1. Dielectric and energy storage density studies in electrospun fiber mats of polyvinylidene fluoride (PVDF)/zinc ferrite (ZnFe2O4) multiferroic composite.
- Author
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Durga Prasad, P. and Hemalatha, J.
- Subjects
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POLYVINYLIDENE fluoride , *ENERGY storage , *ENERGY density , *DIELECTRIC polarization , *ZINC ferrites , *FIBROUS composites , *DIELECTRICS - Abstract
Flexible free standing electrospun poly (vinylidene fluoride)/ZnFe 2 O 4 composite fiber mats were synthesized through electrospinning technique. Structural and morphological studies of PVDF/ZnFe 2 O 4 composite fibers were examined by X-ray diffraction and scanning electron microscopy. The functional groups and the percentage of β phase were analysed using FTIR studies. 92% beta phase was achieved with the incorporation of ZnFe 2 O 4 filler. The enhancement in dielectric and ferroelectric properties of the composite fiber mats were observed with a maximum dielectric constant and polarization values of 15 and 0.72 μC/cm2 respectively for 20 wt% filler loading. The domain switching behaviour of the mats were analysed using DC-EFM. Vibration sample magnetometry results revealed the antiferromagnetic nature of the composite fiber mats with a maximum magnetization of 0.18 emu/cm3. Further, the energy storage density of the mats was studied and a maximum energy storage density of 239 mJ/cm3 was obtained which was 1.4 times than that of pure PVDF mat. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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