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Abstract Mantle xenoliths usually represent fragments derived from the depleted and degassed lithospheric mantle with 3He/4He isotope ratios (6 ± 1 RA) lower than those of mid-ocean ridge basalts (8 ± 1 RA). Otherwise, basalts from oceanic islands related to hotspots often have high 3He/4He ratios (>10 RA), suggesting a deep and pristine undegassed mantle source. Here we present a striking high-3He/4He component (up to 27.68 RA) recorded by spinel-facies mantle xenoliths from Patagonia. Remarkably, the highest ratios were found in a long-lived trans-lithospheric suture zone related to the Carboniferous-Permian collision of two continental blocks: the Deseado and the North Patagonian massifs. The mantle xenoliths with notably high-3He/4He ratios are inferred to be fragments of the shallow asthenosphere rising through the eroded and rejuvenated thin lithosphere. The pristine helium component is derived from the western margin of the Karoo mantle plume, related to the initial stages of the Gondwana fragmentation.

Abstract The lithium cycling in the supra-subduction mantle wedge is crucial for understanding the generation of Li-rich magmas that may potentially source ore deposition in continental arcs. Here, we look from the mantle source perspective at the geological processes controlling the Li mobility in convergent margins, by characterizing a set of sub-arc mantle xenoliths from the southern Andes (Coyhaique, western Patagonia). The mineral trace element signatures and oxygen fugacity estimates (FMQ > + 3) in some of these peridotite xenoliths record the interaction with arc magmas enriched in fluid-mobile elements originally scavenged by slab dehydration. This subduction-related metasomatism was poorly effective on enhancing the Li inventory of the sub-arc lithospheric mantle, underpinning the inefficiency of slab-derived fluids on mobilizing Li through the mantle wedge. However, major and trace element compositions of mantle minerals in other xenoliths also record transient thermal and chemical anomalies associated with the percolation of slab window-related magmas, which exhibit an “adakite”-type geochemical fingerprint inherited by slab-derived melts produced during ridge subduction and slab window opening event. As these melts percolated through the shallow (7.2–16.8 kbar) and hot (952–1054 °C) lithospheric mantle wedge, they promoted the crystallization of metasomatic clinopyroxene having exceptionally high Li abundances (6–15 ppm). Numerical modeling shows that low degrees (

Constructed wetlands are standard conservation practices used to reduce nitrate loads in agricultural watersheds. Many studies have examined the efficiency of denitrification in wetlands under various scenarios, but quantifying the watershed-scale impact of wetlands on downstream nitrate levels is rarely done using field observations. In this study, we estimated nitrate removal in a constructed wetland in the headwaters of Mud Creek, a HUC12 watershed in eastern Iowa, from May–September 2022 and May–September 2023 (a ten-month period). We also measured nitrate loads at four successive downstream sites, three along Mud Creek and one below its confluence with the larger Cedar River. The wetland removed 6,200 kg of nitrate (74% of total inputs). At the three downstream locations in Mud Creek, the percentage of each site’s total nitrate load removed by the wetland decreased to 19, 8.6, and 4.1%—this latter value represents the wetland’s influence on nitrate removal in the entire Mud Creek basin. The wetland’s impact of nitrate loads in the Cedar River was negligible (reduction of 0.02%). The percentage of a site’s drainage area treated by the wetland approximately followed a 1:1 relationship to that site’s percent reduction in nitrate. Profiles of nitrate concentrations in Mud Creek notably varied pre- and post-wetland. Concentrations before the installation steadily decreased along the waterway, while post-wetland concentrations rapidly decreased directly downstream of the wetland and steadily increased at each succeeding site. Our results demonstrate that while the wetland successfully lowered local nitrate levels, its effect on the basin’s overall nitrate loads was minimal. Achieving nutrient reduction goals at the watershed scale solely using constructed wetlands appears infeasible given that the required number of practices greatly exceeds current efforts.

Phosphorus (P) is a widespread waterborne pollutant that impairs many waterbodies. However, it is challenging to measure directly, and much research has been dedicated to developing surrogacy models that can repeatedly predict its concentration. Optimal approaches for modeling strategies are often unclear and depend upon local P dynamics and the availability of financial and technical resources. This study presents a schema for developing P surrogacy models at a statewide scale (16 major rivers in Iowa, USA). Specifically, we examined the relationship between particulate phosphorus (Part P) and orthophosphate (OP) and explored the viability of eight potential surrogates in predicting their concentrations using multiple linear regression and power regression methods. We also investigated similarities between surrogate models for Part P and total suspended solids (TSS). At all sites, OP and Part P were not strongly correlated (mean R = 0.20 ± 0.17). Many instances were observed where samples had high concentrations of one form but not the other. Modeling results demonstrated that turbidity was consistently the best predictor (t-statistics >10) of Part P, and adding other surrogates alongside turbidity did little to improve model performance. No surrogates proved useful in estimating OP. Viable power regression models were created using turbidity to predict Part P (mean R2 = 0.69 ± 0.12). These models had a nonlinear form where Part P concentrations leveled off as waters became exceptionally turbid. This contrasted with TSS, which maintained a strong linear relationship across all turbidity levels. Turbidity-based models show promise in quantifying statewide P levels, as they enable high-resolution and real-time Part P estimates.

Although grass waterways are an effective conservation practice to reduce soil erosion, less is known about their subsurface hydrogeology. New research is highlighting the potential for NO3-N load reductions in waterways, but studies have not been done to characterize regional patterns. In this study, we used field investigation and numerical modeling to evaluate subsurface hydrogeological conditions beneath grass waterways found in major landform regions of Iowa. Our goal was to identify waterways that could be best utilized in a new conservation practice aimed at reducing tile NO3-N export from cropped fields. Waterway stratigraphy consisted of a layer of fine-textured, nutrient-rich sediment overlying glacial or post-glacial parent material. The mean hydraulic conductivity (K) of the alluvial sediments reflected a dominantly silty matrix and it was highest in northeast Iowa where sand contents were higher. Groundwater was largely anaerobic in lowland waterway areas, where high water tables contributed to low dissolved oxygen and NO3-N concentrations in shallow groundwater. Numerical modeling parameterized using the field data showed that in terms of annual water balance, more water is exported from grass waterways in surface runoff compared to subsurface tile and groundwater flow. In terms of subsurface flow, tile water yields were higher in smaller and steeper catchments and when the K of the waterway alluvium was higher. Based on regional patterns of sedimentology and landscape topography, smaller and steeper catchments within a landform region found in NE Iowa may be most appropriate to test a new conservation practice aimed to capture and remediate tile NO3-N export from grass waterways.

Continued large-scale public investment in declining ecosystems depends on demonstrations of “success”. While the public conception of “success” often focuses on restoration to a pre-disturbance condition, the scientific community is more likely to measure success in terms of improved ecosystem health. Using a combination of literature review, workshops and expert solicitation we propose a generalized framework to improve ecosystem health in highly altered river basins by reducing ecosystem stressors, enhancing ecosystem processes and increasing ecosystem resilience. We illustrate the use of this framework in the Mississippi-Atchafalaya River Basin (MARB) of the central United States (U.S.), by (i) identifying key stressors related to human activities, and (ii) creating a conceptual ecosystem model relating those stressors to effects on ecosystem structure and processes. As a result of our analysis, we identify a set of landscape-level indicators of ecosystem health, emphasizing leading indicators of stressor removal (e.g., reduced anthropogenic nutrient inputs), increased ecosystem function (e.g., increased water storage in the landscape) and increased resilience (e.g., changes in the percentage of perennial vegetative cover). We suggest that by including these indicators, along with lagging indicators such as direct measurements of water quality, stakeholders will be better able to assess the effectiveness of management actions. For example, if both leading and lagging indicators show improvement over time, then management actions are on track to attain desired ecosystem condition. If, however, leading indicators are not improving or even declining, then fundamental challenges to ecosystem health remain to be addressed and failure to address these will ultimately lead to declines in lagging indicators such as water quality. Although our model and indicators are specific to the MARB, we believe that the generalized framework and the process of model and indicator development will be valuable in an array of altered river basins.

Abstract Livestock are a critical agricultural commodity in the Midwestern United States and are directly linked to row crop production. Chemical and manure nutrient application for row crop production has resulted in significant losses of nitrogen (N) and phosphorus (P) to downstream ecosystems causing environmental crises like seasonal hypoxia in the Gulf of Mexico. However, the use of cattle manure has multiple benefits over commercial fertilizer including increased soil carbon levels and improved nutrient cycling and should be considered a critical component for future agricultural production in Iowa. In this study, we evaluated influences of bedded cattle manure and commercial fertilizer on groundwater quality in a field with varying soil parent material of glacial till and colluvium in eastern Iowa. We found that soil parent material predominately influenced groundwater quality. Multiple water quality parameters including nitrate varied significantly (p

Existing surface inlets behind terraces and water and sediment control basins (WASCoBs) were replaced with alternative tile intakes (ATIs) in agricultural fields of southeast Iowa. These ATIs consisted of a buried column of gravel atop woodchips. Computational, experimental, and field methods were used to design and evaluate the ATIs’ capacity to reduce sediment and nutrient export. Single-storm simulations using the Watershed Erosion Prediction Project (WEPP) provided boundary conditions for permeameter experiments that yielded a hydraulic conductivity for the layered gravel–woodchip configuration of 4.59 cm/s ± 0.36 cm/s. Additionally, a proportional amount of sediment was retained in the permeameter (42%) compared to the amount that settled on the permeameter surface (58%). Event monitoring of field-installed ATIs during three growing seasons measured a sediment trapping efficiency of 86 ± 12% that led to deposition rates of 5.44 ± 3.77 cm/yr, quantified with 210Pb profiles. Percent reduction values were 43% for nitrate and 17% for ortho-phosphate. Finally, long-term continuous-storm modeling using the WEPP suggested that these ATIs could withstand at least 75 25-year events before clogging. Modeling using the Agricultural Conservation Planning Framework suggested watershed-scale load reductions of 1.6% for NO3 and 1.4% for total P for ATIs draining 6.8% of the modeled watershed. Using ATIs in conjunction with WASCOBs and terraces, or as standalone practices, can be a cost-effective means for keeping sediment and nutrients in the landscape.

Streambank erosion is a major contributor to watershed suspended sediments and phosphorus exports in many regions, but in Iowa and other midwestern states, the load contribution from streambanks is not considered by state nutrient reduction strategies. The study’s objectives were to evaluate the annual bank erosion rates measured in Iowa using erosion pins and aerial imagery and assess how recession rates vary across space, time, and stream order. The overall goal was to determine whether there are global similarities to these streambank recession rates that could be generalized and scaled up for regional assessments using data from Iowa-based erosion pin studies and original research on stream migration rates. At the erosion pin sites, the recession rates averaged approximately 11 cm yr−1 in third-order streams and, when combined with stream migration analyses, we observed scaling associated with bank recession rates at longer time scales across a range of stream orders. More bank recession occurs in larger streams and rivers with greater discharge from larger watershed areas and an increase in stream power. Variations in these bank recession rates were observed in Iowa landform regions mainly due to differences in geology and the composition of the streambank sediments. The study’s results provide a temporal and spatial context for evaluating streambank recession in Iowa and the glaciated Midwest.

Risks from flooding and poor water quality are evident at a range of spatial scales and climate change will exacerbate these risks in the future. Natural infrastructure (NI), consisting of structural or perennial vegetation, measures that provide multiple ecosystem benefits have the potential to reduce flood and water quality risks. In this study, we intersected watershed-scale risks to flooding and nitrate export in the Mississippi-Atchafalaya River Basin (MARB) of the central U.S. with potential locations of seven NI practices (row crop conversion, water, and sediment control basins, depressional wetlands, nitrate-removal wetlands, riparian buffers, and floodplain levees and row crop change) to prioritize where NI can be most effective for combined risk reduction at watershed scales. Spatial data from a variety of publicly-available databases were analyzed at a 10 m grid cell to locate NI practices using a geographic information system (GIS). NI practices were presented at the regional basin scale and local Iowa-Cedar watershed in eastern Iowa to show individual practice locations. A prioritization scheme was developed to show the optimal watersheds for deploying NI practices to minimize flooding and water quality risks in the MARB. Among the 84 HUC4 basins in the MARB, 28 are located in the Upper Mississippi and Ohio Rivers basins. The Wabash and Iowa-Cedar basins (HUCs 0512 and 0708, respectively) within these basins were found to rank among the uppermost quintile for nearly all practices evaluated, indicating widespread opportunities for NI implementation. Study results are a launching point from which to improve the connections between watershed scale risks and the potential use of NI practices to reduce these risks.

Abstract Excessive nutrient loss threatens local and regional water resources, and many midwestern U.S. states are adopting nutrient reduction strategies to reduce export of N and P. A common practice to reduce N loss is improved fertilizer management. In this study, we used a strip trial design to assess the effects of split N application form (urea and urea ammonium nitrate [UAN]) and placement method (broadcast, coulter, Y‐drop) on corn (Zea mays L.) yields and shallow groundwater quality at an agricultural field at Kirkwood Community College in Cedar Rapids, IA. Twelve shallow monitoring wells were installed within the production field and sampled 14 times across a corn–soybean [Glycine max (L.) Merr.] rotation. Results showed that split application of UAN applied with either coulter injection or Y‐drop method produced approximately 8–11% higher corn yields than broadcast urea, but no statistically significant relation was found between groundwater quality and N form and placement method. Instead, we report that groundwater quality and levels were significantly influenced by variations in aquifer lithology. Groundwater within fine‐textured glacial till had significantly higher dissolved reactive P, SO4, and specific conductivity, whereas groundwater within the sand aquifer had a deeper water table and had higher NO3–N and dissolved oxygen. Study results suggest aquifer lithology can play a much larger role than varying the N form and application method on shallow groundwater quality in agricultural fields.

Huanul is a shield volcano with several lava flows hosting mantle xenoliths erupted during the Pleistocene (0.84 ± 0.05 Ma). It is located in the southern part of the Payenia Volcanic Province, which is among the largest Neogene-Quaternary volcanic provinces of South America. The volcanism here has been ascribed as the northernmost expression of the back-arc volcanism of the Andean Southern Volcanic Zone. We present the first petrographic and mineral chemistry study of mantle xenoliths collected from Huanul lavas with the aim of reconstructing directly the mantle source of the Payenia Volcanic Province. Xenoliths are commonly small (2 geotherm. Evidences of interaction with the host basalts occur as spongy textures in clinopyroxene and reacted spinel, which tend to became more restitic in composition and show chromatographic or complete overprinting of the trace element compositions. The presence of plagioclase and calculated P-T values constrain this melt/rock reaction process between 6 and 14 kbar, during magma ascent, and fit the mantle adiabat model. Calculated melts in equilibrium with the primary clinopyroxenes do not fit the composition of the host basalt and, together with the geothermobarometric estimations, point to an asthenospheric mantle source for the magmatism in southern Payenia. The PM geochemical affinity of the xenoliths of Huanul is an extremely rare finding in the South America lithospheric mantle, which is commonly extensively refertilized by subduction-derived melts.

The oxidation state of the Earth’s mantle and its partial melting products exert a key control on the behavior and distribution of sulfur and chalcophile and siderophile elements between the mantle and crust, underpinning models of ore deposit formation. Whether the oxidized nature of magmas is inherited from the asthenospheric mantle source or acquired during ascent and differentiation is vigorously debated, limiting our understanding of the mechanisms of extraction of sulfur and metals from the mantle. Here, we focused on the redox-sensitive behavior of sulfur in apatite crystallized from quenched alkaline basaltic melts preserved within a peridotite xenolith from the El Deseado Massif auriferous province in southern Patagonia. We took advantage of this unique setting to elucidate the redox evolution of melts during their ascent through the subcontinental lithospheric mantle (SCLM) and grasp the inner workings of the Earth’s mantle during gold metallogenesis. Our data reveal that an initially reduced silicate melt (ΔFMQ −2.2 to −1.2) was oxidized to ΔFMQ between 0 and 1.2 during percolation and interaction with the surrounding peridotite wall-rock (ΔFMQ 0 to +0.8). This process triggered changes in sulfur speciation and solubility in the silicate melt, boosting the potential of the melt to scavenge ore metals such as gold. We suggest that large redox gradients resulting from the interaction between ascending melts and the surrounding mantle can potentially modify the oxidation state of primitive melts and enhance their metallogenic fertility. Among other factors including an enriched metal source and favorable geodynamic conditions, redox gradients in the mantle may exert a first-order control on the global-scale localization of crustal provinces endowed with gold deposits.

Pityopsis includes several regionally and one federally endangered species of herbaceous perennials. Four species are highly localized, including the federally endangered P. ruthii. The genus includes several ploidy levels and interesting ecological traits such as drought tolerance and fire-dependent flowering. Results from previous cladistic analyses of morphology and from initial DNA sequence studies did not agree with one another or with the infrageneric taxonomic classification, with the result that infrageneric relationships remain unresolved. We sequenced, assembled, and compared the chloroplast (cp) genomes of 12 species or varieties of Pityopsis to better understand generic evolution. A reference cp genome 152,569 bp in length was assembled de novo from P. falcata. Reads from other sampled species were then aligned to the P. falcata reference and individual chloroplast genomes were assembled for each, with manual gapfilling and polishing. After removing the duplicated second inverted region, a multiple sequence alignment of the cp genomes was used to construct a maximum likelihood (ML) phylogeny for the twelve cp genomes. Additionally, we constructed a ML phylogeny from the nuclear ribosomal repeat region after mapping reads to the Helianthus annuus region. The chloroplast phylogeny supported two clades. Previously proposed clades and taxonomic sections within the genus were largely unsupported by both nuclear and chloroplast phylogenies. Our results provide tools for exploring hybridity and examining the physiological and genetic basis for drought tolerance and fire-dependent flowering. This study will inform breeding and conservation practices, and general knowledge of evolutionary history, hybridization, and speciation within Pityopsis.

Currently, in the USA and especially in the Midwest region, urban expansion is developing turfgrass landscapes surrounding commercial sites, homes, and recreational areas on soils that have been agriculturally managed for decades. Often, golf courses are at the forefront of conversations concerning anthropogenic environmental impacts as they account for some of the most intensively managed soils in the world. Iowa golf courses provide an ideal location to evaluate whether golf course management is affecting the quality of soils at depth. Our study evaluated how soil properties relating to soil health and resiliency varied with depth at golf courses across Iowa and interpreted relationships of these properties to current golf course management, previous land use, and inherent soil properties. Systematic variation in soil properties including sand content, NO3, and soil organic matter (SOM) were observed with depth at six Iowa golf courses among three landform regions. Variability in sand content was identified between the 20 and 50 cm depth classes at all courses, where sand content decreased by as much as 37 %. Highest concentrations of SOM and NO3 were found in the shallowest soils, whereas total C and P variability was not related to golf course management. Sand content and NO3 were found to be directly related to golf course management, particularly at shallow depths. The effects of golf course management dissipated with depth and deeper soil variations were primarily due to natural geologic conditions. The two abovementioned soil properties were very noticeably altered by golf course management and may directly impact crop productivity, soil health, and water quality, and while NO3 may be altered relatively quickly in soil through natural processes, particle size of the soil may not be altered without extensive mitigation. Iowa golf courses continue to be developed in areas of land use change from historically native prairies and more recently agriculture to urban landscapes. As soils are continually altered by human impacts, it is imperative that we monitor the changes, both physical and chemical, in order to establish management practices that maintain environmental sustainability and productivity.

The lithospheric controls on giant gold deposits remain unclear. Here, the authors show evidence for native gold in the mantle from the Deseado Massif in Patagonia demonstrating that refertilisation of the lithospheric mantle is key in forming metallogenic provinces.

Study region: The study was focused on total phosphorus (TP) concentrations measured in rivers in Iowa, a Midwestern state located in the central United States. Study focus: Accurate measurement of TP concentrations in rivers is needed to quantify loads and evaluate the progress of nutrient reduction strategies. We evaluated the relation of water quality surrogates, turbidity, orthophosphorus (OP), chlorophyll a, chloride and discharge to TP concentrations at 43 different river monitoring sites over a 15-year period. New hydrological insights for the region: TP concentrations were highly correlated to turbidity (0.78 ± 0.20) and OP (0.69 ± 0.13) across all sites and less correlated to chlorophyll a (0.07 ± 0.15), chloride (−0.10 ± 0.24) and discharge (0.41 ± 0.23). When the regression models included OP as a variable, the mean r2 for all 43 sites was 0.90 ± 0.08 and ten of the 43 sites had r2 values greater than 0.95. When OP was excluded in the regression model, the overall mean r2 values decreased to 0.72 ± 0.14 and for six of the river sites, the r2 value decreased by 50%. Other variables (discharge, chlorophyll a, chloride) were included in the regression equations on a case-by-case basis. Including OP in the regression models was critically important for rivers draining the tile-drained Des Moines Lobe region.

In intensively managed landscapes, interactions between surface (tillage) and subsurface (tile drainage) management with prevailing climate/weather alter landscape characteristics, transport pathways, and transformation rates of surface/subsurface water, soil/sediment, and particulate/dissolved nutrients. To capture the high spatial and temporal variability of constituent transport and residence times in the critical zone (between the bedrock and canopy) of these altered landscapes, both storm event and continuous measurements are needed. The Intensively Managed Landscapes Critical Zone Observatory (IML-CZO) is comprised of three highly characterized, well instrumented, and representative watersheds (i.e., Clear Creek, Iowa; Upper Sangamon River, Illinois; and Minnesota River, Minnesota). It is organized to quantify the heterogeneity in structure and dynamic response of critical zone processes to human activities in the context of the glacial and management (anthropogenic) legacies. Observations of water, sediment, and nutrients are made at nested points of the landscape in the vertical and lateral directions during and between storm events (i.e., continuously). The measurements and corresponding observational strategy are organized as follows. First, reference measurements from surface soil and deep core extractions, geophysical surveys, lidar, and hyperspectral data, which are common across all Critical Zone Observatories, are available. The reference measurements include continuous quantification of energy, water, solutes, and sediment fluxes. The reference measurements are complemented with event-based measurements unique to IML-CZO. These measurements include water table fluctuations, enrichment ratios, and roughness as well as bank erosion, hysteresis, sediment sources, and lake/floodplain sedimentation. The coupling of reference and event-based measurements support testing of the central hypothesis (i.e., system shifts from transformer to transporter in IML-CZO due to the interplay between management and weather/climate). Data collected since 2014 are available through a data repository and through the Geodashboard interface, which can be used for process-based model simulations.

Stemming the export of agricultural contaminants such as nitrogen, phosphorus, sediment, and bacteria in rivers is needed to improve water quality in agricultural regions. However, patterns and trends of these co-occurring agricultural contaminants are relatively unexplored owing to the lack of long-term and high-frequency data sets needed to capture their fluctuations over different time scales. Using a dataset measured at the Raccoon River in west-central Iowa for more than 17 years, spectral analyses were used to characterize the variability and temporal scaling of co-occurring nutrients, sediment, and bacteria in long-term monitoring data in a water-supply river draining a highly agricultural watershed. Results showed that scaling exponents of pollutant concentrations gradually increased from bacteria (0.27) to sediment (0.64), chloride (1.02), orthophosphate (0.75), and nitrate (1.73). The smaller scaling exponents of bacteria and sediment indicate transport primarily by surface water runoff whereas the larger exponents of nutrients indicate transport by groundwater and subsurface tile drainage. Nitrate export exhibits a chemostatic behavior whereas the other constituents deviate from the chemostatic behavior, indicating that the agricultural watershed has a large reservoir of nitrogen relative to the other pollutants. The results are seen to provide guidance for implementation of conservation practices in agricultural watersheds by helping watershed managers more correctly match the appropriate practice to the dominant hydrologic transport pathway.

Water quality sensors deployed on boats, buoys, and fixed monitoring stations along rivers allow high frequency monitoring at dense spatial and temporal resolutions. Research characterizing nitrate (NO3−N) delivery along extended reaches of navigable rivers, however, is sparse. Since land use and stream biogeochemistry can vary within agricultural watersheds, identifying detailed spatial patterns of stream NO3−N can help identify source area contributions that can be used to develop strategies for water quality improvement. Identifying spatial patterns is especially critical in agricultural watersheds that span multiple landscapes and have dynamic hydrological regimes. We developed and tested a new method that quantifies NO3−N delivery to streams at a high spatial resolution by continuously measuring stream NO3−N using a boat-deployed sensor. Traveling up the Iowa and Cedar Rivers (located within agricultural Upper Mississippi River Basin) and their major tributaries with the system, we automatically measured NO3−N concentrations every 15 s during four excursions spanning the months of May to August, 2018, and characterized stream NO3−N both laterally and longitudinally in river flow. Iowa River NO3−N concentrations were highest nearest the headwaters and gradually declined as the river flowed toward the Mississippi River. Conversely, Cedar River NO3−N concentrations increased from the headwaters toward the mid-watershed areas due to elevated NO3−N delivery from tributaries of the Middle Cedar River; NO3−N concentrations declined in the lower reaches. Our results confirm that NO3−N mitigation efforts should focus on level and intensely-farmed subwatersheds. Data collected with our sensor system compliments permanently deployed sensors and provides an option to support NO3−N removal efforts.

Pityopsis ruthii (Ruth’s golden aster) is a federally endangered herbaceous perennial endemic to the Hiwassee and Ocoee Rivers in southeastern Tennessee, United States. Comprehensive genetic studies providing novel information to conservationists for preservation of the species are lacking. Genetic variation and gene flow were evaluated for 814 individuals from 33 discrete locations using polymorphic microsatellites: seven chloroplast and twelve nuclear. A total of 198 alleles were detected with the nuclear loci and 79 alleles with the chloroplast loci. Gene flow was estimated, with the Hiwassee River (Nm = 2.16; FST = 0.15) showing higher levels of gene flow and lower levels of population differentiation than the Ocoee River (Nm = 1.28; FST = 0.19). Population structure was examined using Bayesian cluster analyses. Nuclear and chloroplast analyses were incongruent. From the chloroplast microsatellites, three clusters were identified; all were present in sampling sites at both rivers, indicating a lack of allele fixation along rivers. Nuclear markers revealed two clusters and separated by river. When the Hiwassee River locations were analyzed, four clusters were identified for both the chloroplast and nuclear microsatellites, though the individuals clustered differently. Analysis of the Ocoee River revealed two clusters for the chloroplast microsatellites and three for the nuclear microsatellites. We recommend P. ruthii be managed as four populations for the Hiwassee River and three populations for the Ocoee River. Our results provide critical genetic information for P. ruthii that can be used for species management decisions to drive future population augmentation/reintroduction and ex situ conservation efforts.

The main objective of this work was to quantify and update the U.S. Midwest agricultural state of Iowa's contribution of nitrate-nitrogen to the Mississippi River stream network against the backdrop of the ongoing problem of Gulf of Mexico hypoxia. To achieve this objective, we used stream nitrate and discharge data collected from 1999 until 2016 at 23 Iowa stream sites near watershed outlets, along with publicly-available data for sites downstream of Iowa on the Missouri and Mississippi Rivers. Our analysis shows that Iowa contributes between 11 and 52% of the long-term nitrate load to the Mississippi-Atchafalaya Basin, 20 to 63% to the Upper Mississippi River Basin, and 20 to 89% to the Missouri River Basin, with averages of 29, 45 and 55% respectively. Since 1999, nitrate loads in the Iowa-inclusive basins have increased and these increases do not appear to be driven by changes in discharge and cropping intensity unique to Iowa. The 5-year running annual average of Iowa nitrate loading has been above the 2003 level for ten consecutive years, implying that Gulf hypoxic areal goals, also based on a 5-year running annual average, will be very difficult to achieve if nitrate retention cannot be improved in Iowa. An opportunity exists for land managers, policy makers and conservationists to manifest a positive effect on water quality by targeting and implementing nitrate reducing-practices in areas like Iowa while avoiding areas that are less likely to affect Gulf of Mexico hypoxia.

Tallgrass prairie once occupied 67.6 million hectares in the North American Midwest but less than 0.1% remains today. Consisting of more than 2200 ha, Neal Smith National Wildlife Refuge (NSNWR) was established by the US Fish and Wildlife Service in the 5217 ha Walnut Creek watershed in Jasper County, Iowa. Large tracts of land are being converted from row crop agriculture to native prairie and savanna with the goal to restore the landscape to a semblance of the condition that existed prior to Euro-American settlement. Understanding hydrologic processes at the watershed scale has been a focus of research at NSNWR for nearly two decades and the purpose of this paper is to integrate research results from monitoring projects to assess the progress made towards restoring five key hydrologic components: the water balance, stream network, streamflow hydrograph, groundwater levels and water quality. Restoration of hydrology is severely challenged by the history of hydrologic changes that occurred in the basin during a century of intensive agricultural activity. We document measurable progress in restoring key hydrologic processes in some areas, particularly in upland catchments compared to the larger watershed scale and discuss the timeframe needed to observe changes at short- and long-term scales.

Anthropogenic development of floodplains and alteration to natural hydrological regimes have resulted in extensive loss of off-channel habitat. Interest has grown in restoring these habitats as an effective conservation strategy for numerous aquatic species. This study developed a process to reproducibly identify areas of former stream meanders to assist future off-channel restoration site selections. Three watersheds in Iowa and Minnesota where off-channel restorations are currently being conducted to aid the conservation of the Topeka Shiner (Notropis topeka) were selected as the study area. Floodplain depressions were identified with LiDAR-derived digital elevation models, and their morphologic and topographic characteristics were described. Classification tree models were developed to distinguish relic streams and oxbows from other landscape features. All models demonstrated a strong ability to distinguish between target and non-target features with area under the receiver operator curve (AUC) values ≥ 0.82 and correct classification rates ≥ 0.88. Solidity, concavity, and mean height above channel metrics were among the first splits in all trees. To compensate for the noise associated with the final model designation, features were ranked by their conditional probability. The results of this study will provide conservation managers with an improved process to identify candidate restoration sites.