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The driving processes responsible for producing the Central Atlantic Magmatic Province, the Large Igneous Province associated with end-Triassic rifting of Pangea, remain largely debated. Because their compositions encompass most of the Central Atlantic basalt spectrum, tholeiites from southern Eastern North America are considered pivotal for identifying magma origins. New(176)Hf/Hf-177 measurements for 201 Ma Eastern North American tholeiites dominantly record a local petrogenetic history. Their epsilon(Hf)ratios, corrected to an emplacement age of 201 Ma (-7.85 to +5.86), form a positive but shallowly sloped array slightly deviating from the terrestrial array on a epsilon(Hf)versus epsilon(Nd)diagram. Comparison of(176)Hf/Hf-177 to other isotope ratios and trace elements helps to rule out several petrogenetic scenarios, particularly mixing of melts from global depleted or enriched mantle components. In contrast, partial melting of subduction-metasomatized mantle can explain the parental magma composition for southern Eastern North America. Such metasomatism likely occurred during Paleozoic subduction around Pangea and may have been dominated by sediment-derived fluid reactions. The observed(176)Hf/Hf-177 versus(143)Nd/Nd-144 array may reflect subsequent assimilation of lower continental crust, perhaps together with limited direct melting of recycled continental crust in the asthenosphere. The proposed recycling scenario does not specifically support or preclude a mantle plume origin for the Central Atlantic Magmatic Province but instead points toward the presence of a distinct local mantle source and crustal assimilation processes during magma transport. Detailed understanding of these local effects is needed in order to more accurately understand the origins of Large Igneous Provinces.

Thesis (Ph. D.)--Joint Program in Marine Geology and Geophysics (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2009., Includes bibliographical references., To explore the ability of melting mafic lithologies to produce alkaline ocean-island basalts (OIB), an experimental study was carried out measuring clinopyroxene (Cpx)melt and garnet (Gt)-melt partition coefficients during silica-poor garnet pyroxenite melting for a suite of trace elements, including U and Th, at 2.5GPa and 1420-1450°C. Partition coefficients range from 0.0083+0.0006 to 0.020+0.002 for Th and 0.0094+0.0006 to 0.024+0.002 for U in Cpx, and are 0.0032+0.0004 for Th and 0.013+0.002 for U in Gt. Forward-melting calculations using these experimental results to model time-dependent uranium-series isotopes do not support the presence of a fixed quantity of garnet pyroxenite in the source of OIB. To use U-series isotopes to further constrain mantle heterogeneity and the timing and nature of melting and melt transport processes, U-Th-Pa-Ra disequilibria, radiogenic isotopes, and trace-element compositions were measured for the slow-spreading Arctic mid-ocean ridges (MOR). A focused case study of 33 young (<10ka) MOR basalts (MORB) from the shallow endmember of the global ridge system, the Kolbeinsey Ridge (67°05'-70°26'N) found that unaltered Kolbeinsey MORB have universally high (230Th/238U) (1.165-1.296) and relatively uniform (230Th/232Th) (1.196-1.324), ENd (8.4310.49), 87Sr/86Sr (0.70274-0.70301), EHf(16.59-19.56), and Pb isotopes (e.g. 208Pb/206Pb 2.043-2.095). This suggests a homogeneous mantle source and a long peridotite melting column produces the thick Kolbeinsey crust. Trace element ratios suggest a young, depleted mantle source. Data from the slow- to ultraslow Mohns and Knipovich Ridges north of Kolbeinsey form a sloped array, and (230Th/232Th) correlates systematically with radiogenic isotopic variations., (cont.) These data are readily reproduced by models for heterogeneous mantle melting. MORB from 85oE on the global ultraslow-spreading endmember Gakkel Ridge are homogeneously depleted with low (230Th/238U) and high (226Ra/230Th) that lie along a global negative correlation. Arctic data support a global mantle temperature control on mean (230Th/238U)., by Lynne J. Elkins., Ph.D.

To explore the ability of melting mafic lithologies to produce alkaline ocean-island basalts (OIB), a study was carried out measuring clinopyroxene (Cpx)- melt and garnet (Gt)-melt partition coefficients during silica-poor garnet pyroxenite melting for a suite of trace elements, including U and Th, at 2.5GPa and 1420-1450 degrees C. Forward-melting calculations using the results to model time-dependent uranium-series isotopes do not support presence of a fixed quantity of garnet pyroxenite in the source of OIB. To use U-series isotopes to further constrain mantle heterogeneity and the timing and nature of melting and melt transport processes, U-Th-Pa-Ra disequilibria, radiogenic isotopes, and trace-element compositions were measured for the slow-spreading Arctic mid-ocean ridges (MOR). A case study of 33 young MOR basalts (MORB) from the shallow endmember of the global ridge system, the Kolbeinsey Ridge found that unaltered Kolbeinsey MORB have universally high (230Th/238U) (1.165-1.296) and relatively uniform (230Th/232Th) (1.196-1.324), SigmaNd, 87Sr/86Sr SigmaHf, and Pb isotopes. This suggests a homogeneous mantle source and a long peridotite melting column produces the thick Kolbeinsey crust. Trace element ratios suggest a young, depleted mantle source. Data from the slow- to ultraslow Mohns and Knipovich Ridges north of Kolbeinsey form a sloped array, and (230Th/232Th) correlates systematically with radiogenic isotopic variations. These data are readily reproduced by models for heterogeneous mantle melting. MORB from 85 degrees E on the global ultraslow-spreading endmember Gakkel Ridge are homogeneously depleted with low (230Th/238U) and high (226Ra/230Th) that lie along a global negative correlation. Arctic data support a global mantle temperature control on mean (230Th/238U)., Sponsored in part by the the National Defense Science and Engineering Graduate Fellowship Program. The original document contains color images.