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Background Understanding the chemical composition of fluorescent lamp residue, particularly potentially toxic elements, is crucial for reducing environmental impacts and human health risks after disposal. However, the challenge lies in effectively analyzing these heterogeneous solid samples. Techniques involving quantitative dissolution become imperative, playing a fundamental role in quantifying trace elements. Objective The aim of this work is to develop and present a new, faster, and more efficient and environmentally friendly method using ultrasound-assisted acid extraction to quantify potentially toxic elements (Cu, Mn, Ni, Sr, and Zn) present in fluorescent lamp waste using the inductively coupled plasma-optical emission spectrometry technique. Methods An ultrasound-assisted acid extraction method for the quantification of potentially toxic elements in fluorescent lamp waste was developed and applied as a greener alternative to conventional digestion methods. For variable optimization, a full factorial design with two levels and two variables (time and temperature) was used to determine which factors significantly affected the observed response. Results The results obtained for the developed extraction method were compared with a reference method employing a heating acid digestion (with a mixture of HCl, HClO4, and HF) using statistical tools. The best results were obtained using an extraction time of 10 min and a temperature of 25°C. Inductively coupled plasma optical emission spectrometry was applied for element quantification. Conclusion The proposed extraction method showed good results for Cu, Mn, Ni, Sr, and Zn. Furthermore, the proposed method based on ultrasound radiation presents additional criteria that align with the concepts of green analytical chemistry. Highlights A greener alternative method for the determination of Cu, Mn, Ni, Sr, and Zn in fluorescent lamp waste was developed. Optimal conditions for ultrasound extraction of potentially toxic elements were achieved in 10 min at a temperature of 25°C. Environmentally friendly aspects of ultrasound align with the requirements of green analytical chemistry. [ABSTRACT FROM AUTHOR]