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Sorghum is the fifth most harvested crop worldwide, being the popped sorghum as one of the most common snacks in India and some Asian regions. Therefore, this study evaluated how the processing method influences the microstructure, volumetric and textural properties of popped sorghum microstructure, volumetric and textural properties. White sorghum "Paloma" variety (11% moisture) was assessed, which was popped using three processing methods: microwave, pan-frying, and hot salt-frying using three temperature levels. Volumetric and yield characteristics were evaluated for the popped kernels, as their microstructure and texture profile. The popped sorghum obtained through the hot salt-frying method had a microstructure composed of polygonal cells. Also, it showed the best volumetric characteristics (volume), good expansion index, and high process yield. Finally, the hot salt-frying method showed better textural features associated with the attributes of a satisfactory product for consumers.

Amylose is well known to be organized helically with six glucose per turn, allowing it to form complexes with various ligands. This interaction can be affected by the type of crystalline structure present in the starch sources. This study evaluated the effect of extrusion on the crystalline structure of starch during RS5 formation. Rice and potato starches were extruded at 100 °C and 15 rpm with 5% and 10% oleic acid (OA), then the physical, thermal, paste properties, and resistant starch content (RS) were evaluated. Potato starch extruded with 10% OA showed granules embedded in a gelatinized starch matrix. The X-ray revealed that rice (orthorhombic) and potato (hexagonal) structures remain unchanged even after extrusion. Differential scanning calorimetry (DSC) evidenced the formation of type IIa amylose-lipid complexes in OA treatments, where potato extruded with 10% OA had the highest enthalpy (0.9 J/g). Moreover, the extruded potato showed the highest pasting temperature (87.19 °C), supporting the complex formation. The RS was reduced from 15.8 (isolated) to 4.14 mg/100 mg (extruded 10% OA) in rice. For potato, RS decreased from 17 to 13 mg/100 mg (isolated and extruded 10% OA). Overall, these findings suggest a tendency in potato starch (ortho-rhombic) to interact with OA during the extrusion process, promoting a crystalline lamellae growth when extruded with 10% OA, therefore, changing their properties.

The use of pectin from coffee mucilage (PI) is an alternative to reduce the environmental impact of the wet processing coffee industries by applying it in the generation of degradable films. Hence, the aim of this work was to valorize industrial coffee waste as a source of pectin to prepare biodegradable films by a novel methodology (electrospraying), perform chemical characterization of pectin, and compare the films with a control method (casting) and pectin (citric, PC). Coffee mucilage pectin composition (PI) was different, having smaller galacturonic acid content (52.2%) than PC. The presence of neutral sugars (ribose, xylose, glucose), the high degree of esterification (84.92 ± 1.70) and the diffractogram and Raman spectra results, gave the basis to consider PI as a high methoxyl pectin. PI films showed different physical properties and structure than Pc, depending on the composition and method of production. Regarding mechanical and barrier characteristics, films prepared with pectin from coffee mucilage presented a typical behavior of rigid polymers; they were also more permeable to water vapor (2.91 ± 0.02 × 10−12 g/s m Pa) and were highly biodegradable and soluble in water. Due to these characteristics, the production of films from coffee mucilage pectin becomes a suitable alternative to give added value to this unexploited waste.

The aim of this study was to evaluate the effect of acid hydrolysis and succination upon single and a combination of both of them as a dual modification on the morphological, structural, thermal, and pasting profile of the achira starch in order to expand its potential food applications. The surface of achira starch granules was eroded with acid hydrolysis, while the succination resulted in the formation of pores or cavities, having a slight impact on the crystallinity and the gelatinization enthalpy. Succinated starch presented the lowest transition temperatures (To = 60.29 °C, Tp = 65.03 °C and Te = 69.86 °C) compared to other starches in this study. The succination increased the final viscosity (3808 cp) when compared with the native starch (3114 cp), while acid hydrolysis resulted in a decreased value (735 cp). These are desirable properties for its possible use as an additive in bakery industry processes.

Biological, physicochemical, structural, and thermal properties of PVA-based electrospun wound dressings added with hydrolyzed collagen (HC) and different concentrations of

El desarrollo de métodos predictivos para determinar la calidad y el uso final del trigo ha sido una necesidad para fitomejoradores y para productores, molineros y panaderos. En este estudio se investigó el uso de granos individuales de trigo (Triticum spp.) con la técnica de ultrasonido como método predictivo para la caracterización de la calidad. Se evaluaron 45 muestras de trigos mexicanos de la cosecha 2003. La señal ultrasónica viajó más rápido en el grano de trigo duro o cristalino, seguida por el trigo panadero y por último el trigo suave. La ecuación polinomial de mejor ajuste de los parámetros del grano del trigo (contenido de cenizas, número de caída, microsedimentación y contenido de proteína) con la velocidad ultrasónica, fue una polinomial de segundo grado, excepto para peso hectolítrico que fue lineal. Las variables de la harina como rendimiento harinero, número de caída, sedimentación y temperatura de pastificado, se relacionaron linealmente con la velocidad ultrasónica. También la mayoría de los datos reológicos del alveógrafo y farinógrafo se relacionaron linealmente con la velocidad ultrasónica. Para una misma clase de trigo la tendencia es que a mayor dureza del grano la velocidad ultrasónica se incrementa y así representa mejor calidad. Entonces, las mediciones de velocidad ultrasónica en granos individuales pueden ser utilizadas para predecir el volumen del pan, así como para la evaluación no destructiva y rápida de la calidad del trigo.

The use of particles obtained from biopolymers is of interest in fields such as bioengineering and nanotechnology, with applications in drug encapsulation, tissue engineering, and edible biofilms. A method used to obtain these particles is electrohydrodynamic atomization (EHDA), which can generate different structures depending on the process conditions and raw materials used, opening a wide range of research in the biopolymers field, where starch is considered an excellent material to produce edible and biodegradable films. This chapter is a compilation and analysis of the newest studies of this technique, using starch with or without modifications to prepare films or membranes and their potential applications. A systematic literature review, focused on starch, and EHDA was carried out, finding 158 articles that match these criteria. From these results, a search inside them, using the words edible and biodegradable was conducted, showing 93 articles with these key words. The information was analyzed observing the preference to use corn, potato, rice, and cassava starches, obtaining mainly scaffolds and fibers and, in much less proportion, films or capsules. This review shows a window of opportunity for the study of starchy materials by EHDA to produce films, coatings, and capsules at micro or nano levels.

Pulque is a Mexican alcoholic, probiotic beverage with shelf life of 3 days. The physicochemical, probiotic, and sensory properties of pulque depend on its content of lactic acid bacteria (LAB) and yeasts. The aim of this study was to apply ohmic heating (OH) in order to extend the shelf life of pulque without altering its properties. Pulque processed by conventional pasteurization (63 °C, 30 min) was used as control. Parameters such as electrical conductivity (0.22 S/m) and optimal pasteurization conditions by OH (65 °C, 5 and 7 min; 70 °C, 3 and 5 min) were determined. Shelf life was evaluated with these parameters during 22 days of storage at 4 ± 1 °C. A higher content of LAB (6.68 and 5.96 log10 CFU/mL) was obtained at 65 °C for 5 and 7 min, respectively, compared with conventional pasteurization (3.54 log10 CFU/mL). After 22 days, physicochemical properties (pH, color, and alcohol content) were stable for both methods of pasteurization. However, the pulque treated with OH had greater sensory acceptance. For the first time, OH was used to process pulque, and results revealed that is an effective technology for extending the shelf life until 22 days, preserving microbiological and physicochemical properties. Microorganisms as surviving the OH treatments were identified as Lactobacillus acidophilus, Lactobacillus kefiri, and Saccharomyces cerevisiae.

Simple equation Mt/M∞ = Ktn is evaluated to describe the Fickian mechanism of oil absorption and water release during the frying of tortilla chips in nixtamalized samples with lime and without lime where Mt/M∞ is the fractional solute absorption or release, and n is the diffusional exponent characteristic of the Fickian mechanism that changes with food physical and chemical properties. For the Fickian mechanism, the exponent (n) is ≤0.50, and non-Fickian is 0.5

We studied the changes in the phytochemicals profile of two instant corn flours produced by different process: traditional nixtamalization process (TN) and by ohmic heating process (OH). The highest total phenolics content was found in the OH flours (OHF), which showed predominance of bound phenolics and free flavonoids compared with the TN flours (TNF). Ferulic acid measured by HPLC-DAD was the most abundant compound in its bound form in the OHF, but decreased by 57% in TNF. The insoluble fiber content was preserved by the OHF (17.49%) and the soluble fiber increased ∼65% compared with TNF. These data suggest that instant corn flours processed by OH preserves the phenolic profile and antioxidant profile similarly than flours processed by TN; furthermore, water waste was reduced significantly, and no effluents were produced in the ohmic heating process.

This work proposed a controlled method to modify the physicochemical properties of corn starch through heating and cooling extrusion (HCE) cycles. It was used native corn starch adjusted to 60% moisture. It was then subjected to 5 HCE cycles at 100 and 125 °C, at 10 rpm. Water absorption index (WAI), water solubility index (WSI), resistant starch (RS), thermal properties, viscosity, FTIR, and X-ray were evaluated. For WAI and WSI, a gradual increase was observed on each HCE cycle. Thermal properties shown that enthalpy decrease with each HCE cycles due to more gelatinization. Viscosity properties shown a thermally stable starch conditions being directly proportional to HCE cycles. The RS increased for each 5 HCE. XRD revealed that HCE cycle changed the starch structure from an orthorhombic structure to V-type crystalline structure. Finally, it was concluded that HCE cycles is a method to produce corn starch with controlled physicochemical properties.

Black garlic (BG) is obtained by the Maillard reaction under controlled conditions of temperature and humidity. This study describes the traditional processing (TT-BG) and the use of ohmic heating (OH) as pre-treatment (OH-BG) to improve time processing. Physicochemical composition and sensory properties were of particular interest in this study. The OH as a pretreatment causes the hydrolysis of fructans to fructose, which are degraded during storage under traditional treatment conditions (70 °C/94% RH) through the Maillard reaction causing the faster formation of compounds responsible for the color of black garlic compared to black garlic without pre-treatment. This reaction cuts down the time to attain the characteristic color of black garlic from 30 to 12 days. The 5-hydroxymethyl-2-furaldehyde (HMF) content was 3.6 times higher in OH-BG than in TT-BG. The polyphenol content and antioxidant capacity did not show differences between TT-BG and OH-BG, but their levels were superior to commercial sample. Both products (OH-BG and TT-BG) were sweet (36.8 and 31.6 °Bx, respectively) and had an excellent organoleptic acceptance (75 and 70%). These results highlight the potential of ohmic heating pretreatment in reducing the time to obtain good quality BG., Ríos-Ríos was supported by a scholarship from the Consejo Nacional de Ciencia y Tecnología (CONACYT-Mexico).

Sorghum has been used to expand snacks such as pop sorghum. However, it is still unknown how the structural changes during the popping affect its rheological and functional properties. This study evaluated the structural changes of popped sorghum starch (PS) and their impact on rheological behavior. Moisture sorghum was adjusted to 11, 15, and 20% before popped. Morphology, X-ray pattern (XRP), infrared spectra (IR), thermal properties, and rheological behavior before and after popping were evaluated. Micrographs showed a honeycomb-like structure in PS. XRP showed partial damage to the orthorhombic crystals of the sorghum starch after PS, while the growth of crystalline lamellae was also generated (13.08 and 20.01°). IR showed structural damage as the signal at 1045 cm−1 disappeared in PS. The IM increased to gelatinization of the starch. The rheological behavior of PS displayed better thermal stability, with the lowest breakdown (25 ± 3.5 cP), setback (253 ± 11.3 cP), and final (1337 ± 5.7 cP) viscosity. The consistency coefficient k and flow behavior index n increase, meaning a loss of the pseudoplastic character. Viscoelastic properties increased in PS, suggesting the formation of cross-links and a stable matrix. Correlation analysis showed a strong relationship between structural changes and the rheological behavior of PS., Author A. H. Cabrera-Ramírez was supported by a scholarship from the CONACYT-Mexico, grant number: 734975. This work was supported by Instituto Politécnico Nacional, grant numbers SIP-20196083, SIP-20200568.

The popping process has been widely used as a technique for obtaining snacks. This study evaluated the effect of the popping process on the structural and thermal properties of sorghum. Seven varieties of sorghum were used. Raw sorghum grains were adjusted to 11% moisture and popped at 210 °C for 90 s with hot air. Microstructure, thermal and viscosity properties, and X-Ray and infrared spectrum were measured in raw and popped sorghum. The popping process produced an ordered honeycomb-like structure in the sorghum. The viscosity profile showed an increase in the thermal stability of popped sorghum. DSC measurements showed a starch gelatinization and a second transition about to 145 °C. XRD diffractograms display a reduction in the amplitude of the crystalline orthorhombic structure peaks. Finally, infrared indicated a change in the short-range structure and protein denaturation due to the popping process., Authors F.G. Castro-Campos and A.H. Cabrera-Ramírez thanks the “Consejo Nacional de Ciencia y Tecnología” (CONACYT-Mexico) for the financial support of their post-graduate position [Grant numbers: 712859 and 734975, respectively]. This research was supported by the FOPER-2018 and 2019 of the Universidad Autónoma de Querétaro.

The aim of this study was to evaluate the effect of acid hydrolysis and succination upon single and a combination of both of them as a dual modification on the morphological, structural, thermal, and pasting profile of the achira starch in order to expand its potential food applications. The surface of achira starch granules was eroded with acid hydrolysis, while the succination resulted in the formation of pores or cavities, having a slight impact on the crystallinity and the gelatinization enthalpy. Succinated starch presented the lowest transition temperatures (To = 60.29 °C, Tp = 65.03 °C and Te = 69.86 °C) compared to other starches in this study. The succination increased the final viscosity (3808 cp) when compared with the native starch (3114 cp), while acid hydrolysis resulted in a decreased value (735 cp). These are desirable properties for its possible use as an additive in bakery industry processes.

The nutritional, cooking and technological properties of the Tepary bean (TB) cultivated in Mexican northeast comparing to two common beans varieties (Pinto Americano and Black Jamapa) were evaluated in this study. Nutritional parameters evaluated of TB resulted significantly different from common beans varieties analysed, except lipid fraction. Cooking times of soaked (4 and 8 h) and non-soaked varieties varied significantly; TB shows between 55.1–80.49 min by cooking time. The textural profile analysis (TPA) of TB showed a significant reduction of hardness, chewiness and adhesiveness in soaked compared to non-soaked. In addition, TB presented a similar behaviour to Pinto Americano in TPA non-soaked and cooked and soaked 8h and cooked, except to adhesiveness. Technological properties of TB and resistant and non-resistant starch content showed significant differences between species. Due to, TB has nutritional, cooking and technological properties comparable to other edible legumes as common bean, mainly Pinto Americano variety.

Commercially, crab meat is obtained by hand-picking after a cooking process, followed by pasteurizing or canning. Jumbo lump is one of the pieces of meat obtained from the blue crab. The aim of this study was to evaluate the effect of the commercial cooking process (boiling and steaming) on the mechanical and functional properties of whole jumbo lump and the gels obtained from cooked and minced jumbo lump from blue crab (Callinectes sapidus). The gels were prepared combining the washing process and microbial transglutaminase. The boiling and steaming processes showed a different effect on the textural and color properties. Whole jumbo lump pieces cooked by immersion in boiling water showed a higher hardness value as compared to steamed jumbo lump pieces, suggesting a different internal structural. The cooking processes used in this study did not modify the water holding capacity, gelling capability, or color of the minced jumbo lump. The addition of microbial transglutaminase to washed minced jumb...

Current consumer trends emphasize the need for designing ready-to-use food that besides convenience render health benefits, including low calorie content and higher amounts of protein, fibers and antioxidants. The aim of this research was to assess the acceptance as well as the nutritional and bioactive compounds content of a snack bar elaborated with common bean and oat flour. A mixture design was used to generate 27 different combinations of ingredients that were evaluated in a ranking test to select the most preferred formulations. Protein, total flavonoids and antioxidant capacity were significantly higher (p

In this study, achira (Canna edulis) starch (AS), a non-conventional starch, was hydrolyzed using hydrochloric acid (7.5%) from 3 to 15 days to investigate the effect of long term acid hydrolysis on the evolution of the crystalline and double-helical structure changes, and its repercussion on the functionality. After 15 days, the degree of hydrolysis was 40.3 ± 0.8%. Micrographs revealed the granular structure loss after 6 days of hydrolysis. Acid hydrolysis decreased the crystallinity from 36.6 to 21.1% after 3 days but it increased to 27.0% after 15 days, while the degree of double helix and degree of order decreased after the acid treatment. Structural degradation of AS induced by the acid hydrolysis was reflected in the significant reduction of the enthalpy change of gelatinization and swelling, and the significant increase of the water solubility and water holding capacity, reaching maximum values at 9 (52.6 ± 1.0%) and 15 (266.4 ± 0.4%) days, respectively. Through the appropriate modification of the crystalline and double-helical structure by acid hydrolysis, the AS functionality can be regulated by adjusting the hydrolysis time, expanding the use of AS in the food industry.

Blending native starches is a feasible alternative for modifying the functional properties of starch dispersions. Granular interactions between starches lead to desirable properties that can be used for specific applications. Starch blends from amaranth (AmS) and achira (AS) were prepared at different proportions, and the pasting properties, flow curves and low-shear dynamic rheology were evaluated at 5, 7.5 and 10 g/100 g of solids. Granular interactions between starches were promoted when the solid content increased, affecting the formation of pasta. A polynomial model was used to predict the viscosity of the starch blends. The mechanical spectra showed that G′ and G″ had a slight dependence on the frequency. The incorporation of granules of AmS improved the stability of AS gels. Blending AmS and AS modified the rheological properties compared to pastes obtained from pure starches, mainly due to the concentration, size and granule interactions, resulting in low stability of the gels formed.

Sorghum, a competitive crop due to its agronomical advantages, has gained interest as functional food. Sorghum contains phytochemicals with health benefits and presents some antinutritional compounds such as condensed tannins (CTs). However, it is well known that CTs exhibit antioxidant capacity. This study evaluated the effect of Mexican nixtamalization on total phenols, CTs and antioxidant capacity using two varieties of sorghum. Different conditions of lime (0, 1 and 2%) and cooking time (20, 30 and 40 min) were tested to obtain the best treatment after optimization using multiple linear regression analysis, aiming to minimize the CTs content and maximize the antioxidant capacity. CTs were reduced at 27% in white sorghum and 90%, in red sorghum. Total phenols, flavonoids and antioxidant capacity had an inverse correlation with lime concentration and cooking time. The best conditions for preserving antioxidant capacity with low content of tannins were 1.13% of lime and 31.11 min cooking. The phenolic profile obtained by HPLC showed reductions in gallic and chlorogenic acids only in white sorghum, whereas catechin and quercetin decreased in both varieties. We concluded that nixtamalization effectively reduced CTs to safety intake values, allowing to preserve other phenolic compounds and antioxidant capacity.

Extrusion was used for obtaining corn masa. Particle size, Ca(OH)2 concentration, and tempering time had significant effects on the viscosity of extruded flours. Ground corn tempered for different periods of time (0.016–10 h) increased viscosity without application of heat. This behavior can be explained by the release of starches from the protein matrix. Viscoelastic properties of masas showed storage modulus (G′) > loss modulus (G″) for all samples. G′ and G″ increased as a function of tempering time, indicating higher water absorption capacity (WAC). The same behavior was found for Ca(OH)2 concentration, suggesting formation of cross-links between starch and polymers. Viscosity of masas modeled by the power law showed a value of n close to 0.1, suggesting that the dispersed solid phase was greater than the liquid phase. Index n and consistency coefficient K were associated with water absorption and viscosity, respectively. Regarding Ca(OH)2, the higher the Ca(OH)2 concentration, the lower the index n; ...

Two maize starches (Normal and Hylon VII) were hydrolyzed using HCL for 15 days at room temperature. The water holding capacity -WHC and oil holding capacity- OHC were evaluated to describe the changes during the reorganization of hydrolyzed material. The structure was assessed using differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR). A hydrolysis degree of 20% was reached with a complete granular structure disruption. During acid hydrolysis, the rearrangement of decoupled double helices favored the order degree. The hydrolysis of the amorphous region decreased the enthalpy of gelatinization. This effect was more noticeable in the normal starch. The changes promoted during the hydrolysis favored the reorganization of the network resulting in high values in WHC and OHC for both starches. The acid-treated starches obtained could be used as fillers, employing these materials with induced crystalline regions.

Ohmic heating (OH) is an emerging technology with potential for pasteurization and enzyme inactivation in mango pulp. This research aimed to investigate the effect of OH and conventional boiling treatment (CT) at moderate pasteurization conditions (72 °C, 2 min) on the physicochemical characteristics and the polyphenol oxidase (PPO) residual activity in Ataulfo mango pulp. Pulp's physical features, such as titratable acidity (TA) and pH did not show differences (p > 0.05) between treatments, whereas OH increased the apparent viscosity of mango pulp (10.26–15.64%). This effect was associated to a higher release of insoluble fiber. Both thermal treatments affected the color (ΔE values > 5) of mango pulp. PPO inactivation reached 95.7 ± 5.9% after 15 s with both thermal treatments. In silico molecular dynamics suggested that temperature and pH contributed to the PPO inactivation by inducing modifications in its catalytic site and altering the protein-substrate interaction. Our results indicate that OH is an effective technology to inactivate PPO at moderate pasteurization conditions (72 °C, 15 s), with minimal modifications on the physicochemical properties of Ataulfo mango pulp.

Normal and high amylose corn starches were modified using HMDSO plasma at different time treatments. Changes in functional properties of starch granule, film-forming solutions (FFS) and films were investigated. SEM analysis revealed HMDSO coating deposition on the granule surface, which limited the amylopectin leach out from the granules to the continuous matrix, affecting the rheological properties of the FFS. The amylopectin restriction resulted in a low reinforcement of the network decreasing the viscosity as indicated by n and k values. Also, a gel-like behavior (G′ > G″) was observed when the amylose and time treatment increased, suggesting that the matrix becomes less elastic with softer entanglement. This behavior was confirmed by creep test and Burger model parameters. The plasma treatments allowed obtaining FFS with low viscosity, suitable for developing soft and hydrophobic films with low flexibility, as indicated by the decrease of the maximum stress, Hencky strain and permeance values.

The quality of extruded snacks can be affected not only by processing conditions, but also by some factors like the concentration and type of ingredients incorporated in their formulation and the working conditions used. Although the process conditions have been established with measurable textural properties, sensory qualities have not been correlated with these responses in expanded extruded snacks made with added functional ingredients. Therefore, in this study the effect of adding textured soy flour (TSF) and whole wheat flour (WWF) to refined wheat flour in the production of extruded snacks and expanded with hot air was evaluated. A response surface design using two levels with five central points was applied to obtain the best combinations of functional ingredients added, holding the parameters of the extrusion process and moisture of treatments. Some texture characteristics and sensory analysis were used as response variables, such as, hardness, fracturability, toughness, crispness, granularity, and chewiness. Likewise, the rate of expansion was evaluated. The results showed that the level of substitution of WWF, especially levels of 15%, had a significant effect on the hardness perceived by the panelist during sensory evaluation. The TSF at concentrations of ≥15%, favored the fracturability and crispness of the samples. It was found that the best expansion index was with the combination of 5% TSF and 15% WWF. Although a correlation between instrumental and sensory tests carried out on the extruded snacks expanded was not found. Practical applications The physical characteristics of the extruded snacks such as expansion, hardness, and density are important parameters in terms of consumer acceptability of the final product as well as their functional properties. In other words, the appearance and texture are two of the most important attributes that can be seen in snack foods. In particular, the texture can be measured by intrinsic tests: objective (instrumental) and subjective (sensory). That is because the instrumental analysis provides parameters such as firmness, brittleness, consistency, chewiness, among others, when subjected to different stress, strain, and strain rates at the snacks. Similarly, sensory analysis, allows us to see features that include mechanical attributes (concerning the reaction to the applied force), geometric attributes (concerning the shape, size, and orientation of the particles within the food), and attributes related to the perception of moisture or fat content.

In this study, the resistant starch (RS) formation, crystallinity, and double helical order of autoclaved (120 °C) normal (ANS) and high amylose (AHS) corn starches retrograded at ~4–26% of water content were investigated. ANS and AHS retrograded at ~25–26% of water content were more crystalline (~35–40%) and formed by more close-packed double helices (R1000/1022 cm−1 = 1.145–1.290). The highest content of RS (38.8%) was found in AHS retrograded at 25.52% of water content meanwhile in ANS, the maximum content of RS was 6.6% at 21.60% of water content despite its structural order was increased with the increase of water content. The recrystallization of amylopectin interfered with the formation of homogeneous crystalline structures of amylose preventing the formation of retrograded RS in ANS, while in AHS, a relationship between structure and RS formation was observed, suggesting that the close-packed double helices and the proportion of homogeneous amylose crystallites increased the resistance to enzymatic digestion.

Functional modifications of starch, such as paste properties, retrogradation, water absorption indexes, solubility, and swelling capacity, are induced by the amylose-lipid complex. This research comprehends the study of functional properties of extruded maize starch mixed with fatty acids (stearic acid, oleic acid, and maize oil) and the formation of amylose-lipid complexes. Maize starch with lipids (5 or 10 %), moisture (35 %) was extruded (single screw). Starch granule was modified by extrusion, to a lesser extent at 10 % of lipids, especially stearic acid, which covers starch granule surface. Viscosity decreased meaningfully with stearic acid addition. DSC showed both starch gelatinization enthalpy and amylose-lipid complex enthalpy for stearic or oleic acid, but it was just the first enthalpy for maize oil. X-ray diffraction showed orthorhombic crystals with or without the presence of lipids. Our results indicated that stearic acid yielded the highest amount of amylose-lipid complexes.

Popcorn is a healthy snack suggested by nutritionists. However, some countries in Europe, Asia, and South America have evaluated the use of sorghum as a popped cereal. Therefore, this study aims to evaluate the content of corneous and floury endosperm of sorghum and its influence in the popped sorghum quality. Five red varieties and three white varieties were evaluated. The physical and microstructural characteristics of the raw varieties were evaluated. The correlation matrix showed that physical properties such as the pericarp thickness, the hectoliter weight, and the type of endosperm are crucial to obtain popped sorghum. A high percentage of corneous endosperm and the size distribution of starch granules in the floury endosperm determine the popping ability of sorghum. The analysis of the principal components showed that the Paloma variety was the most suitable to obtain popped sorghum.

In this study, the effect of amylose content and cold plasma treatment on starch films properties was investigated. Films from normal (30%) and high amylose (50 and 70%) starches were subjected to hexamethyldisiloxane (HMDSO) cold plasma treatment. Morphological, structural, mechanical and barrier properties of the films were evaluated. The amount of remnant starch granules (RSG) in the films depended on the amylose content and on the gelatinization extent of the starch. This behavior was corroborated on the films from starch with 50% amylose, where the loss of RSG resulted in poor barrier properties and high hydrophilicity. Moreover, HMDSO cold plasma treatment incorporated methyl groups improving the hydrophobic properties and favored the helix ordering of the starch components resulting in a limited water-film interaction. Furthermore, the simultaneous effect of HMDSO coating and the ordering of the structures reinforced the surface of the films, improving the mechanical properties.