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The JWST has captured the sharpest IR images ever taken of the Horsehead nebula, a prototypical moderately irradiated PDR that is fully representative of most of the UV-illuminated molecular gas in the Milky Way and star-forming galaxies. We investigate the impact of FUV radiation of a molecular cloud and constrain the structure of the edge of the PDR and its illumination conditions. We used NIRCam and MIRI to obtain 17 broadband and 6 narrowband maps from 0.7 to 28 $\mu$m. We mapped the dust emission, scattered light, and several gas phase lines. We also used HST-WFC3 maps at 1.1 and 1. 6 $\mu$m, along with HST-STIS spectroscopic observations of the H$\alpha$ line. We probed the structure of the edge of the Horsehead and resolved its spatial complexity. We detected a network of faint striated features extending perpendicularly to the PDR front into the H\,II region in filters sensitive to nano-grain emission and light scattered by larger grains. This may indeed figure as the first detection of the entrainment of dust particles in the evaporative flow. The map of the 1-0 S(1) line of H$_2$ presents sharp sub-structures on scales as small as 1.5 arcsec. The ionization and dissociation fronts appear at distances 1-2 arcsec behind the edge of the PDR and seem to spatially coincide, indicating a thickness of the neutral atomic layer below 100 au. All broadband maps present strong color variations which can be explained by dust attenuation. Deviations of the emissions in the H$\alpha$, Pa$\alpha,$ and Br$\alpha$ lines also indicate dust attenuation. With a very simple model, we derive the main features of the extinction curve. A small excess of extinction at 3 $\mu$m may be attributed to icy H$_2$O mantles onto grains. In all lines of sight crossing the inner regions of the Horsehead, it appears that dust attenuation is non-negligible over the entire spectral range., Comment: 25 pages, 17 figures

We study the emission of dust grains within the Orion Bar - a well-known, highly far-UV (FUV)-irradiated PDR. The Orion Bar because of its edge-on geometry provides an exceptional benchmark for characterizing dust evolution and the associated driving processes under varying physical conditions. Our goal is to constrain the local properties of dust by comparing its emission to models. Taking advantage of the recent JWST PDRs4All data, we follow the dust emission as traced by JWST NIRCam (at 3.35 and 4.8 micron) and MIRI (at 7.7, 11.3, 15.0, and 25.5 micron), along with NIRSpec and MRS spectroscopic observations. First, we constrain the minimum size and hydrogen content of carbon nano-grains from a comparison between the observed dust emission spectra and the predictions of the THEMIS dust model coupled to the numerical code DustEM. Using this dust model, we then perform 3D radiative transfer simulations of dust emission with the SOC code and compare to data obtained along well chosen profiles across the Orion Bar. The JWST data allows us, for the first time, to spatially resolve the steep variation of dust emission at the illuminated edge of the Orion Bar PDR. By considering a dust model with carbonaceous nano-grains and submicronic coated silicate grains, we derive unprecedented constraints on the properties of across the Orion Bar. To explain the observed emission profiles with our simulations, we find that the nano-grains must be strongly depleted with an abundance (relative to the gas) 15 times less than in the diffuse ISM. The NIRSpec and MRS spectroscopic observations reveal variations in the hydrogenation of the carbon nano-grains. The lowest hydrogenation levels are found in the vicinity of the illuminating stars suggesting photo-processing while more hydrogenated nano-grains are found in the cold and dense molecular region, potentially indicative of larger grains., Comment: 18 pages, 11 figures, accepted for publication in A&A

Diffuse interstellar bands comprise hundreds of absorption features in the ISM. Most DIBs are observed in the optical, but some are in the IR. We observed 76 early-type stars at R=50,000 and S/N ratios of several hundreds using CRIRES. We measure DIBs around 1318, 1527, 1561, 1565, 1567, 1574 and/or 1624 nm. We detect a total of 6 DIB features and 17 likely stellar features assisted by a CMFGEN model. We also measured the DIBs at 1318 and 1527 nm using X-shooter towards ten Ceph. variables with 3.2 < E(B-V) < 6.5 and 4 stars at low values of water vapour. Correlation coeffs. of 0.73-0.96 are found comparing NIRDIB eq. width vs. E(B-V) and with r > 0.8 when comparing the NIR and optical DIBs 5705, 5780, 6203, 6283 and 6269 A. The 5797 A DIB is less well correlated with the NIDIBs. The "C60+" DIB at 9632 A is not well correlated with the 1318 nm DIB. Partial correlation coefficients using E(B-V) as the covariate were also determined. For stars earlier than B2, the 1318 nm DIB is affected by an emission line on its blue wing, likely stellar in nature, although we cannot rule out interstellar/circumstellar origin for example caused by by a DIB in emission. The 1318 nm DIB has a red wing and is reasonably well fitted by two gaussians. Neither the component ratios nor separation are correlated with 5780/5797 or E(B-V). EW(1318 nm) correlates with HI with EW(1318 nm)/E(B-V) decreasing with f(H2). Five pairs of stars within 1 am show similar 1318 nm DIB profiles. Variation in 1318 nm is seen in HD 145501/145502 and HD 168607/168625 pairs. CRIRES data for 17 stars separated by 6-14 months and 2 X-shooter sightlines separated by 9.9 yr were analysed. No time-variability is detected in the 5780, 5797 A, 1318 nm or 1527 nm DIBs. Tentative time variation is observed in the C60+ DIBs at 9577 and 9632 A towards HD 183143 although very close to the noise level with confirmation required., Comment: Accepted for publicaion in the main journal of Astronomy and Astrophysics on 25th November 2022

The so-called C2-DIBs are a class of very weak bands that fall in the blue part of the optical spectrum and are associated with high column densities of the C2 molecule. DIB profile structures constrain potential molecular carriers, but their measurement requires high S/N and spectra and the use of sightlines without Doppler splitting, as typical for a single-cloud situation. Spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) conducted at the VLT (ESO/Paranal) were explored to identify single-cloud and high C2 column sightlines, extract the corresponding C2-DIBs and study their strengths and profiles, and to investigate in detail any sub-structures. The target selection was made based on profile-fitting of the Sodium doublets and the detection of C2 lines. The C2 (2-0) Phillips system was fitted using a physical model of the host cloud. C2 column densities, temperatures as well as gas densities were derived for each sightline. 18 known C2-DIBs and 8 strong non-C2 DIBs were extracted towards 8 targets, comprising 7 single-cloud and one multi-cloud line-of-sights. Correlational studies revealed a tight association of the former group with the C2 columns, whereas the non-C2 DIBs are primarily correlated with reddening. We report three new weak diffuse band candidates. We show for the first time that at least 14 C2-DIBs exhibit spectral sub-structures which are consistent with unresolved rotational branches of molecular carriers. The variability of their peak separations among the bands for a given sightline implies that their carriers are different molecules with quite different sizes. We also illustrate how profiles of the same DIB vary among targets and as a function of physical parameters and provide tables defining the sub-structures to be compared with future models and experimental results., Comment: 19 pages, 15 figures, accepted for publication in A&A

Gaia data and stellar surveys open the way to the construction of detailed 3D maps of the Galactic interstellar (IS) dust based on the synthesis of star distances and extinctions. Reliable extinction measurements require very accurate photometric calibrations. We show the first step of an iterative process linking 3D dust maps and photometric calibrations and improving them simultaneously. Our previous 3D map of nearby IS dust was used to select low reddening SDSS/APOGEE-DR14 red giants, and this database served for an empirical effective temperature- and metallicity-dependent photometric calibration in the Gaia G and 2MASS Ks bands. This calibration has been combined with Gaia G-band empirical extinction coefficients recently published, G, J and Ks photometry and APOGEE atmospheric parameters to derive the extinction of a large fraction of the survey targets. Distances were estimated independently using isochrones and the magnitude-independent extinction K(J-Ks). This new dataset has been merged with the one used for the earlier version of dust map. A new Bayesian inversion of distance-extinction pairs has been performed to produce an updated 3D map. We present several properties of the new map. Its comparison with 2D dust emission reveals that all large dust shells seen in emission at mid- and high-latitude are closer than 300pc. The updated distribution constrains the well debated, X-ray bright North Polar Spur to originate beyond 800 pc. We use the Orion region to illustrate additional details and distant clouds. On the large scale the map reveals a complex structure of the Local Arm. 2 to 3 kpc-long chains of clouds appear in planes tilted by 15 deg with respect to the Galactic plane. A series of cavities oriented along a l=60-240deg axis crosses the Arm. (http://stilism.obspm.fr), Comment: 12 pages, to appear in Astronomy and Astrophysics

Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red. Detecting these in astronomical spectra is difficult due to the strong contamination of ground-based spectra by atmospheric water vapor, to the presence of weak and shallow stellar lines and/or blending with other weak DIBs. The detection of the two strong bands has been claimed by several teams, and the three additional and weaker bands have been detected in a few sources. Certain recent papers have argued against the identification of C60+ based on spectral analyses claiming (i) a large variation in the ratio between the equivalent widths of the 9632 and 9577\AA\: bands, (ii) a large redshift of the 9632\AA\: band for the Orion star HD 37022, and (iii) the non-detection of the weaker 9428\AA~DIB. Here we address these three points. (i) We show that the model stellar line correction for the 9632\AA~DIB overestimates the difference between the strengths of the lines in giant and dwarf star spectra, casting doubts on the conclusions about the ratio variability. (ii) Using high quality stellar spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES), recorded with the ESO/Paranal Ultraviolet Echelle Spectrograph (UVES) in about the same atmospheric conditions, we find no wavelength shift in the 9632\AA\ band towards HD 37022. (iii) Using EDIBLES spectra and data from the Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) at CFHT we show that the presence of a weak 9428\AA\ band cannot be ruled out, even in the same observations that a previous study claimed it was not present., Comment: 8 pages, 9 figures, accepted in Astronomy and Astrophysics

High obscuration of background stars behind dark clouds precludes the detection of optical diffuse interstellar bands (DIBs) and hence our knowledge of DIB carriers in these environments. Taking advantage of the reduced obscuration of star-light in the near-infrared (NIR) we used one of the strongest NIR DIBs at 15273 AA to probe the presence and properties of its carrier throughout the nearby interstellar dark cloud Barnard 68. Equivalent widths (EW) have been measured for different ranges of visual extinction AV, using VLT-KMOS H-band (1.46-1.85 micron) moderate-resolution (R = 4000) spectra of 43 stars situated behind the cloud. To do so we fitted the data using synthetic stellar spectra from the APOGEE project and TAPAS synthetic telluric transmissions appropriate for the observing site and time period. The results show an increase of DIB EW with increasing AV. However, the rate of increase is much flatter than expected from the EW-AV quasi-proportionality established for this DIB in the Galactic diffuse interstellar medium. Based on a simplified inversion assuming sphericity, it is found that the volume density of the DIB carrier is 2.7 and 7.9 times lower than this expected average value in the external and central regions of the cloud which have n(H)= 0.4 and 3.5 x 105 cm3, respectively. Further measurements with multiplex NIR spectrographs should allow detailed modeling of such an edge effect of this DIB and other bands and help to clarify its actual origin., Comment: 4 pages, 4 figures

Information on the existence and properties of diffuse interstellar bands (DIBs) outside the optical domain is still limited. Additional infra-red (IR) measurements and IR-optical correlative studies are needed to constrain DIB carriers and locate various absorbers in 3D maps of the interstellar matter. We extended our study of H-band DIBs in Apache Point Observatory Galactic Evolution Experiment (APOGEE) Telluric Standard Star (TSS) spectra. We used the strong 15273A band to select the most and least absorbed targets. We used individual spectra of the former subsample to extract weaker DIBs, and we searched the two stacked series for differences that could indicate additional bands. High-resolution NARVAL and SOPHIE optical spectra for a subsample of 55 TSS targets were additionally recorded for NIR/optical correlative studies. From the TSS spectra we extract a catalog of measurements of the poorly studied 15617, 15653, and 15673A DIBs in about 300 sightlines, we obtain a first accurate determination of their rest wavelength and constrained their intrinsic width and shape. In addition, we studied the relationship between these weak bands and the strong 15273A DIB. We provide a first or second confirmation of several other weak DIBs that have been proposed based on different instruments, and we add new constraints on their widths and locations. We finally propose two new DIB candidates. We compared the strength of the 15273A absorptions with their optical counterparts 5780, 5797, 6196, 6283, and 6614A. Using the 5797-5780 ratio as a tracer of shielding against the radiation field, we showed that the 15273A DIB carrier is significantly more abundant in unshielded (sigma-type) clouds, and it responds even more strongly than the 5780A band carrier to the local ionizing field., Comment: 15 pages, 40 figures, accepted for publication in Astronomy&Astrophysics