1. Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields
- Author
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Du, Guangle, Dean, David S., Miao, Bing, and Podgornik, Rudolf
- Subjects
Condensed Matter - Statistical Mechanics ,Condensed Matter - Soft Condensed Matter - Abstract
It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance $H$ is screened by an intervening electrolyte. Here we show how this interaction is modified when an electric field of strength $E$ is applied parallel to the dielectric boundaries, leading to a non-equilibrium steady state with a current. The presence of the field induces a long range thermal repulsive interaction, scaling just like the thermal Casimir interaction between dielectrics without the intervening electrolyte, {\em i.e.} as $1/H^3$. At small $E$ the effect is of order $E^2$ while at large fields it saturates to an $E$ independent value. We explain the results in terms of a decoupling mechanism between the charge density fluctuations of cations and anions at large applied fields., Comment: 6 pages, 2 figures
- Published
- 2024