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Acetic acid is a common pollutant for which photocatalytic degradation over titania provides a mitigating strategy. Knowledge of the bonding of acetate/acetic acid to this substrate is needed to aid interpretation of the photocatalytic data. In this work we use ambient pressure near edge X-ray absorption fine structure to measure the coverage and geometry of acetate in the TiO2(110) contact layer as well as acetic acid in an additional layer. A saturation coverage of 0.5 monolayers in both layers is found up to an acetic acid pressure of 10−1 Torr at 266 K. The geometry of acetate appears to be unchanged by adsorption of an additional layer of acetic acid, with the contact layer involving a majority acetate species bidentate bonded to neighboring Ti5c sites and a minority acetate species bonded in a perpendicular geometry. Acetic acid has a similar geometry dictated by hydrogen bonding to the contact layer as well as the substrate.

In the present study, we demonstrate that soft tissue fiber architectural maps captured using polarized spatial frequency domain imaging (pSFDI) can be utilized as an effective texture source for DIC-based planar surface strain analyses. Experimental planar biaxial mechanical studies were conducted using pericardium as the exemplar tissue, with simultaneous pSFDI measurements taken. From these measurements, the collagen fiber preferred direction [Formula: see text] was determined at the pixel level over the entire strain range using established methods ( https://doi.org/10.1007/s10439-019-02233-0 ). We then utilized these pixel-level [Formula: see text] maps as a texture source to quantify the deformation gradient tensor [Formula: see text] as a function of spatial position [Formula: see text] within the specimen at time t. Results indicted that that the pSFDI approach produced accurate deformation maps, as validated using both physical markers and conventional particle based method derived from the DIC analysis of the same specimens. We then extended the pSFDI technique to extract the fiber orientation distribution [Formula: see text] as a function of [Formula: see text] from the pSFDI intensity signal. This was accomplished by developing a calibration procedure to account for the optical behavior of the constituent fibers for the soft tissue being studied. We then demonstrated that the extracted [Formula: see text] was accurately computed in both the referential (i.e. unloaded) and deformed states. Moreover, we noted that the measured [Formula: see text] agreed well with affine kinematic deformation predictions. We also demonstrated this calibration approach could also be effectively used on electrospun biomaterials, underscoring the general utility of the approach. In a final step, using the ability to simultaneously quantify [Formula: see text] and [Formula: see text], we examined the effect of deformation and collagen structural measurements on the measurement region size. For pericardial tissues, we determined a critical length of [Formula: see text] 8 mm wherein the regional variations sufficiently dissipated. This result has immediate potential in the identification of optimal length scales for meso-scale strain measurement in soft tissues and fibrous biomaterials., (© 2022. The Author(s) under exclusive licence to Biomedical Engineering Society.)

Objective: To evaluate the impact of a registered nurse (RN)-led Medicare annual wellness visit (AWV) on preventive services in a family medicine clinic., Patients and Methods: A retrospective chart review was performed on patients who underwent an RN-led AWV and patients who underwent a standard assessment (SA) between October 2017 and October 2018. A total of 630 patients (330 AWV and 300 SA) were included in this study., Results: There were seven preventive services examined for in women and five preventive services examined for in men. Each service was used more often by patients in the AWV group than the SA group (all odds ratios ≥1.64; all P values ≤.004)., Conclusion: The RN-led AWV is an effective way to assist Medicare beneficiaries in meeting their preventive needs while allowing physicians more time to focus on chronic and acute needs.

Recent findings have extended the documentation of complex sociality to the Platyhelminthes, describing the existence of a reproductive division of labour involving a soldier caste among the parthenitae of trematode parasites. However, all species examined to date occupy high positions in trematode interspecific dominance hierarchies and belong to two closely related families, the Echinostomatidae and the Philophthalmidae (Superfamily Echinostomatoidea). Further, the two species documented as lacking soldiers also belong to the Echinostomatidae. Here, we examine four species of intermediate dominance, all belonging to the family Heterophyidae (Superfamily Opisthorchioidea): Euhaplorchis californiensis, Phocitremoides ovale, Pygidiopsoides spindalis and Stictodora hancocki, all of which infect the California horn snail, Cerithideopsis californica (=Cerithidea californica). We quantify morphology, distribution and behaviour of rediae from fully developed colonies. We also provide information on colony structure for three developing heterophyid colonies to better understand colony development. We discuss the implications of our findings, particularly with respect to how they suggest alternatives to the conclusions of other researchers concerning the nature of trematode sociality. Our analyses of morphological, distributional and behavioural patterns of developed colonies indicate that these heterophyid trematodes have a non-reproductive caste whose function is defence of the colony from invading trematodes. Hence, a soldier caste occurs for species lower in dominance hierarchies than previously known, and is present in at least two superfamilies of digenean trematodes, suggesting that selection for a soldier caste may be much more common among the Trematoda than previously recognised., (Copyright © 2016 Australian Society for Parasitology. Published by Elsevier Ltd. All rights reserved.)

Supported metal nanoparticles form the basis of heterogeneous catalysts. Above a certain nanoparticle size, it is generally assumed that adsorbates bond in an identical fashion as on a semiinfinite crystal. This assumption has allowed the database on metal single crystals accumulated over the past 40 years to be used to model heterogeneous catalysts. Using a surface science approach to CO adsorption on supported Pd nanoparticles, we show that this assumption may be flawed. Near-edge X-ray absorption fine structure measurements, isolated to one nanoparticle, show that CO bonds upright on the nanoparticle top facets as expected from single-crystal data. However, the CO lateral registry differs from the single crystal. Our calculations indicate that this is caused by the strain on the nanoparticle, induced by carpet growth across the substrate step edges. This strain also weakens the CO-metal bond, which will reduce the energy barrier for catalytic reactions, including CO oxidation.