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'Cookbook' style laboratory tasks have long been criticised for the lack of critical and independent thought that students need in order to complete them. We present an account of how we transformed a 'cookbook' lab to a genuine inquiry experiment in first year physics. Crucial features of the work were visits to see other teaching laboratories, understanding student preparedness and the selection of an appropriate experiment to develop. The new two session laboratory work is structured so students make decisions related to the method of a basic experiment in the first session and then have freedom to investigate any aspect they wish to in the second. Formative feedback on laboratory notebook keeping is provided by short online activities.

We report the first experimental evidence of spontaneous electron emission from a homonuclear dimer anion through direct measurements of $\rm{Ag}_2^- \rightarrow \rm{Ag}_2 + \rm{e}^-$ decays on milliseconds and seconds time scales. This observation is very surprising as there is no avoided crossing between adiabatic energy curves to mediate such a process. The process is weak but yet dominates the decay signal after 100 ms when ensembles of internally hot Ag$_2^-$ ions are stored in the cryogenic ion-beam storage ring, DESIREE, for 10 seconds. The electron emission process is associated with an instantaneous, very large, reduction of the vibrational energy of the dimer system. This represents a dramatic deviation from a Born-Oppenheimer description of dimer dynamics.

Spontaneous decays of small, hot silver cluster anions Ag$_{n}$, $n=4-7$ have been studied using one of the rings of the Double ElectroStatic Ion Ring ExpEriment (DESIREE). Observation of these decays over very long time scales is possible due to the very low residual gas pressure ($\sim10^{-14}$) and cryogenic (13 K) operation of DESIREE. The yield of neutral particles from stored beams of Ag$_{6}$ and Ag$_{7}$ anions were measured for 100 milliseconds and were found to follow single power law behaviour with millisecond time scale exponential cut-offs. The Ag$_{4}$ and Ag$_{5}$ anions were stored for 60 seconds and the observed decays show two-component power law behaviors. We present calculations of the rate constants for electron detachment from, and fragmentation of Ag$_{4}$ and Ag$_{5}$. In these calculations, we assume that the internal energy distribution of the clusters are flat and with this we reproduce the early steep parts of the experimentally measured decay curves for Ag$_{4}$ and Ag$_{5}$, which extends to tens and hundreds of milliseconds, respectively. The fact that the calculations reproduce the early slopes of Ag$_{4}$ and Ag$_{5}$, which differ for the two cases, suggests that it is the changes in fragmentation rates with internal cluster energies of Ag$_{4}$ and Ag$_{5}$ rather than conditions in the ion source that determines this behavior. Comparisons with the measurements strongly suggest that the neutral particles detected in these time domains originate from Ag$_{4} \rightarrow$ Ag$_{3}+$ Ag and Ag$_{5}\rightarrow$ Ag$_{3}+$ Ag$_{2}$ fragmentation processes.

We have measured the spontaneous neutral particle emission from copper cluster anions (Cu$_n^-$, $n=3-6$) stored at cryogenic temperatures in one of the electrostatic ion storage rings of the DESIREE (Double ElectroStatic Ion Ring ExpEriment) facility at Stockholm University. The measured rate of emission from the stored Cu$_3^-$ ions follows a single power law decay for about 1 ms but then decreases much more rapidly with time. The latter behavior may be due to a decrease in the density of available final states in Cu$_3$ as the excitation energies of the decaying ions approach the electron detachment threshold. The emissions from Cu$_4^-$, Cu$_5^-$ and Cu$_6^-$ are well-described by sums of two power laws that are quenched by radiative cooling of the stored ions with characteristic times between a few and hundreds of milliseconds. We relate these two-component behaviors to populations of stored ions with higher and lower angular momenta. In a separate experiment, we studied the laser-induced decay of Cu$_6^-$ ions that were excited by 1.13 eV or 1.45 eV photons after 46 milliseconds of storage.

The intrinsic radiative lifetimes of the $5d^{10}6s$ $^{2}\text{S}_{1/2}$ and $5d^{9}6s^{2}$ $^{2}\text{D}_{3/2}$ bound excited states in the platinum anion $\text{Pt}^{-}$ have been studied at cryogenic temperatures at the Double ElectroStatic Ion Ring Experiment (DESIREE) facility at Stockholm University. The intrinsic lifetime of the higher-lying $5d^{10}6s$ $^{2}\text{S}_{1/2}$ state was measurement to be 2.54$\pm$0.10 s, while only a lifetime in the range of 50 - 200 ms could be estimated for the $5d^{9}6s^{2}$ $^{2}\text{D}_{3/2}$ fine-structure level. The storage lifetime of the $\text{Pt}^{-}$ ion beam was measured to be a little over 15 minutes at a ring temperature of 13 K. The present study reports the lifetime of an atomic negative ion in an excited bound state with an electron configuration different from that of the ground state., Comment: 6 pages, 5 figures

A sputter ion source with a solid graphite target has been used to produce dianions with a focus on carbon cluster dianions, $\text{C}_{n}^{2-}$, with $n=7-24$. Singly and doubly charged anions from the source were accelerated together to kinetic energies of 10 keV per atomic unit of charge and injected into one of the cryogenic (13 K) ion-beam storage rings of the Double ElectroStatic Ion Ring Experiment facility at Stockholm University. Spontaneous decay of internally hot $\text{C}_{n}^{2-}$ dianions injected into the ring yielded $\text{C}^{-}$ anions with kinetic energies of 20 keV, which were counted with a microchannel plate detector. Mass spectra produced by scanning the magnetic field of a $90^{\circ}$ analyzing magnet on the ion injection line reflect the production of internally hot $\text{C}_{7}^{2-}-\text{C}_{24}^{2-}$ dianions with lifetimes in the range of tens of microseconds to milliseconds. In spite of the high sensitivity of this method, no conclusive evidence of $\text{C}_{6}^{2-}$ was found while there was a clear $\text{C}_{7}^{2-}$ signal with the expect isotopic distribution. An upper limit is deduced for a $\text{C}_{6}^{2-}$ signal that is two orders-of-magnitue smaller than that for $\text{C}_{7}^{2-}$. In addition, $\text{C}_{n}\text{O}^{2-}$ and $\text{CsCu}^{2-}$ dianions were detected., Comment: 6 pages, 6 figures

We apply near-threshold laser photodetachment to characterize the rotational quantum level distribution of OH$^-$ ions stored in the cryogenic ion-beam storage ring, DESIREE, at Stockholm University. We find that the stored ions relax to a rotational temperature of 13.4$\pm$0.2 K with 94.9$\pm$0.3 % of the ions in the rotational ground state. This is consistent with the storage ring temperature of 13.5$\pm$0.5 K as measured with eight silicon diodes, but in contrast to all earlier studies in cryogenic traps and rings where the rotational temperatures were always much higher than those of the storage devices at their lowest temperatures. Furthermore, we actively modify the rotational distribution through selective photodetachment to produce an OH$^-$ beam where 99.1$\pm$0.1 % of approximately one million stored ions are in the $J$=0 rotational ground state.