge. These results require the critical analysis of existing geodynamic models and call for alternative scenarios of continuous convergence between the late Oligocene and the early Pliocene with a major intervening phase of extension in the middle Miocene allowing for the isostatic re-equilibration of the Northern Apennines wedge. Extension started again in the Pliocene and is still active in the innermost portion of the Northern Apennines. In general terms, long-lived, mature faults can be architecturally very complex. Their unraveling, including understanding the dynamic evolution of their mechanical properties, requires a multidisciplinary approach combining detailed structural analyses with dating the deformation events recorded by the complex internal architecture, which is a phenomenal archive of faulting and faulting conditions through time and in space.

We studied the Zuccale Fault (ZF) on Elba, part of the Northern Apennines, to unravel the complex deformation history that is responsible for the remarkable architectural complexity of the fault. The ZF is characterized by a patchwork of at least six distinct, now tightly juxtaposed brittle structural facies (BSF), i.e. volumes of deformed rock characterized by a given fault rock type, texture, colour, composition, and age of formation. ZF fault rocks vary from massive cataclasite to foliated ultracataclasite, from clay-rich gouge to highly sheared talc phyllonite. Understanding the current spatial juxtaposition of these BSFs requires tight constraints on their age of formation during the ZF lifespan to integrate current fault geometries and characteristics over the time dimension of faulting. We present new K-Ar gouge dates obtained from three samples from two different BSFs. Two top-to-the-east foliated gouge and talc phyllonite samples document faulting in the Aquitanian (ca. 22 Ma), constraining east-vergent shearing along the ZF already in the earliest Miocene. A third sample constrains later faulting along the exclusively brittle, flat-lying principal slip surface to < ca. 5 Ma. The new structural and geochronological results reveal an unexpectedly long faulting history spanning a ca. 20 Myr time interval in the framework of the evolution of the Northern Apennines. The current fault architecture is highly heterogeneous as it formed at very different times under different conditions during this prolonged history. We propose that the ZF started as an Aquitanian thrust that then became selectively reactivated by early Pliocene out-of-sequence thrusting during the progressive structuring of the Northern Apennine wedge. These results require the critical analysis of existing geodynamic models and call for alternative scenarios of continuous convergence between the late Oligocene and the early Pliocene with a major intervening phase of extension in the middle Miocene allowing for the isostatic re-equilibration of the Northern Apennine wedge. Extension started again in the Pliocene and is still active in the innermost portion of the Northern Apennines. In general terms, long-lived, mature faults can be very architecturally complex. Their unravelling, including understanding the dynamic evolution of their mechanical properties, requires a multidisciplinary approach combining detailed structural analyses with dating the deformation events recorded by the complex internal architecture, which is a phenomenal archive of faulting and faulting conditions through time and space., Solid Earth, 13 (8), ISSN:1869-9510, ISSN:1869-9529

Brittle reactivation of plastic shear zones is frequently observed in geologically old terranes. To better understand such deformation zones, we have studied the >700 Ma long structural history of the Himdalen–Ørje Deformation Zone (HØDZ) in SE Norway by K–Ar and 40Ar–39Ar geochronology, and structural characterization. Several generations of mylonites make up the ductile part of HØDZ, the Ørje Shear Zone. A 40Ar–39Ar white mica plateau age of 908.6 ± 7.0 Ma constrains the timing of extensional reactivation of the Ørje mylonite. The mylonite is extensively reworked during brittle deformation events by the Himdalen Fault. 40Ar–39Ar plateau ages of 375.0 ± 22.7 Ma and 351.7 ± 4.4 Ma from pseudotachylite veins and K–Ar ages of authigenic illite in fault gouge at c. 380 Ma are interpreted to date initial brittle deformation, possibly associated with the Variscan orogeny. Major brittle deformation during the Early–Mid Permian Oslo Rift is documented by a 40Ar–39Ar pseudotachylite plateau age of 294.6 ± 5.2 Ma and a K–Ar fault gouge age of c. 270 Ma. The last datable faulting event is constrained by the finest size fraction in three separate gouges at c. 200 Ma. The study demonstrates that multiple geologically significant K–Ar ages can be constrained from fault gouges within the same fault core by combining careful field sampling, structural characterization, detailed mineralogy and illite crystallinity analysis. We suggest that initial localization of brittle strain along plastic shear zones is controlled by mechanical anisotropy of parallel-oriented, throughgoing phyllosilicate-rich foliation planes within the mylonitic fabric.

It is well known that faults, once formed, become permanent weaknesses in the crust, localizing subsequent brittle strain increments. The case of repeated brittle reactivations localized along pre-existing plastic shear zones is less recognized, although this situation is frequently observed in many geologically old terranes.We have studied the prolonged deformation history of the Himdalen–Ørje Deformation Zone (HØDZ) in SE Norway by combining K–Ar and 40Ar–39Ar geochronology with structural analysis. The HØDZ consists of a large variation of deformation products from mylonites and cataclasites to pseudotachylites and fault gouge. Several generations of mylonites make up the ductile part of HØDZ, called the Ørje shear zone, a km-think SW-dipping shear zone within the late Mesoproterozoic Sveconorwegian orogen. 40Ar–39Ar dating of white mica from one of these mylonites give a plateau age of c. 908 Ma, interpreted to constrain the timing of late-Sveconorwegian extensionial reactivation of the Ørje shear zone.This mylonitic fabric is extensively reworked in a brittle fashion along the SW-dipping Himdalen fault, a 10–25 m thick fault zone of cataclasite, breccia, fault gouge and, in places, abundant pseduotachylite veins. 40Ar–39Ar dating of pseduotachylite material gives several small plateaus between c. 375 and 300 Ma, whereas K-feldspar clasts from the cataclasitically deformed host rock carry a Caledonian signal (plateau at c. 435 Ma). K–Ar dating of three fault gouges constrain the timing of gouge development at c. 270 and 200 Ma. Two of the fault gouges also contain protolithic K-bearing mineral phases that overlap in age with the c. 375 Ma pseudotachylite 40Ar–39Ar plateau age, consistent with field observations of the former reworking the latter.In sum, the HØDZ records multiple Paleozoic and Mesozoic brittle reactivations of the early Neoproterozoic (and older) mylonitic Ørje shear zone. Most of the brittle deformation is interpreted to have accumulated during development of the Permian Oslo rift and its subsequent latest Triassic evolution. The suggested late Devonian (c. 375 Ma) initiation of brittle deformation does not have a clear tectonic association, but we speculate that it relates to strike-slip displacements caused by the Variscan orogen, as also suggested for the sub-parallel Tornquist zone to the south.

Geological mapping, zircon U–Pb dating of 28 samples, and mica 40Ar–39Ar dating of 7 samples in the Stavanger–Ryfylke region (Stavanger, Suldal, Nedstrand, Randøy) characterizes the tectonostratigraphy of the southernmost nappes in the Scandinavian Caledonides. Four main tectonostratigraphic levels are described. (1) The lowest phyllite/mica schist nappes –Buadalen, Holmasjø, Lower Finse, Synnfjell– represent the Cambro–Ordovician sediment cover of the Baltic margin. (2) The overlying nappes –Madla, Storheia, Dyrskard, Hallingskarvet– consist of felsic metaigneous rocks with a consistent age between c.1525 and 1493 Ma. They host c.1040 Ma intrusives and c.1025 Ma Sveconorwegian metamorphism. They likely represent transported Baltican (Sveconorwegian) basement, widely exposed in S Norway. (3) The overlying nappes –Sola, Boknafjord, Kvitenut, Revseggi– are more diverse and lack counterparts in the exposed Baltican crust. The Sola nappe, near Stavanger, comprises a marine succession –Kolnes succession– of mica schist, metasandstone, marble, amphibolite and felsic metavolcanic rocks. The metavolcanic rocks –Snøda metadacite–rhyolite– are fine-grained mica gneisses, with calc-alkaline composition. Their extrusion age of c.941–934 Ma date deposition of the sequence. Detrital zircons in a metasandstone sample (n=138) yield main age modes at c.1040, 1150 and 1395 Ma, as well as significant Paleoproterozoic and Archaean modes. The Kolnes succession was affected by Taconian/Grampian metamorphism peaking in eclogite-facies conditions between c.471 and 458 Ma (Smit et al., 2010), followed by regional cooling around 445–435 Ma. Leucogranite bodies (c.429 Ma) cut the Grampian fabric. Several 40Ar–39Ar white mica and biotite plateau ages constrain the timing of Scandian top-to-the SE nappe stacking at c.420 Ma. The Boknafjord nappe in Nedstrand comprises a c.932 Ma augen gneiss, overlain successively by amphibolite and mica schist units. Preliminary detrital zircon data (n=11) imply an Ordovician (We propose that the Iapetan Karmøy–Bømlo ophiolite complexes were accreted onto the Kolnes succession on the Laurentian side of the Iapetus realm, during the Grampian orogeny, before integration of both in the Scandian nappe pile. The age of HP metamorphism in the Kolnes succession (471–458 Ma) matches the inferred timing for obduction of the Karmøy–Bømlo complexes (485–448 Ma). The evidence for a Laurentian margin obduction stems from a conspicuous similarity with Shetland. On Shetland, the c.492 Ma Unst–Fetlar ophiolite complex was obducted during the Grampian orogeny onto Neoproterozoic Laurentian marine sequences (psammite-marble-mica gneiss) of the Westing, Yell Sound and East Mainland successions. The Westing and Yell Sound successions are characterized by a c. 944–925 Ma, Renlandian, high-grade metamorphism, a dominant detrital zircon mode at 1030 Ma, and common Archean detrital zircons. They correlate well with the Kolnes succession and suggest an ancestry along the Neoproterozoic Renlandian active margin of Laurentia and Rodinia, before opening of Iapetus.

The E-vergent Northern Apennines formed by Oligocene-Miocene convergence and westward subduction of Adria beneath Europe. Extension ensued in the Mid-Late Miocene reflecting lower plate roll-back and causing opening of the back-arc Northern Tyrrhenian Sea. Post-orogenic extension is commonly advocated as the main driver of the exhumation of the belt's inner domain high-pressure/low-temperature (HP-LT) rock units. The Acquadolce Subunit of the Eastern Elba nappe stack contains HP-LT rocks recording peak blueschist conditions of 1.5–1.8GPa at 320°C–370°C loosely dated to the Oligocene-Early Miocene. It is sandwiched by two Late Miocene, out-of-sequence top-to-the E thrusts between Jurassic LP serpentinites on top and HT–LP contact metamorphosed marbles at its base. We document widespread W-verging ductile asymmetries within the Acquadolce Subunit, which correspond to top-to-the W extensional shearing for the nappe stack current orientation. This allowed for early syn-orogenic exhumation from blueschist- to greenschist-facies conditions, wherein coeval W-directed extension at the top of the exhuming units acted synchronously with E-directed thrusting at their base causing exhumation by extrusion in an overall contractional setting. The basal, E-vergent thrusting is, however, challenging to document as the wedge has since been reworked by Late Miocene, E-verging compressive tectonics, contact metamorphism, and later extension, obliterating much of the evidence supporting exhumation by extrusion during the early stages of wedge build-up. Syn-orogenic exhumation by extrusion from deep structural levels within the orogenic wedge is a viable mechanism to account for other exhumed HP-LT units in the inner part of the belt.

Kristiansand is one of the participating cities in the European URGE project (URban GEochemistry) that aims to map potentially toxic elements (PTEs) in the soil of European cities, identify sources of contamination, use health-based criteria for classification and cooperate with the local health authorities. For more than a century a metallurgical industry, including a large nickel smelter, was in operation in Kristiansand City. Despite the long industrial history of the Ni smelter, elevated Ni values (contaminated 200–

This study was conducted to determine which sample material provides the most reliable signal for geochemical exploration under Norwegian conditions. A 100-km long transect was placed over two mineral deposits in southern Norway; the Nordli Mo deposit with surfaces exposure of molybdenite (MoS 2 ) and a sandstone-hosted Pb mineralization with surface exposures of sphalerite. At each of 41 sampling sites, soil C- and O-horizon samples and terrestrial moss ( Hylocomium splendens ) were collected. All samples were analysed for 53 chemical elements following an aqua regia extraction. The Pb deposit is indicated by all three sample materials by anomalous high consentratons of Pb, especially by the C-horizon. The Mo deposit is indicated by more than one anomalous high Mo value in both O- and C-horizon but is not indicated by any clear anomaly in moss. The general mineraliation area of the two deposits is detected on a regional scale using low sample density. However, to exactly localise the mineralization and to define drill targets, a sample density >10 sites/km 2 would be required. Though high Pb concentrations in moss are usually interpreted as being due to anthropogenic activities, results presented here demonstrate that locally moss reacts strongly to the presence of Pb mineralization. Supplementary material: South-north transect plots of all elements are provided as a PDF. A Google Earth file showing the analytical results of moss, O- and C horizon at all sample sites in addition to topographical details is available. All data are also downloadable as an Excel file. All are available at https://doi.org/10.6084/m9.figshare.c.4082981

he Northern Apennines (NA) orogenic wedge formed during Oligocene‐Miocene convergence and westward subduction of Adria beneath the European Plate. Extension ensued in the Mid‐Late Miocene in response to Adria roll‐back, causing opening of the back‐arc Northern Tyrrhenian Sea. Whether extension continues uninterrupted since the Mid‐Late Miocene or it was punctuated by short‐lived compressional events, remains, however, uncertain. We used the K‐Ar method to date a set of brittle‐ductile and brittle deformation zones from the Island of Elba to contribute to this debate. We dated the low‐angle Zuccale Fault (ZF), the Capo Norsi – Monte Arco Thrust (CN‐MAT) and the Calanchiole Shear Zone (CSZ). The CN‐MAT and CSZ are moderately west‐dipping, top‐to‐the east thrusts in the immediate footwall of the ZF. The CSZ slipped 6.14 ± 0.64 Ma (

K-Ar clay fraction ages of brittle faults often vary with grain size, decreasing in the finer size fractions, producing an inclined age-grain-size spectrum. K-Ar ages and mineralogical characterization of gouges from two normal faults in the Kongsberg silver mines, southern Norway, suggest that inclined spectra derived from brittle fault rocks reflect the mixing of inherited components with authigenic mineral phases. The ages of the coarsest and finest fractions constrain faulting at c. 260-270 Ma and reactivation around 200-210 Ma, respectively. This study demonstrates how wall-rock contamination influences the K-Ar age of the coarsest size fractions and that authigenic illite and K-feldspar can crystallize synkinematically under equivalent conditions and thus yield the same K-Ar ages.

Faults are by nature dynamic , as their architecture and composition evolve progressively in space and through time steered by the interplay between strain weakening and hardening mechanisms. This study combines structural analysis, geochemistry and chlorite geothermometry to investigate deformation and strain localization mechanisms of the Kvenklubben fault, a Paleozoic brittle–ductile thrust in northern Norway, with the goal to constrain their temporal variations and the consequences thereof on fault architecture development and rheological behavior. The fault evolved from an initially discrete brittle feature slipping mainly by seismogenic ruptures to a wide brittle–ductile phyllonite deforming by aseismic creep. The formation of mechanically weak phyllosilicates by decarbonation of footwall dolostones and carbonation of hanging wall metabasalts was the main weakening mechanism, whereas partitioning of fluid flow and fracture sealing following transient high pore pressure-driven embrittlement caused episodic and localized strain hardening. The interplay between strain weakening and hardening mechanisms caused the fault core to widen. We suggest that the ability for carbonate-hosted faults to slip by seismogenic rupture is also a function of the faults' structural-evolutionary stage, and that it decreases progressively with fault maturity. This study demonstrates the importance of calibrating the present-day fault anatomy against the dynamic character of faults, which evolve geometrically, compositionally and mechanically in space and through time.

Present-day exposures of ancient faults represent only the end result of the faults’ often protracted and heterogeneous histories. Here we apply K–Ar dating of synkinematic illite/muscovite to constrain the timing of the complete temporal evolution of a complex, multiply-reactivated brittle–ductile fault, the Kvenklubben Fault in northern Norway. All obtained ages vary as a function of grain size. Geologically significant events are identified principally on the basis of detailed structural analysis presented in a companion paper (Torgersen and Viola, 2014). Faulting initiated at 531 ±11 Ma, but most strain was accommodated during Caledonian compression at 445 ±9 Ma. The fault was reactivated extensionally at 121 ±5 Ma. C and O isotopic composition of carbonates and silicates in the fault rocks demonstrates that mineral authigenesis was linked to wall–rock disintegration through dolomite decarbonation and metabasalt carbonation. We suggest that the commonly observed case of age decreasing with grain size in K–Ar and 40Ar/39Ar dating of brittle fault rocks can be interpreted as a consequence of mixing between two end-member illite/muscovite generations: an authigenic and a protolithic, in which the finest authigenic grains constrain the timing of the last faulting increment. Integrating detailed structural analysis with age dating is the key towards a better understanding of fault architecture development and the temporal evolution of strain localization and deformation mechanisms.

Mesothermal chalcopyrite + pyrite + magnetite-bearing calcite-dominated vein deposits in the Repparfjord Tectonic Window, northern Norway, have been studied to constrain the mechanics of their emplacement and the timing of initial vein formation and reactivation. The veins cut across Paleoproterozoic tholeiitic metabasalts and present textural contrast between their hydrofractured, coarse-grained margins, and the fine-grained mylonitic cores. They formed under overall viscous conditions, although cyclically increased fluid pressures caused transient embrittlement. As mineral precipitation sealed the fractures, deformation was accommodated again viscously leading to mylonitization of the vein's core. Local brecciation of the calc-mylonite demonstrates the cyclicity of this process. Re–Os chalcopyrite–pyrite and K–Ar fault gouge dates define an almost continuous age range from ~ 2540 Ma to ~ 460 Ma. Regression of three Re–Os analyses yields a 2069 ± 14 Ma age (187Os/188Os = 0.18 ± 0.04), interpreted as the age of vein emplacement, sulfide precipitation, and initial frictional–viscous deformation. K–Ar ages are mixed ages that constrain a maximum age of faulting in association with the veins at approximately 460 Ma, hence indicating structural reactivation connected with Silurian Caledonian orogenic compression. The spread in Re–Os model ages reflects this reactivation, wherein renewed strain accommodation and circulating oxidizing fluids caused fracturing, dynamic recrystallization, and isotopic disturbance of the sulfides. The study provides evidence for fluid flow during viscous deformation and demonstrates that strain, and flow of oxidizing fluids, can have a significant yet localized control on the integrity of the Re–Os systematic in pyrite and chalcopyrite.

Zircon U–Pb geochronological data in 18 samples from Finnmarksvidda and one sample from the Repparfjord Tectonic Window, northern Norway, constrain the evolution of the Palaeoproterozoic Kautokeino Greenstone Belt and neighbouring units in a Fennoscandia context. The Jergul Complex is an Archaean cratonic block of Karelian affinity, made of variably gneissic, tonalite–trondhjemite–granodiorite–granite plutonic rocks formed between 2975 ± 10 and 2776 ± 6 Ma. It is associated with the Archaean Goldenvárri greenstone–schist formation. At the base of the Kautokeino Greenstone Belt, the Masi Formation is a typical Jatulian quartzite, hosting a Haaskalehto-type, albite–magnetite-rich, mafic sill dated at 2220 ± 7 Ma. The Likčá and Čáskejas formations represent the main event of basaltic magmatism. A synvolcanic metagabbro dates this magmatism at 2137 ± 5 Ma. The geochemical and Nd isotopic signature of the Čáskejas Formation (eNd = +2.2 ± 1.7) is remarkably similar to coeval dykes intruding the Archaean Karelian Craton in Finland and Russia (eNd = +2.5 ± 1.0). The Čáskejas Formation can be correlated with the Kvenvik Formation in the Alta–Kvænangen Tectonic Window. Two large granite plutons yield ages of 1888 ± 7 and 1865 ± 8 Ma, and provide a maximum age for shearing along two prominent NNW–SSE-oriented shear zones recording Svecokarelian transpression. The Bidjovagge Au–Cu deposit formed around 1886 to 1837 Ma and is also related to this NNW–SSE-oriented shear system. The Ráiseatnu Complex is mainly composed of granitic gneisses formed between 1868 ± 13 and 1828 ± 5 Ma, and containing metasediment rafts and zircon xenocrysts ranging from c. 3100 to 2437 Ma. The Kautokeino Greenstone Belt and Ráiseatnu Complex are interpreted as Palaeoproterozoic, pericontinental, lithospheric domains formed during rifting between Archaean cratonic domains. They accommodated oblique convergence between the Karelian and the Norrbotten Archaean cratons during the Svecokarelian orogeny.

Present-day exposures of ancient faults represent only the end result of the faults' often protracted and heterogeneous histories. Here we apply K–Ar dating of synkinematic illite/muscovite to constrain the timing of the complete temporal evolution of a complex, multiply-reactivated brittle–ductile fault, the Kvenklubben Fault in northern Norway. All obtained ages vary as a function of grain size. Geologically significant events are identified principally on the basis of detailed structural analysis presented in a companion paper (Torgersen and Viola, 2014). Faulting initiated at 531±11Ma, but most strain was accommodated during Caledonian compression at 445±9Ma. The fault was reactivated extensionally at 121±5Ma. C and O isotopic composition of carbonates and silicates in the fault rocks demonstrates that mineral authigenesis was linked to wall–rock disintegration through dolomite decarbonation and metabasalt carbonation. We suggest that the commonly observed case of age decreasing with grain size in K–Ar and 40Ar/39Ar dating of brittle fault rocks can be interpreted as a consequence of mixing between two end-member illite/muscovite generations: an authigenic and a protolithic, in which the finest authigenic grains constrain the timing of the last faulting increment. Integrating detailed structural analysis with age dating is the key towards a better understanding of fault architecture development and the temporal evolution of strain localization and deformation mechanisms.