Search

Advances in the chemical and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware. Equally, the creation of novel methods of data acquisition and interpretation, including access to better reference materials, can also be crucial components enabling important breakthroughs. This biennial review highlights key advances in either instrumentation or data acquisition and treatment, which have appeared since January 2010. This review is based on the assessments by scientists prominent in each of the given analytical fields; it is not intended as an exhaustive summary, but rather provides insight from experts of the most significant advances and trends in their given field of expertise. In contrast to earlier reviews, this presentation has been formulated into a unified work, providing a single source covering a broad spectrum of geoanalytical techniques. Additionally, some themes that were not previously emphasised, in particular thermal ionisation mass spectrometry, accelerator-based methods and vibrational spectroscopy, are also presented in detail.

The Ikkattoq gneisses of the Archaean gneiss complex in the Nuuk region, southern West Greenland, are the orthogneiss component within the amphibolite facies Tre Brodre terrane. They have mostly granodioritic compositions, with a small amount of quartz diorite. Sm-Nd isotopic data for a quartz diorite and five granodiorite Ikkattoq gneiss samples from within 5 km of the Ikkattoq (fjord) type locality yielded a regression with a slope equivalent to 2005 +/- 52 Ma (MSWD = 0.72). Regardless of the low MSWD, this cannot be the true age of the Ikkattoq gneisses, because all Ikkattoq gneisses yield U-Pb zircon dates of c. 2825 Ma and they are cut by the undeformed 2560 Ma Qorqut granite complex. This anomalously young regression 'age' resulted instead from mixing of different Nd components, indicating that the Ikkattoq gneisses are derived from mixed source materials. Taking the true age of the Ikkattoq gneisses as 2825 Ma from U-Pb zircon dating, the range of initial epsilon(Nd) in the Ikkattoq gneisses is -7.1 to -1.8. The negative initial epsilon(Nd) values mean that older, light rare earth enriched, sialic crust contributed to the igneous precursors of the Ikkattoq gneisses. This Nd evidence for contribution of older sialic crust is supported by positive epsilon(Sr) values for the Ikkattoq gneisses. With epsilon(Nd) values as low as -7.1 this older crustal component has to be Eoarchaean. The presence of scarce quartz diorites (low SiO(2), high MgO) suggests that ultramafic rocks (upper mantle?), metasomatised by the passage of fluids or silicic melts, were another contributing source. The Ikkattoq gneisses are proposed as a complex suite incorporating material derived from melting of much older sialic crust and probably upper mantle. The intercalation of tectonostratigraphic terranes during collisional orogeny at c. 2720 Ma destroyed the architecture of this 2825 Ma magmatic system, and the Ikkattoq gneisses now form a slice tectonically isolated from their source reg